Lateral isotopic discontinuity in the lower crust: an example from antarctica

The lower continental crust is one of the least known variables in the crust-mantle evolutionary equation. In order to study the nature and compositional heterogeneity of the lower crust, more than 20 inclusions of lower crustal granulites in volcanic rocks from the McMurdo Sound region of Antarctica were analyzed for strontium and oxygen isotopes. These inclusions were erupted from volcanic centers covering an area of 12,000 square kilometers. Along with results from analyses of major and trace elements, the isotopic data reveal a profound discontinuity in the composition and probably the age of the lower crust that coincides with the boundary between the Transantarctic Mountains and the Ross Embayment. Although this topographic boundary between East and West Antarctica is largely a Cenozoic development, which apparently reflects a simple subvertical faulting relationship due to crustal rifting, the isotopic differences in the lower crust across the boundary suggest that the current faulting and rifting may coincide with an older crustal suture, the age of which is uncertain.     

Fit between Africa and Antarctica: A Continental Drift Reconstruction

A computerized (smallest average misfit) best fit position is obtained for the juxtaposition of Africa and Antarctica in a continental drift reconstruction. An S-shaped portion of the Weddell and Princess Martha Coast regions of western East Antarctica is fitted into a similar profile along southeastern Africa. The total amount of overlap is 36,300 square kilometers, and the underlap is 23,600 square kilometers; the total mismatch is thus of 59,900 square kilometers. The congruency along the 1000-fathom isobath is remarkably good and suggests that this reconstruction is valid within the overall framework of the Gondwana supercontinent.     

Origin of the sudbury complex by meteoritic impact: neodymium isotopic evidence

Samarium-neodymium isotopic data on whole rocks and minerals of the Sudbury Complex in Canada gave an igneous crystallization age of 1840 +/- 21 x 10(6) years. The initial epsilon neodymium values for 15 whole rocks are similar to those for average upper continental crust, falling on the crustal trend of neodymium isotopic evolution as defined by shales. The rare earth element concentration patterns of Sudbury rocks are also similar to upper crustal averages. These data suggest that the Sudbury Complex formed from melts generated in the upper crust and are consistent with a meteoritic impact.     

Orbital and millennial Antarctic climate variability over the past 800,000 years

A high-resolution deuterium profile is now available along the entire European Project for Ice Coring in Antarctica Dome C ice core, extending this climate record back to marine isotope stage 20.2, approximately 800,000 years ago. Experiments performed with an atmospheric general circulation model including water isotopes support its temperature interpretation. We assessed the general correspondence between Dansgaard-Oeschger events and their smoothed Antarctic counterparts for this Dome C record, which reveals the presence of such features with similar amplitudes during previous glacial periods. We suggest that the interplay between obliquity and precession accounts for the variable intensity of interglacial periods in ice core records.     

Rubidium-strontium date of possibly 3 billion years for a granitic rock from antarctica

A single total rock sample of biotite granite from Jule Peaks, Antarctica, has been dated by the rubidium-strontium method at about 3 billion years. The juxtaposition of this sector of Antarctica with Africa in the Dietz and Sproll continental drift reconstruction results in a possible geochronologic fit of the Princess Martha Coast of Antarctica with a covered possible notheastern extension of the African Swaziland Shield, which contains granitic rocks that are also 3 billion years old.     

Isotopic composition of rare gases in lunar samples

Data from total melt and step-by-step heating experiments on the Apollo 11 lunar samples suggest a close affinity between lunar and meteoritic rare gases. Trapped neon-20/neon-22 ratios range from 11.5 to approximately 15, resembling those for the gas-rich meteorites. Trapped krypton and xenon in the lunar fines and in the carbonaceous chondrites are similar except for an interesting underabundance of the heavy isotopes in both lunar gases which suggests that the fission component found in carbonaceous chondrites is depleted in lunar material. Spallation gases are in most cases quite close to meteoritic spallation gases in isotopic composition.     

Meltwater input to the southern ocean during the last glacial maximum

Three records of oxygen isotopes in biogenic silica from deep-sea sediment cores from the Atlantic and Indian sectors of the Southern Ocean reveal the presence of isotopically depleted diatomaceous opal in sediment from the last glacial maximum. This depletion is attributed to the presence of lids of meltwater that mixed with surface water along certain trajectories in the Southern Ocean. An increase in the drainage from Antarctica or extensive northward transport of icebergs are among the main mechanisms that could have produced the increase in meltwater input to the glacial Southern Ocean. Similar isotopic trends were observed in older climatic cycles at the same cores.     

Rhenium-osmium and samarium-neodymium isotopic systematics of the stillwater complex

Isotopic data for the Stillwater Complex, Montana, which formed about 2700 Ma (million years ago), were obtained to evaluate the role of magma mixing in the formation of strategic platinum-group element (PGE) ore deposits. Neodymium and osmium isotopic data indicate that the intrusion formed from at least two geochemically distinct magmas. Ultramafic affinity (U-type) magmas had initial epsilon(Nd) of -0.8 to -3.2 and a chondritic initial (187)Os/(186)Os ratio of approximately 0.88, whereas anorthositic affinity (A-type) magmas had epsilon(Nd) of -0.7 to +1.7 and an initial (187)Os/(186)Os ratio of approximately -1.13. These data suggest that U-type magmas were derived from a lithospheric mantle source containing recycled crustal materials whereas A-type magmas originated either by crustal contamination of basaltic magmas or by partial melting of basalt in the lower crust. The Nd and Os isotopic data also suggest that Os, and probably the other PGEs in ore horizons such as the J-M Reef, was derived from A-type magmas. The Nd and Os isotopic heterogeneity observed in rocks below the J-M Reef also suggests that A-type magmas were injected into the Stillwater U-type magma chamber at several stages during the development of the Ultramafic series.     

Isotopic tracking of change in diet and habitat use in african elephants

The carbon, nitrogen, and strontium isotope compositions of elephants in Amboseli Park, Kenya, were measured to examine changes in diet and habitat use since the 1960s. Carbon isotope ratios, which reflect the photosynthetic pathway of food plants, record a shift in diet from trees and shrubs to grass. Strontium isotope ratios, which reflect the geologic age of bedrock, document the concentration of elephants within the park. The high isotopic variability produced by behavioral and ecological shifts, if it is representative of other East African elephant populations, may complicate the use of isotopes as indicators of the source region of ivory.     

A Cold Suboceanic Mantle Belt at the Earth's Equator

An exceptionally low degree of melting of the upper mantle in the equatorial part of the mid-Atlantic Ridge is indicated by the chemical composition of mantle-derived mid-ocean ridge peridotites and basalts. These data imply that mantle temperatures below the equatorial Atlantic are at least approximately 150 degrees C cooler than those below the normal mid-Atlantic Ridge, suggesting that isotherms are depressed and the mantle is downwelling in the equatorial Atlantic. An equatorial minimum of the zero-age crustal elevation of the East Pacific Rise suggests a similar situation in the Pacific. If so, an oceanic upper mantle cold equatorial belt separates hotter mantle regimes and perhaps distinct chemical and isotopic domains in the Northern and Southern hemispheres. Gravity data suggest the presence of high density material in the oceanic equatorial upper mantle, which is consistent with its inferred low temperature and undepleted composition. The equatorial distribution of cold, dense upper mantle may be ultimately an effect of the Earth's rotation.     

Airborne geophysical study in the pensacola mountains of antarctica

A seismic reflection, gravity, and aeromagnetic reconnaissance was made in the Pensacola Mountains, Antarctica, during the 1965-66 austral summer. Prominent ice streams located between the Neptune and Patuxent Ranges and east of the Forrestal Range overlie channels in the rock surface 2000 meters below sea level which are probably of glacial origin. Seismic reflections show that the Filchner Ice Shelf is 1270 meters thick near its southern margin. Along the boundary between West and East Antarctica, Bouguer anomalies decrease from +60 milligals in West Antarctica to -80 milligals in East Antarctica. An abrupt change in crustal structure across this boundary is required to explainl the 2 milligals per kilometer gradient. This may indicate a fault extending through the crust into the mantle. Aeromagnetic profiles delineate anomalies up to 1800 gamma associated with the basic stratiform intrusion which comprises the Dufek and Forrestal ranges. A probable minimum area of 9500 square kilometers is calculated for the intrusive body on the basis of the magnetic anomalies, making it one of the largest bodies of its type. The extension of this magnetic anominaly across a fault forming the north border of the Pensacola Mountains probably precludes transcurrent movement.     

Oxygen and carbon isotopic growth record in a reef coral from the Florida keys and a deep-sea coral from blake plateau

Carbon and oxygen isotope analysis through a 30-year (1944 to 1974) growth of Montastrea annularis from Hen and Chickens Reef (Florida Keys) shows a strong yearly variation in the abundances of both carbon-13 and oxygen-18 and a broad inverse relationship between the two isotopes. Normal annual dense bands are formed during the summer and are characterized by heavy carbon and light oxygen. "Stress bands" are formed during particularly severe winters and are characterized by heavy carbon and heavy oxygen. The isotopic effect of Zooxanthellae metabolism dominates the temperature effect on the oxygen-18/oxygen-16 ratio. The isotopic results on the deep-sea solitary coral Bathypsammia tintinnabulum, where Zooxanthellae are nonexistent, indicates that the abundance of the heavy isotopes carbon-13 and oxygen-18 is inversely related to the growth rate, with both carbon and oxygen approaching equilibrium values with increasing skeletal age.     

One thousand centuries of climatic record from cAMP century on the greenland ice sheet

A correlation of time with depth has been evaluated for the Camp Century, Greenland, 1390 meter deep ice core. Oxygen isotopes in approximately 1600 samples throughout the core have been analyzed. Long-term variations in the isotopic composition of the ice reflect the climatic changes during the past nearly 100,000 years. Climatic oscillations with periods of 120, 940, and 13,000 years are observed.     

18O/16O, 30Si/28Si, D/H, and 13C/12C Studies of Lunar Rocks and Minerals

The delta (18)O of minerals from lunar gabbros and basalts are: plgioclases +6.06 to +6.33), pyroxenes (+5.70 to +5.95), and ilmenites (+3.85 to +4.12). The uniformity of these results indicates isotopic equilibrium in the mineral assemblages. Estimated plagioclase-ilmenite temperautres range from 1150 degrees C to 1340 degrees C. The bulk (18)/ (16)O and (30)Si/ (28)Si ratios of these lunar rocks are identical with ratios of terrestrial basalts, but the lunar glass, breccia, and dust are slightly enriched in the heavier isotopes. The lunar hydrogen (formed from solar wind) has a delta D/H of less than-873 per mil and the value may be even lower, as it is probably contaminated with terrestrial hydrogen. The delta (13)C of lunar dust and breccia is unusually high relative to reduced carbon in meteorites or on earth.     

Lower Pliocene hominid remains from Sterkfontein

Cosmogenic aluminum-26 and beryllium-10 burial dates of low-lying fossiliferous breccia in the caves at Sterkfontein, South Africa, show that associated hominid fossils accumulated in the Lower Pliocene. These dates indicate that the skeleton StW 573 and newly discovered specimens from Jacovec Cavern have much the same age: approximately 4 million years. These specimens are thus of an age similar to Australopithecus anamensis from East Africa.     

Cllsworth Mountains: Position in West Antarctica ue to Sea-Floor Spreading

Similarities of middle anld upper Paleozoic deposits of the Ellsworth fountains with those of the Pensacola, Horlick, and other Transtarctic mountains indicate that all these ranges may have had a related geologic history. A native explanation is now suggested which involves sea-floor spreading atnd anslocationi of the Ellsworth crutstal block from its originilal location adjacent to the East Antarctic Shield. Accordingly, the islands of West Antarctica may differ it origin and the Transantarctic Mountains of East Antarctica may represent one margin of an ancient rift.     

A change in the geodynamics of continental growth 3 billion years ago

Models for the growth of continental crust rely on knowing the balance between the generation of new crust and the reworking of old crust throughout Earth's history. The oxygen isotopic composition of zircons, for which uranium-lead and hafnium isotopic data provide age constraints, is a key archive of crustal reworking. We identified systematic variations in hafnium and oxygen isotopes in zircons of different ages that reveal the relative proportions of reworked crust and of new crust through time. Growth of continental crust appears to have been a continuous process, albeit at variable rates. A marked decrease in the rate of crustal growth at ~3 billion years ago may be linked to the onset of subduction-driven plate tectonics.     

Theoretical and experimental rate constants for two isotopic modifications of the reaction h + h2

Theoretical rate constants for two isotopic modifications of the simplest possible chemical reaction, namely, H + D(2) --> HD + D and D + H(2) --> HD + H, are presented. Experimental results, which have previously been obtained in the higher temperature regime by a shock tube technique, are combined with lower temperature results to give an experimental determination of the rate behavior over the large temperature range approximately 200 to 2000 K. It is now possible to assess the accuracy of ab initio potential energy surface calculations and to judge theoretical chemical kinetic methods.     

Stable carbon isotope ratios of rock varnish organic matter: a new paleoenvironmental indicator

Stable carbon isotope ratios of organic matter in rock varnishes of Holocene age from western North America and the Middle East show a strong association with the environment. This isotopic variability reflects the abundance of plants with different photosynthetic pathways in adjacent vegetation. Analyses of different layers of varnish on late Pleistocene desert landforms indicate that the carbon isotopic composition of varnish organic matter is a paleoenvironmental indicator.     

Did the breakout of laurentia turn gondwanaland inside-out?

Comparative geology suggests that the continents adjacent to northern, western, southern, and eastern Laurentia in the Late Proterozoic were Siberia, Australia-Antarctica, southern Africa, and Amazonia-Baltica, respectively. Late Proterozoic fragmentation of the supercontinent centered on Laurentia would then have been followed by rapid fan-like collapse of the (present) southern continents and eventual consolidation of East and West Gondwanaland. In this scenario, a pole of rotation near the Weddell Sea would explain the observed dominance of wrench tectonics in (present) east-west trending Pan-African mobile belts and subduction-accretion tectonics in north-south trending belts. In the process of fragmentation, rifts originating in the interior of the Late Proterozoic supercontinent became the external margins of Paleozoic Gondwanaland; exterior margins of the Late Proterozoic supercontinent became landlocked within the interior of Gondwanaland.