Einfluß von Bodenreaktion,Redoxbedingungen und organischer Substanz auf die Phosphatgehalte der Bodenlösung

Influence of soil reaction, redox conditions and organic matter on the phosphate content of soil solutions Samples of seven agriculturally used soils of different composition (A_p-horizons), one marine underwater soil and two garbage composts were adjusted in suspensions (soil-water-ratio 1:3) to different pH values between 3 and 8 by additions of NaOH or HCl. By a different degree of aeration the redox potential was kept constant at selected values between +600 and ?300 mV. After an incubation period of 22–24 days under controlled E_h-pH-conditions the content of total phosphate and orthophosphate was measured in the equilibrium solutions. At oxidizing conditions all soil and compost samples show the lowest phosphate content in solution at pH S6. At higher and lower pH values the phosphate content increases. The results indicate that the phosphate concentration is determined by adsorption/desorption processes – mainly connected with iron oxides – and not by dissolution or precipitation of definite phosphorus compounds. Under reducing conditions the phosphate content increases in the equilibrium solutions of all samples. Especially in samples with high content of sulphides a considerable increase of the phosphate concentration could be measured at Eh values below +300 mV at pH 5, +200 mV at pH 6, and ± 0 mV at pH7 and 8. Below these values phosphate containing iron(II1) oxides were reduced and – with further decreasing redox potentials – transformed to iron sulphides. In samples without sulphide formation the phosphate mobilization is much lower. With increasing amount of soluble organic matter the phosphate content of the solutions also increases because of phosphate desorption by organic anions or complexation of aluminium and iron from phosphate adsorbing compounds. But also the content of soluble organically bound phosphate increases and may amount to 70 % of the total phosphate content in solution.     

Der Einfluß agrochemischer Substanzen auf den Stroh- und Zelluloseabbau im Boden

The influence of agrochemical compounds on the decomposition of straw and cellulose in soil Supplementary to earlier investigations the decay of large amounts of straw-material with normal quantities of pesticides and normal amounts of straw-material with large quantities of pesticides was proved in a gasanalytical instrument and in pot-experiments. At the same time the straw-decay was tested in pot-experiments. The soil used in these pots has been untreated or treated for several years with different kinds of plant-Protecting-solutions. Finally there was made a test about the decay cellulose (KOZOVA 1963) with the same and different investigation materials. The results are as follows: 1. The use of plant-protection in wheat does not diminish the decay of straw even if the double quantity of straw treated with a medium-quantity of pesticides is added and normal quantities of straw treated with high quantities of pesticides are added to the soil. 2. Agricultural soils, which are cultivated for many years by using pesticides, do not show less straw-decay. 3. The decay of pure cellulose in the laboratory tested by the method of Kozova (1963) was diminished in soils, which had been treated for many years with herbicides and herbicides added with other plant-protection-means. This restriction seems to depend on unfavorable food-conditions for microorganisms eating cellulose in a soil without weed, since the direct dipping of cellulose in herbicid-liquid is not causing any decay-restriction. 4. On the other hand the direct sprinkling of the cellulose-filter-discs with fungicid-solutions of normal concentration diminished the decay strongly. However the decay was not restricted under field-conditions. This seems to be due to the fact that in the growing plants the fungicides have been transformed to a large extend and only small amounts could reach the soil.     

Einfluß der Kalkung und Düngung auf den Ionenaustausch und die chemische Zusammensetzung der Bodenlösung am Beispiel von vier Waldstandorten im Hessischen Bergland

Impact of liming and fertilization on ionic exchange and chemical composition of soil solutions from four forest sites in the colline region of Hesse Between February 1985 and July 1987 soil seepage experiments were carried out on fertilizer trial plots in mature beech stands of four forest districts of Hesse. Encompassed by this study are in addition the most important results from soil-chemical analyses of the subsequent years 1988 to 1991. Aim of the investigations was to study the influence of liming and K/Mg-fertilization on the chemical composition of soil and soil solution under different site conditions. In the percolated soil solution liming did not led to a significant pH increase in subsequent years. In contrast, in some cases the pH level dropped by 0.1 to 0.2 units on average and Al-concentration increased correspondingly. In most cases, fertilization led to a significant increase in soil solution concentrations of the metal cations potassium, calcium and magnesium, especially at a depth of 50 cm. On those trial plots where a pH decrease was observed, the concentrations of K, Ca and Mg exhibited either a slight or no increase at all. Furthermore on some trial sites with freely drained soils, liming led to a faster mineralisation of the humus layer and thus to an increase of nitrate contents in the percolated soil solution from about 1–2 mg/l to 10–20 mg/l on average. Increased concentrations of sulfate and in most cases also of heavy metals (Mn, Zn, Cu. Cd) were observed in the soil solution which was attributed to the mobilizing effect of Ca-fertlization. In general, the mobility of most chemical parameters showed a slight increase following liming and soil tillage. Even after 5 to 8 years considerably higher pH-values and base saturation were evident in limed and fertilized soils, especially in the top 15 cm of soil profiles.     

Einfluß der Probenvorbereitung auf die Adsorption von Cd und Cu in sauren Waldböden

Influence of Soil Sample Preparation on Cd and Cu Adsorption in Acid Forest Soils The influence of soil sample preparation on Cd and Cu adsorption was investigated using six acid forest soil samples and comparing adsorption isotherms for fresh and air-dried samples. While no influence of sample preparation on Cd adsorption capacity was found, air-drying resulted in a significant decrease in Cu adsorption density in all six soil samples under investigation at ecotoxicologically relevant concentrations in the soil solution.     

Einfluß der Bodenentwicklung auf den Zusammenhang zwischen Lagerungszustand und vertikaler Spannung im Boden

Effect of soil formation on packing and on vertical stresses in soils The relationship between void ratio and vertical stress was investigated for 34 profiles (loess, glacial till, sands) mostly under forest and some under meadows. Development in terrestric forest soils obviously results in ?non overconsolidated”? structure. The stress distributions as a function of depth partly point to constant shear parameters, partly to differences in the profile, especially clear in the case of Podsol and Sandbraunerde. Whereas the absolute value of the void ratio can be explained by the soil-own shear parameters, the decrease of void ratio as a result of equal load increments will be explained by the extent of translation, which is necessary to increase the mean number of grain contacts.     

Vergleich zwischen Total- und königswasserextrahierbaren Elementgehalten in natürlichen Böden und Sedimenten

Comparison between total- and aqua regia extractable contents of elements in natural soils and sediments Total- and aqua regia extractable contents of 19 elements from 28 soil samples with widely varying composition of the ISE ring analytical program (INTERNATIONAL SOIL-ANALYTICAL EXCHANGE) of the year 1995 to 1997 have been taken to find out the comparability between the two fractions. The relations between the two fractions and pH, organic matter and clay content were considered by means of single and multiple regressions. The correlations between the total and aqua regia extractable contents of As, Ca, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Ni, P, Pb and Zn are very close, whereas Al, Ba, K, Na and Sr are not or only weakly correlating. The multiple regressions show that the content of some aqua regia extractable elements and the proportion (in %) of the total contents is correlated with pH, organic matter and/or content of clay. In the same way the proportion of aqua regia extractable elements is closely related (except Fe and Hg) to the soil pH. Hereby the proportion of the aqua regia extractable content increases with increasing pH in the range 3,5—7,7. The determined equations are tested for As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb and Zn by using the values of certified reference material. The estimated aqua regia extractable contents are being compared with values of reference material. The average proportion of the calculated to the measured aqua regia contents of an element in percent are 99 for Zn, 98 for Co, Cu and Mn, 94 for Cd, 90 for Ni, 88 for Cr, 105 for Hg, 113 for As and 114 for Pb.     

Der Einfluß der Expositionszeit auf die Höhe der Bodenatmung bei Anwendung der Lundegardhmethode

The influence of exposure time on the magnitude of soil respiration under employment of the Lundegardh-procedure To assess the role of carbon-rich soils under a potential climate change much more data are needed then currently available. These have to be collected also under conditions, where only limited technical and personal resources are available. Therefore the easy to be accomplished Lundegardh-procedure, which is accepted as a standard procedure for exposure times up to 24 hours (Anderson, 1982), was tested for its suitability to longer periods of exposure. For this purpose six Lundegardh-traps were installed on seven consecutive days (treatment B), and the means of the six repetitions added to a weekly value. In the immediate vicinity to the former, six Lundegardh-traps were installed for periods from one to seven days (treatment A) This was done during the warm season as well as in the winter. The comparison of the treatments A and B revealed a linear correlation, which allows to substitute cumulated daily values by values of traps, that have been installed for several days. However, the “chamber-effect”, an overestimation of respiration by the traps installed for more than 24 hours found by Tesarova and Gloser (1976) has to be considered. In the summer, the same degree of overestimation (16%) was found as reported by Tesarova and Gloser (1976). In the winter, far lower absolute values and therefore higher statistical importance of extremes led to an overestimation of 46%.     

Kurzmitteilung Einfluß der Qualität der organischen Substanz auf die Konsistenz landwirtschaftlicher Böden

Influence of organic matter quality on consistency of agricultural soils The soil organic matter of two samples similar in the texture and approximately in the organic C contents, but very differently in the consistency properties, were investigated by pyrolysis-field ionization mass spectrometry (Py-FIMS). The shifts of the values of the liquid and plastic limits towards higher moisture contents are explained by a different quality of soil organic matter, in particular by higher amounts of longchained lipids (C_8-32 alkanes, alkenes, fatty acids), N-compounds and lignin dimers.     

Der Einfluß des NO3 : NH4 -Verhältnisses in der Nährlösung auf Ertrag und Gehalte an organischen und anorganischen Ionen von Tomatenpflanzen

The influence of the relation between NO₃ and NH₄ in the nutrient solution on yield and organic and inorganic ion contents of tomato plants. . Tomato plants were grown in aerated media of oppositly varying supply of (NH₄)₂SO₄-and NaNO₃ with a constant N-quantity of 15 meq/1 or a quantity of NH₄-, NO₃ or (NO₃ + NH₄) increasing from 3 to 30 meq.N/1. Yield and ion content were determined. A maximum yield was achieved by a mixed N-supply i.e. 4 to 5 parts NO₃, 1 part NH₄-N and 7, 5 meq N/l. The “(C-A) value” was calculated by the content of the cationions “C” (=K⁺ + Na⁺ + Ca⁺⁺ + Mg⁺⁺ + NH₄⁺) and the inorganic anions “A” (= NO₃^? + Cl^? + H₂PO₄^? + SO₄^–). The “(C-A)” value is equivalent to the content of the organic anions. Furthermore we determined the citrate, malate, oxalate, and pektinate content. These make up 60–80% of the (C-A) value. The NO₃- and K content increase considerably, the Ca-, Mg-, Na-, Citrate, Malate and Oxalate content increase less pronounced, the Cl-, H₂PO₄- and SO₄- content decrease as the NO₃ content increases from 0–80%. If the medium contains 80–100% NO₃ - N, the NO₃ and K content remain almost constant, while the Ca-, Mg-, citrate, malate and oxalate content especially increase in this case. The K content decreases in the presence of a high (NH₄)₂SO₄ supply. Parallel to this the value (C-A) decreases greatly, so that it is less than the sum of the determined organic anions. In this case the content of organic anions obviously does not correlate with the (C-A) value. The yield correlates with the carboxylate contents. (C-A) values of 150–170 mval/100 gm. d. m. cause a lowering of the yield. The plants contain an almost equal amount of citrate, malate and oxalate. Depending on the N-concentration of the medium, the malate content will be a bit more than the amount of citrate in case of maximum yield. If there is a lack or toxicity in the medium the citrate content will be higher than the malate content. The yield per dry weight correlates positivly with the quotients of citrate and malate.     

Der Einfluß der Fauna auf die Stoffverlagerung sowie die Homogenität und die Durchlässigkeit von Böden

The influence of the fauna on displacement and on homogeneity and permeability of soils The influence of the most important soil animals (mammals, ants, termites, woodlice and earthworms) on displacement and on homogeneity and permeability of soils is discussed in reference to both older and more recent literature. Nearly all soil animals cause displacement of organic and mineral soil particles. The quantity, intensity and direction of this activity depends upon the morphological characters of the species involved. The homogeneity of soils is positively influenced only by the earthworms (and related forms) whereas the activity of the other soil fauna mostly has a contrary effect as far as shorter periods are concerned. The permeability of soils increases in different dimensions due to the activity of all species discussed. Permanent vegetation and non-tilling for the most part favour the activity of the soil fauna. Recent field experiments dealing with minimum or zero tillage have made this fact fairly evident.     

Der Einfluß von Klärschlamm auf die mikrobielle Tätigkeit im Boden

The influence of sewage sludge on microbial activity in soil The effect of untreated, pasteurized and irradiated sewage sludge on soil biology was studied in model and field experiments. Sewage sludge from the sewage plant Geiselbullach in the west of Munich city was used for these experiments. The investigations were performed with 4 soil types according to the different locations. All the results demonstrate that there is an increase in biomass after application of sewage sludge while there were definite influences from the location. No significant relation could be observed according to sewage sludge treatment. Under favourable lab conditions the mineralization of the organic matter applied to the soil with higher amounts of sewage sludge induces in short time a definite decrease in pH. In accordance with these changes in pH there is a corresponding decrease in microbial biomass. Early results on the influence of microbial N-cycle demonstrated that amounts of sewage sludge applied under practical conditions brought an increase in denitrification capacity of the soil. In the experiment with soils nitrification rate was doubled after sewage sludge application.     

Die Beeinflussung der Bodenlösung durch Saugkerzen aus Ni-Sintermetall und Keramik

Influencing soil solution by suction cup material (Ni, ceramics) The influence of suction cup material (ceramics, Ni) on the chemical composition of the soil solution was tested in the laboratory by percolating soil solutions of different concentration (pH ～ 4.0). Ceramic cups of P 80 material can be used for the collection of soil solution and its determination for the concentrations of H, Na, K, NH₄, Ca, Mg, Mn, Al, S, Cl and NO₃. They can't be used to determine P-concentrations. The cups must be prepared and preconditioned by leaching large amounts of equilibrium soil solution which should not be oversaturated with respect to the solubility product of AlOHSO₄. The changes in the concentration of extracted soil solution when it passes through the cups depend upon the extracted volume. The lower the volume, the greater are the changes. Sintered Ni-cups show many severe disadvantages (decreasing permeability, insufficient resistence against acid solutions, large variability among single cups), and can only be used for cases where Na, Ca, K, and S are to be determined. Ceramic cups of the type ‘Czeratzki’ are comparable with those of P 80. However, they can only be used, when the concentrations don't vary too much and large amounts of water can be extracted.     

Der Einfluß von Cadmium im Boden auf den Ertrag verschiedener Pflanzenarten und deren Cadmiumgehalt

Influence of Cadmium in Soil on the Yield of Various Plant Species and their Cadmium Content In pot experiments the influence of increasing quantities of cadmium in the soil (< 250 mg Cd/kg) on the growth of carrot, bushbean, tomato, ray grass and the cadmium content of various plant parts were studied. Considerable differences of the various plant species are observed. Sensitivity increases in the order: tomato (low) < broccoli < oat < lettuce < ray grass = carrot root < radish < bushbean = pea < spinach (very sensitive). Symptoms of toxicity are found in bush beans only. Fruit, seeds and roots accumulate less cadmium then leaves and straw.     

Einfluß der Bodeneigenschaften auf die Freisetzung der gelösten organischen Substanz (DOM) aus dem Oberboden

Influence of Soil Properties on the Release of Dissolved Organic Matter (DOM) from the Topsoil A percolation experiment over a period of three month with small monoliths from forest and grassland soils varying in their anthropogenic changes was carried out to identify, to weigh and to quantify important soil properties for DOM release from the topsoil. Quality of soil organic matter determines the amount of DOM released from the topsoil if the soils have a low ability to adsorb and to precipitate DOM. Favorable conditions for high DOC concentrations in the soil solution are wide C/N ratios in the soil and in the hot water soluble fraction, a high soil content of hot water soluble organic carbon and a high portion of hot water soluble organic carbon in the total organic carbon content. Anthropogenic changes of the soils are effective to DOM release via changing quality of soil organic matter. Long dry periods and large water fluxes can further increase DOM release. The effects of soil organic matter can be disguised in soils with a high DOM retention capacity (high CEC, high content of exchangeable bases, Fe_ox and Fe_d). Then adsorption and precipitation determine DOM release from the topsoil and contribute to a decrease of DOM release.     

Zusammensetzung und Speziierung der Bodenlösung eines mit Schwermetallen belasteten kalkreichen Bodens

Composition and Speciation of Soil Solution collected in a Heavy Metal polluted calcareous Soil Close to a brass foundry, which had emitted heavy metal containing dusts for over 80 years, soil water was collected in the topsoil (18 cm) and in the subsoil (40 cm) of a severely polluted Calcic Fluvisol by means of polyethylen suction cups over a period of 2 years. The total metal content of the topsoil (extracted with 2M HNO₃ at 100 °C for 2 hours) was 38 nmol g^?1, 24 μmol g^?1, and 25 μmol g^?1 for Cd, Cu, and Zn, respectively. The mean heavy metal concentrations of the soil solution were 0.5 mol L^?1, 300 nmol L^?1, and 200 nmol L^?1 in the topsoil and 0.6 nmol L^?1, 90 nmol L^?1, and 30 nmol L^?1 in the subsoil for Cd, Cu, and Zn, respectively. Solubility calculations showed that the soil solutions were undersaturated with respect to heavy metal carbonates as well as to hydroxides. It seems that the heavy metal concentration is determined by sorption processes rather than by precipitation. The composition of the soil solution has been shown to be governed by the presence, of calcite, by the soil temperature and by the partial pressure of CO₂ in the soil air. The pCO₂ in the soil air (in both depths) has been estimated at 2 mbar during the winter term and at 20 mbar during the summer term. A corresponding increase of the concentration of macroelements (Ca, Mg, Na) as well as of total dissolved carbonate and of dissolved organic matter (DOC) has been measured in the summer half year. No significant seasonal variations of the heavy metal concentrations were detected and no correlations with concentrations of other components could be found.