Weathering and mobility sequence of minor elements on a basaltic pedomorphic surface,Galilee, Israel

A number of minor elements was determined in 21 samples of several soil profiles of a young pedomorphic surface on basalt, Upper Galilee, Israel, ranging from red basaltic Lithosols to lithic Red Mediterranean soils and montmorillonitic Grumusols (Xerorthents, Lithic Xerochrepts, and Chromoxererts).Strontium and to a lesser extent barium are lost during the weathering of the feldspars; Sr continues to be leached out on the slope. Titanium concentrates in the non-clay residue and follows iron during its redistribution on the slope. Manganese is more mobile than iron. Cobalt is partially correlated with manganese, but like Ni, Cr, Cu and V, these elements do not show any definite trend and appear to be rather immobile under the moderate weathering conditions of the Mediterranean environment where montmorillonite is the major clay mineral.     

不同施磷量对蔬菜地土壤硝态氮淋失的影响

【目的】在两种蔬菜地土壤上研究不同磷肥施用量对土壤硝态氮淋失的影响,为武汉城郊蔬菜合理施用磷肥和安全生产提供理论依据。【方法】利用大型原状土柱渗漏装置,2种实验土壤(粉质粘土和粉质粘壤土)均为武汉城郊典型蔬菜土壤,分别采自华中农业大学校内蔬菜基地和湖北新洲。试验期间共种植了四种蔬菜(小白菜、 辣椒、 苋菜及萝卜)。试验设置了4个P2O5水平处理(0、 125、 250、 375 kg/hm2),氮肥施用量均为N 750 kg/hm2,钾肥施用量均为K2O 500 kg/hm2。试验期间年降雨量为1043.0 mm,各土柱总灌溉量为120.1 L。秋冬季每15天、 春夏季每10天收集一次淋洗液,另外根据天气和降雨情况适当调节,每次收集淋洗液时记录淋洗液体积并测定淋洗液硝态氮浓度。在每季蔬菜生长成熟后将蔬菜收获称重,烘干后测定蔬菜中氮素含量。【结果】1)与不施磷肥相比,施用磷肥显著增加了两种土壤上小白菜、 苋菜、 萝卜产量以及四季蔬菜总产量,其产量随磷肥施用量增加而增加或显著增加,在磷肥施用量最大时产量达到最大值。粉质粘土上的产量显著低于粉质粘壤土上的产量,粉质粘壤土总产量约是粉质粘土总产量的1.63~2.36倍。2)施用磷肥显著增加了小白菜、 苋菜氮素吸收累积量以及四季蔬菜总吸收累积量,且两种土壤上总氮素吸收累积量均在磷肥施用量最大时达到最大值。粉质粘壤土上氮素总吸收累计量显著高于粉质粘土上氮素总吸收累积量。3)磷肥水平对土壤总渗漏液体积并无显著影响(粉质粘壤土P2O5 125 kg/hm2处理除外),粉质粘土渗漏水量显著大于粉质粘壤土。4)施用磷肥降低或显著降低土壤淋失液硝态氮浓度(粉质粘土苋菜季除外),随着磷肥施用量的增加硝态氮淋失浓度不断降低,4季蔬菜平均淋失浓度最大降低了38.6%(粉质粘土)和28.8%(粉质粘壤土)。5)磷肥施用显著降低了两种土壤上硝态氮淋失量(苋菜季除外),且在粉质粘土上随着磷肥施用量的增加硝态氮淋失量不断降低,而在粉质粘壤土上硝态氮淋失量先降低后上升。粉质粘土硝态氮淋失量显著大于粉质粘壤土,磷肥施用降低硝态氮淋失量分别达到达26.4%~33.7%和23.5%~39.9%。【结论】磷肥施用增加了蔬菜产量和作物氮素吸收累积量,从而显著降低了两种土壤上硝态氮的淋失; 土壤质地对硝态氮淋失有较大影响,质地较轻的粉质粘壤土硝态氮淋失显著小于质地较重的粉质粘土; 粉质粘壤土上施用P2O5量为250 kg/hm2时能提高产量同时减少硝态氮淋失,而粉质粘土上施用P2O5量为375 kg/hm2时能获得较大产量和较少硝态氮淋失量。     

EXTRACTABLE SESQUIOXIDES IN SIX MEDITERRANEAN SOILS DEVELOPED ON BASALT AND SCORIA

Iron, Al, and Mn were extracted by oxalate and dithionite from two Brown Mediterranean Soils, two Red Mediterranean Soils, one Vertisol and one Gley soil, all derived from basalt or scoria in the sub-humid and humid Mediterranean regions of the Golan Heights. Ratios of oxalate: dithionite extracted iron (Fe_o:Fe_d) were low in all soils, indicating that the predominant form of free iron is crystalline. Fe_o accumulates in the argillic B horizons of the Mediterranean soils, while Fe_d accumulates in the surface horizons. A large part of the free iron oxide in the surface horizons of Mediterranean soils is associated with non-clay fractions. While manganese behaves in a manner somewhat similar to that of iron, no definite trends could be discerned in the vertical distribution of free aluminium. In the Vertisol, Fe_o and Mn_o accumulate in the subsoil. Fe_d and Mn_d increase slightly with soil depth. In the Gley soil, amorphous iron accumulates in the surface horizon, total free iron in the bottom horizon. Both amorphous and total free Mn had been depleted from the upper horizons of the Gley soil.     

Clay illuviation in Red Mediterranean soils

Theories regarding pedogenesis in Red Mediterranean soils have undergone several stages of development. The concept of clay illuviation in these soils was not a part of early theories and it is not yet unanimously accepted as a leading soil forming process. A methodology is presented for studying the illuviation of clay in these soils emphasizing typology of textural features and fabrics. The problem of age determination is also addressed, through the use of radiometric dates and correlation with archaeological artifacts. Clay illuviation in Red Mediterranean soils under present day environmental conditions suggests that it occurs presently only on humid and sub-humid margins of the Mediterranean basin. Elsewhere illuvial clay accumulations are inherited from Interglacial periods. Red Mediterranean soils during glacial periods were eroded, colluviated, aggraded with aeolian dust, calcitic fraction of which was redistributed in form of calcitic features and eventually were affected by water logging. An example of water logging of Red Mediterranean soils (Mamora, Morocco) which took place during the last Glacial cycle, consists of yellow illuvial clays accompanied by a yellowing of the ground mass. During earlier cycles water logging resulted in whitish grey stains in which hydromorphic textural features were deposited.     

Land evaluation of basaltic terrain under semi-arid to mediterranean conditions in the Golan Heights

Abstract. Soils derived from basalt bordering the northern Jordan Valley have developed under semi-arid to humid Mediterranean conditions and belong to two major soil orders: Vertisols in the drier south and Alfisols (Brown and Red Mediterranean soils) in the more humid north. Major limitations on land use of the vertisols are low hydraulic conductivity, slow infiltration and strong susceptibility to erosion by water. Crops growing on basalt-derived soil also suffer from phosphorus deficiency, though the soils contain much inorganic phosphorus. The natural vegetation is mainly herbaceous and grows well even under intensive and continuous grazing. The land is best used for pasture wherever limitations restrict other uses.     

Soil chronosequences in Israel

Chronosequences of Israel soils are summarized. Soil development in the coastal plain is related to the time of the dune deposits while those of the inland valley is related to the formation of the sedimentological terraces. Soil development in the mountains is related to the features and stability of the slope.The properties of young soils resemble those of the parent material. With advancing development the soils are affected by various processes, among them also the accretion of aeolian dust. Leaching is significant already at early stages; in some cases like Hamra and Terra-rossa soils the leaching stage is more advanced in earlier stages than in the final stage of soil development.In advanced stages of soil development the effect of the underlying rock on soil properties is reduced. At the final stage soils on moderate relief in the same climatic zone on different bedrocks resemble each other. This is attributed mainly to the effect of the aeolian dust accretion. The final stage of soil development on moderate relief consists of Grumusols in the northern parts of Israel, grumic dark Brown soils in the semi-arid parts of central Israel, loessial light Brown clay loam and loessial Serozems in the arid parts of the northern Negev and Regs in the extremely arid areas of the Southern Negev and Sinai. Petrocalcic horizons are developed on slopes and terraces where the rate of soil erosion equals that of accumulation of aeolian dust. The formation of petrogypsic horizons in the extremely arid zones is restricted to areas where erosion is negligible.The final stages of soil development exhibit a clear climatic zonality. This zonality differs from the soil zonality in the USSR and the USA due to the special features of dust accretion on the soils of Israel.     

Hydromorphic and clay-related processes in soils from the Llanos de Moxos (northern Bolivia)

The Llanos de Moxos is one of the largest wetlands in the world (more than 100,000 km²) due to seasonal floods. The soil parent materials are fine Quaternary sediments brought by tributaries of the Amazon River. Forests cover some areas, although the dominant vegetation is a pastured savannah and backswamps. At present, the main land use is a very extensive rangeland, and slash and burn agriculture in minor areas.We have studied 15 profiles from several sample areas between Trinidad and San Ignacio. Field and laboratory studies have been carried out in order to elucidate the soil-forming processes taking place and to gain basic knowledge for a sustainable land management.Coarser soils are located near the present river system or in former riverbank areas, often under forest; textures here are loam or silty loam, silty clay loam being dominant. Finer soils may have up to 85% clay and are usually under savannah cover. Illite is the dominant clay mineral in all soils, followed by smectite and kaolinite; vermiculite is absent. Quartz is present in a very significant amount in the clay fraction of all studied soils. Goethite and lepidocrocite are present in all soils, lepidocrocite being a good indicator of poor drainage conditions.Soils are mainly acid, but there are soils with calcium carbonate accumulation in the subsoil, or even saline soils (salitrales). Soils are flooded for a significant period (3–6 months) and bypass flow is very active. Hydromorphic processes are always present and morphologies include hard and soft iron–manganese concretions with diffuse boundaries within peds, impregnative Fe coatings and Fe depletion hypocoatings along pore walls. The micromorphological study shows different degrees of hydromorphism, some of them associated to the present pore system and some with a palaeo character, often disturbed by active slickensides. Microsparite nodules are also present in some low-lying soils. The soils present several morphological features related to the mobility of the fine fraction that can be related to drainage conditions, as recent clay coatings, clay and silt infillings and coatings and clay-depleted hypocoatings. The most clayey soils show striated b-fabrics and frequent slickensides, and some others point to ferrolysis as iron-depleted hypocoatings and low crystallinity clay coatings along pores, although this is not supported by mineralogical data. A moderate cation supply probably prevents strong acidification.     

Determining weathering rates of soils in China

As an important parameter for critical load calculation and soil acidification simulation, weathering rates of soils in China were studied using different methods of calculation. The approaches used were the mass balance approach, the soil mineralogical classification, the total analysis correlation, the PROFILE model, the MAGIC model and a simulated leaching experiment. Since chemical weathering of secondary minerals usually plays a much more important role in neutralizing the long-term acidification of soils in China than that of parent material, soil mineralogy rather than parent rock/material type, which is regarded as the most suitable factor representing weathering rates in Europe, should be adopted as the basis for soil classification. The weathering rate assigned to each soil should also be corrected when the effect of temperature is considered. Due to the variation in experimental conditions, the weathering rates of soils from laboratory experiment may be difficult to compare with field determined rates, and should be adjusted by pH and percolation rate. The comparison of various methods in this study shows that the weathering rates of soils estimated by the PROFILE model coincide well with those from other independent methods such as the dynamic modeling by MAGIC and the modified leaching experiment. The weathering rates were very low (usually lower than 1.0 kEq·ha⁻¹·year⁻¹) for Allites (including Latosol, Lateritic Red Earth, Red Earth, Yellow Earth and Yellow-Brown Earth) in south China and Silalsols (consisting of Dark Brown Forest Soil, Black Soil and Podzolic Soil) in northeast China, and very high for Alpine Soils, Desert Soils and Pedocals in west China. The content of weatherable minerals in soil is the most important factor in determining the spatial distribution of weathering rate in China, while the difference in temperature may be the reason why the weathering rate of soil in northeast China was lower than that in southeast China.     

Potassium dynamics of a forest soil developed on a weathered schist regolith

Soils of the humid tropics are poor in available potassium due to intensive weathering and leaching of nutrients. A study was conducted to investigate the mineralogy and potassium supplying capacity of a forest soil developed on a weathered schist regolith. The quantity–intensity (Q/I) approach was used in thisstudy. The schist regolith showed deep weathering and intense leaching throughout the profile, resulting in low cation exchange capacity (CEC) and available K in soil and saprolite layers. The mineralogy of the regolith was dominanted by kaolinite, gibbsite and goethite. Feldspar, mica and mica–smectite minerals were observed in the lower saprolite layers. The Q/I parameters showed that the soils and saprolites were low in K supply power. This observation was attributed to weathering and intense leaching. The free energy values of K replacement (ΔG _r°) also suggest that soils and saprolites of the schist regolith were deficient in K. The Q/I parameters significantly correlated with organic carbon and clay content, CEC, pH and exchangeable K.     

Clay minerals of soils from olivine basalt in Kyushu

Soil scientists have been encouraged to investigate soils for clay minerals by very fact that soil characteristics fundamentally depend upon the nature of their clay. It is generally recognized that clays of different species develop under different conditions such as drainage, temperature weathering age, and parent rocks. On Kyushu Island, heavy, reddish soils derived from olivine basalt cover a considerably large area of its northeastern part, and a numbar of small islands belonging to Kyushu. Koga ^* Hiroshi Koga, Clay minerals of Oura basaltic soil, 1954 (unpublished). of this laboratory found a basaltic soil of clay consisting of hydrated halloysite, halloysite, hematite, and gibbsite at the eastern foot of Mt. Tara, by examining its clay separates by X-ray, thermal, chemical, and electron microscopical techniques. Kanno et al⁵ reported that in a basaltic soil at Oura, Saga prefecture, hydrated halloysite developed from plagioclase and ferro-magnesian minerals with gibbsite and hematite which was more abundant than in other Red and Yellow Soils. They also found some illite present in the soil derived from unknown minerals, and halloysite dehydrated in upper layers.     

Organic carbon mineralization responses to temperature increases in subtropical paddy soils

Purpose

Understanding organic carbon mineralization and its temperature response in subtropical paddy soils is important for the regional carbon balance. There is a growing interest in factors controlling soil organic carbon (SOC) mineralization because of the potential for climate change. This study aims to test the hypothesis that soil clay content impedes SOC mineralization in subtropical paddy soils.

Materials and methods

A 160-day laboratory incubation at temperatures from 10 to 30 °C and 90% water content was conducted to examine the dynamics of SOC mineralization and its temperature response in three subtropical paddy soils with different clay contents (sandy loam, clay loam, and silty clay soils). A three-pool SOC model (active, slow, and resistant) was used to fit SOC mineralization.

Results and discussion

Total CO₂ evolved during incubation following the order of clay loam > silty clay > sandy loam. The temperature response coefficients (Q ₁₀) were 1.92?±?0.39, 2.36?±?0.22, and 2.10?±?0.70, respectively, for the sandy loam soil, clay loam soil, and silty clay soil. But the soil clay content followed the order of silty clay > clay loam > sandy loam. The sandy loam soil neither released larger amounts of CO₂ nor showed higher temperature sensitivity, as expected, even though it contains lower soil clay content among the three soils. It seems that soil clay content did not have a dominant effect which results in the difference in SOC mineralization and its temperature response in the selected three paddy soils. However, dissolved organic carbon (DOC; representing substrate availability) had a great effect. The size of the active C pool ranged from 0.11 to 3.55% of initial SOC, and it increased with increasing temperature. The silty clay soil had the smallest active C pool (1.40%) and the largest Q ₁₀ value (6.33) in the active C pool as compared with the other two soils. The mineralizable SOC protected in the silty clay soil, therefore, had even greater temperature sensitivity than the other two soils that had less SOC stabilization.

Conclusions

Our study suggests that SOC mineralization and its temperature response in subtropical paddy soils were probably not dominantly controlled by soil clay content, but the substrate availability (represented as DOC) and the specific stabilization mechanisms of SOC may have great effects.     

Primary particle size distribution of eroded material affected by degree of aggregate slaking and seal development

Primary particle size distribution (PSD) of eroded sediment can be used to estimate potential nutrient losses from soil and pollution hazards to the environment. We studied eroded sediment PSDs from three saturated soils, packed in trays (20 × 40 × 4 cm), that had undergone either minimal aggregate slaking (MAS) or severe aggregate slaking (SAS) prior to a 60 mm simulated rainstorm (kinetic energy, 15.9 kJ m⁻³; droplet diameter, 2.97 mm) and collected runoff at regular intervals. The degree of aggregate slaking was controlled by the rate at which soils were wetted to saturation. The PSDs of eroded materials and of parent soils were determined using a laser particle size analyser. For each soil, PSD frequency curves of eroded sediments and parent soils were generally of a similar shape but most eroded sediments had larger clay contents than their parent soils. In the SAS treatment, cumulative clay enrichment in the eroded materials was inversely related to the parent soil clay content, these being 28.5, 26.6 and 22.8% richer in clay than their parent soils for the loam, sandy clay and clay, respectively. Generally, total clay loss was greater from soils with SAS than from those with MAS because of erosion rates; however, clay enrichment of sediments, compared with parent soil clay contents, was mostly greater in samples with MAS. Greater clay enrichment took place during the early seal development stage in the loam, but could not readily be associated with specific stages of seal development for the clay. In the sandy clay, the relation between seal development and clay enrichment in the eroded material depended on the initial degree of aggregate slaking. The observed large preferential loss of clay by erosion in cultivated soils re-emphasizes the need to employ erosion control measures.     

江淮流域白浆化土壤的矿物组成与化学特性的研究

对采自江淮流域的7个典型白浆化工土壤剖面不同粒级的矿物特性与化学组成进行了研究。结果表明：该区域白浆化土壤的质地为粉砂质壤土及粘壤土，粉粒含量为45%～76%。粘粒矿物以水云母为主，含量为60%～80%，继承了黄土母质的特性，土体硅铝率（Sa)与硅铁铝率（Saf）分别为7.70～14.05与6.43～10.24，而粘粒的分别为3.53～4.22和2.40～3.35。各剖面土体Sa与Saf以表层较高或最高，有明显富硅现象；而粘粒的Sa和Saf及矿物组成，颗粒组成的层次差异则表现出母质层次上的不连续性，白土层与粘化层的显著分异是由于全新世黄土性沉积物，经过冲积淤积交替更迭，加上后期淋溶淀积而成；脱硅、脱盐基和富铝化及氧化还原淋溶淀积是其重要成土过程，后一过程不同的利用方式，强度有所差别，以水稻土较强。     

Clay minerals from diallage in a warm and humid climate

In the course of chemical weathering, rockforming minerals release constituent ions changing into secondary minerals by alteration or recrystallization. Minerals formed in this way are primarily of colloidal nature, and are the most active portion in soils together with humus. The chemical weathering has dual meaning for soil fertility, that is, it provides soils with nutrients released and inorganic colloids formed, namely clay minerals. It has been well established that climate, vegetation, parent material, topography and time influence the formation of soils. Generally speaking, Japanese soils have developed under a warm and humid climate which causes leaching of released bases resulting in acid reactions, and a predominance of kaolin in soils. Accumulated information pertaining to Japanese soils, however, has disclosed that physical, chemical, and mineralogical properties of parent rocks are still obviously reflected in the clay minerals of soils.     

Chemical properties and pedogenesis of yellowish/yellow brown forest soils in the submontane and mountain zones of Kyushu district,southwestern Japan

Abstract

This study aimed to clarify pedogenetic processes and classification of yellowish Brown Forest Soils according to the Classification of Forest Soils in Japan and the Yellow Brown Forest soils according to the Unified Soil Classification System of Japan in the warm and cool temperate forest of Kyushu district, Japan. In addition, the study aimed to clarify a problem with the Unified Soil Classification System of Japan. Thirty-six soil profiles of Brown Forest Soils, including 13 yellowish Brown Forest Soils and 15 Yellow Brown Forest soils, were compared with regard to their chemical properties and the relationship with climatic conditions was assessed. The yellowish Brown Forest Soils had thin A horizons, low pH and low levels of free oxides in the B horizons, and a low amount of silica and a high aluminum and iron to silica ratio. These features were related to the paleo reddish weathering. The immaturely developed A horizon of the yellowish Brown Forest Soils was caused by these weathered, low-activity substances. The Yellow Brown Forest soils had low levels of active iron oxides and a low activity ratio of free iron oxides compared with the Haplic Brown Forest soils in the same thermal climatic conditions. The activity ratio of free iron oxides was correlated to mean annual air temperature with the carbon stocks and with many other chemical properties. Accordingly, classification of Brown Forest Soils was clearer according to thermal climatic conditions. The activity ratio of free iron oxides can become an effective index that distinguishes Yellow Brown Forest soils under warm temperate lucidophyllous forest and Haplic Brown Forest soils under cool temperate broad-leaved deciduous forest with considerable vertical soil zonality.     

Influence of texture on habitable pore space and bacterial-protozoan populations in soil

Summary Soil texture affects pore space, and bacterial and protozoan populations in soil. In the present study we tested the hypothesis that bacteria are more protected from protozoan predation in fine-textured soils than in coarse-textured soils because they have a larger volume of protected pore space available to them. The experiment consisted of three sterilized Orthic Black Chernozemic soils (silty clay, clay loam, and sandy loam) inoculated with bacteria, two treatments (with and without protozoa), and five sampling dates. The soils were amended with glucose and mineral N on day 0. On day 4 bacterial numbers in all three soils were approximately 3×10⁹ g^–1 soil. The greatest reduction in bacteria due to protozoan grazing occurred between day 4 and day 7. Compared to the treatment without protozoa, bacteria in the treatment with protozoa were reduced by 68, 50, and 75% in the silty clay, clay loam, and sandy loam, respectively. On day 4, 2 days after the protozoan inoculation, all protozoa were active. The numbers were 10330, 4760, and 15 380 g^–1 soil for the silty clay, clay loam, and sandy loam, respectively. Between day 4 and day 7, the period of greatest bacterial decline, total protozoa increased greatly to 150480, 96160, and 192100 g^–1 soil for the three soils, respectively. Most protozoa encysted by day 7. In all soils the addition of protozoa significantly increased CO₂–C evolution per g soil relative to the treatment without protozoa. Our results support the hypothesis that bacteria are more protected from protozoan predation in fine-textured soils than in coarse-textured soils.     

Nitrate leaching from reseeded pasture

Abstract. Nitrate leaching and soil mineral N status under grassland were measured on three contrasting soils, spanning winters 1995/96, 1996/97 and 1997/98, in Western England. The soils investigated were a freely draining silty clay loam (Rosemaund), a well drained loam (IGER 1) and a poorly drained clay loam (IGER 2). The effects of reseeding (ploughing and resowing grass) at IGER 1 and IGER 2 in autumn 1995 or 1996 were compared with undisturbed pasture. Reseeding at Rosemaund, in autumns 1995 or 1996, or spring 1996 was compared with undisturbed pasture of 3 sward ages (2, 5, >50 years).
Nitrate-N leaching losses during the winter immediately following autumn reseeding ranged between 60 and 350 kg N ha^–1 in 1995/96, depending on soil type, sward management history and rainfall. Losses were much less in the following winter when treatments were repeated (10–107 kg N ha^–1).
Reseeding in spring had little effect on soil mineral N content or leaching losses in the following autumn, compared with undisturbed pasture. Similarly, leaching losses from autumn reseeds in the second winter after cultivation were the same as undisturbed pasture (1-19 kg N ha^–1). The effect of ploughing grassland for reseeding was relatively short-term, in contrast to the effect of repeated annual cultivation associated with arable rotations.     

Data transformations between soil texture schemes

Various soil texture schemes are in current use. These differ in the size ranges of their particle fractions. There is a need to establish simple methods to correlate these conventional schemes. Therefore I have defined closed-form exponential and power law functions to fit models to cumulative particle-size distribution data. I have tested the functions for their suitability (i) to represent cumulative particle-size distribution curves and (ii) to transfer data between distributions that differ in the size ranges of the particle fractions. I found that closed-form exponential functions adequately represent the cumulative particle-size distributions of fine-textured soils (clay, silty clay, silty clay loam, clay loam, silt loam and loam texture), whilst closed-form power functions better describe the cumulative particle-size distributions of coarse-textured soils (sand, loamy sand, sandy loam, sandy clay and sandy clay loam texture). The functions defined are found to be suitable to transfer data between different texture schemes. The use of this approach is illustrated by examples of data transformations between three widely used soil texture schemes: ISSS, Katschinski's and USDA.     

Effects of Selected Surfactants on Nutrient Uptake in Corn (Zea mays L.)

Surfactants in herbicide formulations eventually enter soil and may disrupt various processes. Research examined effects on nutrient uptake in corn caused by surfactants, herbicides, and surfactant-herbicide combinations applied to silt loam and silty clay loam soils in the greenhouse. Surfactants evaluated were Activator 90, Agri-Dex, and Thrust; herbicides were glyphosate, atrazine, and bentazon. Corn was planted in fertilized soils with moisture content maintained for optimum growth. Foliage (V8 growth stage) was collected for elemental analyses. Nutrient uptake differed with soil texture. Nutrient uptake from silty clay loam was more affected by surfactants and/or herbicides than in silt loam. Potassium uptake was significantly (P = 0.05) decreased in silt loam only by Thrust but uptake of phosphorus (P), potassium (K) calcium (Ca), sulfur (S), copper (Cu), and zinc (Zn) decreased by ≤30% in silty clay loam treated with surfactants. Surfactants and/or herbicides may interact with soil texture to affect nutrient uptake. Long-term field studies to validate changes in nutrient uptake and grain yields after annual applications of surfactants plus herbicides are needed.     

Effect of Select Surfactants on Activities of Soil Enzymes Involved in Nutrient Cycling

Experiments were conducted to investigate the impact of commonly used herbicides and surfactants on the activity of acid phosphatase, β-glucosidase, arylsulfatase, β-glucosaminidase, and dehydrogenase, using two soils (silt loam and silty clay loam) from Mid-Missouri, USA. The surfactants used in this study were alkylphenol ethoxylate + alcohol ethoxylate (ACTIVATOR 90), polyethoxylate (Agri-Dex®) and a blend of ammonium sulfate, drift reduction/deposition polymers, and an antifoam agent (THRUST®). The herbicides were glyphosate, atrazine, and bentazon. Surfactants and herbicides were applied to soils at the label rate, either alone or combined. In general, enzyme activity was enhanced more in silt loam soil than in silty clay loam soil. Acid phosphatase displayed the greatest amount of enzymatic activity within soils; dehydrogenase displayed the most inhibition, whilst β-glucosidase and β-glucosaminidase fluctuated based on treatment. ACTIVATOR 90 appeared to have the most inhibitory effect on enzymatic activity within soils compared to the control.