Humus status and distribution of the underground phytomass in eroded chernozems of the Cis-Salair region

It is shown that humus loss may reach 1.7 t/ha per year as a result of plowing of leached chernozems and erosion development. Distribution of underground phytomass in uneroded and eroded chernozems and slightly aggraded meadow-chernozemic soils of dissected areas in the Cis-Salair region is analyzed. It is shown that an increase in the degree of soil erosion is accompanied by a decrease in the total phytomass reserves, whereas the average depth of the root zone increases.     

Specific features of soil formation in the taiga zone of Western Siberia

Specific features of soil formation in the taiga zone of Western Siberia are considered. The polygenetic nature of podzolic and gley-podzolic soils in the middle taiga zone, soddy-podzolic and soddy gley soils in the southern taiga zone, and meadow soils in the subtaiga zone is related to the pre-Holocene transformation of the lithogenic matrix upon activation of denudation and accumulation processes and the complicated Holocene evolution of these soils. A soil profile can be subdivided into separate layers according to the geomorphic features of the cryogenesis, the indices of interruption of soil formation, and the differences in the composition of the organic matter in the relict and modern humus horizons.     

Transformation of soil organic matter in leached chernozems under minimized treatment in the forest-steppe of West Siberia

Changes in the contents of total organic carbon and the carbon of easily mineralizable fractions of organic matter (labile humus, detritus, and mortmass) in the layers of 0–10, 10–25, and 0–25 cm were studied in leached chernozems ((Luvic Chernozems (Loamic, Aric)) subjected to deep plowing and surface tillage for nine years. In the layer of 0–25 cm, the content of Corg did not show significant difference between these two treatments and comprised 3.68–3.92% in the case of deep plowing and 3.63–4.08% in the case of surface tillage. Tillage practices greatly affected the distribution of easily mineralizable fractions of organic matter in the layers of 0–10 and 10–25 cm, though the difference between two treatments for the entire layer (0–25 cm) was insignificant. Surface tillage resulted in the increase in the contents of mortmass (by 59%), detritus (by 32%), and labile humus (by 8%) in the layer of 0–10 cm in comparison with deep plowing. At the same time, the contents of these fractions in the layer of 10–25 cm in the surface tillage treatment decreased by 67, 46, and 3%, respectively. The estimate of the nitrogen-mineralizing capacity made according to the data on the uptake of soil nitrogen by oat plants in a special greenhouse experiment confirmed the observed regularities of the redistribution of easily mineralizable organic matter fractions by the soil layers. In case of surface tillage, it increased by 23% in the layer of 0–10 cm; for the layer of 0–25 cm, no significant differences in the uptake of nitrogen by oat plants were found for the two studied treatments.     

The formation of the humus profile of chernozems in the Azov province

The regularities of the formation of the humus profiles in chernozems of the Azov province (“priazovskii chernozems”) were revealed from studying the paleosols of burial mounds (archeological monuments) of the Bronze Age, Early Iron Age, and Middle Ages. The principal differences in the geneses of different parts of the humus profiles were revealed. From 40 to 70% of the current humus reserves in the 1-m-thick layer were shown to be accumulated by the late 3rd and early 2nd millennia BC. In the following 4000 thousand years, the development of the upper soil layers was cyclic. In favorable climatic periods, the humus content increased and accumulation processes predominated. Under aridization, the humus mineralization was intensified, the humus content decreased to 3%, and its reserves did not exceed 18 kg/m². The fluctuations in the humus reserves in the past were not higher than 30% as compared to the recent reference soils. They were most actively replenished from the 1st to the 8th centuries A.D., and the rate of this process reached 0.5 kg/m² for 100 years. In the same period, the thickness of the layer with the humus content above 1% drastically increased. The illuviation of peptized organic matter and its further bioturbation upon the development of the solonetzic process had the greatest importance in the formation of the lower part of the humus profiles.     

Agrochemical assessment of bog phosphates in Western Siberia

Bog phosphates of Western Siberia were characterized; the agrochemical properties of vivianite in peat deposits were studied, and its positive effect on the phosphate pool of zonal soils was revealed. A high and prolonged effect of peat vivianite on the main agricultural crops was experimentally proved. It was shown that the wide use of bog phosphates as fertilizers offers much promise for the regional agriculture.     

Modern Hydromorphism of Solonetzes in the Forest-Steppe Zone of Western Siberia

Eurasian Soil Science - Soil salinization and alkalization is an acute problem in Western Siberia because of the rise of saline groundwater above the critical level. We studied modern hydromorphism...     

Biological mineralization of organic matter in the modern virgin and plowed chernozems,buried chernozems,and fossil chernozems

The phenomenon of mineralization (biological mineralization) of organic matter in chernozems has been studied. A decrease in the content of C_org with time can be considered an index of the organic matter mineralization. It is suggested that the humus horizons of modern chernozems contain the pools of organic matter of different ages: easily decomposable organic matter, labile biologically active humus, stable biologically active humus, and relatively inert humus. The composition and mean residence times of these pools and their contribution to the total organic matter content have been estimated. The particular types of the biological mineralization have been determined on the basis of the comparison between the velocities of mineralization (M) and humification (H) processes: total unidirectional mineralization (M ≫ H), equilibrium mineralization (M ∼ H), nonequilibrium mineralization (M> <H), and zero mineralization. The separation of subtypes is based on data on the relative rates (%) of the organic matter mineralization. On the basis of available experimental data on chernozems buried under kurgans and in loess sediments (with the age of up to 800 ka), the quantitative relationship of the humus content in the buried soils on their age has been found; it has an exponential shape. During the first 100 ka after the soil burial, the soil humus content gradually (with a slowing intensity) decreases from 100–75 to 6.5% of its content in the virgin chernozems. Then, 100–1000 ka after the soil burial, the soil humus content remains approximately constant (6.5% of the initial level, or 0.3% of the soil mass). The rates of mineralization have been estimated. It is shown that the elemental composition (C, H, N, O) of humic acids remains relatively stable for a long time due to the regeneration of the chemical structure of humus (matric restoration of humus). It is suggested that several different forms of humus related to pedogenesis should be distinguished in the biosphere. The renewable humus in the equilibrium state with the environment is typical of the open biospheric (soil) systems. The fossil humus, whose content decreases with time, and whose composition remains stable, is typical of the semiclosed and closed systems. With time, it transforms into residual humus, whose content and composition remain stable. The fossilized organic matter in the fossil soils and sediments of the past geological epochs (Mesozoic and Paleozoic) considerably differs from the renewable, fossil, and residual humus.     

The humus formation and humus in forest-steppe and steppe chernozems of the southern Cisural region

The ecological features of the humus formation in typical, ordinary, and southern chernozems of the Orenburg Cisural region were considered. The fractional-group composition and amphiphilic properties of the forest-steppe and steppe chernozem subtypes were studied in relation to the dynamics of the hydrothermal regime, the vegetation, and the biological (enzymatic) activity of these zonal soils. The particular properties of the humus in virgin and arable landscapes were established. Arguments were presented for the probable existence of a genetically controlled relationship between the fractional-group composition of the humus and its amphiphilic properties     

Iron oxidation in different types of groundwater of Western Siberia

Background, aim, and scope  The groundwaters of Western Siberia contain high concentrations of iron, manganese, silicon, ammonium, and, in several cases, hydrogen sulfide, carbonic acids, and dissolved organic substances. Generally, the groundwaters of Western Siberia can be divided into two major types: one type with a relatively low concentration of humic substances and high hardness (water of A type) and a second type with a relatively low hardness and high concentration of humic substances (water of B type). For drinking water production, the waters of A type are mostly treated in the classical way by aeration followed by sand bed filtration. The waters of B type often show problems when treated for iron removal. A part of iron practically does not form the flocs or particles suitable for filtration or sedimentation. The aim of this work was to determine the oxidizability of Fe(II), to characterize the iron colloids, and to investigate the complexation of the iron ions with humic substances and the coagulation of the iron colloids in the presence of dissolved organic matter. Materials and methods  Water samples of the A and B types were taken from bore holes in Western Siberia (A type: in Tomsk and Tomsk region, B type: in Beliy Yar and Kargasok). Depth of sampling was about 200 m below surface. The oxidation of the groundwater samples by air oxygen and ozone was done in a bubble reactor consisting of a glass cylinder with a gas-inlet tube. To produce ozone, a compact ozone generator developed by Tomsk Polytechnic University was used. For the characterization of the colloids in the water of B type, the particle size distribution and the zeta potential were measured. To investigate the formation of complexes between iron and humic substances in the water of B type, size exclusion chromatography was used. The coagulation behavior of iron in the presence of dissolved organic substances was investigated at different pH values. The agglomerates were detected by measuring the optical density using a UV-Vis spectrometer. Results  Ozone showed, as expected, a faster oxidation of Fe(II) than air oxygen. The rate constants for Fe(II) oxidation were not much different for the waters of A and B types when the same oxidation process was used. However, the removal of iron after oxidation and filtration was higher in the water of A type than in the water of B type. No evidence for the formation of soluble complexes between iron and humic substances were found. In the water of A type, the coagulation process started at pH = 4.5 and accelerated with increasing pH value. In the water of B type, the coagulation of colloids occurred only at pH = 11 and higher. Discussion  The oxidation experiments indicated no major effect of dissolved organic carbon concentration on the kinetics of Fe(II) oxidation. In contrast to this, the humic substances showed a significant influence on the aggregation behavior of the iron hydroxide colloids. Due to the sorption of humic substances on the iron hydroxide colloids, they were highly stable in the pH range between 4.5 and 10. The particle size measurements confirmed the presence of small colloids in the water of B type. In contrast to this, the iron hydroxide colloids aggregated rapidly at pH = 11. Conclusions  The results showed a great influence of humic substances on the iron removal from groundwaters of Western Siberia with high organic content. The sorption of humic substances on the iron colloids does not obviously allow their coagulation and formation of flocs suitable for filtration or sedimentation. Recommendations and perspectives  By treatment of groundwaters containing high amounts of humic substances, some problems with the removal of iron are likely to occur. To increase the effectiveness of iron removal, the surface coating and pH-dependent charge effects should be taken into account by the selection and optimization of water treatment processes. The iron colloids coated by humic substances should be separated from the water phase by membrane filtration or by flocculation followed by filtration through different solid materials.     

Distribution of calcium in peat deposits of the central part of Western Siberia

Distribution patterns of calcium in peat deposits of seventeen bogs in the middle and southern taiga of Western Siberia have been studied. Four types of Ca distribution patterns related to the genesis of peat deposits are specified. Up to three Ca-enriched peat layers are distinguished in thick deposits. This Ca distribution pattern is typical of different peat deposits formed under various conditions. It is shown that Ca accumulation in particular layers of peat deposits is related to the warm stages of the Holocene.     

Multiparametric analysis of soil properties in the drained forest bogs of Western Siberia

The application of multiparametric statistical methods has confirmed that peat soils are different in the degree of their drainage and properties because of their modification during a 20–25 year period of artificial drainage operation. The following sequence represents the relative significance of the contribution to the soil changes of the parameters studied: groundwater table > air capacity > pH > ⁰T > Eh > water-soluble: C > Fe³⁺ > NH ₄ ⁺ and the activity of soil oxidoreductases in the following sequence: peroxidase > catalase > dehydrogenase. The necessity to supplement the substantive-genetic principle of the classification of drained peat soils with characterization of their water regime is substantiated.     

Soil formation in the technogenic forest-steppe landscapes of the Nazarovskaya Depression in western Siberia

The soil formation was studied in the 21- to 35-year-old pine plantations created on the overburden dumps of the Nazarovskaya Depression without applying the material of the humus horizon. The surface technogenic formations under the pine plantations belong to the group of naturfabricats (surface formations devoid of the humus horizon and composed of natural substrate). The morphological characteristics, bulk chemical and particle-size compositions, and labile properties of the soils indicate that the accumulation and transformation of organic matter are dominant processes in the artificially planted forests. The accumulation of organic residues and destruction and humification are tightly related to the environmental conditions transformed by the technogenesis and conceal other processes forming the soil profiles. Quasizems created for agricultural production purposes were the objects of the study. They were formed by covering the technically planned overburden rocks with the material of humus layers. The thickness of the humus horizons of the quasizems varies greatly (25–64%); the variation of the humus reserves in them is 34–122%. Middle-profile horizons have not been formed by the present time.     

Nonhydrolyzable residue in humus of chernozems

Mismanagement of chernozems results in a decreasing humus content at the expense of the carbon of the nonhydrolyzable residue (the humin fraction). This conclusion is proved by the original data obtained by the authors and by other scientists. It is also shown that the newly formed humus is dominated by the carbon of nonhydrolyzable residue. These facts attest to the presence of labile humus compounds subjected to mineralization in the humin fraction of chernozems.     

Temperature Sensitivity of Soil Respiration in Palsa Peatlands of the North of Western Siberia

Eurasian Soil Science - Palsa peatland soils are known as significant terrestrial storage of the Earth’s soil carbon. The response of these soils to changing climate may result in a strong...     

Diversity of clay minerals in soils of solonetzic complexes in the southeast of Western Siberia

Data on the mineralogical composition of clay in soils of solonetzic complexes of the Priobskoe Plateau and the Kulunda and Baraba lowlands have been generalized. The parent materials predominating in these regions have loamy and clayey textures and are characterized by the association of clay minerals represented by dioctahedral and trioctahedral mica–hydromica, chlorite, kaolinite, and a number of irregular interstratifications. They differ in the proportions between the major mineral phases and in the qualitative composition of the minerals. Mica–hydromica and chlorites with a small amount of smectitic phase predominate on the Priobskoe Plateau and in the Kulunda Lowland; in the Baraba Lowland, the portion of mica–smectite interstratifications is higher. An eluvial–illuvial distribution of clay fraction in solonetzes is accompanied by the acid–alkaline destruction and lessivage of clay minerals, including the smectitic phase in the superdispersed state. This results in the strong transformation of the mineralogical composition of the upper (suprasolonetzic) horizons and in the enrichment of the solonetzic horizons with the products of mineral destruction; superdispersed smectite; and undestroyed particles of hydromica, kaolinite, and chlorite from the suprasolonetzic horizons. A significant decrease in the content of smectitic phase in the surface solodic horizons of solonetzic complexes has different consequences in the studied regions. In the soils of the Priobskoe Plateau and Kulunda Lowland with a relatively low content (10–30%) of smectitic phase represented by chlorite–smectite interstratifications, this phase virtually disappears from the soils (there are only rare cases of its preservation). In the soils of the Baraba Lowland developed from the parent materials with the high content (30–50%) of smectitic phase represented by mica–smectite interstratifications, the similar decrease (by 10–20%) in the content of smectitic phase does not result in its complete disappearance. However, the smectitic phase acquires the superdispersed state and the capacity for migration.     

Background Contents of Heavy Metals in Soils and Bottom Sediments in the North of Western Siberia

Eurasian Soil Science - Background concentrations of heavy metals (Cu, Zn, Ni, Co, Fe, Mn, Cr, Pb, Hg, Cd, Ba, Sr, and Sc) in soils and bottom sediments were determined for the background and...     

Changes in acidity parameters of chernozems in the Kamennaya Steppe

The analysis of long-term data on the acidity parameters of chernozems in the Kamennaya Steppe indicated a tendency for some alkalization of the soils.     

Influence of Land Use on the Physical Properties of Chernozems in the Forest-Steppe Zone of Western Siberia

Eurasian Soil Science - The land use type and agricultural practices significantly affect the aggregate state and many physical properties of soils. In this study, we provide a comparative...     

Impact of reclamation treatment on the biological activity of soils of the solonetz complex in Western Siberia

The abundance and activity of the soil microflora were studied in a field experiment with the use of green manure crops to assess the impact of reclamation measures on the biological activity of soils of the solonetz complex. The number of microorganisms in the plow soil horizon increased in the background of the green fallows as compared to the black ones. Coefficients of mineralization, immobilization, and transformation of organic compounds were calculated for different variants of the soil treatment. The value of the mineralization coefficient indicates the intense decomposition of the green manure that entered the soil. In the first year, peas were actively decomposed, while oats, in the second year (aftereffect). The activity of the soil enzymes (invertase, urease, and catalase) was determined. A close relationship between the catalase activity and the intensity of the microbiological processes in the soils was revealed.