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阳离子分散松香施胶剂施胶性能的研究 总被引:6,自引:1,他引:5
阳离子分散松香施胶剂(CDRS)作为松香系列施剂的新型换代产品之一,其施胶性能是评价其应用价值的重要依据。本研究对自制的CDRS在不同条件下的施胶效果进行了试验并与现有的商品松香施胶剂进行了对比。中碱性条件一的施胶试验结果表明,CDRS相对阴离子分散松香胶而言,消耗助留剂硫酸铝的量约低50%,而且在PH6.5-7.5条件下具有较好的施胶效果。 相似文献
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用苯乙烯、丙烯酸酯与甲基丙烯酸二甲胺乙酯或二甲基二烯丙基氯化铵的共聚物作乳化剂分别制备了叔胺型阳离子分散松香施胶剂(SYM-1)和季铵型阳离子分散松香施胶剂(JYM-1),并比较了它们的施胶性能。实验结果表明,叔胺型高分子表面活性剂(SYS-1)的电荷密度和SYM-1的施胶性能受pH值影响较大,SYM-1的施胶度在相同施胶条件下比JYM-1大10 s以上,但在含碳酸钙抄纸体系中失去其施胶性。季铵型高分子表面活性剂(JYS-1)的电荷密度不受pH值的影响,用硫酸铝和聚乙烯胺复合物作定着剂时JYM-1在含碳酸钙抄纸体系中的施胶度大于5 s。 相似文献
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松香酸酯用于中性施胶的研究 总被引:3,自引:0,他引:3
合成了4种松香酯用于中性施胶。探讨了松香酯结构与施胶性能的关系,研究了施胶条件对香酯施胶效能的影响。松香酯在中,碱性条件下表现了优良的施胶效率。 相似文献
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松香酰胺在中性造纸施胶中的应用 总被引:2,自引:0,他引:2
利用松香与异腈酸的酰经反应在100-150℃下合成了三个松香酰胺,并应用它们到中性造纸松香乳酸,PH4-8的抄造试验表明这些松香衍生物在这个PH范围内具有高的施胶效果。松香酰结构与酰胺化度对施胶效果有很大的影响。 相似文献
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阳离子型分散松香胶制备的初步探索 总被引:21,自引:2,他引:19
松香中添加适量的助乳剂和新型乳化剂可以使松香充分的乳化。在常压依靠机械作用转相,可得到阳离子型分散松香的胶体乳液。在近中性条件下用于纸张施胶,施胶度良好,纸张的耐久性明显优于酸性施胶的纸张。 相似文献
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阳离子型分散松香施胶剂HPCRZ的研究 总被引:3,自引:0,他引:3
自德国的Illig发明松香皂-铝矾的施胶体系以来,纸张的浆内施胶和松香用作施胶剂已有近200年历史,虽然解决了纸张“洇水”的问题,但同时由于在酸性条件下施胶,也带来了成纸耐久性差、设备腐蚀较严重等问题(Kulick,1977;陈蕴智等,2001)。近些年,由于中碱性造纸与酸性造纸相比较具 相似文献
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根据多种松香化合物及松香施胶剂的热分解谱图信息,详尽地探讨了热分解气相色谱与四甲基氢氧化铵(TMAH)联用方法对纸中松香类施胶剂及其成分含量的定量测定。结果表明该方法作为定量分析法方便可靠。本文还提出了有关中性松香施胶剂中松香酯成分由于TMAH作用而产生的酯交换问题及其解决办法。在其热分解过程中,松香酯的结构对其酯交换的程度有着显著的影响,热分解产生的烃基正碳离子越稳定的松香酯就越容易发生酯交换。另外,在分析探讨的基础上成功地测定了多种不同商品松香施胶剂于不同施胶条件下在纸中的助留情况。 相似文献
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DRS—1高分散松香胶分散剂的合成及应用研究 总被引:3,自引:1,他引:2
合成了碘基琥珀酸AEO-9单酯二钠盐,表征了其结构和性质,并将其用作松香分散剂,在中、低转速搅拌和戒严用硬水转相,制备了固含量高「(45±2)%」、粒度小(0.1-0.5μm≥90%)、稳定性好的松香分散胶。 相似文献
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Preparation and sizing mechanisms of neutral rosin size II: functions of rosin derivatives on sizing efficiency 总被引:1,自引:0,他引:1
Four rosin derivatives, including rosin esters and rosinamides, were synthesized and used to prepare neutral rosin sizes. Their effects during sizing are discussed in detail. Compared to natural rosin, the rosin derivatives had nearly no effect on sizing even at high retention levels in paper. However, the rosin derivatives in the rosin sizes improved the stability of the emulsion size particles, and there was good correlation between the sizing effect and the stability of the emulsion sizes under neutral to alkaline conditions. On the other hand, the structure of the rosin derivatives significantly influenced the stability and sizing effect of the neutral rosin sizes. In particular, for glycerin rosin ester-rosin sizes, the emulsion stability and sizing effect increased with an increasing proportion of dirosinate, among the glycerin rosin esters. Consequently, it was suggested that the rosin derivatives hardly contribute to the sizing performance of paper but predominantly function to stabilize the neutral rosin size particles, thereby improving the efficiency of the size under neutral to alkaline sizing conditions. Also it was supposed that glycerol dirosinate in the neutral rosin size would probably enable formation of a more stable particle structure to prevent the destructive action of the OH– ion.This research was presented in part at the 48th annual meeting of the Japan Wood Research Society, Shizuoka, April 1998 相似文献
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以塔尔油为主要原料,研究制造纸用施胶剂的配方及生产工艺条件,该施胶剂可代替松香用于造纸浆内施胶,并对施胶工艺条件进行了探讨。 相似文献
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Application of cationic polymer prepared from sulfuric acid lignin as a retention aid for usual rosin sizes to neutral papermaking 总被引:3,自引:0,他引:3
Cationic polymers that acted as the retention aids for usual rosin sizes in neutral papermaking were prepared from sulfuric acid lignin (SAL), one type of acid lignin. To convert SAL to the cationic polymer (MP-SAL), SAL was phenolated and then treated by the Mannich reaction to introduce the amino groups. In the MP-SAL single system, MP-SAL exhibited high sizing effectiveness in neutral papermaking with the rosin emulsion size. However, MP-SAL showed no sizing effectiveness when soap rosin size was used. MP-SAL showed increased sizing effectiveness as the pK
a of the introduced amino group increased. From this and comparison of the sizing degrees of MP-SAL and polyethylenimine, which possesses a linear structure, it was suggested that the sizing effectiveness was not only affected by the charge density and molecular weight, but also by the basicity of the introduced amino groups and the molecular structure of the retention aid. In the alum–MP-SAL dual system, alum and MP-SAL synergistically enhanced the sizing effectiveness in the rosin emulsion sizing at neutral pH. In turn, this allowed a decrease in the MP-SAL dosage and resulted in a small decrease in brightness.Part of this report was presented at the 48th Lignin Symposium, October 2003, Fukui 相似文献