滨海废弃盐田复垦区土壤盐分和有机质的空间变异特征

为了揭示废弃盐田复垦区棉田土壤盐分和有机质的时空变化特征,该文利用棉花关键生长节点的土壤采样数据,采用经典统计学和地统计学相结合的方法,对土壤盐分和有机质的空间分布特征进行分析。结果表明:研究区不同时期不同深度的土壤含盐量和有机质含量变幅较大,二者的变异强度均为中等;随着时间的变化土壤含盐量和有机质含量均呈现下降的趋势,各层土壤含盐量与有机质含量相关性程度不高。研究区土壤含盐量与有机质含量均具有中等强度的空间自相关性。Kriging插值结果表明土壤有机质呈条带状分布,苗期和花期土壤有机质含量由西向东逐渐增加,花铃期土壤有机质含量以东北部含量最低,收获期有机质含量高值区主要集中在西北部和东南部。土壤含盐量的三维空间分布在不同时期不同深度具有相似性,其空间分布特征总体较为接近;苗期和花期土壤含盐量高值区出现在东南部方向;花铃期和收获期土壤含盐量空间分布比较散乱,呈斑块状分布。研究结果为莱州湾南岸盐田复垦区的盐渍土科学改良、合理利用及农业可持续发展提供技术支持。     

Soil organic matter, effects on soils and crops

Abstract. Manurial treatments and cropping history have remained unchanged for many years in classical and long-term experiments at Rothamsted and Woburn, in some cases for more than 100 years. Soil samples taken periodically have been analysed to follow changes in organic carbon content with time and treatment. Data presented here clearly show effects of carbon input and soil texture on equilibrium organic matter content.
Until recently increasing amounts of soil organic matter had little effect on yields of arable crops especially if fertilizer nitrogen dressings were chosen correctly. However the yield potential of many crops has increased and various agronomic inputs have become available to achieve that potential. Yields of many crops are now larger on soils with extra organic matter both on the sandy loam at Woburn and the silty clay loam at Rothamsted. Some of the effect appears to be related to extra water holding capacity, some to availability of nitrogen in ways which cannot be mimicked by dressings of fertilizer N, and some to improved soil physical properties. Responses to fertilizer N have been larger on soils with more organic matter.     

砒砂岩与沙复配土壤质地与有机质动态变化特征

为了研究毛乌素沙地砒砂岩与沙混合构成的一种新型复配土壤在长期种植过程中土壤质量发育状况,基于2010-2018年不同比例砒砂岩与沙(1∶1,1∶2,1∶5)复配土壤的田间定位试验,综合分析了不同比例复配土壤机械组成、颗粒分形特征、有机质的变化特征及之间的关系。结果表明:(1)随着种植年限的增加,3种比例复配土壤耕层质地向变细和颗粒组成合理的方向发展,土壤颗粒分形维数和有机质含量总体呈增加趋势;(2)1∶2复配土壤粉黏粒含量、分形维数值和有机质含量增加速率均大于1∶1,1∶5;1∶2复配土壤种植9年后有机质含量达到最高值(6.24±0.30)g/kg,与种植前相比较提高了12倍;(3)不同比例复配土壤颗粒分形维数与有机质含量均存在显著正相关关系(p<0.05),粉粒和黏粒是研究区沙化土地复配土壤质地改善和有机质提升最关键的两个粒级。综上,随种植年限的增加,复配土向无机-有机胶体复合状态发展,1∶2复配土壤最适合玉米种植,提高了土壤的稳定性和农业适应性。     

Biologically Active Organic Matter in Soils of European Russia

Experimental and literature data on the contents and stocks of active organic matter in 200 soil samples from the forest-tundra, southern-taiga, deciduous-forest, forest-steppe, dry-steppe, semidesert, and subtropical zones have been generalized. Natural lands, agrocenoses, treatments of long-term field experiments (bare fallow, unfertilized and fertilized crop rotations, perennial plantations), and different layers of soil profile are presented. Sphagnum peat and humus–peat soil in the tundra and forest-tundra zones are characterized by a very high content of active organic matter (300–600 mg C/100 g). Among the zonal soils, the content of active organic matter increases from the medium (75–150 mg C/100 g) to the high (150–300 mg C/100 g) level when going from soddy-podzolic soil to gray forest and dark-gray forest soils and then to leached chernozem. In the series from typical chernozem to ordinary and southern chernozem and chestnut and brown semidesert soils, a decrease in the content of active organic matter to the low (35–75 mg C/100 g) and very low (<35 mg C/100 g) levels is observed. Acid brown forest soil in the subtropical zone is characterized by a medium supply with active organic matter. Most arable soils are mainly characterized by low or very low contents of active organic matter. In the upper layers of soils, active organic matter makes up 1.2–11.1% of total C_org. The profile distribution of active organic matter in the studied soils coincides with that of C_org: their contents appreciably decrease with depth, except for brown semidesert soil. The stocks of active organic matter vary from 0.4 to 5.4 t/ha in the layer of 0–20 cm and from 1.0 to 12.4/ha in the layer of 0–50 cm of different soil types.     

县域尺度土壤有机质与土地利用动态耦合关系定位对比研究——以渭北旱塬区长武县为例

以陕西省长武县为研究区域,根据大规模采样数据,结合1983年和2008年土地利用空间数据,运用定位对比监测方法,分析了25年来不同土地利用变化的幅度、空间分布特征和方向,并对这种变化影响下的土壤有机质含量演化特征进行了研究。结果表明:该区土地利用方式在这一时期变化显著,旱地、草地、非农用地面积大幅减少,林地、果园面积大幅增加。土地利用方式的转变已经成为土壤有机质含量变化的驱动因素,其中,旱地转变为林地和果园,土壤有机质含量变化明显,分别增加了6.6 g/kg和5.11 g/kg,而林地转变为旱地和草地则无明显增量。土壤有机质含量的变化不仅改变了土壤结构,有效地控制了水土流失的发生,而且为该区域的土地利用方式朝着健康的方向发展,提供了参考价值。     

马颊河流域影响土壤盐渍化的几个因素的研究

本研究是根据马颊河流域区域水盐动态监测预报分区定量化的要求进行的室内模拟试验,采用了扰动土的土柱法。试验进行分干土柱的毛管水上升湿润锋的观测与湿土状态的蒸发两个阶段。共3个组合21个处理,在人为控制条件下,仅就地下水(潜水)矿化度、耕层土壤有机质、土体构型等三因素对土壤盐渍化的影响,进行了观测。试验表明:地下水矿化度与土壤积盐量之间存在着极显著的正相关;耕层有机质的含量在1.5%开始有明显的抑制土壤盐渍化的作用;明确了在有粘土夹层的土体中,不能以在风干土柱的毛管水上升速度来推测土壤表层返盐的快慢,而应以在湿润土时,土壤水的蒸发速度为依据。粘土夹层的抑盐作用是随其厚度的增加和层位的升高而加强。     

东北地区黑土硫的分布特征及其与土壤性质的关系

在兼顾土壤样点空间分布相对均匀的前提下,采集了中国东北地区具有代表性的黑龙江省北安市、海伦市和吉林省公主岭市的黑土样,对这些地区的黑土中硫素含量进行了分析。结果看出,不同地区黑土中全硫含量存在明显差异,其全硫含量依次为北安(北部黑土)海伦(中北部黑土)公主岭(南部黑土)。随剖面的加深,自上而下土壤全硫都呈下降的趋势,但在145cm深处升高。全硫在开垦前期呈下降趋势,随着开垦年限的增加,土壤全硫含量下降逐渐趋于平稳。相关分析表明,土壤全硫与土壤有机质等指标都达到了显著或极显著相关水平。黑土中三种形态有机硫含量占全硫含量的78％。     

Selenium retention in the organic matter of Swedish forest soils

Fractions of selenium present in the soil profiles of three Swedish podzols were analysed using a sequential extraction scheme to characterize Se distribution among the organic and inorganic fractions. The process by which selenite deposited from the atmosphere is retained in a podzolic profile rich in organic matter was studied in a column experiment. Selenium present in organic fractions accounted for most of the Se extracted by Na₄P₂O₇/NaOH. All soil organic matter fractions, particularly those in the B horizons, were considerably enriched with Se as compared with plant biomass. The most enriched fraction was that containing hydrophobic fulvates which had C to Se ratios ranging from 33 000 to 80 000. The distribution of Se among the organic fractions differed markedly from that of sulphur. Selenite applied to columns continuously for 67 d was fixed very rapidly upon entering the forest floor layers, with 77% being recovered in the top 2 cm of the forest floor after the experiment. In column leachates from the surface layers, C to Se ratios decreased progressively following Se application. No effect specifically related to Se application was observed for leachates and soil horizons underlying Bs1. The mechanism responsible for the efficient and rapid Se immobilization by organic matter is unknown.     

Seasonal changes in the content of dissolved organic matter in arable soils

Purpose

The aim of this paper has been to determine the seasonal changes in the content of dissolved organic matter (DOM) in the soils under agricultural use based on assaying changes in dissolved organic carbon (DOC) and dissolved nitrogen (DNt) as well as determining the factors which can define the DOM in soils.

Materials and methods

The research has involved the soils under agricultural use sampled in the Kujawsko-Pomorskie province (Poland). Phaeozems and Luvisols were sampled from the depth of 0–30, 30–60, and 60–100 cm, November 2011 through September 2013, in November, March, May, July, and September. The soil samples were assayed for the grain size composition, pH, dry weight content, content of total organic carbon, and total nitrogen. Dissolved organic matter was extracted with 0.004 mol dm³ CaCl₂; in the DOM extracts, the content of dissolved organic carbon (DOC) and dissolved nitrogen (DNt) were assayed. The research results were statistically verified.

Results and discussion

It has been demonstrated that in the first year of research, the content of dissolved organic carbon in the soils was changing throughout the year. The highest differences in the content of that carbon fraction occurred across the soil sampled in autumn and the soil sampled in spring. In the second year of research, an inverse dependence was noted. DOC was migrating to deeper layers of the soil profile; yet, the migration got more intensive in summer. The content of dissolved nitrogen was not changing significantly throughout the year. Higher DNt content in the surface layer, in general, resulted in a higher content of dissolved nitrogen in deeper profile layer, which could have been due to leaching of the nutrient deep down the soil profile.

Conclusions

The content of dissolved organic carbon was significantly related to the content of total organic carbon and total nitrogen. Significant changes in the content of dissolved forms of nitrogen were reported in the profile of Phaeozems due to mineral fertilization and irrigation. The soils where irrigation and higher nitrogen rates had been applied demonstrated a higher content and share of soluble forms of nitrogen, as compared with the soils non-irrigated and the soils where lower nitrogen rates had been supplied.

     

Organic carbon dynamics in soil particle-size separates of sandy Spodosols when forest is cleared for maize cropping

In southwest France, much of the forest lands on sandy Spodosols has been converted to continuous maize cropping in the last few decades. To evaluate the impacts of such change on the content and properties of the soil organic matter, we compared the amount of organic carbon and ¹³C natural abundance in soil and particle-size separates at three locations, selected on the basis of different contents of 0–50 μm particles (clay + silt). After three decades of cultivation, the amount of carbon from the forest pools ( C _f) decreased by about 60%, attributable mainly to easily degradable material in sand-sized fractions (−70%). However, a recalcitrant residue remained in soil at a constant proportion, showing that organic matter in these fractions is heterogeneous. Organic matter in the clay + silt fraction was relatively resistant, decreasing by only 20% after 30 years of cultivation. Intensive agricultural management has homogenized the characteristics of the soil and the mineralization of the organic matter, which has resulted in a long-term convergence of organic carbon from the three locations. However, small natural variations in fine particle content were associated with significant differences in the accumulation of carbon in soil. The protective capacity of the soil depended on the proportion of clay + silt fraction, which stabilized the organic matter. Furthermore, the degree of saturation of this fraction with original carbon from forest and its rate of decomposition determined the soil's capacity to accumulate newly added carbon derived from maize.     

Organic matter dynamics in a compost-amended anthropogenic landfill capping-soil

The application of municipal waste compost and other organic materials may serve to improve fertility and organic carbon (C) stocks of soils used in land reclamation activities, particularly in the recovery of degraded areas at exhausted quarries, mines and landfill sites amongst others. We investigated long-term organic matter dynamics in such anthropogenic soils by collecting samples at different depths over a 10-year chronosequence subsequent to compost application to the top layer of a landfill capping-soil. Variations in the stable isotope composition (¹³C and ¹⁵N) of the soil samples showed that, even after 10 years, amended topsoils were enriched in compost-derived organic matter. The addition of compost to the superficial layer also resulted in an input of soluble organic compounds that was subject to leaching along the soil profile. Sorption isotherms for compost-derived water-extractable organic matter onto mineral materials used for landfill covering suggest that sorptive preservation was primarily responsible for the increase in C content and the shift in the C isotopic signature to values similar to that of the applied compost, in the deeper soil horizons over the 10-year period. This was also confirmed by the accumulation of lignin-derived phenolic compounds in the deeper horizons. Nevertheless, analysis for non-cellulosic carbohydrates in soil samples and their respective water-extractable fractions suggest that a proportion of the compost-derived, labile organic matter fraction is leached through the profile and potentially lost from the soil system.     

连续施用不同比例鸡粪氮对水稻土有机质积累及土壤酸化的影响

【目的】土壤酸化是自然过程。随着农业集约化发展,土壤酸化在部分农田呈加速趋势,而施肥是目前农田土壤酸化加速的重要诱因,研究有机肥和化肥对土壤酸化的作用差异及机理,对合理指导施肥及耕地保育有重要的意义。【方法】通过测定不同施肥处理的不同组分有机质含量及酸碱缓冲容量,探明不同施肥处理的酸化影响,从土壤有机质和盐基累积角度对有机-无机肥料不同比例配施条件下土壤酸化特征进行了研究。【结果】① 连续5年在等氮量（N 270 kg/hm2）且有机－无机肥料不同配施比例的处理中,水稻产量以有机肥比例为25%~50%的处理最高,其平均产量比单施化肥处理提高了5.1%,比对照提高44.9%。但处理间无显著性差异;② 土壤各活性有机质及总有机质等指标中仅总有机质含量随鸡粪施用比例的增加而持续增加,不同比例有机无机肥配合施用后,土壤的高活性有机质及低活性有机质均高于CK和纯化肥氮处理,但随着有机肥投入比例的升高,除中活性有机质和水稻产量之间呈显著的正相关外（P=0.0067**）,高活性有机质、活性有机质及总有机质含量与水稻产量之间的相关性不显著（对应的概率值分别为P=0.192,P=0.208,P=0.160）;③ 施肥提高了土壤的碳库管理指数（CPMI）,且其随有机肥施用比例的上升呈增加趋势。增施鸡粪提高土壤的交换性盐基离子（Ca2+、 Mg2+、 K+、 Na+）含量,导致阳离子代换量（CEC）和pH随鸡粪施用比例的提高而升高。供试土壤酸碱缓冲容量为2.07~2.36 cmol/kg,随鸡粪施用比例的上升而增加,其与土壤阳离子代换量及有机质含量呈显著正相关。表明增施鸡粪可使土壤pH及酸碱缓冲容量上升,与鸡粪使土壤盐基累积量及有机质含量的提高有关。【结论】连续有机-无机肥施用下,土壤pH上升和酸碱缓冲容量的提高可能与该试验点下盐基离子和有机质含量随鸡粪施用比例上升有关,但其最终上升幅度及平衡点尚需进一步研究。鸡粪氮替代化肥氮比例为25%~50%时,土壤性质最优,水稻产量最高。     

基于灰度关联-岭回归的荒漠土壤有机质含量高光谱估算

为改善高光谱技术对荒漠土壤有机质的估测效果,该文采集了以色列Seder Boker地区的荒漠土壤,经预处理、理化分析后将土样分为砂质土和黏壤土2类,再通过光谱采集、处理得到6种光谱指标:反射率(reflectivity,REF)、倒数之对数变换(inverse-log reflectance,LR)、去包络线处理(continuum removal,CR)、标准正态变量变换(standard normal variable reflectance,SNV)、一阶微分变换(first order differential reflectance,FDR)和二阶微分变换(second order differential reflectance,SDR)。通过灰度关联(gray correlation,GC)法确定SNV、FDR、SDR为敏感光谱指标,采用偏最小二乘回归(partial least squares regression,PLSR)法和岭回归(ridge regression,RR)法,构建基于敏感光谱指标的土壤有机质高光谱反演模型,并对模型精度进行比较。结果表明:砂质土有机质含量的反演效果要优于黏壤土;基于SNV指标建立的模型决定系数R~2和相对分析误差RPD均为最高、均方根误差RMSE最低,所以SNV是土壤有机质的最佳光谱反演指标;对SNV-PLSR模型和SNV-RR模型综合比较得出,SNV-RR模型仅用全谱4%左右的波段建模,实现了更为理想的反演效果:其中,对砂质土有机质的预测能力极强(R_p~2为0.866,RMSE为0.610 g/kg、RPD为2.72),对黏壤土有机质的预测能力很好(Rp2为0.863,RMSE为0.898 g/kg、RPD为2.37)。荒漠土壤有机质GC-SNV-RR反演模型的建立为高光谱模型的优化、土壤有机质的快速测定提供了一种新的途径。     

沙地整治下榆林土地利用及土壤有机质时空分异特征

毛乌素沙地是典型的生态脆弱区,近年来针对其在榆林境内的沙地整治利用取得显著成效,也对土壤环境产生了深刻影响。为了探究沙地不同整治利用方式对土壤有机质的影响,该研究选取榆林市显性沙地,利用多光谱遥感影像及相关光谱指数,结合沙地土地利用变化特征,通过XGBoost机器学习方法,反演1990—2020年土壤有机质含量;分析不同土地类型下土壤有机质含量变化,通过半变异函数揭示了其空间变异性,厘清人为因素和自然环境的影响程度。结果表明,30 a间榆林5 460 km2沙地中超过半数得到整治和利用,沙地-草地是最主要的地类转变方式,建设用地面积增长最迅速;沙区土壤有机质含量上升,但整体呈现先增加后降低的趋势,有机质均值由0.34%增长至0.79%,近10年降低至0.51%;榆林沙区土壤有机质具有较强的空间自相关性。起初,人为利用对其有积极作用,但随着沙地的利用强度增大,对土壤有机质产生负向作用,进而致使其含量下降,面临土地退化危机。建议加强退化林草的修复改良,放缓建设用地开发力度,研究以期为沙地整治提供理论和实践借鉴意义,保护榆林沙地土壤环境安全。     

全球黑土区土壤有机质变化态势及其管理技术

黑土富含有机质,适宜耕种,具有极高作物生产潜力。黑土耕地是重要农业自然资源与主要的粮食生产基地。随着我国黑土大规模开发、高强度利用、不合理的田间管理措施以及水土流失导致其耕地地力呈现不断下降的态势,突出表现就是土壤有机质含量的降低,给东北黑土区农业可持续发展带来隐患,直接影响粮食安全和生态安全。因此,深入了解全球黑土有机质变化态势,采取科学、有效的田间管理措施,建立黑土生态保护机制,遏制黑土耕地土壤有机质含量不断下降的趋势,既是农业生产实际的客观需求,也是农田生态学需要解决的科学问题。本文根据近年来国内外黑土有机质的文献资料,参考了国外黑土有机质研究前沿进展,对黑土耕地有机质的利用现状、演变过程和发展趋势进行了深入剖析,总结了黑土区耕地土壤有机质保持与提升技术措施,并提出未来我国黑土耕地农业生产与生态保护兼顾的技术路线。     

Influence of afforestation on soil genesis,morphology and properties in glacial till deposits

A study of soil morphological, physical and chemical properties was performed in woodland of different ages, in which spruce (Picea abies), aspen (Populus tremula) and birch (Betula pendula) growing stocks have colonized former agricultural land. The aim of the study was to clarify changes in soil genesis, morphology and properties due to the afforestation of abandoned agricultural land in glacial till deposits. The research showed that soil in these deposits (loamy sand, loam, clay) retains the morphological properties of agricultural land for up to 100 years. Secondary podzolization features in the soil profiles were observed within 100 years of the start of afforestation, whereas the diagnostic properties of Albic and Spodic horizons had not developed in the soil profile after 200 years. This study demonstrated that the morphological and physico-chemical properties of forest litter horizons, including the accumulation of organic substances, are dependent on forest age; however, changes in the properties of mineral soil horizons are mainly related to woodland age. Following the afforestation of agricultural lands, changes in soil pH_KCl, organic matter content and extractable Al and Fe concentrations occur more rapidly than changes in soil diagnostic properties and profile formation.     

坡面尺度土壤特性的空间变异性

通过对20m长坡面土壤特性空间变异性的经典统计学分析,结果表明:(1)在同一土壤剖面内,各级粒径含量呈弱变异性,而有机质含量随土层深度的增大而逐渐降低,呈中等变异性;(2)土壤干容重的空间变异性较小,呈弱变异性,但土壤饱和导水率的空间变异性较大,呈中等变异性;(3)水分特征曲线具有一定的空间变异性,比水容量空间变异性较大,呈中等变异性。坡面土壤饱和导水率和干容重的等值线图表明,土壤饱和导水率的变化趋势并不仅仅取决于土壤干容重的相对大小,可能与有机质含量、黏粒含量以及根系分布情况等也有一定的关系。     

植茶年限对土壤pH值、有机质与酚酸含量的影响

土壤pH值和有机质是土壤肥力的重要指标,土壤中的酚酸类物质也是一类重要的有机物质,与pH值和有机质关系复杂。本文以四川省名山区茶园土壤为对象,研究植茶年限对土壤pH值、有机质和酚酸含量的影响,并探讨它们之间的相互关系。结果显示:随着植茶年限的延长,各土层土壤的pH值均呈现不同程度的下降趋势,即植茶10年植茶7年植茶5年植茶3年水稻土,表层土壤酸化明显;随着植茶年限的延长,土壤有机质、总酚和水溶性酚含量均呈增加趋势。相关分析表明,0~10 cm土层土壤中,总酚与土壤pH值呈负相关;10~20和30~40 cm土层土壤中,水溶性酚与土壤pH值呈负相关;10~20 cm土层土壤中,总酚与土壤有机质呈正相关;在10~20、20~30和30~40 cm土层土壤中,水溶性酚与土壤有机质呈正相关。说明植茶土壤酚酸含量的增加是影响土壤pH值下降和有机质含量升高的重要因素。     

Effects of drying and wetting on extractable aluminum in strongly acid soils and in aluminum-saturated clays

A number of field-moist strongly acid soils, NaObr-treated soils, and Al-saturated clays were subjected to drying and wetting treatments in the laboratory. Oven drying of samples resulted in decreases in extractable Al and increases in extractable H from field-moist soils containing more than 12 mequiv./100 g exchange acidity and from Al-saturated clays, and wetting the samples resulted in the reverse. However, when field-moist soil samples containing less than 7 mequiv./100 g exchange acidity were oven dried, both the extractable Al and extractable H tended to increase. Removing organic matter with NaOBr from a soil sample low in exchange acidity resulted in a change from an increase to a decrease in extractable Al upon oven drying. In all cases, the extractable Al and extractable H contents fluctuated cyclically with repeated drying and wetting. The cause for the observed changes was attributed to Al hydrolysis, with additional influence from soil acidity buffering, Al interlayer formation, and inorganic and organic matter dissolution.     

Soil development along primary succession sequences on moraines of Hailuogou Glacier,Gongga Mountain,Sichuan, China

Soil properties related to soil development were measured in six profiles over approximately 180 years of soil development on recessional moraines of the Hailuogou Glacier, Sichuan of southwestern China. It is hypothesized that soil development is strictly time-dependent. Field and laboratory work indicate that as soil develops from initially coarse gravel outwash, the properties undergo a progressive physical and chemical change such that there is a considerable profile differentiation between the youngest and the oldest soils. The pH is also highly stratified; it decreases with time from 8.5 to 4.2 in the upper mineral soil and increases with depth in all profiles. Accumulation of soil organic C and N increases with time but the rates of accumulation become slower with time. Within the investigated timespan, soil C and N accumulated to a considerable level of 3.5 and 0.6 kg/m² respectively, with mean annual rates of 28 g/m² for carbon and 3.5 g/m² for nitrogen. The rapid accumulation of organic C and N accelerates the processes of soil formation, but the content of organic C and N did not reach a steady-state during the observed timespan. The accumulation of soil organic matter results in increased acid production and in the chemical weathering of minerals that promote formation and translocation of the clay fraction and leaching of carbonate; it is also directly responsible for development of soil properties such as cation exchange capacity (CEC), and bulk density.