Rocket ultraviolet spectrophotometry of comet kohoutek (1973f)

Observations of Comet Kohoutek (1973f) in the spectral region between 1200 and 3200 angstroms were made from an Aerobee rocket on 5.1 January 1974 universal time. The strongest features observed were the Lyman alpha line of neutral atomic hydrogen at 1216 angstroms and the hydroxyl (OH) bands at 3090 and 3142 angstroms. Atomic oxygen and atomic carbon were also detected, and their luminosity implies a production rate (of carbon monoxide or carbon dioxide) commensurate with that of water vapor.     

Pioneer 10 observations of the ultraviolet glow in the vicinity of jupiter

A two-channel ultraviolet photometer aboard Pioneer 10 has made several observations of the ultraviolet glow in the wavelength range from 170 to 1400 angstroms in the vicinity of Jupiter. Preliminary results indicate a Jovian hydrogen (1216 angstrom) glow with a brightness of about 1000 rayleighs and a helium (584 angstrom) glow with a brightness of about 10 to 20 rayleighs. In addition, Jupiter appears to have an extensive hydrogen torus surrounding it in the orbital plane of Io. The mean diameter of the torus is about equal to the diameter of the orbit of Io. Several observations of the Galilean satellites have also occurred but only a rather striking Io observation has been analyzed to date. If the observed Io glow is predominantly that of Lyman-alpha, the surface brightness is about 10,000 rayleighs.     

Mariner 6: ultraviolet spectrum of Mars upper atmosphere

Emission features from ionized carbon dioxide and carbon monoxide were measured in the 1900- to 4300-angstrom spectral region. The Lyman alpha 1216-angstrom line of atomic hydrogen and the 1304-, 1356-, and 2972-angstrom lines of atomic oxygen were observed.     

Apollo 16 far-ultraviolet camera/spectrograph: Earth observations

A far-ultraviolet camera/spectograph experiment was operated on the lunar surface during the Apollo 16 mission. Among the data obtained were images and spectra of the terrestrial atmosphere and geocorona in the wavelength range below 1600 angstroms. These gave the spatial distributions and relative intensities of emissions due to atomic hydrogen, atomic oxygen, molecular nitrogen, and other species-some observed spectrographically for the first time.     

Extreme ultraviolet observations from voyager 1 encounter with saturn

The global hydrogen Lyman alpha, helium (584 angstroms), and molecular hydrogen band emissions from Saturn are qualitatively similar to those of Jupiter, but the Saturn observations emphasize that the H(2) band excitation mechanism is closely related to the solar flux. Auroras occur near 80 degrees latitude, suggesting Earth-like magnetotail activity, quite different from the dominant Io plasma torus mechanism at Jupiter. No ion emissions have been detected from the magnetosphere of Saturn, but the rings have a hydrogen atmosphere; atomic hydrogen is also present in a torus between 8 and 25 Saturn radii. Nitrogen emission excited by particles has been detected in the Titan dayglow and bright limb scans. Enhancement of the nitrogen emission is observed in the region of interaction between Titan's atmosphere and the corotating plasma in Saturn's plasmasphere. No particle-excited emission has been detected from the dark atmosphere of Titan. The absorption profile of the atmosphere determined by the solar occultation experiment, combined with constraints from the dayglow observations and temperature information, indicate that N(2) is the dominant species. A double layer structure has been detected above Titan's limb. One of the layers may be related to visible layers in the images of Titan.     

Mariner 9 ultraviolet spectrometer experiment: initial results

The ultraviolet airglow spectrum of Mars has been measured from an orbiting spacecraft during a 30-day period in November-December 1971. The emission rates of the carbon monoxide Cameron and fourth positive bands, the atomic oxygen 1304-angstrom line and the atomic hydrogen 1216-angstrom line have been measured as a function of altitude. Significant variations in the scale height of the CO Cameron band airglow have been observed during a period of variable solar activity; however, the atomic oxygen and hydrogen airglow lines are present during all the observations. Measurements of the reflectance of the lower atmosphere of Mars show the spectral characteristics of particle scattering and a magnitude that is about 50 percent of that measured during the Mariner 6 and 7 experiments in 1969. The variation of reflectance across the planet may be represented by a model in which the dominant scatterer is dust that absorbs in the ultraviolet and has an optical depth greater than 1. The atmosphere above the polar region is clearer than over the rest of the planet.     

Structure of langmuir-blodgett films of disk-shaped molecules determined by atomic force microscopy

Monolayer Langmuir-Blodgett films of a discotic mesogen have been studied with atomic force microscopy (AFM). These measurements confirm the "edge on" arrangement for the disk-shaped molecules suggested by surface pressure-area isotherms and show that the molecules form columns that are separated by 17.7 angstroms +/- 10 percent. Column alignment is found to be predominantly along the film deposition direction, with an angular spread of 35 degrees . The AFM images also show that the mean disk separation within the columns is 5.1 +/- 1.3 angstroms, in good agreement with x-ray diffraction (XRD) results. Roomtemperature XRD measurements on bulk samples of the same material indicate a disordered-hexagonal liquid crystalline mesophase, with a column-to-column spacing of 19.9 +/- 0.2 angstroms.     

Ultraviolet spectrometer observations of neptune and triton

Results from the occultation of the sun by Neptune imply a temperature of 750 +/- 150 kelvins in the upper levels of the atmosphere (composed mostly of atomic and molecular hydrogen) and define the distributions of methane, acetylene, and ethane at lower levels. The ultraviolet spectrum of the sunlit atmosphere of Neptune resembles the spectra of the Jupiter, Saturn, and Uranus atmospheres in that it is dominated by the emissions of H Lyman alpha (340 +/- 20 rayleighs) and molecular hydrogen. The extreme ultraviolet emissions in the range from 800 to 1100 angstroms at the four planets visited by Voyager scale approximately as the inverse square of their heliocentric distances. Weak auroral emissions have been tentatively identified on the night side of Neptune. Airglow and occultation observations of Triton's atmosphere show that it is composed mainly of molecular nitrogen, with a trace of methane near the surface. The temperature of Triton's upper atmosphere is 95 +/- 5 kelvins, and the surface pressure is roughly 14 microbars.     

The Framework Topology of ZSM-18, a Novel Zeolite Containing Rings of Three (Si,Al)-O Species

ZSM-18 is the first known aluminosilicate zeolite to contain rings of three (Si,Al)-O species (3-rings). Its framework topology has been determined by hypothetical model building, subsequent constrained distance and angle least-squares refinements of atomic coordinates, and x-ray powder diffraction pattern simulations. Its channel structure is characterized by a linear unidimensional 12-ring channel, with an approximate pore opening of 7.0 angstroms. In addition, the channels are lined with pockets that are capped by 7-rings with dimensions of 2.8 angstroms by 3.5 angstroms. An intraframework packing model of the organic moiety used in the synthesis suggests that a strong templating effect may be responsible for the formation of this unusual zeolite structure.     

Ultraviolet observations of venus from mariner 10: preliminary results

An objective grating spectrometer on Mariner 10 has measured air-glow in the wavelength range 200 to 1700 angstroms. The data reveal the presence of significant concentrations of hydrogen, helium, carbon, and oxygen atoms in the upper atmosphere of Venus. A preliminary analysis of the hydrogen data indicates an exospheric temperature of 400 degrees K. There is evidence for intense air-glow emission at wavelengths longward of 1350 angstroms; the nature of this emission is unclear, but the radiation is spatially extensive and detectable on both day and night sides of the planet.     

Magnetospheric dayside cusp: a topside view of its 6300-angstrom atomic oxygen emission

An interference filter photometer on the ISIS-1l spacecraft generates global maps of the atomic oxygen emission at 6300 angstroms from the ionosphere. The most prominent feature observed is a band of permanent red aurora on the dayside of the earth, centered on magnetic noon at about 78 degrees magnetic (invariant) latitude, brighter than the quiet-time nightside aurora.     

Galileo ultraviolet spectrometer experiment: initial venus and interplanetary cruise results

The Galileo Extreme Ultraviolet Spectrometer obtained a spectrum of Venus atmospheric emissions in the 55.0- to 125.0-nanometer (nm) wavelength region. Emissions of helium (58.4 nm), ionized atomic oxygen (83.4 nm), and atomic hydrogen (121.6 nm), as well as a blended spectral feature of atomic hydrogen (Lyman-beta) and atomic oxygen (102.5 nm), were observed at 3.5-nm resolution. During the Galileo spacecraft cruise from Venus to Earth, Lyman-alpha emission from solar system atomic hydrogen (121.6 nm) was measured. The dominant source of the Lyman-alpha emission is atomic hydrogen from the interstellar medium. A model of Galileo observations at solar maximum indicates a decrease in the solar Lyman-alpha flux near the solar poles. A strong day-to-day variation also occurs with the 27-day periodicity of the rotation of the sun.     

Methanobactin, a copper-acquisition compound from methane-oxidizing bacteria

Siderophores are extracellular iron-binding compounds that mediate iron transport into many cells. We present evidence of analogous molecules for copper transport from methane-oxidizing bacteria, represented here by a small fluorescent chromopeptide (C45N12O14H62Cu, 1216 daltons) produced by Methylosinus trichosporium OB3b. The crystal structure of this compound, methanobactin, was resolved to 1.15 angstroms. It is composed of a tetrapeptide, a tripeptide, and several unusual moieties, including two 4-thionyl-5-hydroxy-imidazole chromophores that coordinate the copper, a pyrrolidine that confers a bend in the overall chain, and an amino-terminal isopropylester group. The copper coordination environment includes a dual nitrogen- and sulfur-donating system derived from the thionyl imidazolate moieties. Structural elucidation of this molecule has broad implications in terms of organo-copper chemistry, biological methane oxidation, and global carbon cycling.     

Atomic force microscopy of the electrochemical nucleation and growth of molecular crystals

In situ atomic force microscopy reveals the morphology, surface topography, and growth and dissolution characteristics of microscopic single crystals of the low-dimensional organic conductor (tetrathiafulvalene)Br(0.76)' which are grown by electrocrystallization on a highly oriented pyrolytic graphite electrode in an atomic force microscope liquid cell. The growth modes and the distribution and orientation of topographic features on specific crystal faces, whose identity was determined by "atomic force microscope goniometry," can be correlated with the strength and direction of anisotropic solid-state intermolecular bonding. Growth on the (011) face of (tetrathiafulvalene)Br(0.76) crystals involves the formation of oriented self-similar triangular islands ranging in size from 200 to 5000 angstroms along a side. These nuclei eventually transform into rectangular rafts at larger length scales, where bulk intermolecular bonding interactions and surface energies dominate over nuclei-substrate interactions.     

The structure of ferrihydrite, a nanocrystalline material

Despite the ubiquity of ferrihydrite in natural sediments and its importance as an industrial sorbent, the nanocrystallinity of this iron oxyhydroxide has hampered accurate structure determination by traditional methods that rely on long-range order. We uncovered the atomic arrangement by real-space modeling of the pair distribution function (PDF) derived from direct Fourier transformation of the total x-ray scattering. The PDF for ferrihydrite synthesized with the use of different routes is consistent with a single phase (hexagonal space group P6(3)mc; a = approximately 5.95 angstroms, c = approximately 9.06 angstroms). In its ideal form, this structure contains 20% tetrahedrally and 80% octahedrally coordinated iron and has a basic structural motif closely related to the Baker-Figgis delta-Keggin cluster. Real-space fitting indicates structural relaxation with decreasing particle size and also suggests that second-order effects such as internal strain, stacking faults, and particle shape contribute to the PDFs.     

Atomic-level models of the bacterial carboxysome shell

The carboxysome is a bacterial microcompartment that functions as a simple organelle by sequestering enzymes involved in carbon fixation. The carboxysome shell is roughly 800 to 1400 angstroms in diameter and is assembled from several thousand protein subunits. Previous studies have revealed the three-dimensional structures of hexameric carboxysome shell proteins, which self-assemble into molecular layers that most likely constitute the facets of the polyhedral shell. Here, we report the three-dimensional structures of two proteins of previously unknown function, CcmL and OrfA (or CsoS4A), from the two known classes of carboxysomes, at resolutions of 2.4 and 2.15 angstroms. Both proteins assemble to form pentameric structures whose size and shape are compatible with formation of vertices in an icosahedral shell. Combining these pentamers with the hexamers previously elucidated gives two plausible, preliminary atomic models for the carboxysome shell.     

Antiprismatic Coordination about Xenon: The Structure of Nitrosonium Octafluoroxenate(VI)

The structure of nitrosonium octafluoroxenate(VI), 2NOF . XeF(6), has been determined by means of single-crystal x-ray counter methods (R-index = 0.046, weighted R-index = 0.042). The space group is Pnma, with a = 8.914(10) angstroms, b = 5.945(10) angstroms, and c = 12.83(2) angstroms (the numbers in parentheses are the standard deviations to the least significant digit or digits); the calculated density (rho) is 3.354 grams per cubic centimeter, and there are four formula units per unit cell. The material consists of well-separated NO(+) and (XeF(8))(2-) ions; the structural formula is thus (NO)(2) (XeF(8)). The anion configuration is that of a slightly distorted Archimedean antiprism. The observed distortion appears incompatible with a lone-pair repulsion model. Xenon-fluorine bond lengths of 1.971(7), 1.946(5), 1.958(7), 2.052(5), and 2.099(5) angstroms were found.     

The structural basis of ribosome activity in peptide bond synthesis

Using the atomic structures of the large ribosomal subunit from Haloarcula marismortui and its complexes with two substrate analogs, we establish that the ribosome is a ribozyme and address the catalytic properties of its all-RNA active site. Both substrate analogs are contacted exclusively by conserved ribosomal RNA (rRNA) residues from domain V of 23S rRNA; there are no protein side-chain atoms closer than about 18 angstroms to the peptide bond being synthesized. The mechanism of peptide bond synthesis appears to resemble the reverse of the acylation step in serine proteases, with the base of A2486 (A2451 in Escherichia coli) playing the same general base role as histidine-57 in chymotrypsin. The unusual pK(a) (where K(a) is the acid dissociation constant) required for A2486 to perform this function may derive in part from its hydrogen bonding to G2482 (G2447 in E. coli), which also interacts with a buried phosphate that could stabilize unusual tautomers of these two bases. The polypeptide exit tunnel is largely formed by RNA but has significant contributions from proteins L4, L22, and L39e, and its exit is encircled by proteins L19, L22, L23, L24, L29, and L31e.     

Garnet-like structures of high-pressure cadmium germanate and calcium germanate

Crystals of CdGeO(3) grown at a pressure of 65 kilobars are tetragonal and have an ordered, garnet-like crystal structure with cadmium occupying the dodecahedral and octahedral sites, and germanium the octahedral and tetrahedral sites. The crystal structure (a = 12.406 +/- 1 angstroms, c = 12.256 +/- 1 angstroms, and space group 14,/a) has been refined by least-squares analysis to an R (discrepancy index) of 0.073. Two high-pressure phases of CaGeO(3) were synthesized, one isotypic with tetragonal CdGeO(3) (a = 12.514 +/- 3 angstroms, c = 12.358 +/- 3 angstroms), and the other isotypic with perovskite.     

Induced photolysis of DDT

Photolysis of mixtures of certain alkyl halides and aromatic amines produces dehalogenation of the halide. These reactions involve a photoinduced charge transfer from the amine to the halide. Photolysis of tritolylamine and carbon tetrachloride produces tritolylaminium chloride. Photolysis of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) and diethylaniline at 3100 angstroms yields 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (DDE), 1,1-dichloro-2,2-bis(p-chlorophenyl)ethane (DDD), p,p'-dichlorobenzophenone (DDCO), and hydrogen chloride. Photolysis of DDT does not occur unless an inducer which has a low ionization potential, such as diethylaniline, is present. The DDT-diethylaniline mixture is stable in the dark, and the induced photolysis is not affected by triplet quenchers.