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1.
Permeable pavements mitigate the impacts of urbanization on surface waters through pollutant load reduction, both by sequestration of pollutants and stormwater volume reduction through exfiltration. This study examined the non-winter water quality performance of two side-by-side permeable pavements in the Ohio snowbelt. The permeable interlocking concrete pavements were designed to drain impervious catchments 2.2 (large) and 7.2 (small) times larger than their surface area, were located over clay soils, and incorporated the internal water storage design feature. Nutrient reduction was similar to past studies—organic nitrogen and particulate phosphorus were removed through filtration and settling, while dissolved constituents received little treatment. Because of 16 and 32 % volume reductions in the small and large installations, respectively, nutrient loads were often significantly reduced but generally by less than 50 %. Aluminum, calcium, iron, magnesium, lead, chloride, and total suspended solids (TSS) concentrations and loads often increased after passing through the permeable pavements; effluent TSS loads were three- to five-fold higher than influent TSS loads. This was apparently due to seasonal release of clay- and silt-sized particles from the soils underlying the permeable pavement and inversely related to elapsed time since winter. The application of de-icing salt is thought to have caused deflocculation of the underlying soils, allowing particulates to exit with stormwater as it discharged from the underdrain of the permeable pavements. By autumn, both permeable pavements discharged metals and TSS concentrations similar to others in the literature, suggesting the de-icing effects lasted 3–6 months post-winter. Sodium may substantially affect the performance of permeable pavements following winter de-icing salt application, particularly when 2:1 clay minerals, such as vermiculites and smectites, predominate.  相似文献   

2.
Bioretention systems are of immense importance as they serve as small “sponges” for cities, cutting stormwater runoff, removing pollution, and using precipitation resources. However, performance data for these facilities are generally lacking, particularly at the field scale. This study investigated the runoff quantity regulation and pollutant removal performance of bioswale and rain garden systems from 2014 to 2017. A performance assessment of these facilities demonstrated that anti-seepage rain garden, bioswale-A, and bioswale-B effectively retained inflow volumes by the filter media, reducing runoff volumes by 54.08, 98.25, and 77.65%, respectively, on average, with only two events of overflowing. According to the water quality data in 24 rainfall events, the main pollutant indexes for the new city include total nitrogen and chemical oxygen demand, and the median values for their respective effluent event median concentrations were 1.29 and 40.13 mg/L for anti-seepage rain garden and 1.68 and 74.00 mg/L for bioswale-B systems. The mean values of pollutant removal of the three bioretention systems, except for infiltration rain garden, were 39.8–59.73% (median?=?54.32%), 61.06–72.66% (median?=?73.47%), and 76.67%–88.16% (median?=?80.64%). Meanwhile, outflow volume of water was found to be most influenced by inflow volumes for the bioswales and anti-seepage rain garden. Mass removals were higher than concentrations owing to water volume attenuation. Based on the data of monitored pollution loads, this study estimated the annual pollutant load removal as 75.45 and 90.7% for anti-seepage rain garden and bioswale-B according to the percent of monitoring rainfall depth in total annual precipitation. This study also established the target pollutant service life model on the basis of accumulated annual load and media adsorption capacity. The results of this study will contribute to a greater understanding of the treatment performance of bioretention systems, assisting in the design, operation, and maintenance of them.  相似文献   

3.
This study investigates the impact of future climate change on heavy metal (i.e., Cd and Zn) transport from soils to surface waters in a contaminated lowland catchment. The WALRUS hydrological model is employed in a semi-distributed manner to simulate current and future hydrological fluxes in the Dommel catchment in the Netherlands. The model is forced with climate change projections and the simulated fluxes are used as input to a metal transport model that simulates heavy metal concentrations and loads in quickflow and baseflow pathways. Metal transport is simulated under baseline climate (“2000–2010”) and future climate (“2090–2099”) conditions including scenarios for no climate change and climate change. The outcomes show an increase in Cd and Zn loads and the mean flux-weighted Cd and Zn concentrations in the discharged runoff, which is attributed to breakthrough of heavy metals from the soil system. Due to climate change, runoff enhances and leaching is accelerated, resulting in enhanced Cd and Zn loads. Mean flux-weighted concentrations in the discharged runoff increase during early summer and decrease during late summer and early autumn under the most extreme scenario of climate change. The results of this study provide improved understanding on the processes responsible for future changes in heavy metal contamination in lowland catchments.  相似文献   

4.
This study evaluated the impacts of three sugarcane residue management techniques, namely postharvest burning of residue (BR), shredding of residue (SR), and full postharvest retention of residue (RR), on the water quality of surface runoff from February 2006 to September 2007 in Iberia, LA. Total runoff volumes recorded were 58,418, 57,923, and 46,578 L for the BR, SR, and RR treatments, respectively. Except for total Kjeldahl nitrogen (TKN), which was higher for BR than RR or SR, there were no significant differences in total loads of total suspended solids (TSS), total dissolved solids (TDS), biological oxygen demand at 5 days (BOD5), total phosphorus (TP), nitrate-N, nitrite-N, and sulfate among the three residue management techniques, although the RR treatment generally exported the lowest total loads. Regression analyses on the pollutant load and rainfall event showed that the load exported for each water quality parameter was positively correlated with precipitation, with the BR treatment being more sensitive to rainfall amount than the RR and SR treatments in TSS, TKN, TP, BOD, nitrate, and sulfate exports. Runoff TSS and turbidity were also highly correlated (R 2?=?0.95, P?<?0.001). The results suggested that the two sugarcane residue retention practices (RR and SR) had limited benefit on improving surface runoff water quality over the BR practice in subtropical region such as Louisiana.  相似文献   

5.
Nonpoint stormwater runoff remains a major threat to surface water quality in the USA. More effective stormwater control measures can be designed by understanding patterns in pollutant export with respect to the runoff hydrograph. In particular, nutrient concentrations in urban stormwater can cause deleterious effects in sensitive watersheds in the Southeast and Mid-Atlantic USA. A year-long study captured stormwater samples from 36 storm events at two catchments (one primarily impermeable and the other substantially wooded) and analyzed for total suspended solids and various nutrient species. Using these data, the first flush effect (the assumption that the initial portion of a rainfall-runoff event is more polluted than the later portions) was evaluated based on several published methods and definitions. Based on an analysis of multiple methodologies, the ranking of first flush strength among the pollutants was total suspended solids (TSS) > ammonia (NH3) > total Kjeldahl nitrogen > NO2-NO3 > total phosphorus > orthophosphate (O-PO4). Nitrogen species generally displayed a stronger first flush than phosphorus species, with O-PO4 showing the weakest first flush effect. Various relationships ° climate, land use, and the first flush strength were also explored. Of the rainfall characteristics analyzed, total rainfall and runoff volume each inversely affected the first flush strength of TSS on the more impervious catchment. Although orthophosphate did not have a strong first flush effect, the relative first flush strength for O-PO4 increased with increasing rainfall or runoff. Land use did not influence the first flush strength of the pollutants. On average, most pollutants exhibited a slight first flush effect, but substantial pollutant loading still occurred in the latter portion of the storm??s total runoff volume. Thus, treating the majority of a storm??s total pollutant load requires capturing a commensurate fraction of runoff volume.  相似文献   

6.
昆明市云龙水库径流区氮磷非点源污染负荷分析   总被引:4,自引:2,他引:2  
郝旭  张乃明  史静 《水土保持通报》2013,(6):274-278,284
云龙水库是昆明市最大的城市集中式饮用水源地。水源区农业非点源污染是影响水库水质的主要来源,因此分析水库径流区氮磷非点源污染负荷与来源构成,可为饮用水源区水质保护提供科学依据。采用输出系数模型法,对昆明市云龙水库径流区氮、磷负荷的产生量与入库量进行了估算。结果表明:(1)云龙水库径流区氮、磷非点源污染负荷产生量分别为2079.8和454.32t/a,入库量分别为207.98和24.73t/a。(2)从不同乡镇分析,撒营盘镇的氮、磷负荷产生量最高,云龙乡和茂山镇产出量较低,其余乡镇产生量相近。(3)从不同污染源类型分析,该区非点源污染的主要污染源为农村生活污染和畜禽粪便污染。  相似文献   

7.

Purpose

Closed erosion plots have been used extensively to investigate soil loss and its spatial variation within a watershed. However, erosion rates measured on closed plots at various locations within a watershed may not reflect the “real world” conditions due to plot boundary problems. The purpose of this study was to identify runoff and sediment sources in a semi-arid, complex terrain catchment by using the data collected from open plots, nested catchments, and tunnel systems.

Materials and methods

The study catchment, in the Loess Plateau of China, was partitioned into various-level geomorphic units. Runoff and sediment discharges were measured from 55 storm events between 1963 and 1968 on open plots and nested catchments. Storm flows were also monitored in 14 rainfall events from the tunnel systems between 1989 and 1990. This study combined the data collected from the two periods to investigate runoff and sediment sources from the different geomorphic units of the catchment.

Results and discussion

On the four open plots (S1, S2, S3, and S4) of the hill slope, total runoff depths of 128.5 mm (S1), 84.3 mm (S2), 101.92 mm (S3), and 141.73 mm (S4) were recorded from all the events over the first period, which correspondingly produced total sediment yields of 3.056 kg m?2 (S1), 9.058 kg m?2 (S1), 42.848 kg m?2 (S3), and 97.256 kg m?2 (S4). The number of runoff events also varied due to a non-uniformity in runoff generation among the different geomorphic units of the catchment. Tunnel flows generally had higher mean sediment concentrations than catchment outflows. Three nested catchments located from the headwaters (C1) to the mouth of the catchment (C3) generated total runoff depths of 120.02 mm (C1), 143.92 mm (C2), and 149.43 mm (C3), and correspondingly produced sediments yields of 62.01 kg m?2 (C1), 144.02 kg m?2 (C2), and 123.92 kg m?2 (C3) for the first period.

Conclusions

Significant variations in runoff and erosion existed within the catchment. The spatial variation of runoff generation on the hill slopes resulted from the variation of soil infiltration. Sediment produced from the lower hill slope zone was disproportionally higher than that from the upper hill slope zone. Nevertheless, a significant portion of the sediment eroded on the lower slope zone was caused by runoff generated from the upper slope zone. Tunnel erosion also played a significant role in sediment production.  相似文献   

8.
9.
珠海城区暴雨径流污染负荷估算及其评价   总被引:9,自引:0,他引:9       下载免费PDF全文
基于对广东珠海城区暴雨径流污染的监测,引用SCS模型对城区暴雨径流污染负荷进行估算并分析评价。结果表明,珠海城区暴雨产流年平均1529.2mm,其中以交通主干道和商业区径流量最大。暴雨径流污染物浓度水平较高,T—N,T—P,COD_(Cr)和BOD_5负荷总量分别为765.27,74.06,11 958.94和1104.71t,其中COD_(Cr)负荷为工业点源污染的72.32%,占珠海非点源污染总负荷的24.69%。暴雨径流在雨后短时间内会使受纳水体的水质迅速恶化。因此,珠海城区暴雨径流对水环境的威胁较大。  相似文献   

10.
For a half century, total suspended solids (TSS) has been the most commonly utilized particulate matter (PM) gravimetric index for wastewater. While TSS has been extended to urban runoff, runoff phenomena are unique. Runoff is unsteady and transports heterodisperse inorganic granulometry, giving rise to the PM index, suspended sediment concentration (SSC). With respect to PM-associated chemical oxygen demand (CODp) in runoff, it is hypothesized that, while the TSS method can represent effluent CODp, the SSC method is required to represent influent CODp. CODp and PM indices (TSS and SSC) for runoff events with mass balances and manual sampling are analyzed to investigate this hypothesis. This study examined a series of rainfall-runoff events captured from an instrumented fully paved urban catchment subject to traffic loadings in Baton Rouge, LA. Results indicate TSS generated substantial event-based mass balance errors for CODp and Δm p (mg/g) across a hydrodynamic separator (HS) as compared to SSC. TSS underestimates sediment-bound COD (>75 µm), a significant portion (maximum of 63% and median of 50%) of influent load. Negative bias by the TSS method for influent CODp load increases as the heterodisperse particle size distribution becomes coarser. Above a PM of 250 mg/L, underestimation of CODp by the TSS method is statistically significant. Utilizing the SSC method, CODp reduction by a HS upstream of a batch clarifier (BC) indicates that a HS does not provide CODp reduction, compared to a BC with 60 min of residence time. Representative PM and CODP assessment suggests frequent BMP and drainage system maintenance to ensure proper operation and reduce pollutant elution.  相似文献   

11.
In the beginning of March 2006, polluted snow from a roadside in Luleå, in the north of Sweden, with a traffic intensity of approximately 7,400 vehicles per day, was collected. The snow was homogenously mixed and divided into samples of 30 litres. The initial volumes and densities of the snow samples were measured and calculated. The snow samples were melted in climate rooms, with four different experimental configurations, to investigate the influence of road salt, temperature, and surface slope upon the transport of total suspended solids (TSS) (three replicates for each experimental configuration). The total volume of snowmelt runoff was collected and analysed for pH, conductivity, and concentrations of TSS and chlorides. The results showed that measured concentrations, calculated mass loads, and performed statistical t-tests of TSS for the snowmelt of the four different configurations implied that the transported mass load of TSS was higher with the addition of road salt and at higher ambient temperatures. However, the results showed a lower mass load of transported TSS for the lower slope.  相似文献   

12.
In six small catchments located at the Cordillera de la Costa in southern Chile (40° S), concentrations and fluxes of NO3-N, NH4-N, organic-N, total-N and total-P in bulk precipitation and runoff water were measured. The main objective of this study was to compare nitrogen and phosphorus retention of catchments with varying land cover of native forest and exotic plantations, in order to evaluate possible effects of land use change. Nitrate-N was the dominant fraction (>50%) of nitrogen loss, especially in the catchments dominated by exotic plantations. In the catchment with native forests, NO3 ? only contributed with 34% of the nitrogen loss and DON was the main output with 55%. Annual NO3 ? export was lower in the catchment with native forest compared to the catchments with exotic plantations where the streamflow output exceed the precipitation input. Average inputs of total-N were 2.6 kg ha?1 year?1 (DIN?=?1.4 kg ha?1 year?1, DON?=?1.2 kg ha?1 year?1) and outputs were 1.7 kg ha?1 year?1 (DIN?=?1.2 kg ha?1 year?1, DON?=?0.5 kg ha?1 year?1). Annual retention of total nitrogen fluctuated between 61% in a catchment dominated by native forests to 15% in catchments dominated by exotic plantations of Eucalyptus sp. Nitrogen retention was positively related with native forest coverage. The N retention capacity of the catchments could be both attributed to consequences of clear cutting practices and differences in vegetation cover.  相似文献   

13.
Relationships between total suspended solids (TSS) and metals (Cu, Pb and Zn) were tested and compared amongst base and high flows of three urbanised catchments in Sydney Estuary, Australia. Significant relationships between TSS and Cu, Pb and Zn were detected for high flows within each catchment; however, no significant relationship was detected for TSS/Zn and TSS/Cu in one of the creeks (Whites Creek) and for TSS/Zn in another (Hawthorne Canal) in 2010 during base flow. Relationships between metals and TSS also varied significantly in locations of intercept and slope between high and base flow and amongst catchments. Spatial variance in TSS/metal relationships were likely caused by specific anthropogenic activities because land uses, meteorology and geology within the study catchments were similar. Results suggest TSS may be used as a surrogate for estimating metal loading in real time for urban catchments, once relationships between metals and TSS were established for individual catchments and for base and high flow conditions. Moreover, no differences in TSS/metal relationships were detected between 2009 and 2010 in Hawthorne Canal during high flow conditions, suggesting that this method of real-time monitoring may be reliable for assessing Cu, Pb and Zn loads during high flows over inter-annual periods. However, long-term consistency of TSS/metal relationships for base flow may need testing since changes in TSS/Zn and TSS/Cu relationships were detected between 2009 and 2010 in Hawthorne Canal. Although irregular discharges to stormwater did not conform to TSS/metal relationships, irregular discharges may be detected in real time by increased flow during dry weather conditions, which may facilitate regulation of these conditions that currently result in potential environmental harm to aquatic biota in Sydney Estuary.  相似文献   

14.
Inorganic chemicals in urban stormwater and snowmelt runoff originate from catchment geology and anthropogenic activities. The occurrence, partitioning and mobility of six minerals and six trace metal (TM) indicators of anthropogenic activities were studied in stormwater, snowmelt and baseflow in four urban catchments, and the sampling of inorganics was supplemented by measurements of electrical conductivity (EC), pH and total suspended solids (TSSs). Minerals occurred at concentrations several orders of magnitude higher (1–102 mg/L) than those of TMs (10?2–102 μg/L) and reflected the composition of local groundwater seeping into sewers. Concentrations of Ca, K, Mg and Na were enhanced by baseflow contributions and followed closely the electrical conductivity. Al and Fe minerals occurred in insoluble forms, and their pollutographs were similar to those of TMs, whose concentrations mimicked, to some extent, the flux of TSS. The TMs with the highest and lowest particulate fractions were Cr&Pb and Cu&Zn, respectively. The concentrations of total TMs in snowmelt were two to four times higher than those in stormwater, and both sources likely exceeded some of the stormwater effluent limits (for Cd, Cu and Zn) proposed in Sweden. Where such concentrations depended on water hardness, the risk of toxicity might be reduced by elevated hardness of the monitored snowmelt and stormwater. Recognizing the good ecological status of the study area receiving water, Lake Storsjön, some protection against polluted runoff and snowmelt may be needed and could be achieved by implementing stormwater management measures controlling TSS and TMs.  相似文献   

15.
Manganese (Mn) contamination of drinking water may cause aesthetic and human health problems when concentrations exceed 50 and 500 μg l?1, respectively. In the UK, the majority of Mn-related drinking water supply failures originate from unpolluted upland catchments. The source of Mn is therefore soil, but the exact mechanisms by which it is mobilised into surface waters remain unknown. Elevated Mn concentrations in surface waters have been associated with the rewetting of dried upland soils and with conifer afforestation. We investigated these hypotheses in a laboratory experiment involving the drying and rewetting of intact soil cores (1,900 cm3 volume) of horizons of four representative soil type-land use combinations from an upland water supply catchment in southwest Scotland. Although no statistically significant effect of land use or soil type was detected on Mn concentrations in soil water, Mn release occurred from three soil horizons upon rewetting. Soil water Mn concentrations in the moorland histosol H2 (10–30 cm), the histic podzol H and Eh horizons increased from means of 5.8, 6.2 and 0.6 μg l?1 prior to rewetting to maxima of 90, 76 and 174 μg l?1 after rewetting, respectively. The properties of these three horizons indicate that Mn release is favoured from soil horizons containing a mixture of organic and mineral material. Mineral material provides a source of Mn, but relatively high soil organic matter content is required to facilitate mobilisation. The results can be used alongside soil information to identify catchments at risk of elevated Mn concentrations in water supplies.  相似文献   

16.
This work presents data on a suite of diffuse pollutants, monitored in a stream draining an intensively managed grassland on a 30 min time step during a period of intense rainfall to better understand their sources and pathways. Nitrite (92 μg l?1), particulate phosphorus (107 μg l?1) and soluble phosphorus (74 μg l?1) exceeded environmental limits during base flow. Concentrations of nitrate and nitrite were decreased during the storm event, whereas all other pollutants generally increased and exceeded environmental limits where specified, especially when associated with a small subsidiary hydrograph on the rising limb of the main hydrograph. Total pollutants loads, when using a 60 min sampling frequency, would have led to significant over and under-estimations depending on which 60 min sample set was used. In the worst case, loads of ammonium could have been under-estimated by 35% or over estimated by 25% with errors being associated with loads on the rising limb of the hydrograph and more specifically a small subsidiary hydrograph. This subsidiary hydrograph may have occurred as a result of runoff from the farm hard standings within the catchment. Incidental transfer of pollutants associate with this runoff have masked the overall grassland pollutant response. To better understand these different source areas and pollutant dynamics, there is a need for novel tracing techniques to elucidate their relative contribution and pathways.  相似文献   

17.
The loads and sources of heavy metals (Cd, Co, Cu, Mn, Mo, Ni, Pb, V, and Zn) in the midstream of Tama River were evaluated on the basis of their chemical analyses in ordinary and stormwater runoff from July 2007 to November 2008. Tama River is one of the three major rivers flowing into Tokyo Bay. The total annual water discharges differed largely for 2007 and 2008, depending on the scales of typhoon rainfalls and other heavy rainfalls in each year. The concentrations of the metals other than Mo in the river did not change markedly at a flow rate of less than approximately 200 m3 s?1, but at higher flow rates, the concentrations of all the metals increased linearly with the increase in the log of flow rate (r 2?=?0.94–0.99). The annual loads of heavy metals for 2007 and 2008 were estimated using regression equations between the above parameters and the hourly flow rate data for each year. For the metals other than Mo, the contribution of the loads at higher flow rates (>200 m3 s?1) was much larger than that at lower flow rates (<200 m3 s?1), showing the importance of the particulate loads (primarily crustal materials) during storm runoff following typhoon rainfalls and other heavy rainfalls. In contrast, the loads of Mo at lower flow rates accounted for major portions (56–78%) of the total loads, because of a relatively small contribution of particulate load during storm runoff. The contribution of the loads of Mo, Zn, Cd, Cu, and Ni at lower flow rates to the annual loads was larger than that of other metals. It was found that the concentrations of these metals in ordinary runoff are strongly affected by the discharge of treated water from sewage treatment plants which are located along the catchment. Thus, treated water from sewage treatment plants may be the primary source contributing to the present pollution of Mo, Zn, Cd, Cu, and Ni in Tokyo Bay.  相似文献   

18.
A plot-scale, rainfall-simulation study measured edge-of-field pollutant losses from conventional-till, strip-till, and no-till treatments in a burley tobacco production system. The field experiment results show that the conventional-till treatment yielded more total runoff than strip- and no-till treatments. Compared to the conventional-till treatment, both no-till and strip-till reduced the total mass losses of total suspended solids (TSS), total nitrogen (TN), total Kjeldahl nitrogen (TKN), nitrate (NO-N), ammonia (NH3-N), total phosphorus (TP), orthophosphate (PO4-P), and the insecticide chlorpyrifos in runoff. Although statistical analyses indicated that there was no significant difference between the no-till and strip-till practices, the no-till practice consistently yielded less edge-of-field pollutant loss than the strip-till practice. This research reinforces the body of knowledge documenting the effectiveness of conservation-tillage practices in reducing edge-of-field pollutant losses.  相似文献   

19.
The contamination status of rivers and their floodplains with inorganic and organic pollutants in central Russia is poorly known. We investigated the concentrations of inorganic (As, Cd, Cu, Hg, Ni, Pb and Zn) and persistent organic pollutants (hexachlorocyclohexane, PCBs, cyclodienes, DDX and other pesticides) in floodplain soils of the Oka River catchment (Russia). The level of contamination was generally lower than in the Elbe River floodplain but in the same range as in other European river systems such as floodplains of the rivers Rhine, D?evnice and Yachroma. Only soil samples from the periphery of the city of Ryazan (200 km southeast of Moscow) had a higher anthropogenic enrichment of Cd, Cu and Zn which was comparable to the contaminated Elbe River floodplains. These soils also had the largest concentrations of persistent organic pollutants among all samples from the Oka River catchment. Therefore, the need for large-scale remediation seems to be less urgent than in Central European river catchments and mainly restricted to some “hot spot” areas.  相似文献   

20.
选择滇池流域典型城郊代表性的两个功能区——居民生活区和居民生活-集市混合区进行降雨径流监测,分析降雨径流污染特征及排放过程。结果表明,降雨地表径流中总氮浓度在2.18~29.40 mg·L-1,总磷浓度在0.18~3.90 mg·L-1,氨态氮浓度在0.87~18.48 mg·L-1,硝态氮浓度在0.02~3.64 mg·L-1, CODCr浓度在22.51~362.92 mg·L-1, TSS浓度在7.00~882.00 mg·L-1之间。降雨地表径流污染物浓度高于地表水Ⅴ类水环境质量标准。降雨径流中氮的主要污染物是氨态氮、颗粒态氮和溶解有机态氮,磷的主要污染物以颗粒态磷和PO3-4-P为主。降雨径流污染物浓度随降雨时间发生变化,开始产生径流时污染物浓度较高,之后随着雨强的平衡而趋于下降。降雨径流各污染物浓度是居民生活-集市混合区大于居民生活区,居民生活区径流大于屋面径流;次降雨径流污染物平均浓度(EMC)为居民生活-集市混合区普遍高于居民生活区。居民生活-集市混合区降雨径流EMC变化表现出更大的随机性。  相似文献   

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