El chichon: composition of plume gases and particles

Aircraft measurements were made of trace gases, atmospheric particles, and condensed acid volatiles in the plume of El Chichón volcano, Chiapas, Mexico, in November 1982. Hydrogen sulfide was the primary gaseous sulfur species in the plume at the time of collection. Concentrations of 28 elements were determined by neutron activation analysis of particulate material from the plume. Rates of trace element emission to the atmosphere for each species were estimated by normlization to the simultaneously determined total sulfur emission rate. The volatile elements sulfur, chlorine, arsenic, selenium, bromine, antimony, iodine, tungsten, and mercury were enriched relative to bulk pyroclastic material by factors of 60 to 20,000. Arsenic, antimony, and selenium were associated predominantly with small (>/= 3 micrometer) particles. Calcium and sodium were present almost exclusively on larger particles and aluminum and manganese were bimodally distributed. Ashladen particulate material injected into the stratosphere during the early violent eruptions was enriched by factors of 10 to 30 relative to ash in some of the same elements observed in the quiescent plume.     

A Major Helium-3 Source at 15{degrees}S on the East Pacific Rise

An extensive plume of water enriched with helium-3 has been discovered in the deep Pacific Ocean at latitude 15 degrees S on the East Pacific Rise. In the core of the plume, at a depth of 2500 meters over the ridge crest, the helium-3/helium-4 ratio is 50 percent higher than the ratio in atmospheric helium, indicating a strong injection of mantle or primordial helium at the spreading center axis through local hydrothermal systems. The helium-3 plume is completely absent east of the rise, but it can be traced over 2000 kilometers to the west above a newly observed physical feature: a density discontinuity here caled the "ridge-crest front." The injected plume provides a unique deep-sea tracer with an asymmetric distribution which shows that the deep circulation across the rise is from east to west. The striking intensity and lateral extent of this helium-3 anomaly, compared to observations at known oceanic hydrohrmal sites, suggest that the largest hydrothermal fields in the ocean are yet to be discovered and that they will be found near 15 degrees S on the East Pacific Rise.     

A close-up look at Io from Galileo's near-infrared mapping spectrometer

Infrared spectral images of Jupiter's volcanic moon Io, acquired during the October and November 1999 and February 2000 flybys of the Galileo spacecraft, were used to study the thermal structure and sulfur dioxide distribution of active volcanoes. Loki Patera, the solar system's most powerful known volcano, exhibits large expanses of dark, cooling lava on its caldera floor. Prometheus, the site of long-lived plume activity, has two major areas of thermal emission, which support ideas of plume migration. Sulfur dioxide deposits were mapped at local scales and show a more complex relationship to surface colors than previously thought, indicating the presence of other sulfur compounds.     

Gaseous constituents in the plume from eruptions of mount st. Helens

Measurements in the stratosphere of gaseous constituents in the plume of Mount St. Helens were obtained during five flights of the NASA U-2 aircraft between 19 May and 17 June 1980. Mixing ratios from gas chromatographic measurements on samples acquired about 24 hours after the initial eruption show considerable enhancement over nonvolcanic concentrations for sulfur dioxide (more than 1000 times), methyl chloride (about 10 times), and carbon disulfide (more than 3 times). The mixing ratio of carbonyl sulfide was comparable to nonvolcanic mixing ratios although 3 days later it was enhanced two to three times. Ion chromatography measurements on water-soluble constituents are also reported. Very large concentrations of chloride, nitrate, and sulfate ions were measured, implying large mixing ratios for the water-soluble gaseous constituents from which the anions are derived. Measurements of radon-222 present in the plume are also reported.     

Flood basalts and hot-spot tracks: plume heads and tails

Continental flood basalt eruptions have resulted in sudden and massive accumulations of basaltic lavas in excess of any contemporary volcanic processes. The largest flood basalt events mark the earliest volcanic activity of many major hot spots, which are thought to result from deep mantle plumes. The relative volumes of melt and eruption rates of flood basalts and hot spots as well as their temporal and spatial relations can be explained by a model of mantle plume initiation: Flood basalts represent plume "heads" and hot spots represent continuing magmatism associated with the remaining plume conduit or "tail." Continental rifting is not required, although it commonly follows flood basalt volcanism, and flood basalt provinces may occur as a natural consequence of the initiation of hot-spot activity in ocean basins as well as on continents.     

Cassini ion and neutral mass spectrometer: Enceladus plume composition and structure

The Cassini spacecraft passed within 168.2 kilometers of the surface above the southern hemisphere at 19:55:22 universal time coordinated on 14 July 2005 during its closest approach to Enceladus. Before and after this time, a substantial atmospheric plume and coma were observed, detectable in the Ion and Neutral Mass Spectrometer (INMS) data set out to a distance of over 4000 kilometers from Enceladus. INMS data indicate that the atmospheric plume and coma are dominated by water, with significant amounts of carbon dioxide, an unidentified species with a mass-to-charge ratio of 28 daltons (either carbon monoxide or molecular nitrogen), and methane. Trace quantities (<1%) of acetylene and propane also appear to be present. Ammonia is present at a level that does not exceed 0.5%. The radial and angular distributions of the gas density near the closest approach, as well as other independent evidence, suggest a significant contribution to the plume from a source centered near the south polar cap, as distinct from a separately measured more uniform and possibly global source observed on the outbound leg of the flyby.     

Kuwait oil fires: correction

In our article "Airborne studies of the smoke from the Kuwait oil fires" (15 May, p. 987) (1), we stated that the depletions of sulfur dioxide (SO(2)) and nitrogen oxides (NO(x)) in the smoke plume from the Kuwait oil fires were 50 and 60% per hour, respectively. These values were derived from measurements made aboard a Convair C-131 aircraft, and measurements of CO(2) were used as a conserved tracer. Subsequent comparisons of these measurements of CO(2) (which were obtained from a continuous analyzer) with independent measurements of CO(2) (obtained from "grab" samples) revealed that the continuous CO(2) measurements were occasionally contaminated by cabin air. Recalculation of the depletion rates of SO(2) and NO(x), with the use of uncontaminated measurements of CO(2) from the "grab" sampler aboard the aircraft yielded values of 6 and 22%, respectively (2). Our conclusions with regard to the climatic effects of the Kuwait oil fires are unchanged.     

A Far-Field Hydrothermal Plume from Loihi Seamount

An extensive helium plume in the north central Pacific emanates from Loihi Seamount on the flanks of Hawaii. The maximum helium signal is found at a depth of about 1100 meters, the same depth as the near-field plume directly above Loihi Seamount. Although this helium plume is strongest near Hawaii, where the 3He/4He ratio at a depth of about 1100 meters reaches values 28 percent above the atmospheric ratio, it can be detected quite clearly at latitude 24°N, over 400 kilometers to the north. Excess 3He is also present on the same isopycnal between 15°N and 20°N at 135°W, some 2000 kilometers east of the Hawaiian Islands.     

Magnetic flux transport on the sun

Although most of the magnetic flux observed on the sun originates in the low-latitude sunspot belts, this flux is gradually dispersed over a much wider range of latitudes by supergranular convective motions and meridional circulation. Numerical simulations show how these transport processes interact over the 11-year sunspot cycle to produce a strong "topknot" polar field, whose existence near sunspot minimum is suggested by the observed strength of the interplanetary magnetic field and by the observed areal extent of polar coronal holes. The required rates of diffusion and flow are consistent with the decay rates of active regions and with the rotational properties of the large-scale solar magnetic field.     

Fullerenes in the 1.85-billion-year-old Sudbury impact structure

Fullerenes (C60 and C70) have been identified by laser desorption, laser desorption post-ionization, and high-resolution electron-impact mass spectrometry in shock-produced breccias (Onaping Formation) of the Sudbury impact structure in Ontario, Canada. The C60 isotope is present at a level of a few parts per million. The fullerenes were likely synthesized within the impact plume from the carbon contained in the bolide. The oxidation of the fullerenes during the 1.85 billion years of exposure was apparently prevented by the presence of sulfur in the form of sulfide-silicate complexes associated with the fullerenes.     

Organic aerosol formation downwind from the Deepwater Horizon oil spill

A large fraction of atmospheric aerosols are derived from organic compounds with various volatilities. A National Oceanic and Atmospheric Administration (NOAA) WP-3D research aircraft made airborne measurements of the gaseous and aerosol composition of air over the Deepwater Horizon (DWH) oil spill in the Gulf of Mexico that occurred from April to August 2010. A narrow plume of hydrocarbons was observed downwind of DWH that is attributed to the evaporation of fresh oil on the sea surface. A much wider plume with high concentrations of organic aerosol (>25 micrograms per cubic meter) was attributed to the formation of secondary organic aerosol (SOA) from unmeasured, less volatile hydrocarbons that were emitted from a wider area around DWH. These observations provide direct and compelling evidence for the importance of formation of SOA from less volatile hydrocarbons.     

硫对大白菜幼苗抗冷性的影响

以"四季王"大白菜为试材,研究了不同硫浓度对其幼苗抗冷性的影响。结果表明,与对照相比,施硫能提高大白菜叶片叶绿素、可溶性蛋白及可溶性糖含量,降低丙二醛含量,随硫浓度的升高,大白菜叶片叶绿素含量呈上升趋势;可溶性蛋白及可溶性糖含量先上升后下降,丙二醛含量先下降后上升。     

Gas emissions and the eruptions of mount st. Helens through 1982

The monitoring of gas emissions from Mount St. Helens includes daily airborne measurements of sulfur dioxide in the volcanic plume and monthly sampling of gases from crater fumaroles. The composition of the fumarolic gases has changed slightly since 1980: the water content increased from 90 to 98 percent, and the carbon dioxide concentrations decreased from about 10 to 1 percent. The emission rates of sulfur dioxide and carbon dioxide were at their peak during July and August 1980, decreased rapidly in late 1980, and have remained low and decreased slightly through 1981 and 1982. These patterns suggest steady outgassing of a single batch of magma (with a volume of not less than 0.3 cubic kilometer) to which no significant new magma has been added since mid-1980. The gas data were useful in predicting eruptions in August 1980 and June 1981.     

Numerical models of caldera-scale volcanic eruptions on Earth, venus, and Mars

Volcanic eruptions of gassy magmas on Earth, Venus, and Mars produce plumes with markedly different fluid dynamics regimes. In large part the differences are caused by the differing atmospheric pressures and ratios of volcanic vent pressure to atmospheric pressure. For each of these planets, numerical simulations of an eruption of magma containing 4 weight percent gas were run on a workstation. On Venus the simulated eruption of a pressure-balanced plume formed a dense fountain over the vent and continuous pyroclastic flows. On Earth and Mars, simulated pressure-balanced plumes produced ash columns, ash falls, and possible small pyroclastic flows. An overpressured plume, illustrated for Mars, exhibited a complex supersonic velocity structure and internal shocks.     

Swept away: resuspension of bacterial mats regulates benthic-pelagic exchange of sulfur

Filaments and extracellular material from colorless sulfur bacteria (Beggiatoa spp.) form extensive white sulfur mats on surface sediments of coastal, oceanic, and even deep-sea environments. These chemoautotrophic bacteria oxidize soluble reduced sulfur compounds and deposit elemental sulfur, enriching the sulfur content of surface sediment fivefold over that of deeper sediments. Laboratory flume experiments with Beggiatoa mats from an intertidal sandflat (Nova Scotia) demonstrated that even slight erosion of sediment causes a flux of 160 millimoles of sulfur per square meter per hour, two orders of magnitude greater than the flux produced by sulfur transformations involving either sulfate reduction or sulfide oxidation by benthic bacteria. These experiments indicate that resuspension of sulfur bacterial mats by waves and currents is a rapid mechanism by which sediment sulfur is recycled to the water column. Benthic communities thus lose an important storage intermediate for reduced sulfur as well as a high-quality bacterial food source for benthic grazers.     

Double flood basalts and plume head separation at the 660-kilometer discontinuity

Several of the world's flood basalt provinces display two distinct times of major eruptions separated by between 20 million and 90 million years. These double flood basalts may occur because a starting mantle plume head can separate from its trailing conduit upon passing the interface between the upper mantle and the lower mantle. This detached plume head eventually triggers the first flood basalt event. The remaining conduit forms a new plume head, which causes the second eruptive event. The second plume head is predicted to arrive at the lithosphere at least 10 million years after the first plume head, in general agreement with observations regarding double flood basalts.     

Io: a surface evaporite deposit?

A model is suggested for Io's surface composition involving evaporite salt deposits, rich in sodium and sulfur. According to this model, these deposits were produced as a result of the migration of salt-saturated aqueous solutions to Io's surface from a warm or hot interior followed by loss of the water to space. This model satisfies cosmochemical constraints based on Io's initial composition, current density, and thermal history. Salt-rich assemblages are easily derivable from the leaching of carbonaceous chondritic material; the chemical and optical properties of such deposits, after modification by irradiation, can be used to explain Io's overall albedo and spectral reflectance, its dark reddish poles, and the observed sodium emission as well as or better than other currently suggested materials.     

Sulfur: simulated long-range transport in the atmosphere

One way to examine the question of whether or not air pollutants are transported over distances on a continental scale is by numerical simulation. A simple atmospheric transport and accumulation model, together with mean wind data and an estimated source distribution in Western Europe, were used in this study. The results suggest that Great Britain and Central Europe contribute to the observed concentrations of sulfur in Northern Europe.     

烤烟烘烤工场附近空气SO2质量浓度分析

选取烤烟烘烤工场为监测对象,对其附近SO2质量浓度进行为期两年的监测,分析了烘烤工场周围SO2质量浓度空间分布.分析结果表明:SO2地面质量浓度高值出现在烘烤工场顺风向50 m的频率最大,且离地面0.9～2.1 m空间范围的SO2质量浓度超出限值;烘烤工场顺风向200～300 m内的作物成长环境内SO2质量浓度超出阈值.建立烘烤工场的”控硫”、”降硫”、”避硫”系统,可以从供热方式的转换,洁净能源的使用以及作物敏感期和敏感区的调整来改善烘烤工场超标排放SO2的现状.     

Mass-independent sulfur isotopic compositions in stratospheric volcanic eruptions

The observed mass-independent sulfur isotopic composition (Delta33S) of volcanic sulfate from the Agung (March 1963) and Pinatubo (June 1991) eruptions recorded in the Antarctic snow provides a mechanism for documenting stratospheric events. The sign of Delta33S changes over time from an initial positive component to a negative value. Delta33S is created during photochemical oxidation of sulfur dioxide to sulfuric acid on a monthly time scale, which indicates a fast process. The reproducibility of the results reveals that Delta33S is a reliable tracer to chemically identify atmospheric processes involved during stratospheric volcanism.