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1.
固定床厌氧反应器处理高浓度糖蜜废水   总被引:9,自引:4,他引:5  
为开发高效处理高浓度有机废水的厌氧沼气发酵技术,以活性炭纤维作为生物膜载体,在实验室规模上对固定床厌氧反应器处理高浓度糖蜜废水的运行性能进行了研究。初始进水COD为5 000 mg/L,水力停留时间(HRT)保持在2 d左右。在进水COD为47 000 mg/L以内时,相应的有机容积负荷(OLR,COD含量)达到21.38 kg/(m3×d),COD去除率保持在86%以上,沼气容积产气率为9.51 L /(L×d),甲烷容积产气率为6.46 L /(L×d);当OLR进一步从21.38 kg/(m3×d) 逐步升高到35.13、39.06、44.88 kg/(m3×d) 时,COD去除率从86.48%分别降低到74.40%,67.02% 和63.50%,相应的沼气容积产气率为13.71,13.98和11.44 L/(L×d),甲烷容积产气率为8.84,8.67和5.89 L/(L×d)。进水的pH值通常在3.5~5.6之间,OLR低于35.13 kg/(m3×d) 时,无需对pH值进行中和调节,出水的pH值自然维持在6.8~7.6的良好状态,超出此范围,则需加碱对进水的pH值作适当调节。最终进水COD高达78 600 mg/L,相应的OLR为44.88 kg/(m3×d)。在165 d的运行过程中污泥形成量小,没有发生堵塞现象,固定床厌氧反应器表现出高效的处理酸性高浓度有机废水和较强的抗负荷冲击的能力。  相似文献   

2.
鲜水葫芦与其汁液厌氧发酵产沼气效率比较   总被引:4,自引:3,他引:1  
为开发高效处理水葫芦的厌氧发酵产沼气技术,该文在35℃中温条件下,分别以鲜水葫芦和经固液分离的水葫芦汁为发酵底物,应用实验室自行设计的2套完全混合搅拌反应器(CSTR)进行了厌氧发酵比较研究。结果表明,以水葫芦为底物直接进行厌氧发酵,最大容积负荷为2.0kg/(m3·d),挥发性固体(VS)产气率为267mL/g,容积产气率为0.61m3/(m3·d),滞留期为27d,平均甲烷体积分数为58%,而以水葫芦汁为底物,COD(化学需氧量)容积负荷可达6.0kg/(m3·d),原料(COD)产气率为231mL/g,容积产气率可达1.4m3/(m3·d),平均甲烷体积分数为66%,滞留期仅需2.4d,COD平均去除率达85%,MLVSS(挥发性悬浮物浓度)平均去除率可达88%。因此,对水葫芦进行固液分离,以水葫芦汁作为厌氧发酵原料可大大提高处理效率,为水葫芦资源化利用提供了一条新途径。  相似文献   

3.
不同有机负荷下混合蔬菜废物厌氧消化性能分析   总被引:1,自引:0,他引:1  
为优化蔬菜废物厌氧消化工艺,提高蔬菜废物厌氧消化处理效率,该文以混合蔬菜废物为原料,通过逐级提高厌氧反应的有机负荷,分析研究了蔬菜废物在不同有机负荷下的厌氧消化性能及相应的物质转化规律。试验在有机负荷率OLR 1.0、1.5、1.75、2.0、2.25、2.5、3.0、3.25、3.5 g/(L·d)条件下共运行170 d。研究结果表明:最优有机负荷率为2.75 g/(L·d),极限有机负荷率为3.5 g/(L·d);在2.75 g/(L·d)条件下有机负荷产气率达到最高,达到0.54 L/(g/(L·d)),甲烷体积分数稳定在51%~59%。有机负荷2.75和3.0 g/(L·d)条件下挥发性固体去除率最高达66.81%。有机负荷率在1.0~3.25 g/(L·d)时,挥发性有机酸质量浓度在409~481 mg/L,乙醇浓度在380~490 mg/L,属乙醇型发酵。该研究结果可为提高蔬菜废物厌氧消化处理效率提供理论依据,具有重要意义。  相似文献   

4.
为优化重庆地区农村户用沼气池的厌氧发酵过程,提高沼气产量和沼液化学需氧量(chemical oxygen demand,COD)去除率,采用均匀设计,研究了不同运行条件(总固体(total solid,TS)浓度,进料比和搅拌频率)对猪粪和玉米秆混合半连续厌氧发酵过程的影响,探讨了适宜条件下的微生物群落结构。结果表明,产气的适宜条件为TS 7%、进料比5%、搅拌频率2次/d;COD去除的适宜条件为TS 5%、进料比10%、搅拌频率1次/d;TS和搅拌频率越小,COD去除率越高,原料的利用程度越好。综上考虑,选择后者为猪粪与玉米秆混合发酵的最优条件,整个过程平均容积产气率为0.498 L/(L·d);增大换料程度后,产气率由0.405 L/(L·d)提升到0.592 L/(L·d),COD去除率为82.7%,且发酵环境中形成了稳定高效的微生物群落,其中细菌和古菌的优势种群都达到了微生物种群的80%以上,细菌主要是厚壁菌门(Firmicutes,占59.16%)和拟杆菌门(Bacteroidetes,占26.89%),古菌主要是甲烷八叠球菌属(Methanosarcina,占65.88%)和甲烷杆菌属(Methanobacterium,占18.01%)。本研究为户用沼气池的稳定产气和运行管理提供了科学依据。  相似文献   

5.
UASB处理养猪场废水条件下进水浓度对污泥颗粒化的影响   总被引:2,自引:0,他引:2  
UASB能够在很高负荷下稳定运行的重要原因在于反应器内形成的厌氧颗粒污泥。该文研究了利用UASB处理猪场废水时进水COD浓度对污泥颗粒化的影响,结果发现:颗粒直径随进水浓度的上升而增高,受传质过程中所能进入颗粒内部的营养量所控制,因此要根据COD去除率的情况适时提高进水浓度,及时地随微生物数量的增加补充营养,促进污泥颗粒化;也可以避免因浓度变化太快引起细菌生长过快,污泥结构松散,沉降性能下降,COD去除率和产气率降低。  相似文献   

6.
增设回流提高厌氧氨氧化反应器脱氮效能   总被引:2,自引:1,他引:2  
采用2套上流式反应器接种厌氧氨氧化污泥,研究了高基质浓度下增设回流对厌氧氨氧化反应器脱氮性能影响.研究结果表明,增设出水回流的反应器1经过116 d的运行,进水NH4+-N和NO2--N质量浓度由初始100、130 mg/L达到602、782 mg/L时,出水质量浓度仅增加到44、60 mg/L,氮容积去除负荷最高达到7.87 kg/(m3·d).NO2--N与NH4+-N的转化比维持在1.303,NO3--N生成量与NH4+-N转化量之比维持在0.24.无回流的反应器2经过67 d运行,进水NH4+-N和NO2--N质量浓度由最初100、130 mg/L分别增加到456和600 mg/L,相应出水质量浓度达到174和253 mg/L,氮容积去除负荷最高达到4.31 kg/(m3·d).NO2--N与NH4+-N的转化比维持在1.298左右, NO3--N生成量与NH4+-N转化量之比维持在0.21.说明回流对进入反应器的基质具有较强稀释作用,有助于避免高基质浓度对厌氧氨氧化活性的影响,同时对厌氧氨氧化反应过程中氮素转化比不产生影响.增设出水回流后的反应器1污泥粒径主要分布在1.25~2 mm之间,而反应器2污泥粒径主要分布在0.9~1.6 mm.说明在反应器运行过程中增设回流有助于反应器内液体上升流速的增加,颗粒污泥具有良好的流态,能够更好地与底物接触,有利于微生物增长.  相似文献   

7.
养猪废水成分复杂,所含悬浮性固体对其生物发酵过程影响显著;利用经过粉碎压实后的玉米秸秆对养猪废水进行负压抽滤,吸附截留废水中的悬浮性固体。再利用上流式厌氧污泥床(UASB,up-flow anaerobic sludge bed/blanket)反应器对过滤后的养猪废水进厌氧发酵,探究发酵过程中随着有机负荷的增加,化学需氧量(COD,chemical oxygen demand)去除率、pH值、产气量的变化规律,并采用高通量测序技术分析最优负荷时厌氧消化污泥中的细菌与古菌群落组成。过滤试验表明,在过滤压差为40kPa、滤层厚度为15cm、滤料压实度为1.6倍密度(148.8kg/m3)时有较好的过滤效果,此时总固体(TS,total solid)、挥发性固体(VS,volatile solid)、COD的去除率分别为33.08%、28.05%、23.01%。厌氧发酵试验结果表明,在温度为(35±1)℃时反应器稳定运行的最高负荷为11 kg/(m3·d);反应器处理效果最优的负荷为10 kg/(m3·d),此时进水COD浓度为5 000 mg/L、COD去除率为76.46%、容积产气率为1.51m3/(m3·d)。高通量测序结果表明,厌氧发酵过程由多种微生物菌群协同作用,主要的细菌群类是Firmicutes、Bacteroidota,主要古菌群类为Halobacterota,且高效产甲烷菌分布丰富。试验结果为利用作物秸秆过滤养猪废水进行以废治废的技术应用提供了依据。  相似文献   

8.
厌氧氨氧化是一种高效的脱氮处理工艺,但其启动和运行过程困难,高效反应器是解决此问题的有效手段。本文利用改进的上流式双层厌氧滤器开展厌氧氨氧化启动反应的试验研究。在反应器填料上分别接种反硝化污泥、厌氧污泥、混合污泥,通过模拟废水提供自养反硝化条件,并逐步提高基质浓度和水力负荷,促使菌群向厌氧氨氧化反应转变。试验发现,反硝化污泥、厌氧污泥、混合污泥均可启动厌氧氨氧化反应,启动时间分别为42、54 d和45 d。以反硝化污泥为接种物的启动效果最好,启动时间较短且废水氮素去除率高,总氮去除率最高达到82.2%。双层填料的反应器有效提高了厌氧氨氧化的稳定性,该反应器中厌氧氨氧化菌对氨氮、亚硝氮的适宜浓度负荷为270、360 mg·L~(-1),废水中COD浓度不宜超过150 mg·L~(-1),系统中存在厌氧氨氧化和甲烷化共存的效应。  相似文献   

9.
有机负荷对厨余垃圾常温厌氧发酵产甲烷的影响   总被引:3,自引:2,他引:1  
为了考察在不同有机负荷下厨余常温厌氧发酵产甲烷的特性,试验以厨余垃圾为原料,在常温(27℃)条件下,采用40L厌氧反应器进行连续式厌氧消化。结果表明,当有机负荷率控制在3.89~6.49 kg/(m3·d)之间,池容产气率可稳定在2.5~4.5 L/(L·d),原料挥发性固体产甲烷率为300.59~488.52 L/kg,平均甲烷体积分数为54.05%~56.04%,挥发性固体物去除率为55.12%~89.58%;因此,将有机负荷率控制在3.89~6.49 kg/(m3·d)之间,厨余垃圾在常温下厌氧消化可达到较高的原料产甲烷率和稳定的产甲烷过程。  相似文献   

10.
为实现从畜禽废水处理中回收能源,先后以厌氧沼液、低浓度畜禽原水及高浓度畜禽原水作为进水,利用厌氧流化床双室微生物燃料电池(anaerobic fluidized bed microbial fuel cell,AFB-MFC)进行微生物产电及有机物去除研究,重点考察氨态氮质量浓度及COD(化学需氧量)容积负荷对系统COD去除率及产电性能的影响。结果表明:以稀释后的沼液作为进水时,当氨态氮质量浓度达到387.6mg/L时,氨态氮对产电微生物产生明显的短期抑制,产电量下降7.0%,但经过5d的适应期后,系统产电恢复到原来的水平。以畜禽原水作为进水时,系统COD容积负荷在12d内由2.3kg/(m3·d)提升至14.9kg/(m3·d)时,COD去除率保持在74.5%~88.1%;随着容积负荷的提升,系统产电量上升,但上升幅度较小,最高输出电压为379.3mV,相应的面积功率密度为74.9mW/m2;由于进水pH值的差异,高浓度畜禽原水最高输出电压较低浓度畜禽原水低21.4mV;AFB-MFC系统内阻较低,仅为48.5Ω,此时功率密度为75.6mW/m2。本装置实现了畜禽废水的高效处理,同时获得电能,为其资源化处理提供新途径。  相似文献   

11.
【目的】以富士(Fuji)、 秦冠(Qinguan)嫁接在平邑甜茶(Malus hupehensis Rehd.)上的当年生盆栽苗为试验材料,采用砂培方法,研究了缺氮胁迫和干旱对富士和秦冠生长情况、 光合参数、 植株各部位氮磷钾含量及氮素利用效率的影响,分析比较了低氮干旱条件下富士和秦冠生长及氮素利用的差异,以期为果树生产高效肥水利用提供理论指导。【方法】试验共设四个处理: 正常氮正常水(ZZ)、 低氮正常水(DZ)、 正常氮干旱(ZG)、 低氮干旱(DG)。氮素和水分均设置两个水平,分别为正常氮(6 mmol/L NO-3-N)、 低氮(0.3 mmol/LNO-3-N)、 正常供水(保持盆中砂子相对含水量为饱和含水量的80%~85%)、 干旱处理(保持盆中砂子相对含水量为饱和含水量的60%~65%)。【结果】富士和秦冠的生物量(茎和叶)、 株高茎粗等生长指标以及光合速率、 气孔导度、 蒸腾速率均为正常氮正常水(ZZ)>低氮正常水(DZ)>正常氮干旱(ZG)>低氮干旱(DG),并且相对应处理下秦冠的以上指标均高于富士;正常供水下,缺氮处理使富士、 秦冠的根冠比比正常氮处理均有所增加,富士提高了2.05%,秦冠提高了22.40%。富士和秦冠的氮、 磷、 钾含量均表现出正常氮正常水(ZZ)>低氮正常水(DZ)>正常氮干旱(ZG)>低氮干旱(DG); 氮、 钾元素含量在植株各部位的分布顺序依次是叶>根>茎,磷元素则是根>叶>茎;光合氮素利用效率(PNUE)和氮素利用效率表现为秦冠处理之间差异极显著,富士处理之间差异不显著;秦冠的PNUE和NUE明显高于富士,在低氮正常水(DZ)处理下,秦冠氮肥利用率比富士高42.07%,在低氮干旱(DG)处理下高64.14%;低氮胁迫下富士和秦冠的NUE显著提高,并且秦冠提高的幅度高于富士。【结论】施用氮肥能够显著提高富士与秦冠的干物质量,同等水肥条件下,秦冠生长优于富士;水分亏缺会减少叶片对氮的吸收,干旱条件下适度增施氮肥,可提高果树的抗旱能力;低氮干旱胁迫下秦冠的生长指标、 光合指标及氮素利用效率指标均优于富士,表现出较强的抗低氮干旱胁迫的能力。  相似文献   

12.
Laser-induced breakdown spectroscopy (LIBS) is a new technique for the analysis of plant material. This study investigates the application of LIBS to pasture-based plant samples. The LIBS measurements were obtained from pelletized pasture samples (100 samples) that had been also analyzed by inductively coupled plasma–optical emission spectroscopy (ICP-OES) following microwave digestion for calibration and comparison purposes. Comparisons for elements sodium (Na), potassium (K), magnesium (Mg), calcium (Ca), manganese (Mn), iron (Fe), copper (Cu), zinc (Zn), boron (B), phosphorus (P), and sulfur (S) showed that LIBS could be used for almost all the standard profile total elements with concentrations down to low mg/kg levels (observed error of Na: 0.024 percent, K: 0.18 percent, Mg: 0.016 percent, Ca: 0.073 percent, P: 0.017 percent, Mn: 31 mg/kg, Fe: 150 mg/kg, Zn: 6.6 mg/kg, and B: 1.1 mg/kg). Elemental analysis at less than mg/kg levels was not possible using LIBS. The elements S and Cu were particularly difficult to analyze with reliability using LIBS at the concentration levels found in the plant samples. Replacing microwave digestion and subsequent ICP analysis with a direct analysis of dried plant samples using LIBS has the potential to improve the productivity and reduce the cost of testing.  相似文献   

13.
正The Center for Agricultural Resources Research(CARR),the Institute of Genetics and Developmental Biology(IGDB),Chinese Academy of Sciences,invites applicants for several research group leader positions.CARR is one of the research organizations in Chinese Academy of Sciences(CAS).We seek nominations and applications from individuals who have expertise and a record of accomplishment in research areas related to ecology,agro-hydrology,  相似文献   

14.
Staff members of the Department of Botany of Palacký University in Olomouc and Gene Bank Department – Workplace Olomouc, Research Institute of Crop Production in Prague, Czech Republic, conducted an expedition in seven European countries (Austria, Czech Republic, France, Germany, Italy, the Netherlands, Switzerland) in August/September 1999 to collect wild Lactuca spp. germplasm and study its geographic distribution, ecology and biodiversity. During the mission, more than 600 locations were visited resulting in the collection of 602 seed samples (accessions) of wild Lactuca species and 13 seed samples of related genera (Chondrilla and Mycelis). Lactuca serriola f. serriola, L. serriola f. integrifolia, L. saligna and L. viminea subsp. chondrilliflora were prevalent in southern Europe (Italy, France), however, only L. serriola was common in central and western Europe (Austria, Czech Republic, Germany, Netherlands, Switzerland). The greatest diversity of Lactuca species was found in France, where also the most seed samples (165) were collected. The most characteristic habitats with a high density of Lactuca spp. populations were observed along roads and highways, grassy ditches, ruderal communities, and dust-heaps. Natural infections by powdery mildew (Erysiphe cichoracearum) and downy mildew (Bremia lactucae) on some wild Lactuca spp. were observed. Recent observations concerning the geographic distribution, population structure, habitats, and natural occurrence of diseases of Lactuca spp. are discussed. This assemblage of genetic resources of Lactuca spp. can serve as the basis of future studies of species diversification, spatial population structure, plant microevolution, domestication processes, and genetic variability of host-parasite interactions.  相似文献   

15.
The responses of tallgrass prairie plant communities and ecosystem processes to fire and grazing are well characterized. However, responses of invertebrate consumer groups, and particularly soil-dwelling organisms, to these disturbances are not well known. At Konza Prairie Biological Station, we sampled soil macroinvertebrates in 1994 and 1999 as part of a long-term experiment designed to examine the effects and interactions of annual fire, mowing, and fertilization (N and P) on prairie soil communities and processes. For nearly all taxa, in both years, responses were characterized by significant treatment interactions, but some general patterns were evident. Introduced European earthworms (Aporrectodea spp. and Octolasion spp.) were most abundant in plots where fire was excluded, and the proportion of the total earthworm community consisting of introduced earthworms was greater in unburned, unmowed, and fertilized plots. Nymphs of two Cicada genera were collected (Cicadetta spp. and Tibicen spp.). Cicadetta nymphs were more abundant in burned plots, but mowing reduced their abundance. Tibicen nymphs were collected almost exclusively from unburned plots. Treatment effects on herbivorous beetle larvae (Scarabaeidae, Elateridae, and Curculionidae) were variable, but nutrient additions (N or P) usually resulted in greater densities, whereas mowing usually resulted in lower densities. Our results suggest that departures from historical disturbance regimes (i.e. frequent fire and grazing) may render soils more susceptible to increased numbers of European earthworms, and that interactions between fire, aboveground biomass removal, and vegetation responses affect the structure and composition of invertebrate communities in tallgrass prairie soils.  相似文献   

16.
We have studied the effect of anaerobically digested (ADMSW) and composted municipal solid waste (CMSW) on mineralization and foodweb dynamics to verify the hypothesis that ADMSW would immobilize N right after addition to soil in contrast to addition with CMSW. Another hypothesis was that the mesofauna (enchytraeids and microarthropods) would stimulate N release from the decomposer community. We measured excretion of -N and urea-N from the mesofauna and hypothesized that enchytraeids would release urea. ADMSW and CMSW were amended to pots with sandy loam and barley. The pots were divided into treatments with or without mesofauna. Mesofauna, plant N and biomass, soil N and ergosterol (fungal biomass) were measured over a 113-day period of four equidistant samplings. Soil respiration, N mineralization and N release by the mesofauna were modelled from concurrent studies. ADMSW- and CMSW-treated soils initially (<20 days) immobilized N. The amendments did not increase plant growth substantially, and this was probably due to N-limitation in the early stages of plant growth. Enchytraeid abundance was about three times higher in ADMSW- than CMSW-treated soils, indicating that ADMSW contained more labile compounds, bacteria, and microfauna. The mesofauna did not affect N-content, but the cumulated -N excreted by the mesofauna was estimated to be substantial and about one-fifth of total plant N in ADMSW. An explanation for this discrepancy might be that in the absence of the mesofauna, other members of the detrivore and microbivore community performed the mesofauna’s function. Neither enchytraeids nor microarthropods excreted urea.  相似文献   

17.
正The Center for Agricultural Resources Research(CARR),the Institute of Genetics and Developmental Biology(IGDB),Chinese Academy of Sciences,invites applicants for several research group leader positions.CARR is one of the research organizations in Chinese Academy of Sciences(CAS).We seek nominations and applications from individuals who have expertise and a record of accomplishment in research areas related to ecology,agro-hydrology,  相似文献   

18.
正The Center for Agricultural Resources Research(CARR),the Institute of Genetics and Developmental Biology(IGDB),Chinese Academy of Sciences,invites applicants for several research group leader positions.CARR is one of the research organizations in Chinese Academy of Sciences(CAS).We seek nominations and applications from individuals who have expertise and a record of accomplishment in research areas related to ecology,agro-hydrology,  相似文献   

19.
Abstract

A 3-year study was carried out to investigate quality parameters in 14 tree fruit and berry species grown in southern Norway. The species were blueberry, apple, aronia, sour cherry, sweet cherry, red raspberry, strawberry, blackcurrant, gooseberry, red currant and elderberry, harvested along with wild bilberry, cloudberry and lingonberry. Significant differences between species were identified for all quality parameters. The coefficient of variation between species was lowest for pH (12.5%), dry matter (18.9%) and soluble solids (25.3%), followed by titratable acids (59.3%), total phenolics (83.8%), antioxidant capacity FRAP (85.7%) and antiradical power by the DPPH-assay (97.8%), total monomeric anthocyanins (132%) and ascorbic acid (137%). Average coefficient of variation within species were lower and ranged from 4 (pH) to 62% (ascorbic acid). Only the FRAP values were significantly affected by harvesting year with lower levels in 2004 than in 2005 and 2006. There were significant interactions between species and harvesting year for dry matter, soluble solids, pH, ascorbic acid and FRAP. The results indicate generic ranges in composition within species independent upon growing location and climate, and the composition of the tree fruits and berries is not likely to deviate from these ranges. It is concluded that desirable composition of tree fruits and berries and their products should primarily be achieved by selection among species rather than searching fors broadened variation within individual species.  相似文献   

20.
Potassium (K) fixation and release in soil are important factors in the long-term sustainability of a cropping system. Changes in K concentration and characteristics of K fixation and release in rhizosphere and nonrhizosphere soils in the rapeseed (Brassica napus L.)–rice (Oryza sativa L.) rotation were investigated using a rhizobox system. The concentrations of different forms of K in both rhizosphere and nonrhizosphere soils decreased with plants compared to without plants, regardless of K fertilizer application. Potassium uptake by crops mainly came from the rhizosphere soil. In the treatment without K fertilizer (–K), the main form of K supplied by the soil to the crops was 1.0 mol L?1 nitric acid (HNO3) nonextractable K, followed by nonexchangeable K, and then exchangeable K. In the treatment with K fertilizer (+K), the main K forms supplied by the soil to the crops were exchangeable K and nonexchangeable K. The amount and rate of K fixation after one cycle of the rapeseed–rice rotation was greater in rhizosphere soil than in nonrhizosphere soil. The amount and rate of K fixation of soil in the +K treatment were significantly less than in the –K treatment. The cumulative amounts of K released with 1.0 mol L?1 ammonium acetate (NH4OAc) and 1.0 mol L?1 HNO3 extraction increased with the increasing numbers of extractions, but the K-releasing power of soil by successive extraction decreased gradually and finally became almost constant. The release of K was less in rhizosphere soil than in nonrhizosphere soil. The release of K in the +K treatment was similar to that in the –K treatment in rhizosphere soil, but the K release in nonrhizosphere soil was greater with the +K than the –K treatment. Overall, the information obtained in this study will be helpful in formulating more precise K fertilizer recommendations for certain soils.  相似文献   

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