杨树浸渍改性材物理及力学性能研究

利用聚乙烯醇缩甲醛复合改性剂对杨树木材进行浸渍改性处理,对比研究了杨树素材与改性材的物理性能及主要力学性能的变化,并利用扫描电子显微镜(SEM)分析了改性剂在改性材中的分布情况。结果表明:改性材的气干密度和抗缩系数(PASE)随改性剂浓度的上升而增加,改性材的气干密度最高为0.41 g/cm3,比素材的提高了13.9%,抗缩系数(PASE)最大提高到47.8%。改性材吸水率随改性剂浓度的上升而下降,与素材相比最大下降了19.2%。当改性剂的浓度为25%时,改性材的弹性模量和静曲强度达最大,分别为27.4%和13%。SEM分析显示改性剂填充于部分木射线以及交错纤维间的空隙中。     

杨树浸渍改性处理材尺寸稳定性研究

利用聚乙烯醇缩甲醛改性剂对杨树木材进行浸渍改性,对其改性材的尺寸稳定性进行研究。结果表明:改性材的径向、弦向和体积干缩率与素材相比均有不同程度的下降;从全干到吸水饱和状态的过程中,当改性剂达到一定浓度时,改性材的径向、体积湿胀率与素材相比有明显下降,弦向线湿胀率下降不明显。从气干到吸水饱和状态的过程中,改性材的径向、弦向湿胀率与素材相比均有不同程度的下降;改性材体积湿胀率随着改性剂浓度的上升而呈下降趋势,当改性剂浓度为30%时,改性材体积湿胀率为6.85%,与素材相比下降了5.54%。改性材吸水率随改性剂浓度的上升而下降,最低可达159%;改性材的抗干缩系数(ASE)随改性剂浓度上升而增加,最大可达47.8%。改性材的尺寸稳定性能要明显优于杨树素材。     

Viscoelastic properties of wood from Chinese-fir and poplar plantations

Elastic and strength properties(proportional-limit stress(σ prop ),Young's modulus(E),breaking stress(σ max )in static bending parallel to grain in a longitudinal direction),as well as stress relaxation in air-dried condition and water-saturated conditions at seven different constant temperatures and increasing and decreasing temperatures were investigated for wood from Chinese-fir and poplar plantations.The results show that hygrothermal conditions considerably affect these mechanical properties.The higher the moisture content(MC)or temperature,the lower the strength of wood.Further investigation of the effects of constant temperature on stress relaxation indicates that high temperature specimens have low relaxation moduli and high fluidity.In the case of increasing temperature the range of the modulus of relaxation is larger than in the case of a reduction in temperature,while the residual moduli do not show large differences.This is because the modulus at high temperatures decreases more than that at low temperatures.The fluidity of specimens in a state of water desorption increases slowly at the beginning,increases quickly until the MC reaches an equilibrium moisture content(EMC)and then becomes stable,which is quite different from that in a water-saturated state.Fluidity in a desorption state is much higher than in a water-saturated state.This is probably due to the fact that the former is in an unstable state which can be interpreted as a state with internal strain and has therefore a greater potential to release strain.     

The effect of number of joints on bending properties of laminated lumber made from poplar (Populus nigra)

Connection plays an important role in structural components and end jointing is one of the most common connections in structural applications.This study was designed to investigate some mechanical properties (MOE and MOR) of solid wood samples manufactured from poplar (Populus nigra),joined together through end jointing.As well,we studied combinations of lumber manufactured from 10-mm veneer,using a polyvinyl acetate adhesive.The results show that non-jointed lumber (control samples) have better bending properties (MOE and MOR) than jointed specimens and lumber made from laminated layers.On the whole,side-byside joints have a negative effect on the MOR and MOE of laminated products,which is more pronounced in the MOR.By increasing the number of joints,the properties of combination of three-ply,i.e.,bending strength and modulus of elasticity,decreased.     

不同处理方法对杨树木材压缩变形恢复率的研究

采用加热和水蒸气处理方法对人工林杨树木材进行压缩变形恢复率的研究,目的是为了改善人工林软质木材的材性,提高其尺寸稳定性。结果表明:加热和水蒸气处理都是固定人工林木材压缩变形的有效方法;在处理温度相同时,水蒸气处理方法只需要4 min或8 min,而高温加热处理需要10 h或20 h。水蒸气处理方法更加经济。     

混合组坯对杨木单板层积材弹性常数及力学性能的影响

单板层积材具有结构均匀、强度高等优点,材料、结构、制造工艺等差异对其性能影响显著。以13层22 mm厚全顺纹、2层及3层横纹其余顺纹混合组坯的杨木单板层积材为对象,通过电测法、三点弯曲及拉伸实验,对其主要弹性常数及力学性能参数进行测试,得出以下结论:1)随着横纹层数的增加,顺纹方向的弹性模量下降,横纹方向的弹性模量增加,层积方向的弹性模量先减小后增加,单板层积材的各向异性降低;2)随着横纹层数的增加,静曲强度减小,变异性逐渐增大,进行结构设计时需更多考虑材料的性能稳定性;3)组坯方式对LVL抗拉强度的影响不大,适当增加横纹层板可提高抗拉强度;4)组坯方式对泊松比的影响较大,随着横纹层数的增加,泊松比总体降低,采用纵横混合式组坯可能有利于抵抗由拉、压载荷所造成的材料变形。     

杨木水泥刨花板工艺的研究

对杨木水泥刨花板的物理力学性能与主要工艺参数——密度、木灰比、水灰比、添加剂及添加量的关系作了研究。结果表明,密度(D)对板材性能影响最大,木灰比(W/C)次之,水灰比(W_1/C)最小;板材的主要性能如MOR、MOE、IB同密度、木灰比、水灰比的关系,可用方程Y=a_0+a_1D+a_2(W/C)+a_3(W/C)~2+a_4(W_1/C)+a_5(W_1/C)~2表示;在各种添加剂中,以氯化钙的效果最好。     

A5-13杨、A5-17杨木材材性测定

以A5-13杨、A5-17杨等6个杨树种、品种(系)为试验材料,对基本密度、气干密度、干缩系数、纤维长度、纤维宽度及综纤维素含量进行了测定,结果表明:A5-13杨、A5-17杨属于木材密度中等的品系,基本密度均为0.36 g·cm-3,气干密度分别为0.43 g·cm-3、0.42 g·cm-3;体积干缩系数分别为0....     

杨村新无性系木材物理力学性质的研究

研究了7个杨树新无性系和I－69杨的木材物理力学性质。结果表明，杨木新无性系的物理力学性质等主要指标均属于小至甚小级，无性系间物理力学性质差异显著，据此可用木材物理力学性质因子选育优良无性系。尽管新无性系的生长速度超过I－69杨，但由于其某些强度指标低于I－69杨，8年生的速生材尚不能完全替代11年生的I－69杨使用，因此不能作为建筑结构材使用。     

Dielectric properties of Simon poplar wood flour/polypropylene composite at oven-dry state

Interfacial compatibility is a crucial factor to the performance of wood-plastic composites （WPCs）. Yet, so far, the coupling mechanisms of WPC have not been completely understood. In order to further clarify the interfacial coupling mechanism, the dielectric constant and dielectric loss factor of Simon poplar wood flour/polypropylene composites without additives at different wood contents were measured at oven-dry state, and parameters and thermodynamic quantities of the relaxation process were also analyzed and calculated. Consequently, an obvious relaxation process based on the reorientation of methanol groups in amorphous region of wood cell wall was observed exactly that its dielectric loss factor peak decreased with the decreasing wood content within the measured range of 50%-100%. With the trend of dielectric relaxation strength, the two changing trends both revealed that the existence of polypropylene could hinder reorientation of methanol groups. Following the decreasing wood contents, the effect of the hindrance on the dielectric properties turned obvious gradually. It elucidated that introduction of polypropylene caused the quantities of hydrogen bonds formed between each methanol group and the groups around it change. The same conclusion could be drawn from the analysis of thermodynamic quantities during the dielectric relaxation progress.     

杨木制备纤维乙醇过程中化学成分变化的分析

杨树是我国重要的速生树种。以杨木为原料制备生物乙醇是解决当今能源问题的一项新的尝试。对杨木原料蒸汽爆破预处理后以及菌处理后的化学成分及化学性质进行了测定分析。通过对比其化学成分(纤维素、木素、半纤维素、抽出物、灰分及蛋白质)的变化,研究了以杨木为原料制备生物乙醇生产过程中化学成分变化机理,旨在为指导杨木制备木质纤维乙醇的生产,并为发酵后副产物的回收再利用提供理论依据。     

不同栽培林龄和轮次的杨树人工林土壤理化性质

采用空间代替时间的方法,构建了不同栽培林龄和轮次的杨树人工林试验样地,测定了土壤主要物理化学性质.结果表明,不同栽培轮次土壤密度值表现为1轮11年生＞2轮9年生,随着林龄增加,土壤密度呈逐渐下降趋势,表现为2轮3年生＞2轮6年生＞2轮9年生,且各样地之间呈显著差异;土壤饱和持水量、毛管持水量、毛管孔隙度和总孔隙度在各样地之间的变化无明显差异,而土壤非毛管孔隙度的变化则呈显著差异,在不同林龄样地上呈极显著差异.试验结果还显示,表层0～10 cm土壤中各养分元素的含量都对应地高于10～ 30 cm土层的含量,而pH值则呈相反的变化趋势;在不同栽培轮次和林龄的杨树人工林样地上对应土层土壤养分元素无明显的变化规律.     

增强型杨木单板层积材力学性能分析

采用玻璃纤维布与碳纤维布复合材料及分步热压法增强杨木单板层积材,研究了玻璃纤维布与碳纤维布复合材料的铺设位置及分步热压法对杨木单板层积材力学性能的影响.结果表明:两种增强方式对杨木单板层积材静曲强度(MOR)和弹性模量(MOE)的增强效果均较明显;采用对称铺设相同的增强材料时,铺设位置靠近杨木单板层积材表层时对MOR和MOE等力学性能的增强效果较铺设在靠近芯层时的增强效果明显;采用分步热压法可以明显改善单板层积材水平剪切强度.     

The influence of silane coupling agent and poplar particles on the wet-tability,surface roughness,and hardness of UF-bonded wheat straw （Triticum aestivum L.）/poplar wood particleboard

We used silane coupling agents to improve the bonding ability between wheat straw particles and UF resin, and investigated surface properties （wettability and surface roughness） and hardness of parti-cleboard made from UF-bonded wheat straw （Triticum aestivum L.） combined with poplar wood as affected by silane coupling agent content and straw/poplar wood particle ratios. We manufactured one-layered particleboard panels at four different ratios of straw to poplar wood par-ticles （0%, 15%, 30% and 45% wheat straw） and silane coupling agent content at three levels of 0, 5% and 10%. Roughness measurements, average roughness （Ra）, mean peak-to-valley height （Rz）, and root mean square roughness （Rq） were measured on unsanded samples by using a fine stylus tracing technique. We obtained contact angle measurements by using a goniometer connected to a digital camera and computer sys-tem. Boards containing greater amounts of poplar particles had superior hardness compared to control samples and had lower wettability. Panels made with higher amounts of silane had lower Rq values.     

刀具角度对杨木刨片和刨花板性能的影响

以不同角度刀具切制杨木刨片,并制成大片刨花板,对刨片的流变和强度性能及刨花板性能进行了测定和研究。主要结果是:(1)采用较大前角刀具所切出的刨片的流变和强度性能较好,刨花板平面抗拉强度有显著提高,抗弯强度亦有改善;(2)微斜面可在不显著影响刨片和刨花板性能的条件下增强刀刃,为进一步采用更大的前角提供了可能性。     

刨刀角度对杨木和柞木刨片流变性能的影响

以不同前角刨刀切制两种杨木和柞木刨片,根据参数分离法,对其流变性能进行了测定和研究。结果表明:刀具前角不同可导致刨片的流变性能变化;刀具前角增大,刨片流变性能的变化对提高刨花板的性能有利;刀具前角对刨片流变性能的影响在不同树种中基本趋势一致,但对刨花板性能的影响可能因树种而有所不同。     

Vibrational properties of heat-treated green wood

To investigate the influence of water on heat treatment, green wood was heat-treated. Sitka spruce (Picea sitchensis Carr.) with about 60% moisture content (MC) was used. Young's modulus and loss tangent were measured by the free-free flexural vibration test. The specimens were heated in nitrogen at 160°C for 0.5h. The results were as follows. (1) Recognizing that the effects of heat treatment are mild and that the same specimens cannot be used for both heat treatment and as controls, it was necessary to investigate the effects of the heat treatment based on the variations of properties in the whole of the test lumber. (2) Young's modulus increased and the loss tangent decreased due to heat treatment. When the vibrational properties were measured at various MCs, the MCs at the maximum value of Young's modulus and the minimum value of the loss tangent were lower in heat-treated specimens than in controls. The effects of heat treatment in green wood were similar to those in air-dried wood. (3) The loss tangents of heat-treated specimens were smaller than those of controls at about 0% MC but were larger than those of controls at about 10% MC. We thought that this resulted from the decreased MC at the minimum loss tangent after the heat treatment mentioned above. (4) The properties measured at several MCs were more useful than those at only one moisture content for investigating the effects of heat treatment.This study was presented in part at the 46th annual meeting of the Japan Wood Research Society, Kumamoto, April 3–5, 1996; and at the 47th annual meeting of the Japan Wood Research Society, Kochi, April 3–5, 1997     

Influence of moisture content on the vibrational properties of hematoxylin-impregnated wood

The vibrational property of hematoxylinimpregnated wood was investigated from the aspect of moisture content dependence. The specific dynamic Young's modulus (E/) and loss tangent (tan) of hematoxylin-impregnated wood were determined in the relative humidity (RH) range of 0%–97%, and were compared with those of the untreated and some conventional chemically treated woods. The changes in theE/ and tan of wood with increasing RH were suppressed by acetylation and formaldehyde treatment because of a marked reduction in the hygroscopicity of the wood. Although the hematoxylin impregnation did not significantly affect the hygroscopicity of the wood, its influence onE/ and tan were similar to that of formaldehyde treatment at low RH and of acetylation at medium RH. It was supposed that at low to medium RH hematoxylin restrains the molecular motion of amorphous substances in the cell wall because of its bulkiness and rigidity. On the other hand, at high RH it seems to work as a plasticizer with adsorbed water molecules.     

Application of response surface methodology for evaluating particleboard properties made from cotton stalk particles

High-quality wood resource scarcity as well as population growth and demand of wood have encouraged the use of alternative sources of lignocellulosic materials. In this study, the possibility of producing particleboard from waste cotton stalks is evaluated. The effects of the independent variables included weight ratio of melamine-formaldehyde to urea-formaldehyde, shelling ratio and the percentage of cotton stalks to poplar in the core layer were analyzed in the form of response surface methodology based on second-order multiple linear regression model. The results showed that there was perfect agreement between the estimated values and observed data, as with an increase in the ratio of melamine-formaldehyde resin to urea-formaldehyde, shelling ration and amount of poplar in the core layer of panels, modulus of rupture, modulus of elasticity and internal bonding increase. The optimal point of use of investigated variables included 18.30% melamine-formaldehyde, 30.35% thickness of the surface layers and 10.70% of poplar in the core layer.     

Some of the properties of particleboard made from paulownia

The objective of this study was to determine some of the properties of experimental particleboard panels made from low-quality paulownia (Paulownia tomentosa). Chemical properties including holocellulose, cellulose, lignin contents, water solubility, and pH level of the wood were also analyzed. Three-layer experimental panels were manufactured with two density levels using urea–formaldehyde as a binder. Modulus of elasticity (MOE), modulus of rupture (MOR), internal bond strength (IB), screw-holding strength, thickness swelling, and surface roughness of the specimens were evaluated. Panels with densities of 0.65 g/cm³ and manufactured using a 7-min press time resulted in higher mechanical properties than those of made with densities of 0.55 g/cm³ and press times of 5 min. Based on the initial findings of this study, it appears that higher values of solubility and lignin content of the raw material contributed to better physical and mechanical properties of the experimental panels. All types of strength characteristics of the samples manufactured from underutilized low-quality paulownia wood met the minimum strength requirements of the European Standards for general uses.