上海宝山和青浦区表土磁性特征的差异及环境指示意义

分别在上海宝山区和青浦区设置49和36个监测点,对表土磁化率(χl)f和主要重金属污染元素含量进行比较研究。结果表明:宝山表土Cu、Zn、Pb、Cd、Cr、Mn和Ni的平均含量分别为31.2、194.1、140.8、0.55、85.5、805.7和36.5 mg kg-1;青浦区表土平均含量分别为39.7、128.8、38.5、0.36、62.4、567.2和34.7 mg kg-1。宝山表土重金属污染程度普遍高于青浦,尤其是Pb、Cd、Zn含量显著高于青浦。宝山表土χlf显著增强,平均为180.1×10-8 m3 kg-1,且区域分异性较大,变异系数达110.4%;青浦表土χlf平均为32.7×10-8 m3 kg-1,变幅为10.4×10-8~117.5×10-8 m3 kg-1,变异系数为75.5%。宝山表土χlf与Cu、Zn、Pb、Cr、Mn、Ni、Fe含量存在极显著正相关关系(P<0.01);但青浦表土χlf仅与Zn、Mn(P<0.01)、Cu(P<0.05)显著相关。两区表土磁性特征、重金属累积以及两者相关性的差异,与不同的土地利用方式有关。尤其是青浦稻田土壤磁性弱,是该区χlf与重金属含量相关程度较低的重要原因。     

上海宝山不同功能区表土磁化率特征及对重金属污染的指示作用

以上海宝山区为例,开展表土磁化率与其重金属含量相关性研究。根据研究区域土地功能特征,选取工业区表土、公路边表土、居民区表土和农田表土(0~5 cm)作为研究对象,共采集80个样品,进行磁化率和重金属元素(Fe、Zn、Cr、Ni、Mn、Cu、Pb和Cd)含量分析。结果表明,宝山各功能区表土多数重金属含量和磁化率,均不同程度地超出上海土壤背景值。其中,工业区表土重金属Zn、Cr、Pb元素含量以及公路边表土Zn、Pb、Cd元素含量均超出上海土壤背景值的4倍以上,且空间分异性较大。工业区和公路边表土磁性增强显著,且空间变异性大。工业区表土磁化率与Zn、Mn、Pb和Cd含量呈极显著正相关(P0.01);公路边表土磁化率与Zn、Cr、Mn、Cu、Fe2O_3含量呈极显著正相关(P0.01)。表明受工业和交通影响的表土,其磁化率对重金属污染有很好的指标作用。居民区和农田表土的磁化率,只与个别重金属元素呈显著相关,表明以土壤磁化率来指示重金属污染会受到土地利用方式及周边环境等因素的限制。     

上海宝山区城市表土重金属累积的空间分布规律

检测了上海宝山区127个表土样点的重金属含量。宝山区表土Zn、Cr、Cd、Pb、Cu、Ni、Mn的平均含量分别为228.6、127.6、0.56、118.5、55.2、55.7、718.7mg/kg。其中Pb、Zn、Cd的含量分别是上海土壤背景值的5.6、3.0、2.8倍,受污染较明显。宝山区地表的重金属含量呈现出明显的空间分布规律:工业区地表,如吴淞、大场等地,多种重金属污染均很重,Zn、Cr、Cd、Pb、Cu的平均含量分别高达407.6、319.0、0.75、101.2、76.2mg/kg;马路绿地土壤Pb的累积较显著,平均为180.2mg/kg;远郊菜地土壤重金属污染不明显。     

青藏高原表土磁化率空间分布特征及影响因素

土壤磁化率是古环境重建的常用代用指标，对表土磁化率与现代环境的关系研究有助于理解磁化率产生差异的原因。当前，区域尺度上土壤磁化率变化成因认知的缺乏限制了磁化率作为古环境重建重要代用指标的精准应用。本研究系统调查了青藏高原的254个样点表层(发生层A层)土样，测定土壤磁化率和其他土壤属性，结合母质、气候、地形和植被等数据，阐明青藏高原地区土壤磁化率空间变化特征，及其主要影响因素。结果表明：(1)不同母质类型之间，表层土壤磁化率(χlf)无显著差异，百分频率磁化率(χfd%)差异显著，黄土和砂页岩风化物>冰碛物和结晶盐风化物，其他母质类型之间无显著差异；不同土地利用之间，表层土壤χlf无显著差异，χfd%差异显著：森林和旱地>草地>荒地。(2)各因子对土壤磁化率影响，植被>理化性质>地形>母质。(3)空间分布上，东南部的χlf和χfd%均显示较高值。χlf空间分布呈由东南向西北降低的趋势，高值区位于东南部边缘，低值区位于腹地。χfd%空间分布规律与χlf相似，高值区位于东部偏南，低值区位于西部。此外，χlf和χfd%的空间分布规律与青藏高原植被分区相吻合。因此，磁化率能更好地指示植被空间分布。     

开封市城市土壤磁化率空间分布及对重金属污染的指示意义

建立基于土壤磁化率的重金属污染等级标准可为土壤重金属污染评价提供更为简便的磁学方法。采集开封市城市土壤表层样品99个,测定As、Cd、Cr、Cu、Ni、Pb和Zn含量以及低频磁化率(χLF)和高频磁化率(χHF)。采用普通Kriging插值法探讨χLF的空间分布,污染负荷指数(PLI)评价土壤重金属污染程度,并在PLI与χLF相关分析的基础上建立了基于χLF的土壤重金属污染等级标准。结果表明,开封市城市土壤各样点7种重金属的平均PLI为2.53,呈中度污染,Cd是最主要的污染因子。土壤χLF平均值为125.7×10-8m3kg-1,总体上由东南向西北递减,高值区出现在东南部、老城区北部和陇海铁路沿线附近。各样点土壤重金属PLI与其χLF的回归方程为PLI=0.011χLF+0.320(r=0.663),呈极显著正相关(p0.01)。用土壤χLF可以评价开封市城市土壤重金属污染程度:当土壤χLF≤62×10-8m3kg-1时,为无污染;当62×10-8χLF≤153×10-8m3kg-1时,为轻度污染;当153×10-8χLF≤244×10-8m3kg-1时,为中度污染;当χLF244×10-8m3kg-1时,为强度污染。     

大气颗粒沉降对城市土壤性状的影响：道路灰尘的磁学证据

为研究大气颗粒物沉降对城市土壤性状的影响,对上海宝山区典型工业区、交通区、居民区和农业区表土和道路灰尘的磁化率(χ_lf)、重金属元素含量进行了监测分析。结果表明,上海宝山各功能区表土磁性普遍增强,χ_lf平均值为130.7×10^-8 m³·kg^-1,86.2%表土样χ_lf高于当地土壤背景磁性。与各功能区表土相邻的道路灰尘χ_lf增强更加显著,平均值达903.3×10^-8 m³·kg^-1。各功能区道路灰尘重金属的累积量也远高于相邻表土。其铜(Cu)、锌(Zn)、铅(Pb)、镉(Cd)、镍(Ni)、铬(Cr)、钴(Co)、锰(Mn)、铁(Fe)的平均含量分别为表土的3.4倍、2.4倍、4.7倍、2.2倍、1.5倍、2.8倍、1.2倍、1.4倍和1.6倍。宝山区表土χ_lf与Cu、Zn、Mn、Cr、Ni、Cd含量呈极显著正相关(P<0.01),与Pb、F...     

上海城市土壤磁化率的垂向分布特征及环境指示意义

土壤含有各类磁性矿物。土壤磁性矿物可区分为自然成因或人为成因:自然成因的磁性矿物主要来源于母岩,风化成土过程或生物成磁作用;而人为成因的磁性矿物通常产生于工业活动(化石燃料燃烧,钢铁厂、水泥厂、发电厂等)和交通     

川西地区表土磁学性质及其环境意义

通过对川西地区表土样品进行系统的岩石磁学分析,并且结合气候要素探讨表土磁学性质与环境要素之间的关系。结果表明:(1)川西表土在成土过程中生成的细粒超顺磁(SP)和单畴(SD)的亚铁磁性矿物是磁化率增强的主导因素。该地区表土磁性增强机制与黄土高原类似。(2)在空间上,川西高原西部和南部地区的磁性矿物含量要高于东部和北部地区,而成都平原西部地区成土作用最强,磁颗粒细且含有较多高矫顽力磁性矿物。(3)川西表土的磁学参数和气候要素的研究发现年平均降水量(MAP)在600～1000 mm之间磁化率、频率磁化率与MAP呈正相关关系,而磁学参数组合χ_(fd)%/HIRM、ARM/HIRM、χ_(ARM)/SIRM与MAP在这一降雨区间也呈正相关关系,然而这些磁学参数与MAP的相关系数不如黄土高原,可能与研究区复杂的地形、相对湿润的成土条件有关。     

磁性土壤中Cu和Zn污染的指示作用

Concentrations of copper （Cu） and zinc （Zn） and various magnetic parameters in contaminated urban roadside soils were investigated using chemical analysis and magnetic measurements. The results revealed highly elevated Cu and Zn concentrations as well as magnetic susceptibility in the roadside soils. The mean concentrations of Cu and Zn in these roadside soils were almost twice those in average Chinese soils, with the mean magnetic susceptibility of the roadside soils reaching about 179 ×10^-8 m^3 kg^-1. This enhanced magnetic susceptibility was attributed to the presence of anthropogenic soft ferrimagnetic particles. A low frequency-dependent susceptibility （2.5%± 1.0%） observed in the roadside soils indicated the coarse multidomain （MD） ferrimagnetic grains to be the dominant contributor to magnetic susceptibility. The Cu and Zn concentration of the soils had highly significant linear correlations with magnetic susceptibility （P 〈 0.01）, anhysteretic remanent magnetization （P 〈 0.01）, and saturation isothermal remanent magnetization （P 〈 0.01）. This suggested that heavy metals were associated with ferrimagnetic particles in soils, which were attributed to input of traffic emissions and industrial activities. Scanning electron microscopy and energy dispersive X-ray spectra of magnetic extracts of the roadside soils further suggested the llnk between the magnetic signal and concentrations of heavy metals. Thus, the magnetic parameters could provide a proxy measure for the level of heavy metal contamination and could be a potential tool for the detection and mapping of contaminated soils.     

发育于石英岩之上的表土磁学性质及其环境磁学意义

通过对石英岩及发育于石英岩之上表土的磁化率(X)、频率磁化率(Xfd)、等温剩磁(IRM)、非磁滞剩磁(ARM)、κ-T曲线等磁学参数测定和石英岩显微镜下观察,结果表明,石英岩中磁性矿物含量极少;表土中含磁铁矿、磁赤铁矿、铁的氢氧化物等磁性矿物,磁性矿物主要以稳定单畴(SSD)和超顺磁性颗粒(SP)形式存在,磁赤铁矿是石英岩在成土过程中形成的次生矿物.表土磁性增强,说明石英岩的磁性对表土磁性影响甚小,而成土作用对表土磁性增强起到了重要作用.表土的磁化率值和磁赤铁矿含量都反映了成土作用的强弱.     

Magnetic properties of the urban soils in Shanghai and their environmental implications

To study the feasibility of using magnetic techniques for monitoring soil pollution in Shanghai, magnetic properties and heavy metals in the topsoils in an urban site (Songnan Town) and a less-urbanized agricultural site (Luojing Town) in Baoshan District, Shanghai, were studied. Compared with the background, magnetic signals of the urban topsoils are extremely enhanced with magnetic susceptibility (χ_lf) from 127.3–1959 × 10^− 8 m³ kg^− 1; while those of the agricultural topsoils are only slightly increased. However, both the urban and agricultural topsoils contain few pedogenic SP grains, as indicated by their low χ_fd% (< 3.6%). Ratios of χ_arm/SIRM, χ_arm/χ_lf and SIRM/χ_lf indicate that the grain size of magnetic minerals in the urban topsoils is significantly coarser than that in the background and the agricultural topsoils. Furthermore, the urban topsoils show low coercivity and magnetic soft behaviors, as indicated by higher SOFT%, lower HARD%, higher IRM_300 mT/SIRM (close to 1) and lower IRM_− 200 mT/SIRM (close to − 1). It suggests that the urban topsoils have received some coarse ferrimagnetic particles. Heavy metals are highly enriched in the magnetic fractions of the topsoils. Geochemical properties of the magnetic fraction of the urban topsoils are significantly different from those of the agricultural topsoils, further indicating that the extra magnetic minerals accumulated in the urban topsoils are neither inherited from soil parent materials nor from pedogenic processes, but originate from anthropogenic activities. The significant correlations between heavy metals and χ_lf, χ_arm, SIRM, SOFT and HIRM of the topsoils in the district indicate that the magnetic techniques can be used for monitoring soil pollution in Shanghai. The soils with χ_lf from 39–50 × 10^− 8 m³ kg^− 1 in the district are tentatively defined as “slightly polluted soils”; those with χ_lf > 50 × 10^− 8 m³ kg^− 1 are defined as “polluted soils”.     

长春市城区土壤中Pb、Cu、Zn、Cd及Cr化学形态特征

为弄清长春市城市土壤中Pb、Cu、Zn、Cr及Cd的化学形态分布特征,系统采集了26件城市表层(0~20 cm)土壤样品,采用连续提取法对重金属各化学形态含量进行了测定。结果表明:Pb、Zn、Cu及Cr主要以残渣态存在,其次是铁锰氧化物结合态、腐殖酸结合态和强有机结合态占有次要地位,离子交换态和水溶态所占比例均较低;Cd则主要以碳酸盐结合态存在,同时,水溶态和离子交换态所占比例较高。残渣态Pb和Zn在城区表层土壤中所占比例较近郊土壤中略有下降,但幅度不大,除Cu外,其余各元素易迁移、高生物有效性的水溶态在城区表层土壤中所占比例略有上升。Pearson相关分析结果表明,各元素残渣态与全量均呈极显著正相关,其它各活性态与全量间的相关程度与重金属种类有关。土壤pH值和Fe、Mn含量对重金属的化学形态的影响也与重金属种类有关,而且,同一重金属的不同存在形态受土壤pH值和Fe、Mn含量的影响程度也不同。     

皖北平原蒙城县农田土壤有机碳空间变异及影响因素

以皖北平原典型农业生产大县亳州市蒙城县为代表,运用统计学、地统计学方法和GIS技术研究了其农田耕作层(0～20 cm)土壤有机碳(SOC)含量的空间分布及其影响因子。结果表明:研究区SOC含量为10.41±2.52 g kg-1,近30年来提高了55.61%,SOC变异系数为24%,属于中等变异程度。SOC含量在空间分布上表现为东北部、中部和西南部含量高,由西北向东南先逐渐增加后逐渐降低,变异程度较高。整个县域范围内SOC空间变异的主要影响因素为土壤机械组成(粉粒和砂粒含量),其次为秸秆还田。     

Speciation of Zn,Cu, and Pb in the soil depending on soil texture and fertilization with sewage sludge compost

Background, aim, and scope  Heavy metal (HM) mobility in soil depends on the HM species in it. Therefore, knowledge of the HM speciation in soil allows the prediction of HM impact on the environment. HM speciation in soil depends on the metal chemical origin, soil texture, and other factors such as the origin and level of soil contamination. Recently, the problem of organic waste utilization is of great importance as the amount of this recyclable material is continually increasing. One of the possible ways of recycling is the use of processed organic wastes for agricultural needs. In this research, aerobically composted sewage sludge was used, the utilization of which is of essential importance. But one of the most serious restrictions is HM transfer from such material to the soil. Therefore, a prediction of HM mobility in soil and its migration in the environment is an important issue when using sewage sludge compost (SSC) in agriculture. Zn, Cu, and Pb speciation was performed according to the modified methodology of Tessier et al. (Anal Chem 51:844–851, 1979) in two different (sandy and clay) soils with background HM amounts and in soil samples amended with aerobically digested SSC to find out the predominant species of the investigated HM and to predict their potential availability. Materials and methods  The modified method of sequential extraction initially proposed by Tessier et al. (Anal Chem 51:844–851, 1979) is designed for HM speciation into five species where HM mobility decreases in the order: F1—exchangeable HM (extracted with 1 M MgCl₂ at an initial pH of 7 and room temperature), F2—carbonate-bound HM (extracted with 1 M CH₃COONa buffered to pH 5 at room temperature), F3—Fe/Mn oxide-bound HM (extracted with 0.04 M NH₂OH·HCl at an initial pH of 2 at 96°C), F4—organic matter-complexed or sulfide-bound HM (extracted with 0.02 M HNO₃ and 30% (v/v) H₂O₂ at a ratio of 1:1 and an initial pH of 2 at 85°C), and F5—the residual HM (digested with HNO₃, HF, and HCl mixture). After digestion, HM amounts in solution were determined by atomic absorption spectrometry (AAS ‘Hitachi’). Mixtures of uncontaminated soils of different textures (clay and sandy) with SSC in ratios 20:1, 10:1, and 5:1 were used to simulate the land application with SSC. During a period of 7 weeks, changes in Zn, Cu, and Pb content within species were investigated and compared weekly in soil–SSC mixtures with their speciation in pure soil and in the SSC. Results  Results in the SSC showed that more HM were found as mobile species compared to the soils, and in sandy soil, more were found in the mobile species than in clay soil. But the HM speciation strongly depended on the metal chemical origin. According to the potential availability, HM ranked in the following order: Zn>Pb>Cu. Zinc generally occurred in the mobile species (F1 and F3), especially in sandy soils amended with SSC, and changes of the Zn speciation were insignificant at the end of the experiment. Pb transfer to insoluble compounds (F5) was evident in the SSC–soil mixtures. This confirms that Pb is extremely immobile in the soil. However, the observed increase of Pb amounts in the mobile species (F1 and F2) during the course of experiment shows a critical trend of Pb mobilization under anthropogenic influence. Copper in the soil–SSC mixtures had a trend to form compounds of low mobility, such as organic complexes and sulfides (F4) and nonsoluble compounds (residual fraction F5). Initially, the amounts of mobile Cu species (F1 and F2) increased in the soils amended with SSC, probably due to the influence of SSC of anthropogenic origin with lower pH and high organic matter content, but Cu mobility decreased nearly to the initial level again after 3–4 weeks. Hence, the soil has a great specific adsorption capacity to immobilize Cu of anthropogenic origin. Discussion  Zn mobility and environmental impact was greater than that seen for Cu and Pb, while mobility of both Cu and Pb was similar, but variable depending on soil texture and contamination level. The effect on the shift of HM mobility and potential availability was greater in sandy SSC-amended soils than in clay soils and increased with an increasing amount of SSC. Conclusions  Usage of SSC for land fertilization should be strictly regulated, especially regarding Pb amounts. Recommendations and perspectives  The influence of SSC on Cu and Zn mobility and potential availability was more significant only in the case of sandy soil with a higher SSC ratio. Nevertheless, this waste product of anthropogenic origin increased Pb mobility in all cases in spite of only moderate Pb mobility in SSC itself. Therefore, aerobic processing of sewage sludge must be strictly regulated, especially regarding Pb amounts, and SSC ratios must be in control regarding HM amounts when using it for on-land application.     

不同级别城镇土壤重金属含量与潜在生态风险比较——以郑州市、中牟县和韩寺镇为例

以郑州市、中牟县和韩寺镇为例,在野外调查取样、室内测定的基础上,比较分析了Pb、Cd、Zn、Cr、Cu、Ni6种重金属元素在不同级别城镇土壤中的分布特征与潜在生态风险。结果表明:(1)不同重金属在各级别城镇土壤中的分布特征不尽相同。土壤Pb、Cd的分布趋势基本一致,而且含量普遍超过一级环境标准值,具有工业化、城镇化水平越高土壤污染越重、人为扰动越大的特点;土壤Zn、Cr含量在各区域的分布差异显著,体现了人为活动方式与活动强度的复杂性;不同级别的城镇土壤基本上不存在Cu和Ni的富集,两者含量的变化主要受自然波动的影响。(2)各级别城镇土壤存在着不同程度的重金属潜在生态风险,其中Cd的潜在生态风险最大,构成了很强的潜在生态危害,而Pb、Zn、Cr和Cu等元素仅具有轻微生态危害。(3)多种重金属的潜在生态风险大小为:郑州市区韩寺镇区中牟县城对照区。     

广东省典型区域农业土壤中重金属污染空间差异及原因分析

分析了广东东翼(汕头)、西翼(湛江)和珠江三角洲(东莞、惠州、中山和顺德)等典型区域农业土壤中8种重金属(Cu、Zn、Ni、Cr、Pb、Cd、As和Hg)元素的含量。结果表明,578个农业土壤表层样中,有230个样品的重金属含量超过国家土壤环境质量二级标准值,超标率39.79%,Pb没有超标,Ni超标最严重;果园土比水稻土、菜园土污染严重;不同区域的土壤污染程度是珠江三角洲>东翼(汕头)>西翼(湛江),珠江三角洲的西、北江流域(中山、顺德)土壤重金属污染程度要比东江流域(东莞、惠州)严重。人为因素、成土母质和不同流域水质差异是造成广东典型区域农业土壤重金属污染的原因。