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1.
坡缕石包膜对尿素氮行为的影响   总被引:2,自引:1,他引:2  
采用静态吸收和土柱淋溶试验方法,分析对比了3种不同用量坡缕石包膜尿素与普通尿素施入土壤后对尿素氮行为的影响,结果表明:在土壤中施用坡缕石包膜尿素较普通尿素减少10.38%~26.24%的氨挥发损失,减少5.88%~27.74%的氮素(NO3--N+NH4+-N)淋溶损失,20%的坡缕石包膜尿素能显著提高土柱土壤NH4+-N含量,3种坡缕石包膜尿素都能极显著提高土柱土壤NO3--N含量.坡缕石包膜后能减少尿素氨的挥发,降低NH4+-N和NO3--N的淋失,提高土壤NH4+-N和NO3--N含量,以20%的坡缕石包膜尿素的综合生态效应最好.  相似文献   

2.
Extraction of soil nitrate nitrogen (NO3 ?-N) and ammonium nitrogen (NH4 +-N) by chemical reagents and their determinations by continuous flow analysis were used to ascertain factors affecting analysis of soil mineral N. In this study, six factors affecting extraction of soil NO3 ?-N and NH4 +-N were investigated in 10 soils sampled from five arable fields in autumn and spring in northwestern China, with three replications for each soil sample. The six factors were air drying, sieve size (1, 3, and 5 mm), extracting solution [0.01 mol L?1 calcium chloride (CaCl2), 1 mol L?1 potassium chloride (KCl), and 0.5 mol L?1 potassium sulfate (K2SO4)] and concentration (0.5, 1, and 2 mol L?1 KCl), solution-to-soil ratio (5:1, 10:1, and 20:1), shaking time (30, 60, and 120 min), storage time (2, 4, and 6 weeks), and storage temperature (?18 oC, 4 oC, and 25 oC) of extracted solution. The recovery of soil NO3 ?-N and NH4 +-N was also measured to compare the differences of three extracting reagents (CaCl2, KCl, and K2SO4) for NO3 ?-N and NH4 +-N extraction. Air drying decreased NO3 ?-N but increased NH4 +-N concentration in soil. Soil passed through a 3-mm sieve and shaken for 60 min yielded greater NO3 ?-N and NH4 +-N concentrations compared to other treatments. The concentrations of extracted NO3 ?-N and NH4 +-N in soil were significantly (P < 0.05) affected by extracting reagents. KCl was found to be most suitable for NO3 ?-N and NH4 +-N extraction, as it had better recovery for soil mineral N extraction, which averaged 113.3% for NO3 ?-N and 94.9% for NH4 +-N. K2SO4 was not found suitable for NO3 ?-N extraction in soil, with an average recovery as high as 137.0%, and the average recovery of CaCl2 was only 57.3% for NH4 +-N. For KCl, the concentration of extracting solution played an important role, and 0.5 mol L?1 KCl could fully extract NO3 ?-N. A ratio of 10:1 of solution to soil was adequate for NO3 ?-N extraction, whereas the NH4 +-N concentration was almost doubled when the solution-to-soil ratio was increased from 5:1 to 20:1. Storage of extracted solution at ?18 °C, 4 °C, and 25 °C had no significant effect (P < 0.05) on NO3 ?-N concentration, whereas the NH4 +-N concentration varied greatly with storage temperature. Storing the extracted solution at ?18 oC obtained significantly (P < 0.05) similar results with that determined immediately for both NO3 ?-N and NH4 +-N concentrations. Compared with the immediate extraction, the averaged NO3 ?-N concentration significantly (P < 0.05) increased after storing 2, 4, and 6 weeks, respectively, whereas NH4 +-N varied in the two seasons. In conclusion, using fresh soil passed through a 3-mm sieve and extracted by 0.5 mol L?1 KCl at a solution-to-soil ratio of 10:1 was suitable for extracting NO3 ?-N, whereas the concentration of extracted NH4 +-N varied with KCl concentration and increased with increasing solution-to-soil ratio. The findings also suggest that shaking for 60 min and immediate determination or storage of soil extract at ?18 oC could improve the reliability of NO3 ?-N and NH4 +-N results.  相似文献   

3.
The aim of this study was to evaluate the sustainability of an agro-industry sludge as a nitrogen (N) fertilizer in perennial crops by assessing its dynamics of release of: 1) N as ammonium (NH4+)- and nitrate (NO3?)-N, and 2) carbon as soil respiration. In incubation assay, application of agro-industry sludge promoted the maximum NH4+-N concentration (50 mg kg?1) 2 h after application, then it decreased with time until day 26. NO3?-N increased, reaching the maximum between day 60 and day 100, according to a second degree function. Agro-industry sludge showed a slower release of NO3?-N compared with urea. Soil basal respiration and cumulative amount of carbon dioxide were higher in sludge from day 71 on. In field, soil NO3?-N increased after fertilization treatments and was higher in Calcari Stagnic Cambisols soil. Sludge showed a potential lower environment impact in terms of mineral N release, than urea.  相似文献   

4.
Field experiments were conducted to determine the effect of nitrogen (N) fertilizer forms and doses on wheat (Triticum aestivum L.) on three soils differing in their ammonium (NH4) fixation capacity [high = 161 mg fixed NH4-N kg?1 soil, medium = 31.5 mg fixed NH4-N kg?1 soil and no = nearly no fixed NH4-N kg?1 soil]. On high NH4+ fixing soil, 80 kg N ha?1 Urea+ ammonium nitrate [NH4NO3] or 240 kg N ha?1 ammonium sulfate [(NH4)2SO4]+(NH4)2SO4, was required to obtain the maximum yield. Urea + NH4NO3 generally showed the highest significance in respect to the agronomic efficiency of N fertilizers. In the non NH4+ fixing soil, 80 kg N ha?1 urea+NH4NO3 was enough to obtain high grain yield. The agronomic efficiency of N fertilizers was generally higher in the non NH4+ fixing soil than in the others. Grain protein was highly affected by NH4+ fixation capacities and N doses. Harvest index was affected by the NH4+ fixation capacity at the 1% significance level.  相似文献   

5.
Soil NH+4-N and NO?3-N at five soil depths (0–10, 10–20, 20–40, 40–60, 60–80 cm) and some environmental variables were measured in a field trial under fallow and wheat for 9 months.Significant linear and quadratic relationships were obtained relating soil NH+4-N, NO?3-N, NH+4-N + NO?3-N, and NH+4-N + NO?3 + total-N uptake by wheat to soil heat accumulation (temperature), moisture, and rainfall. R2 values generally decreased with soil depth and the maximum value (37%) was obtained for NO?3-N changes in the topsoil (0–10 cm).Although a considerable amount of variation in the inorganic values recorded is not included in the equations, our results suggest that the development of the above relationships particularly of the quadratic type are useful to predict crop requirements for N by measurement of environmental variables in the field.  相似文献   

6.
控释氮肥养分控释效果及合理施用研究   总被引:19,自引:5,他引:19  
试验采用{3,3}单形重心设计方法,研究了普通尿素和2种包膜尿素D90、D60配比对土壤NH4+-N、NO3--N及矿质态氮(Nmin)含量的影响。结果表明,供试的7种包膜肥料初期溶出率均12.0%,微分溶出率在0.26%~2.49%之间。各处理土壤NH4+-N含量均随时间逐渐降低,而NO3--N和Nmin含量随时间逐渐增加。整个培养期内单独施用尿素处理,土壤NH4+-N、NO3--N及Nmin含量最高;2种控释肥单施或其配比施用土壤NH4+-N、NO3--N及Nmin含量最低;尿素与控释肥配合施用,土壤NH4+-N、NO3--N及Nmin含量居中。不同时期内土壤NH4+-N的来源不同,0~20d内,尿素对土壤NH4-N含量贡献最大;30~50d内,土壤NH4+-N主要来自D60;整个培养期内尿素对土壤NO3--N和Nmin的贡献均最大。肥料配比中随着尿素比例的减少,土壤NH4+-N、NO3--N及Nmin均逐渐减少。研究结果初步验证了混料设计在肥料配比研究中的可行性。  相似文献   

7.
The effect of the nitrification inhibitor 3,4-dimethylpyrazole phosphate (DMPP) on N transformations and composition of ammonia-oxidizing bacteria (AOB) communities was investigated at the centimeter scale in a microcosm experiment under laboratory conditions. After 28 days, samples were collected from soil treated with urea or urea and DMPP at increasing distance from the fertilizer zone; this distance ranged from 0 to 5 cm in both horizontal and vertical directions. The results showed that DMPP application significantly increased soil pH and NH 4 + -N and mineral N (NH 4 + -N, NO 3 ? -N, and NO 2 ? -N) concentrations but decreased (NO 3 ? + NO 2 ? )-N concentration, and such effect was decreased by increasing the distance from the fertilizer zone. Fingerprint profiles of denaturing gradient gel electrophoresis showed that the number of bands decreased by increasing the distance from the fertilizer zone due to decreasing NH 4 + -N concentrations in the urea treatment. Compared to urea applied alone, DMPP application increased NH 4 + -N concentrations and decreased AOB diversity from 0 to 3 cm but promoted diversity from 3 to 5 cm distance from the fertilizer zone. A phylogenetic analysis showed that AOB communities were dominated by Nitrosospira cluster 3. Therefore, the nitrification inhibitor DMPP modified the composition of AOB communities by increasing the distance from the fertilizer zone and this probably was related to the changes in soil pH and inorganic N concentration.  相似文献   

8.
The incidence and severity of take-all disease, due to Gaeumannomyces graminis (Sacc.) Arx & Olivier var. tritici Walker, was observed on spring barley plants growing in soil in two glasshouse experiments. Soil amendments of NH+4-N significantly increased the number of diseased plants and roots during the first month after germination in comparison with controls unamended with N (P < 0.05). No significant difference in the incidence of take-all disease was detected between more mature barley plants growing in soil amended with either NH+4 or NO?3-N and unamended controls. The least take-all disease in 3 month-old barley plants was observed when N was supplied as foliar sprays of urea at 0.5 mg N kg?1 soil (P < 0.01). There was no significant correlation between the degree of infection and the NH+4-N to NO?3-N ratio in the rhizosphere soil  相似文献   

9.
Sandy loam soil, with added glucose, was incubated anaerobically under N2 and subjected to repeated 1-h C2H2 reduction assays. In the presence of 1% glucose the addition of 50 μg NH4+ ?N/g or of 20 μg NO?3 N/g (untreated soil contained 1.2 μg NH+4?N and 7.10 μg NO?3-N/g) caused at least some suppression of nitrogenase activity. Activity developed when the KCl-extractable soil inorganic nitrogen concentration dropped below 35 μg/g. In the presence of 0.1 or 0.05% glucose the addition of 5 μg NH+4?N/g caused some suppression of nitrogenase activity. However, activity developed when the soil NH4+-N concentration dropped below about 4 μg/g. With 0.1% glucose and 5 μg added NO?2 N/g, activity did not develop until the soil NO?2 -N concentration dropped to zero. Added NO?3 N was rapidly reduced and denitrified to NO?2- N, N2O-N and NH+4 N and furthermore caused some inhibition of CO2 evolution. The data from NH4?-addition experiments are consistent with a nitrogenase repression/ derepression threshold of 4 and 35μg NH+4-N/g at 0.05 and 1% glucose concentrations, respectively. The data from NO?2- and NO?3-addition experiments suggest a combination of repression and toxicity effects in the presence of added NO?3 N.  相似文献   

10.
氮素形态对巨峰葡萄果实品质的影响   总被引:3,自引:0,他引:3  
为了探讨氮素形态对巨峰葡萄果实品质性状的影响,设置了尿素T1(酰胺态)、全硝T2(硝铵比为100/0)、混合氮T3、T4、T5(硝铵比为70/30、50/50、30/70)及全铵处理T6(硝铵比为0/100)和清水对照CK,于生长季节进行叶面喷施试验。结果表明,不同处理均提高了果实的营养品质,喷尿素的总糖量、糖酸比最大,其次是混合氮处理,全铵处理最小;果实的Vc含量以混合氮处理较高,全铵处理的最低;果实中花青素的含量顺序为:全硝尿素混合氮全铵CK。果实硝酸盐含量从高到低依次为:全硝混合氮全铵尿素CK;硝态氮促进了果实生长,各处理平均单果重为全硝混合氮全铵尿素CK。综上结果,尿素及适当的硝态氮配比有利于巨峰葡萄果实品质的提高。  相似文献   

11.
Optimal fertilizer nitrogen (N) rates result in economic yield levels and reduced pollution. A soil test for determining optimal fertilizer N rates for wheat has not been developed for Quebec, Canada, or many other parts of the world. Therefore, the objectives were to determine: 1) the relationship among soil nitrate (NO? 3)- N, soil ammonium (NH + 4)- N and N fertilizer on wheat yields; and 2) the soil sampling times and depths most highly correlated with yield response to soil NO? 3-N and NH + 4-N. In a three year research work, wet and dried soil samples of 0- to 30- and 30- to 60-cm depths from 20 wheat fields that received four rates of N fertilizer at seeding and postseeding (plants 15 cm tall) were analyzed for NH + 4-N and NO? 3 -N using a quick-test (N-Trak) and a standard laboratory method. Wheat yield response to N fertilizer was limited, but strong to soil NO? 3-N.  相似文献   

12.
A laboratory study determined the effects of salinity on ammonification, nitrification and mineral N accumulation in incubated soils. NH+4-N, NO?2-N and NO?3-N were measured periodically for 102 days in unamended soil of varying salinity and in soil amended with farm compost, mustard oil cake or urea. Increased salinity progressively retarded ammonification but did not suppress it completely. Nitrification was retarded, suppressed or inhibited completely by salinity, the effect depended on both the amount of salt and the type of amendment added to the soil. The amount of mineral N that accumulated generally decreased with increased salinity.  相似文献   

13.
A soil column method was used to compare the effect of drip fertigation (the application of fertilizer through drip irrigation systems, DFI) on the leaching loss and transformation of urea-N in soil with that of surface fertilization combined with flood irrigation (SFI), and to study the leaching loss and transformation of three kinds of nitrogen fertilizers (nitrate fertilizer, ammonium fertilizer, and urea fertilizer) in two contrasting soils after the fertigation. In comparison to SFI, DFI decreased leaching loss of urea-N from the soil and increased the mineral N (NH4+-N + NO3--N) in the soil. The N leached from a clay loam soil ranged from 5.7% to 9.6% of the total N added as fertilizer, whereas for a sandy loam soil they ranged between 16.2% and 30.4%. Leaching losses of mineral N were higher when nitrate fertilizer was used compared to urea or ammonium fertilizer. Compared to the control (without urea addition), on the first day when soils were fertigated with urea, there were increases in NH4+-N in the soils. This confirmed the rapid hydrolysis of urea in soil during fertigation. NH4+-N in soils reached a peak about 5 days after fertigation, and due to nitrification it began to decrease at day 10. After applying NH4+-N fertilizer and urea and during the incubation period, the mineral nitrogen in the soil decreased. This may be related to the occurrence of NH4+-N fixation or volatilization in the soil during the fertigation process.  相似文献   

14.
Pot experiments were conducted on three soils differing in their ammonium (NH4 +) fixation capacity [high = 161 mg NH4-nitrogen (N) kg?1 soil; medium = 31.5 mg NH4-N kg?1 soil; and no = no NH4-N was additionally fixed], and the effect of N fertilizer forms and doses on wheat (Triticum aestivum L.) was investigated. Grain yields responded to almost all forms of N fertilizer with 80, 160, and 240 kg N ha?1 in the high, medium, and no NH4 + fixing soil process, respectively. Agronomic efficiency of applied N fertilizers was significantly greater in the no NH4 + fixing soil. Thousand grain weights (TGW) of wheat grown on the high and medium NH4 + fixing soil decreased with increasing N. Grain protein increased with increasing NH4 + fixation capacity. Nitrogen doses and the forms of N fertilizers affected grain protein at a significance level. The combination of urea + ammonium nitrate (NH4NO3) was most effective in increasing grain protein content.  相似文献   

15.
Corn requires high nitrogen (N) fertilizer use, but no soil N test for fertilizer N requirement is yet available in Quebec. Objectives of this research were (1) to determine the effects of soil nitrate (NO3 ?)-N, soil ammonium (NH4 +)-N, and N fertilizer rates on corn yields and (2) to determine soil sampling times and depths most highly correlated with yields and fertilizer N response under Quebec conditions. Soil samples were taken from 0- to 30-cm and 30- to 60-cm depths at seeding and postseeding (when corn height reached 20 cm) to determine soil NH4 + and NO3 ? in 44 continuous corn sites fertilized with four rates of N in two replications using a quick test (N-Trak) and a laboratory method. The N-Trak method overestimated soil NO3 ?-N in comparison with the laboratory method. Greater coefficients of determination were observed for soil NO3 ?-N analyses at postseeding compared with seeding.  相似文献   

16.
为揭示不同施肥时机(全过程、前1/2和后1/2入渗水量施肥)下土壤水氮运移转化规律,以砂壤土和黏壤土质地的一维垂直肥液(尿素)入渗试验为基础,重点分析不同施肥时机下土壤水氮分布与再分布过程中的运移转化规律,并量化比较其对土壤中氮素含量的影响。结果表明,施肥时机对土壤累积入渗量和湿润体中水分分布影响微小,但对不同形态氮素运移转化影响显著;砂壤土和黏壤土入渗结束时刻,全过程和后1/2入渗水量施肥时,其尿素态氮、铵态氮(NH4+—N)和硝态氮(NO3-—N)含量均随土层深度增大而减小;前1/2入渗水量施肥时,尿素态氮和NO3-—N含量在湿润体边缘累积,NH4+—N呈先增大后减小趋势,且主要分布在5—25 cm土层;再分布阶段,全过程和后1/2入渗水量施肥时,砂壤土和黏壤土中尿素态氮分别在再分布3天和5天时基本水解完成,同时NH4+—N含量达到峰值,NO3-—N含量再分布10天内未出现下降趋势;前1/2入渗水量施肥时,尿素态氮再分布10天时基本水解完成,NH4+—N含量再分布5~10天达到峰值,NO3-—N含量则呈先增加后减小趋势;后1/2入渗水量和全过程施肥条件下,砂壤土和黏壤土再分布10天时0—40 cm土层中NH4+—N和NO3-—N含量均大于前1/2入渗水量施肥,说明其氮素潜在利用效率高,故推荐畦(沟)灌合理施肥时机为后1/2入渗水量或全过程施肥。研究结果可为农田畦(沟)灌施肥系统的设计和管理提供理论基础和技术支撑。  相似文献   

17.
ABSTRACT

Plant nitrogen (N)-acquisition strategy affects soil N availability, community structure, and vegetation productivity. Cultivated grasslands are widely established to improve degraded pastures, but little information is available to evaluate the link between N uptake preference and forage crop biomass. Here an in-situ 15N labeling experiment was conducted in the four cultivated grasslands of Inner Mongolia, including two dicots (Medicago sativa and Brassica campestris) and two monocots (Bromus inermis and Leymus chinensis). Plant N uptake rate, shoot- and root biomass, and concentrations of soil inorganic-N and microbial biomass-N were measured. The results showed that the root/shoot ratios of the dicots were 2.6 to 16.4 fold those of the monocots. The shoot N concentrations of the dicots or legumes were 40.6% to 165% higher than those of the monocots or non-legumes. The four forage crops in the cultivated grassland preferred to uptake more NO3?-N than NH4+-N regardless of growth stages, and the NH4+/NO3? uptake ratios were significantly lower in the non-legumes than in the legumes (p < 0.05). Significant differences in the NH4+-N rather than NO3?-N uptake rate were observed among the four forages, related to plant functional types and growth stages. The NH4+ uptake rate in the perennial forages exponentially decreased with the increases in shoot-, root biomass, and root/shoot ratio. Also, the plant NH4+/NO3? uptake ratio was positively correlated with soil NH4+/NO3? ratio. Our results suggest that the major forage crops prefer to absorb soil NO3?-N, depending on soil inorganic N composition and belowground C allocation. The preferential uptake of NO3?-N by forages indicates that nitrate-N fertilizer could have a higher promotion on productivity than ammonium-N fertilizer in the semi-arid cultivated grassland.  相似文献   

18.
Aerobic incubations to estimate net nitrogen (N) mineralization typically involve periodic leaching of soil with 0.01 M calcium chloride (CaCl2), so as to remove mineral N that would otherwise be subject to immobilization. A study was conducted to evaluate the accuracy of leaching for analysis of exchangeable ammonium (NH4+)-N and nitrate + nitrite (NO3?+ NO2)-N, relative to conventional extractions using 2 M potassium chloride (KCl). Ten air-dried soils were used, five each from Illinois and Brazil, that had been amended with NH4+-N (1 g kg?1) and NO3-N (0.6 g kg?1). Both methods were in good agreement for inorganic N analysis of the Brazilian Oxisols, whereas leaching was significantly lower by 12–48% in recovering exchangeable NH4+-N from Illinois Alfisols, Mollisols, and Histosols. The potential for underestimating net N mineralization was confirmed by a 12-wk incubation experiment showing 9–86% of mineral N recoveries from three temperate soils as exchangeable NH4+.  相似文献   

19.
Root development responds not only to the quantity of inorganic nitrogen in the rhizosphere, but to its form, NH4+ or NO3?. Root growth of tomato showed a hyperbolic response to soil levels of inorganic nitrogen: very few roots were found in soil blocks depleted in inorganic nitrogen, roots proliferated as soils increased to 2 μg NH4+-N g?1 soil or 6 μg NO3?-N g?1 soil, and root growth declined in soils with the higher levels of inorganic nitrogen. High NH4+ concentrations inhibited root growth, but low concentrations promoted the development of an extensive, fine root system. Supply with NO3? as the sole nitrogen source led to a more compact root system. These differences in root morphology under NH4+ and NO3? nutrition may be mediated through pH. Rice and maize roots absorbed NH4+ most rapidly right at the apex and appeared to assimilate this NH4+ in the zone of elongation. During NH4+ assimilation, root cells must release protons, and the resulting acidification around the walls of cells in this region should stimulate root extension. By contrast, NO3? absorption reached a maximum in the maturation zone of rice and maize roots, and this NO3? was probably assimilated in more basal regions. Absorption of NO3? requires proton efflux, whereas NO3? assimilation requires proton influx. The net result under NO3? nutrition was only subtle shifts in rhizosphere pH that probably would not influence root elongation. The signal through which roots detect changes in rhizosphere NH4+ and NO3? levels is still obscure. It is proposed that a product of nitrogen metabolism such as nitric oxide serves as a signal.  相似文献   

20.
稻田土壤中氮素淋失的研究   总被引:88,自引:3,他引:88  
本文应用稻田大型原状土柱渗漏计,研究了双季稻田土壤中氮素随渗漏水流淋失的形态、数量、季节性变化以及若干农化因子的影响。明确了稻田中氮素淋失的基本形态是硝态氮(NO3^--N),估算出双季稻田中氮素淋失总量可接近30kgN/ha,同时肯定了农田施用氮肥对地下水体环境可能的NO3^--N污染,建议双季稻田中每季水稻的氮肥用量宜控制在150kgN/ha;本文还证实氮肥用量对氮素淋失有明显影响,不同氮肥品  相似文献   

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