Inorganic Pollution in PM10 Particles Collected Over Three French Sites Under Various Influences: Rural Conditions, Traffic and Industry

PM₁₀ particles were collected over three sites in France. The first one, Montagney was a rural site that was considered as a reference site. The second site Saclay, close to a highway, was used to study the influence of the traffic. The third site was Dunkerque, one of the most industrial areas in France for the production of steel, aluminium and petroleum refinement. More than 50 element concentrations were determined by instrumental neutron activation analysis and inductively coupled plasma–mass spectrometry. Comparisons between Saclay and Montagney shown that some elements, considered as crustal elements had similar concentration variations and weak (close to 1) enrichment factors. Elements with enrichment factors higher than 10 shown in Montagney correlated variations, with a Winter maximum, that should be due to Winter heating sources. Over Saclay, most of elements with high enrichment factors were attributed to the dense traffic of the highway. This is particularly true for Mn, Fe, Zn, Ba, Sb, Cu. Some additional elements correlated also, without a particular origin that can be ascertained. In Dunkerque, the most important industry is steel production. Correlation studies shown that Tl, Cs, Ba, Ag, Cu, Rb, Se, Mn, Pb concentration variations were closely associated to the Fe concentration variations. The second polluting industry is aluminium production. Correlation studies allowed to associate Ni, Y, Co, V, rare earth elements, Ti, Sr, Th, U, Ca, Sc, concentration variations to the aluminium concentration variations. A third important industry is petroleum refinement. The only element observed here and that is suspected to be emitted more specifically is La, used in cracking processes. An important enrichment of La with respect to Ce is observed. A strong decrease of the ratio Cl/Na was observed over the three sites, between the beginning of the experiment in Autumn 2005, and its end in Spring 2006. This was attributed to a release of gaseous HCl, produced by acidification of aerosols by other pollutants like NO _x and SO _x , that should have been oxidized to NO₂ and SO₃, then dissolved in the aerosols. The effects responsible for the loss of Cl, represents a large surface and long-term pollution event over the North of France. This work allowed a characterization of the heavy metal concentrations of the aerosol that will sustain results published in a companion paper, and that concerned the bio-accumulation of metals by Scleropodium purum, simultaneously exposed in the same sites.     

Seasonal Evolution of Levels of Gaseous Pollutants in an Urban Area (Ciudad Real) in Central-Southern Spain: A Doas Study

Long term continuous monitoring measurements of urban atmospheric concentrations of O₃, NO₂, NO, and SO₂ were performed for the first time in Ciudad Real, a city in central-southern Spain. The measurements were carried out using the differential optical absorption spectroscopy (DOAS) technique, with a commercial system (OPSIS, Lund-Sweden), covering the summer and winter seasons (from 21st July 2000 to 23rd March 2001). Mean levels of O₃, NO₂ and SO₂ monitored during this period were: 27 μg m^?3, 50 μg m^?3 and 7 μg m^?3 respectively. The highest hourly averaged value of O₃ (160 μg m^?3) was measured during the summer period, while NO₂ was enhanced in wintertime (highest values 90 μg m^?3). In the coldest period, when central heating installations were operating, SO₂ showed maximum levels of 20 μg m^?3. The daily, weekly and seasonal analysis of the data shows that photochemical air pollution dominates in this urban atmosphere and is strongly influenced by levels of motor traffic and domestic heating system emissions. These measurements were compared with other studies in Spain and Europe. Also, the long path averaged DOAS measurements were compared with in situ observations made in Ciudad Real, from 23rd August 2000 to 25th September 2000, using a mobile air pollution control station. All gas concentrations reported in this paper are below the WHO guidelines and the different thresholds introduced by the European Environmental Legislation.     

Natural and Anthropogenic Contributions to PM10 and PM2.5 in an Urban Area in the Western Mediterranean Coast

Source apportionment analysis was used to identify the factors contributing to atmospheric pollution at a monitoring location in the Southeast of Spain, a well documented area with an arid climate and high insolation favouring two sources of particulate matter: secondary transformation in the atmosphere and resuspension of crustal dry soils to the air. These conditions are further complicated by numerous industrial facilities in the area of the historical city of Cartagena. This paper describes the air quality of an area which includes a zinc metallurgical industry, a petrochemical factory, an oil power station, a shipyard and natural phenomena including African dust transport and resuspension of regional and/or local crustal materials. Major and trace element concentrations in PM10 and PM2.5 were determined at two monitoring stations in Cartagena (one PM10 sampler located at a traffic hotspot and the PM2.5 sampler at a suburban station), during 2004 and 2005. Results showed that in the PM10 fraction, the zinc metallurgical activity was linked to high levels of Cd, Zn and Pb; shipyard emission was associated with high levels of Cr and Ni; and high Ni and V levels were associated with the secondary aerosol indicating the contribution from oil combustion (oil-fired power station or petrochemical facilities). In the PM2.5 size fraction, the zinc source is defined by Zn and Pb; V, Ni and As appear with the oil combustion emissions. In contrast to PM10, shipyard activity is not consistently defined. Consistent sources found in both size fractions include crustal materials and traffic emissions.     

PM10 and PM2.5 Levels in the Eastern Mediterranean (Akrotiri Research Station, Crete, Greece)

Particulate matter measurements (PM₁₀, PM_2.5) using a beta radiation attenuation monitor were performed at the Akrotiri research station (May 2003–March 2006) on the island of Crete (Greece). The mean PM₁₀ concentration during the measuring period (05/02/03–03/09/04) was equal to 35.0?±?17.7 μg/m³ whereas the mean PM_2.5 concentration (03/10/04–04/02/06) was equal to 25.4?±?16.5 μg/m³. The aerosol concentration at the Akrotiri station shows a large variability during the year. Mean concentrations of particulate matter undergo a seasonal change characterised by higher concentrations during summer [PM₁₀, 38.7?±?10.8 μg/m³ (2003); PM_2.5, 27.9?±?8.7 μg/m³ (2004) and 27.8?±?9.7 μg/m³ (2005)] and lower concentrations during winter [PM₁₀, 28.7?±?22.5 μg/m³ (2003/2004); PM_2.5, 21.0?±?13.0 μg/m³ (2004/2005) and 21.4?±?21.9 μg/m³ (2005/2006)]. Comparative measurements of the PM₁₀ concentration between the beta radiation attenuation monitor, a standardized low volume gravimetric reference sampler and a low volume sequential particulate sampler showed that PM₁₀ concentrations measured by the beta radiation attenuation monitor were higher than values given by the gravimetric samplers (mean ratio 1.17?±?0.11 and 1.21?±?0.08, respectively). Statistical and back trajectory analysis showed that elevated PM concentrations (PM₁₀, 93.8?±?49.1 μg/m³; PM_2.5: 102.9?±?59.9 μg/m³) are associated to desert dust events. In addition regional transport contributes significantly to the aerosol concentration levels whereas low aerosol concentrations were observed during storm episodes.     

神木试区自然条件及环境整治综合分析

神木试区地处毛乌素沙地与黄土丘陵的交错分布地带,其自然环境条件的过渡特征十分明显,从而导致了其生态环境的整治,农林牧业生产的发展与黄土丘陵和风沙丘有明显的区别,文中就试区的环境治理和生产的发展方向作了初步分析。     

Biomonitoring of Metal Availability in the Southern Basin of the Lagoon of Venice (Italy) by Means of Macroalgae

Macroalgae of the following species: Ulva laetevirens, Enteromorpha intestinalis, Gracilaria verrucosa and Sargassum mutycum, were used to monitor metal concentrations (Al, Mn, Fe, Cu, Zn, Cr, Co, Ni, Cd) in the waters of the southern basin of the Lagoon of Venice. Sampling was performed at 5 sites, gradually moving north from the town of Chioggia. Species-specific seasonal variability was observed, with significant increases of Cd in U. laetevirens in January,Al and Pb in E. intestinalis in May, and Al and Ni in S. mutycum in January. Seasonal relative frequencies of metalpeak concentrations emphasize the occurrence of Pb peaks in May for all the studied species. Analysis of inter-site variability shows significant increases of Al, Fe, Cr and Pb in U. laetevirens at the Hydro-Biological Station, located within the town of Chioggia. Metal concentrations in algae are comparable with those in other areas of the lagoon, although Fe, Cr and Ni concentrations are lower than in the northern and central basins.This result fits dissolved metal concentrations determined byother authors, but does not correspond to the reported presence ofCr in the sediments of the southern basin. The hypothesis isdiscussed according to which low Cr levels in algae reflect Crspeciation in sediments.     

Ozone and Nitrogen Dioxide Levels Monitored in an Urban Area (Ciudad Real) in central-southern Spain

This work describes the evolution of NO₂ and O₃ levels from January to December of 2007, covering the four seasonal periods in the urban air of Ciudad Real in the central-southern Spain. The measurements were carried out by means of passive samplers (Radiello® samplers). Eleven samples were collected weekly, placed at different monitoring site locations. The data indicate that the mean levels obtained during this period for O₃ and NO₂ were 38.5?±?3.5 and 20.8?±?3.8 μg/m³, respectively. These measurements were compared with other studies in Ciudad Real. Meteorological conditions (temperature, pressure, humidity relative, wind speed and direction) were also investigated.     

PM10-bound Polycyclic Aromatic Hydrocarbons (PAHs) and Cancer Risk Estimation in the Atmosphere Surrounding an Industrial Area of Shanghai, China

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous pollutants in the urban atmosphere. In particular, atmospheric pollution has increasingly become severe in China due to its rapid urbanization and industrialization. In recent years, a few studies have presented information about POPs (such as PAHs, PCBs, OCPs) in aerosols at a molecular level in a limited number of cities such as Beijing, Qingdao and Guangzhou, as well as Hong Kong. Whereas, these cities are located in northern and southern China, respectively, where characteristics of atmospheric pollution might be different from those in the eastern cities, such as Shanghai. Atmospheric particle pollution is a persistent problem in Shanghai, a typical metropolis of China, which has several huge industrial regions. In order to gain a comprehensive understanding of the present state, properties and sources of PAHs pollution in Shanghai, PM₁₀ samples were collected at Coal-Fired Power Plant (CFP), Chlor-Alkali Chemical factory (CAC) and Coking and Chemical factory (CCF) in an industrial area, during the period, November 2004–September 2005. The concentrations of 16 PAHs were analyzed using the HPLC with UV visible detector. The results showed that the mean value of total PAHs in the industrial area was 64.85 ng m^?3; 3-ring PAHs were found at low levels, while 4-, 5- and 6-ring PAHs were found at high levels. The levels of BaP were 3.07 and 7.16 ng m^?3 at Chlor-Alkali Chemistry Factory and Coking and Chemistry Factory sites, respectively. PAHs levels exhibited distinct seasonal variation, with the highest level in autumn and the lowest in summer. The major source of PAHs at the industrial area was fossil fuel combustion, coal-burning, industrial furnaces including others. There was a very significant correlation of PAHs levels between CCF and CAC (R ²?=?0.91). The average concentration of BaP in the industrial area during the sampling period was 5.95 ng m^?3. It could be concluded the local population appears to be exposed to significantly high cancer risk (exceeding 2 ng m^?3 in autumn and winter) as compared to the population of other areas.     

A Study of PM2.5 and PM2.5-Associated Polycyclic Aromatic Hydrocarbons at an Urban Site in the Po Valley (Bologna, Italy)

PM_2.5 and PAHs bound to PM_2.5 were investigated in downtown Bologna, from January to June 2003, in order to determine the burden of the fine fraction in the aerosol of a typical urban environment of the Po Valley, a critical area in Northern Italy in terms of atmospheric pollution. The sampling campaign was divided into three parts: a winter sub-campaign, an intermediate campaign where PM_2.5 and PM₁₀ were simultaneously sampled and which identified PM_2.5 as the major component of PM₁₀, and a summer sub-campaign. Critical concentrations of both PM_2.5 and PAHs were observed in winter time; for example, in January 2003 the mean value for the 24-h average PM_2.5 concentration was 58 μg/m³, much higher than the annual arithmetic mean of 15 μg/m³ established by the US ambient air quality standard (NAAQS). Correspondingly, the mean value for benzo[a]pyrene (BAP) in PM_2.5 was 1.79 ng/m³, again higher than the annual mean of 1 ng/m³, required by European regulations for BAP in PM₁₀. In summer time the BAP concentration considerably decreases to 0.10 ng/m³ as the likely effect of photolysis and dilution on a higher boundary layer; PM_2.5 decreases too, but the mean concentration (22 μg/m³) is still higher than the NAAQS value. Further analysis included TEM microscopy of collected particles and correlations between PM_2.5, PAHs and gases (benzene, O₃, CO, NO₂, SO₂). All these observations identified on-road mobile sources as the main source of emissions and, in general, of the poor air quality level in the city of Bologna.     

Mineralogy of Inhalable Particulate Matter (PM10) in the Atmosphere of Beijing, China

The study of mineral components in respirable particles (particulate matter with diameter less than 10 μm, PM₁₀) in ambient air is important in understanding and improving air quality. In this study, PM₁₀ samples were collected in various areas around Beijing during 2002～2003, including an urban setting, a satellite city and a rural area. The mineralogical composition of these PM₁₀ samples was studied by X-ray diffraction (XRD), environmental scanning electron microscopy / and energy-dispersive X-ray analyzer (ESEM/EDX). The results indicated that mineral composition of PM₁₀ in different seasons and in different region varied significantly. Mineral mass concentration in Beijing PM₁₀ reached the highest percentage in the spring and fell to the lowest level in the autumn. The minerals in the spring PM₁₀ were dominated by clay minerals and quartz, followed by plagioclase, K-feldspar, calcite, dolomite, hematite, pyrite, magnesite, gypsum and laumontite as well as some unidentified materials. Fewer mineral types were collected in summer, however some new components, including K(NH₄)Ca(SO4)₂·H₂O, NH₄Cl and As₂O₃·SO₃ were noted to be present, suggesting that atmospheric chemical reaction in Beijing air were more active in summer than in other seasons. Mineral components in Beijing urban air were at a higher percentage with fewer phases than that in satellite city air. In conclusion, there was considerable variation in mineral components in PM₁₀ samples collected in different seasons and areas, which reflects the related air quality of sampling areas.     

Multi-criteria Analysis of Air Pollution with SO2 and PM10 in Urban Area Around the Copper Smelter in Bor, Serbia

This work presents the results of 4 years long monitoring of concentrations of SO₂ gas and PM₁₀ in the urban area around the copper smelter in Bor. The contents of heavy metals Pb, Cd, Cu, Ni, and As in PM₁₀ were determined and obtained values were compared to the limit values provided in EU Directives. Manifold excess concentrations of all the components in the atmosphere of the urban area of the townsite Bor were registered. Through application of a multi-criteria analysis by using PROMETHEE/GAIA method, the zones were ranked according to the level of pollution.     

Use of Anguilla anguilla for Biomonitoring Persistent Organic Pollutants (POPs) in Brackish and Riverine Waters in Central and Southern Italy

One of the aims of the Water Framework Directive 2000/60/CE is to assess the ecological status of water bodies in Europe in relation to priority contaminants, including some persistent organic pollutants (POPs). Recognizing the benefits of measuring hydrophobic compounds in biota tissues rather than in water, we used the European eel Anguilla anguilla in the present study as a bioindicator species for monitoring POPs in freshwater/brackish environments. We present the results of a contamination analysis of eels carried out in three Italian sites representative of different pollution levels: the last part of Tevere River, which flows through a very urbanized and industrialized area, Caprolace Lake and Lesina Lagoon, inside two different protected national parks. A very high pollution variability was recorded within each group of eels, in particular for those caught at Caprolace Lake. Due to this high variability, inter-population comparisons were carried out only between eels collected in Tevere River and Lesina Lagoon. PCBs values in Lesina Lagoon were two orders of magnitude lower than those measured in Tevere River, while no significant differences were found for levels of DDT compounds. Our results confirm the suitability of the eel as an indicator of persistent bioaccumulative pollutants in brackish environments and rivers where it can be easily caught, but we are sceptical of its use in deep lakes where its capture might be problematic considering standard operation procedures for fish sampling.     

基于时间序列分析并预测三峡库区局地环境温度的变化

利用湖北秭归三峡库首典型区的气象监测资料,采用时间序列分析和自回归积分滑动平均模型（ARIAM）方法,对三峡库区2001-2015年局地环境温度变化进行趋势和预测分析,以探讨三峡工程蓄水对库区局地气候环境变化的影响。结果表明,研究区域局地气温和地温的时间序列为季节性非平稳时间序列,年际月平均气温峰值在7月（29.0℃）,低谷在1月（6.0℃）;研究期内局地平均气温在2003年降至17.8℃,2007年稳定升至18.3℃;2011年持续降至的17.1℃,之后稳定升至2013年的17.9℃。平均地温在2005年升至21.2℃,2008年持续降至19.4℃,后期在2013年稳定升至20.1℃。分析结果显示,在2003年蓄水前后三峡库首典型区局地环境温度呈现一定程度年际波动,但不存在显著单一的变化趋势,说明在研究期15a内三峡工程蓄水对研究区域的局地环境温度未产生显著影响。用ARIMA模型获得了气温和地温的最佳预测模型,2015年预测值与监测值的符合程度良好,可进一步利用该地区长期监测数据对模型进行优化和应用。     

Polycyclic Aromatic Hydrocarbons and their Molecular Diagnostic Ratios in Airborne Particles (PM10) Collected in Rio de Janeiro, Brazil

Atmospheric polycyclic aromatic hydrocarbons (PAHs) were determined in particulate matter (PM10) collected in a suburban area with industrial and vehicular emissions in the Metropolitan Area of Rio de Janeiro City (Brazil). A total of 22 samples were collected between March and August 2005 by means of a high volume PM10 sampler. The particulate matter contained in the filters was extracted ultrasonically with dichloromethane. The extracts were later analyzed by gas chromatography coupled to a mass spectrometer (GC/MS). The individual concentrations of PAHs ranged between the detection limit and 0.386 ng m^?3. The PAHs concentrations observed in this study were towards the lowest end of the range of values reported for other European locations and also lower than values obtained for South America. PAHs concentrations and molecular ratios showed that light cars seem to be the main contributors to PM10 emissions, but diesel vehicles are clearly minor emission sources and industrial contributions should not be disregarded until more data are obtained.     

三峡库区(重庆段)降雨侵蚀力变化趋势及突变分析

三峡库区水土流失是社会关注的焦点问题,采用Mann—Kendall非参数检验法对三峡库区(重庆段)1955—2010年降雨侵蚀力变化趋势及突变进行分析,获取56a来研究区降雨侵蚀力时间变化特征。结果表明:(1)1955—2010年,研究区年降雨侵蚀力增大趋势不显著(sig=0.05)。季节降雨侵蚀力变化上,仅夏季降雨侵蚀力显著增大,需加强夏季水土流失治理。(2)1955—2010年,研究区年降雨侵蚀力突变开始于1967年,在1980s—1990s显著增大(sig=0.05)。季节降雨侵蚀力突变结果表明,春、秋季降雨侵蚀力突变开始于1950s末,1970s—1980s显著增大(sig=0.05);夏季降雨侵蚀力突变开始于1979年,在2000年后显著增大(sig=0.05),近10a来夏季降雨侵蚀潜能明显增强。(3)沿长江干流的各气象站点中,仅涪陵站年降雨侵蚀力增大显著(sig=0.1)。奉节、万县两站春、秋季节降雨侵蚀力变化趋势与沙坪坝、涪陵两站存在差异;奉节站季节降雨侵蚀力突变与其他3个站点差别较大,地形是影响研究区降雨侵蚀变化空间分异的重要因素,需加强奉节、万县的水土流失防治工作。     

城镇生态化视角下三峡库区人口-经济-环境(PEE)耦合协调发展

[目的] 探索PEE系统的互动耦合特征,可为三峡库区城镇生态化发展提供理论支撑和量化依据。[方法] 在2000—2020年三峡库区PEE系统综合评价基础上,运用耦合协调度模型、引力模型和障碍度模型对系统耦合协调度的时空演化特征、空间联系特征及主要障碍因子进行实证研究。[结果] (1)2000—2020年库区PEE系统综合发展水平呈逐步上升态势;(2)研究期内系统的耦合协调度基本不变,协调等级不高,协调类型呈"西南-东北"中部-北部"的空间特征,总体呈良性上升发展趋势;(3)邻近区域系统耦合协调度的空间相关性存在显著的正自相关,空间联系总量总体上升,空间联系强度较弱,且随着地理距离增大而逐渐减弱;(4)各因素对系统发展影响具有趋同性,经济和人口系统是主要制约子系统,而环境系统的障碍度逐年增加。[结论] 库区PEE系统耦合协调发展水平总体向好,区域差异缩小,未来应重点从单一系统优化向多元系统协调出发,从系统自身与区域协同2个角度进行调整,加强政策制度调控,科学探索发展路径。     

Assessment of the Impact Produced by the Traffic Source on VOC Level in the Urban Area of Canosa di Puglia (Italy)

Volatile organic compounds (VOC) have been monitored in 12 sites of Canosa di Puglia, a city located in the Southern of Italy, in order to identify the main VOC source—vehicular traffic or industrial—and to evaluate the critical situations in the city. Monitoring, carried out by using Radiello® diffusive samplers, has been planned taking into account the traffic density and the architecture of the city. From the study of the data it has been emerged that, among all considered VOC, benzene, toluene, ethylbenzene and xylenes (BTEX) are the pollutants at higher concentration. However no critical situation has appared from the present monitoring. Maps of daily benzene and toluene concentrations have shown that the most significant pollution phenomena happens in the center of the urban area which is in a valley with narrow roads and high buildings that do not allow an efficient dispersion of pollutants. The study of the diagnostic ratios between the toluene and benzene concentrations in the several areas (average T/B?=?3.4) and the high Pearson’s coefficient among the pollutants, and in particular between benzene and toluene concentrations (r?=?0.9505), have suggested that in urban area these pollutants are emitted from the same source: the vehicular traffic.     

Status Quo of Soil Contamination with Inorganic and Organic Pollutants of the River Oka Floodplains (Russia)

The contamination status of rivers and their floodplains with inorganic and organic pollutants in central Russia is poorly known. We investigated the concentrations of inorganic (As, Cd, Cu, Hg, Ni, Pb and Zn) and persistent organic pollutants (hexachlorocyclohexane, PCBs, cyclodienes, DDX and other pesticides) in floodplain soils of the Oka River catchment (Russia). The level of contamination was generally lower than in the Elbe River floodplain but in the same range as in other European river systems such as floodplains of the rivers Rhine, D?evnice and Yachroma. Only soil samples from the periphery of the city of Ryazan (200 km southeast of Moscow) had a higher anthropogenic enrichment of Cd, Cu and Zn which was comparable to the contaminated Elbe River floodplains. These soils also had the largest concentrations of persistent organic pollutants among all samples from the Oka River catchment. Therefore, the need for large-scale remediation seems to be less urgent than in Central European river catchments and mainly restricted to some “hot spot” areas.     

聚丙烯酰胺(PAM)对三峡库区紫色土坡面片蚀的影响

设置不同PAM施加量(0,0.4,0.8,1.6 g/m²),在不同坡度(15°,20°,25°)条件下开展不同雨强(60,90,120 mm/h)的模拟降雨试验。研究不同PAM施加量紫色土坡面片蚀产流产沙过程及其对产流产沙量的影响程度和主要因素,并分析了PAM对坡面片蚀可蚀性的影响。结果表明：坡面产流过程呈现先持续增加后趋于波动稳定的变化趋势,产沙过程则呈现先迅速减少并趋于稳定的变化趋势,PAM对片蚀的产流产沙过程变化趋势没有影响。和空白对照组相比,PAM施加量为0.4,0.8,1.6 g/m²的产流总量平均分别减小7.71%,35.16%,21.12%,产沙总量平均分别减小35.80%,49.39%,17.85%,PAM施加量为0.8 g/m²时产流总量和产沙总量最小。同种雨强下,不同施加量减流效益的大小顺序为0.8 g/m²>1.6 g/m²>0.4 g/m²,而减沙效益则受到坡度影响,在15°坡面减沙效益大小顺序是0.8 g/m