Fractionation of residual cadmium,copper, nickel,lead, and zinc in previously sludge‐amended soil

Abstract

The fractionation of heavy metals in previously sludge‐amended soil is important to evaluate their behavior in the environment in terms of mobility and availability to crop plants. A surface soil that received two types of sludges at two different rates, plus fertilizer only and no treatment (control), having been fallow for nine years, was used in this study. The contents of cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) fractions in previously sludge‐amended soils were governed by the total content of these metals in the sludges applied and by the rate of sludge application. The contents of these metals were higher for soils that received the Chicago sludge as compared to that receiving the Huntsville sludge. Furthermore, soils that received 20 Mg/ha/yr of sludge for five years generally had higher levels of these metals than those receiving a single dose at the 100 Mg/ha application rate. The percentage of the total content in the water soluble and exchangeable forms was very low (≤1%) regardless of sludge application. The application of sludges tended to reduce the residual fraction and to increase the organic and carbonate fractions. Overall, the predominant forms of the metals in the sludges were as the Cd‐, Ni‐, Pb‐, and Zn‐carbonate and Cu‐organic fractions.     

Influence of Soil and Fertilizer Nutrients on Sustainability of Rainfed Finger Millet Yield and Soil Fertility in Semi-arid Alfisols

Productivity of rainfed finger millet in semiarid tropical Alfisols is predominantly constrained by erratic rainfall, limited soil moisture, low soil fertility, and less fertilizer use by the poor farmers. In order to identify the efficient nutrient use treatment for ensuring higher yield, higher sustainability, and improved soil fertility, long term field experiments were conducted during 1984 to 2008 in a permanent site under rainfed semi-arid tropical Alfisol at Bangalore in Southern India. The experiment had two blocks—Farm Yard Manure (FYM) and Maize Residue (MR) with 5 fertilizer treatments, namely: control, FYM at 10 t ha^?1, FYM at 10 t ha^?1 + 50% NPK [nitrogen (N), phosphorus (P), potassium (K)], FYM at 10 t ha^?1 + 100% NPK (50 kg N + 50 kg P + 25 kg K ha^?1) and 100% NPK in FYM block; and control, MR at 5 t ha^?1, MR at 5 t ha^?1 + 50% NPK, MR at 5 t ha^?1 + 100% NPK and 100% NPK in MR block. The treatments differed significantly from each other at p < 0.01 level of probability in influencing finger millet grain yield, soil N, P, and K in different years. Application of FYM at 10 t ha^?1 + 100% NPK gave a significantly higher yield ranging from 1821 to 4552 kg ha^?1 with a mean of 3167 kg ha^?1 and variation of 22.7%, while application of maize residue at 5 t ha^?1 + 100% NPK gave a yield of 593 to 4591 kg ha^?1 with a mean of 2518 kg ha^?1 and variation of 39.3% over years. In FYM block, FYM at 10 t ha^?1 + 100% NPK gave a significantly higher organic carbon (0.45%), available N (204 kg ha^?1), available P (68.6 kg ha^?1), and available K (107 kg ha^?1) over years. In maize residue block, application of MR at 5 t ha^?1 + 100% NPK gave a significantly higher organic carbon (0.39%), available soil N (190 kg ha^?1), available soil P (47.5 kg ha^?1), and available soil K (86 kg ha^?1). The regression model (1) of yield as a function of seasonal rainfall, organic carbon, and soil P and K nutrients gave a predictability in the range of 0.19 under FYM at 10 t ha^?1 to 0.51 under 100% NPK in FYM block compared to 0.30 under 100% NPK to 0.67 under MR at 5 t ha^?1 application in MR block. The regression model (2) of yield as a function of seasonal rainfall, soil N, P, and K nutrients gave a predictability in the range of 0.11 under FYM at 10 t ha^?1 to 0.52 under 100% NPK in FYM block compared to 0.18 under MR at 5 t ha^?1 + 50% NPK to 0.60 under MR at 5 t ha^?1 application in MR block. An assessment of yield sustainability under different crop seasonal rainfall situations indicated that FYM at 10 t ha^?1 + 100% NPK was efficient in FYM block with a maximum Sustainability Yield Index (SYI) of 41.4% in <500 mm, 64.7% in 500–750 mm, 60.2% in 750–1000 mm and 60.4% in 1000–1250 mm rainfall, while MR at 5 t ha^?1 + 100% NPK was efficient with SYI of 29.6% in <500 mm, 50.2% in 500–750 mm, 40.6% in 750–1000 mm, and 39.7% in 1000–1250 mm rainfall in semi-arid Alfisols. Thus, the results obtained from these long term studies incurring huge expenditure provide very good conjunctive nutrient use options with good conformity for different rainfall situations of rainfed semiarid tropical Alfisol soils for ensuring higher finger millet yield, maintaining higher SYI, and maintaining improved soil fertility.     

Sequential fractionation and plant availability of heavy metals as affected by sewage sludge applications to soil

Abstract

The effect of sewage sludge applications on extractability and uptake by chard and lettuce of soil cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), leaf (Pb), and zinc (Zn) was investigated. Ten different treatments (0, 150, 300, and 500 kg N ha^‐1) as mineral fertilizer, and 400, 800, and 1,200 kg N ha^‐1 of aerobically and anaerobically‐digested sewage sludges were applied annually to a sandy‐loam soil since 1984. Seven years after the start of the treatments, higher levels of heavy metals were detected in the soil, depending on the type of metal, depth of sampling, type of sludge used, and, especially, rate of application. Following a sequential extraction procedure incorporating 0.1M CaCl₂, 0.5M NaOH, and 0.05M Na₂EDTA, most of the heavy metals in soil were detected in the Na₂EDTA solution and the residual fractions. Large amounts of Cd appeared to be extracted by CaCl₂, whereas substantial amounts of Cu and Ni were isolated by NaOH. The effect of treatments on the percentages of the metals found in each fraction depended on the type of metal, sampling depth, sludge used, and application rate. No significant increases were found in the heavy metal contents of chard and lettuce leaves, but some of the treatments resulted in a significant decrease of Cd and Cr levels in lettuce leaves.     

Effect of straw biochar application on soil carbon,greenhouse gas emissions and nitrogen leaching: A vegetable crop rotation field experiment

Intensive vegetable crop systems are rapidly developing, with consequences for greenhouse gas (GHGs) emissions, nitrogen leaching and soil carbon. We undertook a field trial to explore the effect of biochar application (0, 10, 20 and 40 t ha⁻¹) on these factors in lettuce, water spinach and ice plant rotation. Our results show that the 20 and 40 t ha⁻¹ soil treatments resulted in the SOC content being 26.3% and 29.8% higher than the control (0 t ha⁻¹), respectively, with significant differences among all treatments (p < .05). Biochar application caused N₂O emissions to decrease during the lettuce and water spinach seasons, by 1.5%–33.6% and 12.4%–40.5%, respectively, compared the control, with the 20 t ha⁻¹ application rate resulting in the lowest N₂O emissions. Biochar also decreased the dissolved nitrogen (DN) concentration in leachate by 9.8%–36.2%, following a 7.3%–19.9% reduction in dissolved nitrogen in the soil. Similarly, biochar decreased the nitrate (NO₃⁻) concentrations in leachate by 3.9%–30.2%, following a 3.8%–16.7% reduction in the soil nitrate level. Overall, straw biochar applied at rate of 20 t ha⁻¹ produced the lowest N₂O emissions and N leaching, while, increasing soil carbon.     

Enhancing the productivity of high‐magnesium soil and water resources in Central Asia through the application of phosphogypsum

Recent evidences from some irrigated areas worldwide, such as Central Asia, suggest that water used for irrigation contains magnesium (Mg²⁺) at levels higher than calcium (Ca²⁺). Excess levels of Mg²⁺ in irrigation water and/or in soil, in combination with sodium (Na⁺) or alone, result in soil degradation because of Mg²⁺ effects on the soil's physical properties. More than 30 per cent of irrigated lands in Southern Kazakhstan having excess levels of Mg²⁺ are characterized by low infiltration rates and hydraulic conductivities. The consequence has been a gradual decline in the yield of cotton (Gossypium hirsutum L.), which is commonly grown in the region. These soils require adequate quantities of Ca²⁺ to mitigate the effects of excess Mg²⁺. As a source of Ca²⁺, phosphogypsum—a byproduct of the phosphorous fertilizer industry—is available in some parts of Central Asia. In participation with the local farming community, we carried out a 4‐year field experiment in Southern Kazakhstan to evaluate the effects of soil application of phosphogypsum—0, 4·5, and 8·0 metric ton per hectare (t ha⁻¹)—on chemical changes in a soil containing excess levels of Mg²⁺, and on cotton yield and economics. The canal water had Mg²⁺ to Ca²⁺ ratio ranging from 1·30 to 1·66 during irrigation period. The application of phosphogypsum increased Ca²⁺ concentration in the soil and triggered the replacement of excess Mg²⁺ from the cation exchange complex. After harvesting the first crop, there was 18 per cent decrease in exchangeable magnesium percentage (EMP) of the surface 0·2 m soil over the pre‐experiment EMP level in the plots where phosphogypsum was applied at 4·5 t ha⁻¹, and a 31 per cent decrease in EMP in plots treated with phosphogypsum at 8 t ha⁻¹. Additional beneficial effect of the amendment was an increase in the soil phosphorus content. The 4‐year average cotton yields were 2·6 t ha⁻¹ with 8 t ha⁻¹ phosphogypsum, 2·4 t ha⁻¹ with 4·5 t ha⁻¹ phosphogypsum, and 1·4 t ha⁻¹ with the control. Since the amendment was applied once at the beginning, exchangeable Mg²⁺ levels tended to increase 4 years after its application, particularly in the treatment with 4·5 t ha⁻¹ phosphogypsum. Thus, there would be a need for phosphogypsum application to such soils after every 4–5 years to optimize the ionic balance and sustain higher levels of cotton production. The economic benefits from the phosphogypsum treatments were almost twice those from the control. Copyright © 2007 John Wiley & Sons, Ltd.     

Using farmer knowledge to combat low productive spots in rice fields of a Sahelian irrigation scheme

In the oldest sections of Burkina Faso's largest irrigation scheme in the Sourou Valley (13° 10′ N, 03° 30′W) rice (Oryza sativa L.) yields dropped from about 5 to 6 t ha⁻¹ in the early 1990s, shortly after establishment of the scheme, to 2 to 4 t ha⁻¹ from 1995 onwards. Farmers blamed this yield decline on the appearance of 2 to 20 m diameter low productive spots. According to farmers and field measurements, the low productive spots decreased yields by 25–50 per cent. The low productive spots are caused by Zn deficiency. Low Zn availability is related to the very low DTPA‐extractable Zn content of the soil (0·08–0·46 mg kg⁻¹), the alkaline‐calcareous character of the soil, the non‐application of Zn fertilizers, and a relatively large P fertilizer dose (21 kg P ha⁻¹). Farmers were correct in relating the calcareous nature of the soil to the presence of the low productive spots. They were instrumental in identifying application of decomposed organic resources (e.g. rice straw at 5 t ha⁻¹) as a short‐term solution that increases yields by 1·5 to 2·0 t ha⁻¹. Application of Zn fertilizer (10 kg Zn ha⁻¹) in 29 farmer fields in the 2001 dry season eradicated the low productive spots and increased yields from 3·4 to 6·0 t ha⁻¹. Although application of Zn fertilizer is strongly recommended, it is not yet available in Burkina Faso. Based on a comparison of fertilizer prices on the world market and the local market, we expect that the use of Zn fertilizers will be highly profitable (cost/value ratio ≫ 2). Despite the relatively recent introduction of irrigated rice cropping, most farmers showed a good understanding of cropping constraints and possible solutions. Both farmers and researchers mutually benefited from each other's knowledge and observations. Copyright © 2004 John Wiley & Sons, Ltd.     

Long-term changes in organic matter of woodland soils cleared for arable cropping in Zimbabwe

Subsistence farmers in Africa depend largely on the soil organic matter to sustain crop productivity. Long-term changes in soil organic carbon and nitrogen were measured after woodland clearance for smallholder subsistence farming or for commercial farming. The contents of organic carbon and nitrogen in soil under reference woodlands were largest (53.3 t C ha⁻¹, 4.88 t N ha⁻¹) in a red clay soil (∼ 50% clay + silt), followed by a granitic sand (∼ 12% clay + silt; 22.8 t C ha⁻¹, 1.47 t N ha⁻¹) and least (19.5 t C ha⁻¹, 0.88 t N ha⁻¹) in a Kalahari sand (∼ 5% clay + silt). Organic carbon declined rapidly under cultivation to attain new equilibria within 10 years on all smallholdings. Greatest losses occurred in soils that initially contained most carbon and nitrogen in the order: red clay (22.4 t C ha⁻¹ and 1.0 t N ha⁻¹) > granitic sand (13.2 t C ha⁻¹ and 0.8 t N ha⁻¹) > Kalahari sand (10.6 t C ha⁻¹ and 0.5 t N ha⁻¹). On the clay soil, commercial farming with intensive use of mineral fertilizers and incorporation of maize stover led to more gradual decline: at equilibrium, contents of carbon and nitrogen were 15 t C ha⁻¹ and 1.7 t N ha⁻¹ greater than on smallholdings with similar soil and climate. In the Kalahari sand the δ¹³C of organic C remained constant after woodland clearance, and maize contributed less than 10% of the total C even after 55 years. The δ¹³C signature increased slightly with increasing duration of cultivation by smallholders in the granitic sands and red clay soil where maize contributed 29% and 35% of the C at equilibrium. Under more productive commercial farming, the carbon derived from maize accounted for 50% of the total after 10 years of cultivation and 67% at equilibrium. The persistence of woodland carbon in the sandy soil is attributed to chemical stabilization resulting from large concentrations of lignin and polyphenols in the tree litter, or as charcoal.     

Urease activity in sewage sludge-amended soils

Three diverse field-moist soil samples were treated with five sewage sludges (applied at five loading rates) containing high concentrations of heavy metals. Urease activity was assayed after 0, 3, 7, 14 and 30 days of incubation. Results showed that when soils were treated with the sewage sludges, urease activity was often inhibited at the lower loading rates (2.2 and 8.9mg sludge g^?1 soil), but was enhanced substantially with the higher application rates (22.2, 44.4 and 100 mg sludge g^?1 soil). Inhibition of urease activity in the sewage sludge amended-soils ranged from 4 to 37% (Domino soil), 8–27% (Hesperia soil), and 3–49% (Ramona soil) at various times of incubation. Inhibition of the enzyme activity was attributed to the presence of heavy metals in the sludges. The increased activity of urease in the sludge-amended soils at the highest application rate (100 mg sludge g^?1 soil) ranged from 1.13 to 5.00-fold (Domino soil), 1.20–4.04-fold (Hesperia soil), and 1.13–5.40-fold (Ramona soil). Enhanced urease activity was believed to be due to the additional source of organic matter and nutrients supplied by the sludge which stimulated microbial activity and subsequent urease synthesis.     

Response of three cereal crops in continuous arable or ley-arable rotations to fertilizer nitrogen and soil nitrogen at Rothamsted's Woburn Ley-arable experiment

Rothamsted's Woburn Ley-arable experiment, started in 1938 on a sandy loam soil, provides valuable real-world data on the effects of all-arable and ley-arable rotations. In this study, six rotations were compared from 1973 to 2001. Two had 3-year arable “treatment” crops, two had 3-year leys, and two had 8-year leys; the leys being all-grass given fertilizer nitrogen (Ln3 and Ln8), or grass/clover (Lc3 and Lc8). Here, we present the yields of two test crops, winter wheat (1981–2000) followed by spring barley (1982–1991) or winter rye (1997–2001) in each of the six rotations, and their response to four rates of fertilizer N and soil N. From fitted yield/N response curves, we show that maximum wheat yields were least (7.10 t ha⁻¹) in the AB rotation, slightly higher, but not significantly so (7.65 t ha⁻¹) following Ln leys but significantly higher (8.12 t ha⁻¹) following Lc leys. Significantly less fertilizer N (30 kg ha⁻¹) was needed to achieve the higher yields following Lc leys. Yields of the second cereal following the leys were 0.3–0.8 t ha⁻¹ higher than those in the AB rotation; these increases were not statistically significant. However, significantly less fertilizer N, 26–38 kg N ha⁻¹, was required to achieve those yields. There was no difference found between the type of ley. The initial benefit of the Lc leys was short-lived. If leys are to be introduced into mainly arable farming systems, they may need to be subsidized to make them financially viable.     

Soil carbon pools of reclaimed minesoils under grass and forest landuses

Minesoils are characterized by low soil organic matter and poor soil physicochemical environment. Mine soil reclamation process has potential to restore soil fertility and sequester carbon (C) over time. Soil organic C (SOC) pool and associated soil properties were determined for reclaimed minesoils under grass and forest landuses of varied establishment year. Three grassland sites of 30, 9, and 1 years after reclamation (G30, G9, and G1) and two forest sites, 11 years after reclamation (RF) and undisturbed stand of 40 years (UF), were selected within four counties (Morgan, Muskingum, Noble, and Coshocton) of southeastern Ohio. Soil bulk density (BD) of reclaimed forest (RF) soil was significantly higher than undisturbed forest (UF) soils within 10–40 cm soil depth profile. Reclamation process increased soil pH from slightly acidic to alkaline and decreased the soil EC in both landuses. Among grassland soils, significant changes in SOC and total soil N contents were observed within 0–10 cm soil depth. SOC contents of G30 (29.7 Mg ha⁻¹) and G9 (29.5 Mg ha⁻¹) were significantly higher than G1 soils (9.11 Mg ha⁻¹). Soil N content was increased from G1 (0.95 Mg ha⁻¹) to G9 (2.00 Mg ha⁻¹) site and then the highest value was found under G30 (3.25 Mg ha⁻¹) site within 0–10 cm soil depth. UF soils had significantly higher SOC and total N content than RF soils at 0–10 and 10–20 cm soil depths. Copyright © 2009 John Wiley & Sons, Ltd.     

Concentrations of heavy metals in forty sewage sludges in England

Samples of forty sewage sludges taken in England during 1979 were analysed for ten heavy metals using a rapid flameless atomic absorption spectroscopic technique. For all metals the mean concentrations were influenced by a small number of sludges containing exceptionally high concentrations. Typically, the concentration ranges showed approximately a 100-fold spread. Calculations based on U.K. guidelines for limiting the addition of toxic metals in sludge to agricultural soils indicated that application rates would theoretically be limited for more than 75 % of the sludges by the concentrations of Zn, Cu and Ni, expressed additively as the Zn equivalent. Calculations of the theoretical maximum quantities of sludges which could be applied to land on an annual basis suggested that a significant proportion of the sludges would be unsuitable for application to agricultural land at rates of more than 2 t ha^?1 yr^?1     

Dairy Cattle Manure Effects on Soil Quality: Porosity,Earthworms, Aggregates and Soil Organic Carbon Fractions

In the European Union, the maintenance of soil quality is a key point in agricultural policy. The effect of additions of dairy cattle (Bos taurus) manure (DCM) during a period of 11 years were evaluated in a soil under irrigated maize (Zea mays L.) monoculture. DCM was applied at sowing, at wet‐weight rates of 30 or 60 Mg ha⁻¹yr⁻¹ (30DCM or 60DCM). These were compared with a mineral‐N treatment (300 kg N ha⁻¹, MNF), applied at six to eight emerged leaves and with a control (no N, no manure). Treatments were distributed in a randomized block design. Factors analysed were stability against wetting stress disaggregation, porosity, soil organic carbon (SOC) fractions and earthworm abundance, studied eight months after the last manure application. The application rate of 30DCM increased aggregate stability and the light SOC fraction, but not the pore volume, nor the earthworm abundance, compared with MNF. The DCM rates did not result in unbalanced agronomic advantages versus MNF, as high yields (12–16 Mg ha⁻¹ yr⁻¹) were obtained. In Mediterranean environments, the use of DCM should be encouraged mainly because of its contribution to the light SOC fraction which protects dry macro‐aggregates from implosion (slaking) during the wetting process. Thus, in intensive agricultural systems, it protects soil from physical degradation. Copyright © 2016 John Wiley & Sons, Ltd.     

Nitrogen Mineralization in Soils Treated with Fly Ash–Amended Wastewater Sludges

Abstract

Alkaline‐treated wastewater sludges with varying doses of fly ash were added to a clay soil at rates equivalent to 100 t (dry weight) raw sludge ha^?1 soil, and the variations in ammonium, nitrate, and total nitrogen contents were monitored throughout an incubation period of 360 days at 28°C. The results showed that inhibition of organic nitrogen mineralization occurred in soil amended with fly ash–containing sludge during the first 90 days of incubation. After the total incubation period of 360 days, the inhibition effects of alkaline sludge amendments totally disappeared. In fact, mineralization was enhanced in alkaline pasteurized sludges containing 80% and 120% fly ash. The overall results indicated that application of sludges amended with fly ash may prolong the use (3 to 6 months) of nitrogen from the organic nitrogen pool in sludge.     

Effects of compost type and storage conditions on climbing bean on Technosols of Tantalum mining sites in Western Rwanda

Little is known about the effects of compost application to reclaim artisanal mining sites for agriculture in Central Africa. A field experiment was therefore conducted to examine the effects of locally available organic household waste composted under traditional (pit under leaf shade) versus improved management (pit under double plastic sheeting) and mixed with either Tithonia diversifolia biomass or Minjingu Phosphate Rock (13–15% P) on climbing bean sown on degraded Technosols (former Tantalum mining sites) and un‐mined control soils (Cambisols). Both soil types were derived from pegmatite. After 6 months of composting, nutrient concentrations in traditional compost were 0.27–0.32% N, 0.06–0.08% P, and 0.20–0.22% K. Comparative values in amended compost were 1.02–1.65% N, 0.10–0.31% P, and 0.41–1.13% K. In farmyard+solid waste, composted under traditional system, dry matter was 65.4%, pH 6.7, and C : N ratio 13.0, as opposed to 81.5% DM, a pH of 8.6, and a C : N ratio of 8.6 in farmyard+solid waste+Minjingu phosphate under improved compost, and 68.3% dry matter, a pH of 8.4, and a C : N ratio of 7.4 for Tithonia +farmyard+solid waste under improved conditions. Compared to bean (Phaseolus vulgaris L.) grain yields of 0.28 (mined soil) and 0.11 (unmined soil) without amendments, the application (on a dry matter basis) of 5 t compost ha⁻¹ led to yields of 3.54 t DM ha⁻¹ for improved compost Tithonia +farmyard+solid waste on mined soil versus 2.26 t DM ha⁻¹ (P < 5%) for the same treatment at the un‐mined sites. The yield obtained for farmyard+solid waste+Minjingu phosphate composted under improved conditions averaged 3.06 t DM ha⁻¹ at mined sites compared with 2.85 t DM ha⁻¹ at un‐mined sites (P > 5%). All amendments were more effective in enhancing bean yields on Technosols with significant positive effects with improved compost than on Cambisols.     

Metal uptake in lolium perenne established on spent mushroom compost amended lead‐zinc tailings

A greenhouse trial was performed to contrast the growth and metal accumulation in Lolium perenne established on pyritic tailings amended with varying applications of spent mushroom compost (SMC). The lead‐zinc tailings were retrieved from a moderately vegetated land impoundment facility located at Gortmore, Silvermines, Co. Tipperary (Ireland) and SMC was incorporated at application rates of 0, 50, 100, 200 and 400 t ha⁻¹. The grass species Lolium perenne was sown at an application rate of 200 kg ha⁻¹ and the subsequent biomass determined after 42 and 84 days. For the most part, metal concentrations in Lolium perenne showed a significant linear response (p < 0·05) to SMC application and generally decreased favourably with increasing SMC application (p < 0·05). This phenomenon may be attributed to the vast biosorption capacity of SMC owing to the presence of phenolic, carboxyl and phenolic functional groups, the development of stable metal chelates by the organic matter present in SMC and/or by the biosorbing of toxic metals by fungal mycelium, however this reduction in metal uptake by Lolium perenne is most likely due to greater plant dry weight caused by the increasing SMC applications. In spite of this, Lolium perenne suffered severe toxicity resulting from the inherently high concentrations of total zinc (1443–5920 mg kg⁻¹), lead (33–478 mg kg⁻¹) and cadmium (1·4–49 mg kg⁻¹) accumulated within the plant 84 days after seeding, the grass had adversely withered irrespective of SMC application. Therefore, a barrier break must be introduced in the tailings facility to prevent the uptake and accumulation of these lethal metal concentrations by plants. Only then should SMC and other suitable soil forming materials be utilized as growing media, as the incorporation of an organic amendment followed by direct seeding of a grass species is not economically or environmentally viable for permanent re‐vegetation of the Gortmore tailings management facility (TMF). Copyright © 2009 John Wiley & Sons, Ltd.     

Raised and sunken bed technique for agroforestry on alkali soils of northwest India

Many forest tree and fruit species can be raised on highly alkali soil (pH > 10) but some of them such as pomegranate (Punica granatum) are unable to tolerate water stagnation. To avoid water stagnation problems during the monsoon the raised and sunken bed technique has been found suitable for agroforestry practices on highly alkali soil. One fruit‐yielding pomegranate and one oil‐yielding salvadora (Salvadora persica) plantation species were successfully grown on raised bunds to avoid water stagnation and rice–wheat and berseem–kallar grass rotation were grown on sunken‐beds constructed for the purpose. The experiment was initiated in 1996 and the above two crop rotations were followed for two consecutive years starting in the summer season. Results of these experiments have also shown that good growth of plantations, on an average 4·3 to 4·9 t ha⁻¹ rice (salt tolerant var. CSR‐10) and 1·2 to 1·4 t ha⁻¹ wheat (KRL 1–4), were obtained in sunken beds. In another rotation 21·3 to 36.8 t ha⁻¹ fresh forage of kallar grass (Leptochloa fusca) and 44·9 to 47·8 t ha⁻¹ fresh forage of berseem (Trifolium alexandrium) were obtained. After two years of the experiment, soil amelioration in terms of reduction in soil pH was significant. The effect of plantation in reducing soil pH showed that the pomegranate and salvadora both helped in reduction of soil pH, but the latter due to its well‐developed lateral root system was more efficient in lowering the soil pH even at lower depths. The reduction in soil pH by the berseem–kallar grass rotation was better than under rice–wheat rotation. Copyright © 2001 John Wiley & Sons, Ltd.     

Changes in carbon stocks of Danish agricultural mineral soils between 1986 and 2009

To establish a national inventory of soil organic carbon (SOC) stocks and their change over time, soil was sampled in 1986, 1997 and 2009 in a Danish nation‐wide 7‐km grid and analysed for SOC content. The average SOC stock in 0–100‐cm depth soil was 142 t C ha^?1, with 63, 41 and 38 t C ha^?1 in the 0–25, 25–50 and 50–100 cm depths, respectively. Changes at 0–25 cm were small. During 1986–97, SOC in the 25–50‐cm layer increased in sandy soils while SOC decreased in loam soils. In the subsequent period (1997–2009), most soils showed significant losses of SOC. From 1986 to 2009, SOC at 0–100 cm decreased in loam soils and tended to increase in sandy soils. This trend is ascribed to dairy farms with grass leys being abundant on sandy soils while cereal cropping dominates on loamy soils. A statistical model including soil type, land use and management was applied separately to 0–25, 25–50 and 50–100 cm depths to pinpoint drivers for SOC change. In the 0–25 cm layer, grass leys added 0.95 t C ha^?1 year^?1 and autumn‐sown crops with straw incorporation added 0.40 t C ha^?1 year^?1. Cattle manure added 0.21 t C ha^?1 year^?1. Most interestingly, grass leys contributed 0.58 t C ha^?1 year^?1 at 25–50 cm, confirming that inventories based only on top‐soils are incomplete. We found no significant effects in 50–100 cm. Our study indicates a small annual loss of 0.2 t C ha^?1 from the 0–100 cm soil layer between 1986 and 2009.     

Potential of mine land reclamation for soil organic carbon sequestration in Ohio

Soils are an effective sink for carbon storage and immobilization through biomass productivity and enhancement of soil organic carbon (SOC) pool. The SOC sink capacity depends on land use and management. Degraded lands lose large amounts of C through SOC decomposition, erosion, and leaching. Thus, restoration of disturbed and degraded mine lands can lead to increase in biomass productivity, improved soil quality and SOC enhancement and sequestration. Reclamation of mined lands is an aggrading process and offers significant potential to sequester C. A chronosequence study consisting of 0‐, 5‐, 10‐, 15‐, 20‐ and 25‐year‐old reclaimed mine soils in Ohio was initiated to assess the rate of C sequestration by pasture and forest establishment. Undisturbed pasture and forest were used as controls. The SOC pool of reclaimed pasture sites increased from 15·3 Mg ha⁻¹ to 44·4 Mg ha⁻¹ for 0–15 cm depth and from 10·8 Mg ha⁻¹ to 18·3 Mg ha⁻¹ for 15–30 cm depth over the period of 25 years. The SOC pool of reclaimed forest sites increased from 12·7 Mg ha⁻¹ to 45·3 Mg ha⁻¹ for 0–15 cm depth and from 9·1 Mg ha⁻¹ to 13·6 Mg ha⁻¹ for 15–30 cm depth over the same time period. The SOC pool of the pasture site stabilized earlier than that of the forest site which had not yet attained equilibrium. The SOC sequestered in 0–30 cm depth over 25 years was 36·7 Mg ha⁻¹ for pasture and 37·1 Mg ha⁻¹ for forest. Copyright © 2000 John Wiley & Sons, Ltd.     

Influence of boron fertilization on cauliflower productivity,nutrient uptake and soil nutrient status in an acid Alfisol in Northwestern Himalaya

ABSTRACT

Modern agriculture over the years has resulted in depletion of boron (B) from soil which has been emerged as a serious obstacle for sustainable agriculture. We studied the availability of B in soil and cauliflower (Brassica oleracea var. botrytis L.) productivity under different levels of B fertilization. A field experiment was conducted during 2013–2014 and 2014–2015, at experimental farm of Himachal Pradesh Agricultural University, Palampur on silt-clay loam soil (acid Alfisol) under mid hill wet temperate condition. Different levels of B for the study included 0, 0.75, 1.5, 2.5, 5, 10, 20 and 30 kg B ha^?1 along with recommended dose (RD) of NPK and farmyard manure (FYM, 20 t ha^?1). The application of B influenced biological yield significantly up to 5 kg ha^?1. Highest curd yield in 2013–2014 (11.03 t ha^?1) and 2014–2015 (12.93 t ha^?1) was recorded in 1.5 and 0.75 kg ha^?1 B along with NPK + FYM, respectively. At higher rates of boron i.e. 10, 20 and 30 kg ha^?1, due to toxic effects, a reduction in curd yield was recorded in both years. Maximum mean uptake of N, P and K by leaves and curd was recorded with the application of boron at 1.5 kg ha^?1, whereas mean B uptake was highest when boron was applied at 2.5 kg ha^?1. The highest mean value (1.79 mg kg^?1) of soil available boron was recorded with 30 kg B ha^?1. Application of boron at 2.4 kg ha^?1 was worked out as optimum dose for cauliflower.     

Remediation of a Sandy Soil Contaminated with Cadmium,Nickel, and Zinc using an Insoluble Polyacrylate Polymer

Abstract

This study was carried out to investigate whether an insoluble polyacrylate polymer could be used to remediate a sandy soil contaminated with cadmium (Cd) (30 and 60 mg Cd kg^?1 of soil), nickel (Ni) (50 and 100 mg Ni kg^?1 of soil), zinc (Zn) (250 and 400 mg Zn kg^?1 of soil), or the three elements together (30 mg Cd, 50 mg Ni, and 250 mg Zn kg^?1 of soil). Growth of perennial ryegrass was stimulated in the polymer‐amended soil contaminated with the greatest amounts of Ni or Zn, and when the three metals were present, compared with the unamended soil with the same levels of contamination. Shoots of plants cultivated in the amended soil had concentrations of the metals that were 24–67% of those in plants from the unamended contaminated soil. After ryegrass had been growing for 87 days, the amounts of water‐extractable metals present in the amended soil varied from 8 to 53% of those in the unamended soil. The results are consistent with soil remediation being achieved through removal of the metals from soil solution.