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1.
We report the morphological features and thermal insulation properties of a series of cotton- and PET-based hybrid fabrics impregnated with silica aerogel. For the purpose, commercially available cotton and PET knitted fabrics were dipped into aqueous dispersions including different silica aerogel contents, dried, and stacked to 1, 3, and 5 layers. The SEM images revealed that the silica aerogel particles were well incorporated into cotton or PET knitted fabrics. The thermal insulating performance of the hybrid fabrics as functions of the silica aerogel content and the number of layers of stacked fabrics were characterized by monitoring the surface temperatures of the fabrics on a plate with a wide temperature range of ~50-80 oC using an infrared camera. The higher thermal insulation performance was attained for both cotton- and PET-based hybrid fabrics with higher silica aerogel contents. In addition, 3-layered hybrid fabrics exhibited noticeably improved thermal insulation performance, compared to 1- or 5-layered fabrics. The thermal insulation property of the cotton-based hybrid fabrics was dominantly influenced by silica aerogel than that of PET-based hybrid fabrics. The overall results demonstrated that the cotton- and PET-based hybrid fabrics with silica aerogel manufactured by a facile dip-dry process could be utilized as protective garments, heat-sensitive devices, pipes, automotive, aircrafts, and buildings for thermal insulation applications. 相似文献
2.
Zahra Talebi Mazraeh-shahi Ahmad Mousavi Shoushtari Ahmad Reza Bahramian Majid Abdouss 《Fibers and Polymers》2014,15(10):2154-2159
In recent years, flexible, mechanically strong and environmental friendly thermal insulation materials have attracted considerable attention. In this work, silica aerogel/polyethylene terephthalate (PET) nonwoven fiber composite with desirable characteristics was prepared via a two-step sol-gel process followed by an ambient drying method through immersing the PET nonwoven fiber into silica sol. The silica aerogel particles were characterized by FTIR, FE-SEM, TGA and nitrogen adsorption analysis. The morphology and hydrophobic properties of neat PET nonwoven fiber and its silica aerogel composite were also investigated. For studying thermal protective properties, the thermal diffusivity was calculated from temperature distribution curves. The mean pore size of 11 nm, the surface area of 606 m2/g and the total pore volume of 1.77 cm3/g for the silica aerogel particles in the composite are obtained from nitrogen adsorption analysis, indicating the aerogel can maintain its high porosity in the nonwoven composite structure. Silica aerogel particles were efficiently covered the surface of the PET fibers and completely filled the micron size pores of the nonwoven fiber leading to a stronger hydrophobicity and higher thermal insulation performance in the aerogel composite samples compared to the neat PET nonwoven. In this regard, an almost 64 % decrease in the thermal diffusivity was achieved with 66 wt% silica aerogel. 相似文献
3.
The dyeing and color fastness properties of two reactive-disperse dyes containing a sulfatoethylsulfone group on nylon, PET
and N/P mixture fabrics were examined. The rate of dyeing on nylon fabric was greatly dependent upon dye bath pH. The final
dye uptakes at all pH, however, were as high as 97 %. Color strength of the dyed nylon fabric linearly increased up to 0.5
%owf and then slowed down over 1 %owf dyeing. Washing and rubbing fastness of the dyed nylon fabric were excellent, but grade
of light fastness was moderate. Dyeability of the reactive-disperse dyes on PET fabric was not much affected by pH, and K/S
values of PET fabric dyed at pH 5–8 were lower than those of nylon fabric at all pH examined. Buildup and color fastnesses
properties on PET fabric showed the same tendency with nylon fabric. The rate of dyeing of the reactive-disperse dyes on nylon
fabric was faster than on PET fabric when both fabrics were dyed simultaneously in the same dye pot, resulting in higher color
strength of nylon than PET. The reactive-disperse dyes were found to be adequate to the one-bath, one-step dyeing of N/P mixture
fabric when applied at pH 5 and 120 °C. 相似文献
4.
We report herein a superhyrodrophobic poly(ethylene terephthalate) (PET) fabric prepared through a biomimetic method of the
Lotus effect. To attain the Lotus effect on the PET fabrics, physical roughness and chemical hydrophobicity were controlled
by adopting silica nanoparticles and a commercial water-repellent agent, respectively. For this, narrow-size distributed silica
nano-particles were prepared by a sol-gel process. The water contact angle on PET fabric treated with both silica nanoparticles
and water-repellent agent reached 158°, which was much higher than 137° reached by the fabric treated with the water-repellent
agent only. 相似文献
5.
The aim of this study is to examine the efficacy of the coconut fiber on the sound absorption and thermal insulation performance towards the composite nonwoven fabrics. The 2D polyester fiber and 12D fire retardant three-dimensional hollow crimp polyester fiber are individually mixed with 4D low-melting point polyester fiber (4DLMf) to produce 2D polyester nonwoven fabric (2D-PETF) and 12D polyester nonwoven fabric (12D-PETF) respectively. Subsequently, the coconut fiber (CF) is then laminated with the 2D-PETF and 12D-PETF to fabricate two types of PET/CF composite boards through the multiple needle-punching techniques. Accordingly, the sound absorption, thermal insulation, Limiting Oxygen Index and relative mechanical properties of the PET/CF composite boards are evaluated properly. The experimental results reveal that both types of PET/CF composite boards possess excellent thermal insulation performance and fire resistance property. Also, for both types of PET/CF composite boards, the average sound absorption coefficient increases with the increased amount of CF. 相似文献
6.
Dyeing and color fastness properties of a reactive disperse dye containing an acetoxyethylsulphone group on PET, Nylon, silk
and N/P fabrics were examined. The reactive disperse dye exhibited almost the same dyeing properties on PET fabric as a conventional
disperse dye except the level of dye uptake. The most appropriate pH and dyeing temperature for the dyeing of Nylon fabric
were 7 and 100°C respectively. The build-up on Nylon fabric was good and various color fastnesses were good to excellent due
to the formation of the covalent bond. Application of the reactive disperse dye on silk fabric at pH 9 and 80°C yielded optimum
color strength. The rate of dyeing on Nylon fabric was faster than that on PET fabric when both fabrics were dyed simultaneously
in a dye bath, accordingly color strength of the dyed Nylon was higher. The reactive disperse dye can be applied for one-step
and one-bath dyeing of N/P mixture fabric with good color fastness. 相似文献
7.
Xiaoyan Song Shengzhi Zhou Yuanfeng Wang Weimin Kang Bowen Cheng 《Fibers and Polymers》2012,13(8):1015-1022
PP/POSS and PP/SiO2 composite non-woven fabrics filled with polyhedral oligomeric silsesquioxanes (POSS) and SiO2 respectively using a convenient blending method were prepared through melt-blown process with corona charging. The morphology of the composite fibers and the distribution of POSS and SiO2 nanoparticles in PP matrix were investigated by field-emission scanning electron microscope (FSEM) and transmission electron microscope (TEM), respectively. POSS and SiO2 can act as nucleating agent and accelerate the crystallization process during nonisothermal cooling. The shear storage modulus G??, loss modulus G??, and complex viscosity ??* of non-woven fabric reduce when 1 wt % POSS was added and increase for PP5/POSS composite non-woven fabric compared with pure PP non-woven fabrics. However, all G??, G?? and ??* of PP/SiO2 non-woven fabric decrease with increasing SiO2 content owing to plasticization by SiO2. Both stress and elongation at break of the PP/POSS melt-blown non-woven fabrics are improved compared with PP non-woven fabrics, however decrease when SiO2 was added, as compared to the neat PP non-woven fabric. The onset temperature of decomposition for both the PP/POSS and PP/SiO2 composite non-woven fabrics is higher (5?C10 °C) than pure PP and char content is increased with increasing POSS and SiO2. 相似文献
8.
Present study is focused on the preparation of two layers composite wound dressing for drug release. The outer layer is made of hydrogel which contains of drug and the core layer is made of fabric. The two layers structure of composite dressing is formed by grafting of polyacrylamide-co-acrylic acid hydrogel on cotton fabric using ammonium per sulphate (APS) as chemical initiator and polyethylene glycol (PEG) as crosslinker. The major factors affecting graft copolymerization of hydrogel on cotton fabric are optimized by varying concentration of monomers & initiator, reaction temperature and addition time of crosslinker. Maximum grafting of hydrogel is obtained at 5 % (w/v) APS and 15 % acrylamide/acrylic acid (1:1 w/w ratio) concentration. The FTIR spectra of composite dressing shows characteristics peak of acrylic acid and acrylamide. The composite wound dressing material is loaded with model drug bovine serum albumin (BSA) and drug release behaviour is studied at different pH. The dressing shows drug release in different pH with maximum release of drug in acidic medium. 相似文献
9.
Silica nanofibers containing silver nanoparticles were successfully prepared using sol-gel chemistry and electro-spinning
technique. Solution of tetraethly orthosilicate in ethanol containing silver nitrate was aged to have sufficient viscosity
and electrospun to form nanofibers. Upon thermal treatment, the gelation reaction between silanols was completed in the prepared
silica nanofibers, and at the same time, silver ions in the nanofiber changed to metallic silver or silver oxides. The reduction
of silver ions could be also achieved by UV irradiation, and the generated silver nanoparticles were present preferentially
on the surface of the silica nanofibers. On testing release behavior of silver ions, it was found that most of silver remained
in the silica nanofiber. The silica nanofibers containing silver nanoparticles exhibited excellent antibacterial and deodorant
properties. 相似文献
10.
In this study, polyester and polypropylene staple fibers were selected as the raw material, and then processed through roller-carder,
cross-lapper and needle-punching machine to produce needle-punched non-woven fabrics. First, the experiment was planned using
the Taguchi method to select processing parameters that affect the quality of the needle-punched non-woven fabric to act as
the control factors for this experiment. The quality characteristics were the longitudinal and transverse tensile strength
of the non-woven fabric as well as longitudinal and transverse tear strength. The L18 (21×37) orthogonal array was selected for the experiment as it offered an improvement on the traditional method that wastes a lot
of time, effort and cost. By using the analysis of variance (ANOVA) technique at the same time, the effect of significant
factors on the production process of needle-punched non-woven fabrics could be determined. Finally, the processing parameters
were set as the input parameters of a back-propagation neural network (BPNN). The BPNN consists of an input layer, a hidden
layer and an output layer where the longitudinal/transverse tensile and tear strength of the non-woven fabric were set as
the output parameters. This was used to construct a quality prediction system for needle-punched non-woven fabrics. The experimental
results indicated that the prediction system implemented in this study provided accurate predictions. 相似文献
11.
Xianlin Xu Fang Zhang Wei Wang Nan Li Xupin Zhuang Hang Wang Lei Shi 《Fibers and Polymers》2017,18(4):633-640
A novel affinity membrane based on PET/PA6 segmented pie bicomponent spunbonded microfiber nonwoven (PET/PA6 SBSNW) was developed for bilirubin adsorption. PET/PA6 SBSNW was initially fabricated as microfiber nonwoven fabric, and was then ammoniated with ethylenediamine (ETDA). Finally, amino acids as affinity ligands were immobilized on the ammoniated PET/PA6 SBSNW. The amino acid-modified PET/PA6 SBSNW was applied to adsorb bilirubin, and the effects of pH, temperature, species of affinity ligands, and time were investigated. The results showed that amino acid-modified PET/PA6 SBSNW has decent adsorption performance, and adsorption capacity of PET/PA6 SBSNW-Lys peaked at 388.35 mg/g. 相似文献
12.
Basalt fibers were surface modified by a new method using nanostructured porous silica aerogel via sol-gel process followed by ambient pressure drying method. FTIR, FE-SEM, and nitrogen adsorption analysis were used for characterization of silica aerogel particles which proved their mesoporous structure with pore size of 7 nm, high porosity and low density. FTIR spectra indicated the formation of silica aerogel on the basalt fibers surface. SEM analysis proved the surface modification of basalt fibers and quantitative measurement showed an increase of 2-fold in the surface roughness compared to unmodified surface fibers. A decrease of 42 % in the density of the surface modified basalt fibers was observed. Also, acoustical properties measurement showed that sound absorption coefficient was increased by 25 %. The obtained results show that silica aerogel structure can affect the physical properties of surface modified basalt fibers. Two silica aerogels with different density and porosity were used in this work. 相似文献
13.
A series of some novel hybrid materials prepared via a sol-gel process have been synthesized from methyltrimethoxysilane and titanium n-butoxide with heterocyclic thiazole azo dyes. Silica/titania/thiazole azo dyes hybrid materials were synthesized via a sol-gel process with a precursor system. Alternatively, the heterocyclic thiazole azo dyes were catalytically processed by means of hydrolysis-condensation reactions with appropriate amounts of a mixture of vinyltriethoxysilane, methyltrimethoxysilane, and titanium n-butoxide at a fixed molar ratio. The structure of these hybrid silica/titania/thiazole dye materials was characterized by Fourier transform infrared (FT-IR) analysis. The surface morphology of processed PET/PA6 nonwoven fabrics was evaluated by scanning electron microscopy (SEM). SEM images showed uniform dyeing, thereby confirming the reaction of the hybrid materials with the PET/PA6 nonwoven fabrics. The water contact angle, washing fastness, color evenness, air permeability, and weatherability characteristics of the as-prepared dyed PET/PA6 nonwoven fabrics were subsequently evaluated. Results revealed improved weatherability and good water repellency. Further, it was also revealed that dyeing and finishing could be achieved in a single bath, which is advantageous to reduce processing costs. 相似文献
14.
The method of recognizing color texture brought forth in the present study is to employ unsupervised learning network to automatically
recognize the fabric type and the main texture types. Firstly, the color scanner is adopted to extract fabric image which
is afterwards saved as the digital image. Secondly,CIE-Lab color model is taken to obtain the feature value and wavelet transform is utilized to display the texture of the fabric image.
Thirdly, co-occurrence matrix is employed to figure out the feature values of the texture structure such as angular second
moment, entropy, homogeneity, contrast. Finally, self-organizing map (SOM) network is used as the classifier. The experiment
result shows that the study can automatically and accurately classify the fabric types (including shuttle-woven fabric, jersey
fabric and non-woven fabric) and main texture type of the fabric (such as plain weave, twill weave, satin weave, single jersey,
double jersey and non-woven fabric). 相似文献
15.
Dimethylaminopropyl methacrylamide (DMAPMA) was grafted onto PET/wool blend fabrics by continuous UV irradiation. Union dyeing
of the photografted fabrics was investigated using three reactive dyes of α-bromoacrylamide reactive groups. The influence of grafting yield, DMAPMA concentration, NaCl amount, pH value, and dyeing
temperature on the dyeability was evaluated. The dyeability of both PET and wool components was improved significantly by
the DMAPMA photografting and successive reactive dyeing. Although the dyeability of the PET component in the blend substantially
was improved with higher grafting, equal dyeability between PET and wool was difficult to achieve due to more facile grafting
and higher reactivity of the wool component compared with the modified PET component. However, the color fastness of the PET/wool
blend fabric was excellent for all three colors. This study may offer a way to achieve union dyeing of PET/wool blend fabrics. 相似文献
16.
This series of paper discussed the dynamic modeling of non-woven fabric roller carding and the control of web density uniformity.
The dynamic system of dry non-woven fabric roller carding was set up to analyze the dynamic model; then in the process of
derivation, theoretical exploration and studies were carried out on one carding unit in the system, consisting of cylinder,
worker roller, stripper roller. After that, we probed into the relation between rotation angle and angular velocity of carding
unit, and analyzed the time-delay of carding unit. With Pade approximation, the time-delay was taken as the simplification
of the system model. The above conditions were utilized to derive the transfer function of carding unit and it was extended
to the dry non-woven fabric roller carding system combining four of carding units, feed roller, take-in and doffer in series
to obtain the transfer function of this whole system. After confirmed by the designed controller, the system was obviously
improved in its tracking property. The steady-state error was also eliminated. Meanwhile, with the participation of the controller,
this system might produce the maximum overshoot during its transient response. Therefore, this research regulated the reference
input according to the designed dominant poles. This combination scheme effectively control the occurrence of the maximum
overshoot and make for good system objectives. 相似文献
17.
Mazeyar Parvinzadeh Gashti Siamak Moradian Abosaeed Rashidi Mohamad-Esmail Yazdanshenas 《Fibers and Polymers》2013,14(5):743-751
Poly(ethylene terephthalate) [PET] based nanocomposites containing three differently modified silica particles were prepared by melt compounding. The influence of type of nano-silica on dispersibility, thermal and dyeing properties of the resultant nanocomposite was investigated by various analytic techniques, namely, polarized optical microscopy (POM), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), reflectance spectroscopy (RS), and light fastness. Optical microscopy images illustrated that nano-silica particles tended to increase the number of spherulites in the PET matrix which were dependent on nano-silica type and content. Thermal studies of the resultant nanocomposites showed a slight decrease in the melting temperature compared to a pristine PET. Silica nanocomposites were finally dyed with a disperse dye and their reflectances were determined by the aid of reflectance spectrophotometer. Such reflectances were converted to the corresponding color coordinate values which are indicative of dyeability of such nanocomposites. 相似文献
18.
Untreated polyethylene terephthalate has limitation in some medical applications, such as wound dressing due to the hydrophobic property. Thereby, Tragacanth Gum (TG) as a natural polysaccharide utilized in polymer solution led to novel semi-bionanofibers of PET/TG blends (15:1, 15:2 and 15:3) through electrospinning method. Fourier transform infrared spectroscopy results confirmed the existence of hydrophilic groups of TG such as hydroxyl groups. Moreover, twice water uptake of PET/TG comparing with PET nanofibers indicated the hydrogel properties, also PET/TG nanofibers possessed high surface wettability through reduction of contact angle from 113 to 0°. Further, differential scanning calorimetry analysis indicated the alteration in the crystalline structure of PET/TG nanofibers that led to faster degradation in various pH values. The SEM images of PET/TG nanofibers displayed the greater average diameter with increasing TG content (283 nm) comparing with PET nanofibers (193 nm). Also introducing more TG in the nanofibers exhibited lower mechanical properties. 相似文献
19.
Yixi Wang Hao Wang Huili Peng Zhicun Wang Jianning Wu Zhiyong Liu 《Fibers and Polymers》2018,19(2):340-349
A novel eco-friendly porous adsorbent of cellulose (CE)/chitosan (CS) aerogel was prepared through sol-gel process and freeze-drying to remove Congo Red (CR). A series of aerogels were prepared by adjusting the mass ratios of CE and CS. Composite aerogels were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). SEM images showed that it was possible to change the structure of the aerogel by adjusting the amount of chitosan. The effects of dosage of chitosan, initial pH, temperature, adsorbent dosage, contact time, and initial dye concentration on adsorption capacities for CR were studied in detail. Batch adsorption studies showed that aerogel exhibited maximum removal efficiency to CR at a composite ratio of 1:3 and dosage of 2.5 g/l. CE/CS aerogel had excellent adsorption capacities for CR at a pH range of 3-11, which indicated stability of the aerogel in both acidic and alkaline conditions. CR adsorption on the composite aerogel fitted pseudo-second-order kinetics and Langmuir isotherm. The Langmuir isotherm model revealed that the maximum theoretical adsorption capacity of this material for CR was 381.7 mg/g at pH 7.0 at 303 K for 24 h. The adsorption mechanism included electrostatic and chemical interactions. The results indicated that the adsorption capacity of CE/CS aerogels was higher than the other chitosan composites adsorbents. 相似文献
20.
Youngmi Park 《Fibers and Polymers》2016,17(3):477-483
The properties of moisture transfer and the comfort of mesh-structured fabrics with various knit compositions and properties were investigated. The comfort effects of the double knitted fabrics combined with different cross-shaped fibers composed of dyeable-polypropylene (PPd) and regular polyester (PET) double-knitted fabrics were studied. A series of PET, PPd, Coolmax® (Cm) with single knitted fabrics and PPd/Cm with double knitted fabrics were evaluated to determine the physical properties and wearing performance for comfortable clothing. To compare the structural properties involving the vapor transfer of 4 types of fabrics with different fiber compositions, fiber types, weights, and thicknesses, the surface structure and pore characteristics were evaluated by scanning electron microscopy and a capillary flow porometer. The properties of moisture transfer were tested using vertical wicking and gravimetric absorbent testing system (GATS). In addition, the comfort performance measured by the thermal insulation value (Rt) and moisture permeability index (im) with a thermal manikin in a conditioned walk-in environmental test chamber was predicted. The result showed that the PPd/Cm sample has potential applications as good comfort fabric materials. 相似文献