Effects of river infrastructures on the floodplain sedimentary environment in the Rhône River

Journal of Soils and Sediments - River infrastructures such as dikes, groynes, and dams are ubiquitous on most large rivers, and although their consequences on the riverbed morphology have often...     

Reactivity of particulate element concentrations: apportionment assessment of suspended particulate matter sources in the Upper Rhône River,France

Journal of Soils and Sediments - Suspended particulate matter (SPM) transport through rivers is a major vector of nutrients and pollutants to continental shelf areas. To develop efficient sediment...     

The hydrological role of ‘sunken lanes’ with respect to sediment mobilization and delivery to watercourses with particular reference to West Sussex, southern England

Purpose

Roads in general and sunken lanes (SLs) in particular play an important hydrological role in connecting areas of runoff and sediment generation with valley floors and therefore with habitation and watercourses. These connections lead to damage and pollution. The role of SLs has been neglected as an important source of runoff and sediment and in hydrological and geomorphological discussion in the literature on connectivity.

Materials and methods

Published data on the role of roads and specifically SLs are reviewed. Fluxes of runoff and sediment have been mapped in a study area during a period of serious erosion (2006–2007). Routes to watercourses and entry points to a vulnerable river are recorded.

Results and discussion

SLs are historic features often hundreds of years old. Unmetalled SLs continue to incise whereas metalled ones generally act as routes for runoff and sediment with inputs from many sources. These include field gateways, other SLs, tracks and trails (some metalled, some unmetalled), bank gullies and mass movements on SL banks, burrows and pipes in banks, and erosion of roadside verges. The proportion of sediments from these sources is unknown and area specific. Impacts and costs include muddy flooding of villages, road clearance and ecological damage to rivers due to pollution and sedimentation.

Conclusions

The location of SLs is influenced by two factors: long-term human occupation of the landscape and soft, easily eroded geology. They are an important element in the connectivity between hillslopes and valley bottoms. They play a role in the muddy flooding of villages and increased sedimentation in rivers in areas such as Flanders, the Polish Carpathians and the study area in southern England.     

Ecotoxicological characterization of sediment cores from the western Baltic Sea (Mecklenburg Bight) using GC–MS and in vitro biotests

Background, aim, and scope

The Mecklenburg Bight (Western Baltic Sea) near Luebeck, Germany was historically used to dump industrial waste at sea and, thus, sediments in some regions are highly polluted at present. While earlier studies identified hot spots of chemical pollution, little is known about biological activities and impacts on exposed marine organisms. This study aimed to assess the pollution in the Mecklenburg Bight to determine the degree of contamination with sediment-bound polycyclic aromatic hydrocarbons (PAHs) as well as biological activities.

Materials and methods

Sediment cores with a depth of 30 cm were sampled at a dumping site and at a reference site, sliced in distinct layers, freeze-dried, and processed using the accelerated solvent extraction method. Sediment was characterized measuring total organic carbon (TOC) and soot contents. Concentrations of the 16 EPA-PAHs were determined with chemical analysis (gas chromatography–mass spectroscopy) in each sediment slice and referred to the determined TOC content. Further on, in vitro biotests were applied to determine toxic effects of contaminants in the sediment. The acute neutral red retention assay indicated no specific cytotoxic effects. Arylhydrocarbon receptor (AhR)-mediated activities were measured using the mechanism-specific 7-ethoxyresorufin-O-deethylase induction assay. Both biotests were performed with rainbow trout (Oncorhynchus mykiss) liver cells (RTL-W1). Analyzed compound concentrations and biological activities were given in toxicological equivalent concentrations (chem- and bio-TEQs) to determine shares of analyzed EPA-PAHs to the overall activity.

Results

TOC and soot contents indicated a significant alteration through the sediment core at the dumping site. EPA-PAH concentrations were referred to TOC and indicated elevated concentrations at the dumping site. Maximum PAH concentrations (14 to 16 cm depth; 5.44 µg/g TOC) were 300-fold increased at the dumping site, compared to the reference site (4 to 6 cm depth; 0.017 µg/g TOC). Cytotoxicity as determined in the neutral red retention assay was elevated in some layers at the dumping site (maximum in 4 to 6 cm depth; NR₅₀?=?14 mg/ml), but not correlated with TOC or soot contents. Ah receptor agonist activities were clearly elevated in highly PAH-loaded layers at both sites. At the dumping site, maximum activities were determined reflected by a bio-TEQ of 223,000 pg/g (19 to 22 cm), in contrast to a bio-TEQ of 41,000 pg/g (6 to 8 cm) at the reference site. Further on, shares of EPA-PAHs to the overall activity were determined and contributed >40% at the dumping site and between 4% and 17% at the reference site. Chem-TEQs were found to exceed bio-TEQs in a depth of 11 to 22 cm, indicating the presence of Ah receptor antagonistic or inhibitive compounds.

Discussion

Sediments from the dumping site were determined to be highly contaminated and caused toxic effects in depths that are known to be influenced by dumping activities. In contrast, the reference sediment indicated only near to surface layers to be minor contaminated. In comparison with highly polluted sediments from other marine sites, the contamination of the dumping site could be ranked as elevated. Chem-TEQs exceeding bio-TEQs in a depth of 11 to 22 cm seem to be caused by AhR antagonistic compounds in the dumped material. Furthermore, particle-bound PAH concentrations assessed in this study were discussed against freely dissolved concentrations in interstitial water, as determined in a different study with the same sediment core.

Conclusions

Sediments in the inner Mecklenburg Bight could be shown to be highly contaminated, at least with PAHs, causing articulate increased Ah receptor-mediated activities. Marine organisms may be exposed to these contaminants, in particular when inhabiting the sediment.

Recommendations and perspectives

Further research activities should extend the range of chemically analyzed pollutants and applied biotests and endpoints. Monitoring should close the gap between analytical methods in the laboratory and the field to determine possible impacts on organisms at site.     

Is mechanical soil aeration a strategy to alleviate soil compaction and decrease phosphorus and suspended sediment losses from irrigated and rain‐fed cattle‐grazed pastures?

Agriculture is a major source of phosphorus (P) and suspended sediment (SS) losses to aquatic ecosystems promoting eutrophication. Mechanical soil loosening equipments such as topsoil looseners or aerators have been reported to improve the physical quality and infiltration of soils susceptible to livestock damage resulting from treading. We hypothesized that soil aeration would significantly decrease the volume of surface runoff and consequent losses of P and SS compared with non‐aerated soil (control) in cattle‐grazed pasture on a poorly structured silt‐loam soil. Hydrologically isolated plots (2 m long × 1 m wide × 0.15 m deep) were installed in aerated and control plots to collect surface runoff following irrigation or rainfall and analysed for P and SS losses for 1 year. Soil physical properties [% macroporosity, bulk density, saturated hydraulic conductivity (K_sat) and unsaturated hydraulic conductivity (K_unsat at ?1kPa)] were measured in the aerated and control treatments and taken before each irrigation event (n = 12). Six months after mechanical aeration was employed, but before cattle grazing commenced, no significant differences in soil physical quality were found between aerated and control treatments, with the exception of a minor increase in K_unsat for the control plots. This lack of treatment difference continued after grazing and was largely attributed to the re‐settling of the poorly structured and dispersive soil. Flow‐weighted mean concentrations and annual loads of dissolved reactive P (DRP) on the mechanically aerated soil (2.24 kg DRP/ha) were approximately double those from the control treatment (1.20 kg DRP/ha). However, no significant differences were observed between treatments for surface runoff volumes and losses of total P and total SS, which may reflect the similar soil physical conditions exhibited between treatments throughout most of the trial. As observed elsewhere, time (days) since grazing or fertilizer application was found to influence P and/or SS losses. We conclude that aeration did not decrease P and SS losses. Any changes in soil physical properties such as macroporosity were short‐lived and therefore unlikely to influence surface runoff and subsequent P and SS losses for this soil type.     

Predicted trends of soil erosion and sediment yield from future land use and climate change scenarios in the Lancang–Mekong River by using the modified RUSLE model

Soil erosion and sediments in the Lancang-Mekong River Basin as a result of climate change and changes in land use pose a threat to the existence of the riparian people, biodiversity and ecosystems. This study seeks to assess the annual soil erosion in terms of spatial distribution and the trends of sediment yield with the climate and land changes in future scenarios in 2030 and 2040 through the modified RUSLE model. Future lands were simulated by using the MLP artificial neural network and the Markov chain analysis. The future climate was examined by using the Max Planck Institute model, which showed a corrected bias and downscaled grid size under the Representative Concentration Pathways (RCPs). The simulated land use indicated that the forest areas were converted mostly to agricultural lands and urban areas. In the future, the average rainfall under all RCP scenarios is higher than that from the historical period. The R and C factors changed constantly, thereby affecting the soil erosion rate and sediment yield. The maximum erosion was estimated at approximately 21,000 and 21,725 t/km²/y under RCP8.5 in both years. Meanwhile, the results of sediment yield in 2030 and 2040 under RCP scenarios were much higher when compared to historical sediment data around 66.3% and 71.2%, respectively. Thailand's plateau, some parts of Cambodia and Laos PDR and the Mekong Delta are vulnerable to increase soil erosion and sediment yield. Measures to address these issues need to be planned to prepare and mitigate the possible effects, especially the loss of storage capacity in dams.     

Are the Conflicts between Israel and Her Neighbors Over the Waters of the Jordan River Basin an Obstacle to Peace? Israel-Syria As A Case Study

Are the conflicts over water resources between Syria, Lebanon and Israel who share the transboundary waters of the Jordan River Basin a major obstacle to the peace process? The Syrians and Lebanese have in the past claimed as their own all of the sources of the Jordan River which arise in their territory. International water law provides a strong legal basis to assure the water rights and continued use of water by a downstream riparian, such as Syria's use of the Euphrates which arises in Turkey and similarly, Israel's use of the Jordan River, based on prior use in an international river basin. This paper will evaluate the water security implications for Israel of a possible peace agreement with Syria and Lebanon which would involve Israel forgoing the continued use of those amounts of water from the Jordan River that were approved by the Israel Government under the so-called Johnston Plan of 1956 — 35 million m³/yr. for Lebanon from the Hasbani Springs and 42 mm³/yr. from the Banias Springs and Jordan River for Syria. The maximum replacement cost for that amount of water by desalination of seawater may be about $0.70/m³ or, some $56,000,000 per year. This is not a great amount of money as part of the price for peace. The paper also shows that Israel does not have to hold on to the entire area of the Golan Heights to assure its water security and that a 1–3 km water security zone along the Syrian side of the international border under joint and international inspection can be an effective water security measure to assure inspection, monitoring and control of all the sources of the Jordan River and Lake Kinneret vital to Israel's water security. The scare stories published by some groups in Israel, that Syria could, after a peace agreement is signed, covertly divert essentially all of Israel's water resources derived from the sources of the Jordan River or 30% of the country's water supply are highly unrealistic. Such major works could not go undetected and Syria and the world recognize that such an act would be viewed as a causus belli and as an act of war by Israel. In an era of peace, development of the shared water resources of the Jordan and continuous water systems in a program of regional cooperation can bring benefits to all of the partners on the Jordan River Basin.     

Does altered rainfall regime change pesticide effects in soil? A terrestrial model ecosystem study from Mediterranean Portugal on the effects of pyrimethanil to soil microbial communities under extremes in rainfall

In this century, agroecosystems are subjected to multiple global change stressors acting in concert such as alterations in rainfall regimes and pesticide use. Alterations in rainfall regimes, characterised by more extreme intra-annual rainfall regimes, have been forecasted for the Mediterranean region. At the same time, the use of pesticides continues to rise. Here, we report the responses of soil microbial community to a model pesticide, i.e., fungicide pyrimethanil (PYR) under altered rainfall regimes (i.e., drought and heavy rainfall) two and eight weeks after PYR application. We measured the functional responses as enzyme activities, potential nitrification and BIOLOG carbon substrate utilisation. We also characterised the soil bacterial communities using polymerase chain reaction–denaturing gradient gel electrophoresis (PCR–DGGE) method. After two weeks, enzyme activities were mainly responsive to PYR and kinetic parameters, calculated from BIOLOG carbon substrate utilisation, indicated interaction effects from PYR and rain treatments. Bacterial band richness increased with PYR treatment under normal rain and drought regimes, but bacterial band richness was higher at 1X than 5X PYR under heavy rainfall. Bacterial community structure was also different with the PYR and rainfall treatments. By week eight, PYR treated soils remained functionally different from untreated soils. Bacterial band richness was consistent across PYR treatment regardless of rain regime. However, the bacterial community structure remained significantly different among the PYR treatments under different rain regimes. We conclude that rainfall extremes can alter the effect of PYR on the soil microbial community structure without altering PYR effects on soil functions (measured as enzyme activities, potential nitrification and BIOLOG carbon substrate utilisation).     

How much do soil and water contribute to the composition of meat? A case study: meat from three areas of Argentina

The main goal of this study was to propose a reliable method to verify the geographical origin of meat, establishing the influence of soil and water on its isotopic and elemental composition. Thus, beef meat, soil, and water samples were collected from three major cattle-producing regions of Argentina (Buenos Aires, Córdoba, and Entre Ríos). Multielemental composition was determined on these three matrices by inductively coupled plasma mass spectrometry (ICP-MS), δ(13)C and δ(15)N by isotope-ratio mass spectrometry (IRMS), and the (87)Sr/(86)Sr ratio by thermal ionization mass spectrometry (TIMS). Soil and drinking water samples could be characterized and clearly differentiated by combining the isotopic ratios and elements, demonstrating differences in geology and climatic conditions of three regions. Similarly, meat originating at each sampling area was characterized and differentiated using only five key variables (Rb, Ca/Sr, δ(13)C, δ(15)N, and (87)Sr/(86)Sr). Generalized procrustes analysis (GPA), using the three studied matrices (soil, water, and meat) shows consensus between them and clear differences between studied areas. Furthermore, canonical correlation analysis (CCA) demonstrates significant correlation between the chemical-isotopic profile of meat with those corresponding to both soil and water (r(2) = 0.93, p < 0.001; and r(2) = 0.83, p < 0.001, respectively). So far, there are clear coincidences between the meat fingerprint and those from soil/water where cattle grew, presenting a good method to establish beef provenance. To the authors' knowledge this is the first report linking the influence of soil and water all together on the composition of beef, presenting the basis for the authentication of Argentinean beef, which could be extended to meat from different provenances.     

Effects of rice cropping intensity on soil nitrogen mineralization rate and potential in buried ancient paddy soils from the Neolithic Age in China’s Yangtze River Delta

Purpose

Rice cropping density, rice cropping duration, and fertilization can affect soil nitrogen (N) supply, but rice cropping intensity (RCI) on soil N fertility is not fully understood, particularly for ancient paddy soils without N fertilization.

Materials and methods

Eight buried ancient paddy soils from the Neolithic Age in China’s Yangtze River Delta, and its parent material, and seven present paddy soils in the same fields were used to investigate the effects of RCI on soil nitrogen mineralization rate and potential. In the present study, concentration of phytolith of rice in soils was used to indicate the RCI.

Results and discussion

Soil N content was obviously greater in the buried Neolithic paddy soils than in the parent material. Total soil N increased with increasing phytolith from 5,200 to 60,000 pellets g^?1, but tended to decrease with increasing phytolith from 60,000 to 105,000 pellets g^?1. A possible reason for RCI-induced increase of soil N was due to biological N₂ fixation in the rice field because there was a significant negative relationship between total N and δ¹⁵N in the buried Neolithic soils. The mineralization rate constant (k) ranged from 0.0126 to 0.0485 d^?1 with an average of 0.0276 d^?1, which was similar to that of the parent material, but lower than those in the present paddy soils. The k value increased with increasing RCI in the Neolithic paddy soils. There was a significant positive relation between RCI and the percentage of cumulative mineralizable N in the 14 d of that within 103 d incubation.

Conclusions

Soil N content tended to increase with the increasing intensity of rice cropping and then decreased under the high intensity of rice cropping; the excessive high intensification of rice cropping could facilitate fast N mineralization (labile N) fraction in the cumulated mineralized N. The unfertilized paddy field could only meet soil N supply under the low intensification of cropping rice in the Neolithic Age. The N fertilization is necessary in order to improve soil fertility for sustaining the present high-yield rice production.     

Phosphorous levels on the ability of an iron‐inefficient and an iron‐efficient corn inbred to take up iron from nutrient solution

Abstract

The Fe‐inefficient corn (Zea mays L.) inbred Ys₁/YS₁ was compared with the Fe‐efflcient WF9 inbred for ability to take up Fe from solution culture at different P levels. A high level of P depressed Fe uptake more in the Ys₁/Ys₁ than in the WF9 inbred. The Ys₁/Ys₁ roots were high in P.     

The Women's Health Initiative. What is on trial: nutrition and chronic disease? Or misinterpreted science, media havoc and the sound of silence from peers?

The first results of the Women's Health Initiative dietary intervention trial were published in the USA in February. This is a colossal intervention designed to see if diets lower in fat and higher in fruits, vegetables and grains than is usual in high-income countries reduce the incidence of breast cancer, colorectal cancer, heart disease and other chronic diseases, in women aged 50-79 years. As interpreted by US government media releases, the results were unimpressive. As interpreted by a global media blitz, the results indicate that food and nutrition has little or nothing to do with health and disease. But the trial was in key respects not reaching its aims, was methodologically controversial, and in any case has not produced the reported null results. What should the public health nutrition profession do about such messes?     

Application of “Four-Plane Model” to the Adsorption of K+, NO3 -, and SO4 2- from a Mixed Solution of KNO3 and K2SO4 on Andisols

To evaluate the interaction between anionic species when they were adsorbed on variable charge soils, we measured the adsorption of NO₃ ^- and SO₄ ^2- on. an Andisol equilibrated with a mixture of KNO₃ and K₂SO₄ solutions. The amount of NO₃ ^- adsorption declined with the increase in the concentration of SO₄ ^2-. On the other hand, the amount of SO₄ ^2- adsorption increased with the increase in the concentration of NO₃ ^-. These phenomena can not be explained by the simple “exchange theory” or the “Three-plane model” unless surface complexation is associated with the changes in the electrical potential of the surface. Therefore, in order to explain the phenomena by using the “Four-plane model” with surface complexation, a new equation was derived for the Diffuse Double Layer (DDL) charge from the “main equation of DDL theory” (equation of electrical potential in DDL) instead of the “Gouy-Chapman equation,” which can be used only for single symmetric electrolytes but nor for a mixture. By introducing the new equation to the computer program for analyzing the Four-plane model, the interaction between anionic species adsorbed on Andisols could be explained well. It was considered that SO₄ ^2- acted as a regulator for the ionic concentration, osmotic pressure and pH of the soil solution, and consequently, these factors affected the vertical distribution and mobility of anionic species and also the mobility of counter-ions in Andisols.