共查询到19条相似文献,搜索用时 140 毫秒
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腐殖物质对有机污染物的吸附行为及环境学意义 总被引:2,自引:1,他引:2
综述了近年来腐殖物质的研究进展,具体包含以下几个方面的内容:腐殖物质的分离、纯化、元素组成和结构特征及其环境意义。重点讨论了腐殖物质的环境学意义,阐述了腐殖物质主要是胡敏素在吸附疏水性有机污染物的过程中所起到的重要作用,其中包括可溶性腐殖物质的增溶作用和不溶性腐殖物质———胡敏素的吸附固定作用;且对吸附/解吸的机理及一些模型的建立进行了探讨。最后针对研究中面临的问题,提出了今后的重点研究方向。 相似文献
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土壤中的腐殖物质大多数是同无机成分相结合以复合体形式存在,大部分不溶于水。为了研究腐殖物质的本质和特征,需要将腐殖物质同无机成分分离开来。目前最常用的提取剂是NaOH和Na4P2O7或其混合液。含强碱的提取剂虽具有提取效率高等优点,但也存在提取过程中腐殖物质被氧化变性,以及一 相似文献
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土壤腐殖物质的形状,与土壤物理性质和物理化学性质有密切关系.已经知道,线型分子对土壤颗粒的团聚化有着特别良好的作用[1].腐殖物质是土壤中主要的有机物质. 相似文献
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大量排放的畜禽粪便若利用不当则会对环境构成威胁,经微生物发酵、制成高效有机肥料是粪肥与秸秆综合利用的一种重要方式。试验以牛粪添加不同比例的小麦秸秆为原料,在接种和非接种微生物的条件下进行堆腐,研究了腐解过程有机组分及腐殖物质的动态变化。结果表明,随着腐解进行,乙醇溶性组分含量逐渐降低;水溶性组分含量先升高再降低;半纤维素和纤维素含量随腐解进行呈现一定波动,但总体呈降低趋势;木质素含量呈增加趋势;全碳含量降低,腐殖物质碳占全碳的比例逐渐增加,H/F比值逐渐升高。秸秆的加入比例越高越有利于木质素的积累,牛粪所占比例越大则越有利于腐殖物质的形成。接种微生物可促进有机物料中各有机组分的分解,并有利于腐殖物质的形成。 相似文献
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纯培养条件下蓝细菌形成腐殖物质的可能性研究 总被引:1,自引:1,他引:1
采用红外光谱和元素分析,初步研究了纯培养条件下水华鱼腥藻(一种常见蓝细菌)不同生长期的菌体和胞外代谢物以及作为唯一基质形成的菌体混合物的结构特征。结果表明:蓝细菌样品的红外光谱图中均没有1 720 cm-1峰。2 926/1 650比值显示,水华鱼腥藻对数生长期与衰亡后期的菌体芳香物质含量高,复杂度与土壤富里酸接近,但低于土壤胡敏酸;微生物处理能使菌体混合物具有更多芳香族物质,但1 530 cm-1峰消失,表明部分C=C及氨基酸类物质被分解。相对于土壤腐殖物质,水华鱼腥藻菌体的H/C比值及(O+S)/C比值均较大,即缩合度较低而氧化度较高;经微生物处理后,其缩合度进一步降低,氧化度升高。总之,本实验条件下蓝细菌自发形成腐殖物质的可能性较低,且其作为唯一基质在其他微生物作用下形成的菌体混合物与土壤腐殖物质在结构上存在差距,但从蓝细菌的组成与结构上看,其可为腐殖物质的形成提供物质条件。该结果为土壤腐殖物质的形成研究与起源探索提供了一定的科学依据。 相似文献
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森林生态系统中硒与腐殖物质之间缔合作用的实验证据 总被引:1,自引:0,他引:1
在针叶林土壤和水系统中,硒通常与腐殖物质缔合存在,为进一步澄清有关机理,作者将标记亚硒酸盐和非标记亚硒酸盐加入两个林地表土和一个棕色湖水样品中,并应用连续提取方法和色谱分析技术对硒和腐殖物质间的缔合作用进行了测定,结果表明,通过微生物的还原作用,加入的亚硒酸盐大部分被林地表土所固定,硒优先进入了低分子量的腐殖物质组分中,相反,在棕色湖水样品的试验中,硒的还原反应速率慢,因此,在所试验的条件下当竞争 相似文献
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《植物养料与土壤学杂志》2017,180(1):5-13
The biological activity of humic substances (HS) has been elucidated in the last 40 years. Growth enhancement from HS has been demonstrated in several plants in the laboratory and the field. Morphogenesis effects have also been investigated and include induction of lateral root formation and root hair initiation in intact plants and stimulation of root and shoot development in treated cell calluses. HS enhance nutrient use efficiency, aiding assimilation of both macro and microelements and promoting plant growth by the induction of carbon, nitrogen, and secondary metabolism. The review aims are to: (1) shed light on the mechanism by which plants “talk” with soil through humic substances, (2) elucidate the plant responses to the stimulatory effects of HS, the regulatory circuits that allow plants to cope with humus, and the feedback between plant community structures, and (3) show (in light of recent debate about the alkaline extraction of soil humic substances) the plant capability to acquire biologically active substances from soil. It will be shown that plants modify soils, creating and maintaining favorable habitats for growth and survival. Therefore, organic substances exuded by roots are not a wasteful loss of carbon and energy. They represent an evolved strategy by which plants “talk” to the soil. The mobilization of bioactive organic/humic substances from bulk soil or bulk humus is critical to plant and soil health. 相似文献
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L. P. Canellas L. B. Dobbss A. L. Oliveira J. G. Chagas N. O. Aguiar V. M. Rumjanek E. H. Novotny F. L. Olivares R. Spaccini A. Piccolo 《European Journal of Soil Science》2012,63(3):315-324
A series of humic matter samples isolated from a soil sequence, different oxisols, size‐fractionated from a vermicompost humic acid and subjected to chemical modifications, were characterized by CPMAS 13C‐NMR spectroscopy. The relative signal areas in chemical shift regions of NMR spectra of the four sets of samples were analysed by principal component analysis (PCA). Hierarchical cluster analysis (HCA) was applied to build a classification model, which allowed the recognition of humic matter according to its origin. The relationship between carbon species and biological activity of humic acids, as promoters of lateral root emergence, was obtained by applying PLS multivariate analysis. This showed that lateral root emergence was mostly related to NMR parameters such as the hydrophobicity index (HB/HI) and the 40–110 and 160–200 ppm chemical shift regions (hydrophilic carbon HI), while the content of hydrophobic (HB) carbon in humic samples was negatively correlated with induction of lateral root hair. Our results represent a step further in the structure‐bioactivity relationship of natural humic substances and confirm their role as plant root growth promoters. 相似文献
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Roberto Pinton Stefano Cesco Simonetta Santi Zeno Varanini 《Journal of plant nutrition》2013,36(10):2111-2120
The effect of a low molecular weight (<5kDa, LMW) and a high molecular weight (>5kDa, HMW) humic fractions on surface redox activities of oat roots was studied. Oxidation of the electron donor NADH and reduction of the artificial electron acceptor ferricyanide [K3Fe(CN)6] exogenously supplied to the roots both alone or in combination, was measured in the presence or absence of soil humic substances. HMW humic fraction inhibited NADH oxidation either in the presence or absence of ferricyanide, while LMW humic fraction inhibited NADH: ferricyanide oxidoreductase activity due to the contemporary addition of the two redox compounds to the solution bathing the roots. NADH: ferricyanide oxido‐reduction was partially due to the release of substances from the roots. However, the presence of soil humic fractions (LMW or HMW) did not significantly modify this behaviour. Rather, the inhibitory effect of soil humic substances was even more evident when the oxidoreduction solely due to the root activity was considered. The results confirm the presence of multiple types of oxidoreductase activities at the surface of oat roots and show that the two humic fractions HMW and LMW may differently affect these activities. Partial inhibition of NADH oxidase activity is interpreted as a possible way of interference of humic substances with metabolic processes involved in cell wall formation. The effects on surface redox activities are discussed in terms of the role of soil humic substances in promotion of plant growth. 相似文献