Andosol to Luvisol evolution in Central Mexico: timing, mechanisms and environmental setting

Surface and buried Andosols and buried Luvisols of the Nevado de Toluca Late Quaternary tephra-paleosol sequence (Central Mexico) were studied to show whether these soils present an evolutionary sequence and to determine the pedogenic mechanisms and environmental factors involved in the evolutionary process. Micromorphological observations and mineralogical composition of fine sand and clay fractions were used to detect type and succession of soil-forming process. Some of the buried Andosols, defined as “intergrade” Andosols, have a predominantly blocky structure, humus-depleted areas, redoximorphic features and thin clay coatings in Ah horizons. Clay fractions of buried Andosols contain halloysite besides amorphous components, whereas in modern Andosols, allophane is dominant. Luvisols have micro-areas with granular structure and abundant phytoliths in the groundmass of Bt horizons assumed to be the relict Andosol features. Luvisol clay fractions are dominated by halloysite and kaolinite. Primary minerals show micromorphological weathering features in all studied soils being stronger in Luvisols; however, even in Luvisols, sand fractions consist mostly of unstable volcanic silicates. We hypothesise that the studied profiles form an evolutionary sequence: Andosols–“intergrade” Andosols–Luvisols; the soil transformation is supposed to be linked to progressive crystallisation of 1:1 clay minerals. Comparing the Nevado de Toluca paleosol properties with the existing data on volcanic soil climo- and chronesequences and assessing the regional paleopedological and lacustrine records of Quaternary paleoclimates, we concluded that wet/dry climatic oscillations took place during the formation of the studied paleosols. Rapid crystallisation of 1:1 minerals occurred during dry phases, which speeded up the Andosol to Luvisol transformation and made it independent from the primary mineral weathering status. The Andosol to Luvisol transformation accelerated by climatic fluctuations is thought to be a common soil evolutionary pathway in the subtropical and tropical regions of recent volcanism, which suffered contrasting precipitation oscillations in the Quaternary.     

Late Holocene paleopedological records contained in tephra from El Chichón volcano,Chiapas, Mexico

High rates of pedogenesis on unconsolidated volcanic materials imply the accelerated generation of the soil memory. The purpose of this research was to extract the high resolution (centennial scale) paleopedological records from the Late Holocene paleosols of the El Chichón volcano formed during the last 2000 years. We studied buried monogenetic Andosols on the dated tephras and a pedocomplex formed from a set of thin ash layers deposited on older Acrisol derived from shales. Particle size distribution, DCB-extractable Fe, oxalate-extractable Fe, Al and Si, sand and clay mineralogy, organic carbon content and stable C isotope composition in humus were evaluated and interpreted as the elements of the soil memory. However, some differences were found in properties of two buried soils, especially in the kind of A horizons. We attribute such differences of individual Andosols to be caused by ancient human impact because it has been demonstrated that humid conditions persisted during the last 1300 years. Thus the drought that was supposed to provoke the collapse of the Maya civilization at the end of I millennium A.D., should have been a short-term event, below the resolution of this paleopedological record. The Andic Acrisol pedocomplex demonstrated the domination of the humid tropical climate over longer time intervals (probably major part of the Holocene) with possible minor dry episodes.     

Late Holocene paleopedological records contained in tephra from El Chichón volcano, Chiapas, Mexico

High rates of pedogenesis on unconsolidated volcanic materials imply the accelerated generation of the soil memory. The purpose of this research was to extract the high resolution (centennial scale) paleopedological records from the Late Holocene paleosols of the El Chichón volcano formed during the last 2000 years. We studied buried monogenetic Andosols on the dated tephras and a pedocomplex formed from a set of thin ash layers deposited on older Acrisol derived from shales. Particle size distribution, DCB-extractable Fe, oxalate-extractable Fe, Al and Si, sand and clay mineralogy, organic carbon content and stable C isotope composition in humus were evaluated and interpreted as the elements of the soil memory. However, some differences were found in properties of two buried soils, especially in the kind of A horizons. We attribute such differences of individual Andosols to be caused by ancient human impact because it has been demonstrated that humid conditions persisted during the last 1300 years. Thus the drought that was supposed to provoke the collapse of the Maya civilization at the end of I millennium A.D., should have been a short-term event, below the resolution of this paleopedological record. The Andic Acrisol pedocomplex demonstrated the domination of the humid tropical climate over longer time intervals (probably major part of the Holocene) with possible minor dry episodes.     

Composition of humus in chronosequences of buried soils in the tundra zone

The humus characteristics in buried Holocene and Late Pleistocene paleosols of the tundra zone have been studied. It is shown that the paleosol sequences encompassing the time span from 55 to 2.5 ka BP contain paleosols with analogous types of humus, attesting to the cyclic repeatability of the corresponding stages of soil formation. A tendency for an increase in the degree of humification in the course of soil development has been revealed. Within the ultracontinental areas of East Siberia, the accumulation of salts accompanied soil formation in the Late Pleistocene and Holocene.     

Humus in paleosols of archaeological monuments in the dry steppes of the Volga-Don interfluve

Traditional chemical methods and ¹³C-NMR spectroscopy were used to study the humus in chestnut paleosols buried under kurgans of different ages (the 16th–15th centuries BC; the 1st, 2nd–3rd, and 13th–14th centuries AD) and under the Anna Ioanovna Rampart (1718–1720) and in their recent analogues on virgin plots. It was found that the decrease in the humus content of the paleosols as a result of the diagenetic processes is exponentially related to the age of the soil burial. The loss of humus from the upper 30 cm of the paleosol buried 3500 yrs ago amounted to 76 ± 14%, and this system did not reach a stationary state. The constants of the humus mineralization in the paleosols were determined. A tendency for an increase in the degree of the organic matter humification in the chestnut soils during the past 3500 yrs was found. With an increase in the age of the burial, the portion of aromatic structures in the structure of the humic acids increased and the portion of aliphatic fragments decreased. The cyclic changes in the composition of the humus related to the secular variations in the climatic humidity were identified.     

Some applications of paleopedology in Japan

Paleosols in Japan consist of buried soils and relict soils. The former occur primarily in tephra deposit, whereas the latter occupy old land surfaces in various parts of the country. The buried soils affect construction of highways and urban development. The relict soils pose problems in forestry.The paleosols formed in tephra and buried by subsequent volcanic eruptions are chiefly Andosols with their low bulk densities, low solid ratios, high specific surfaces and high water losses. These characteristics are responsible for poor engineering performance of the paleosols and tephras. These have been especially troublesome in the Kanto plain near tokyo and around the Ashitaka Volcano. Some buried soils in tephra, as for example those in the San'in district, are exceptions to the general rule and have desirable properties for construction. Those tephras have clay fractions low in allophane and high in layer-silicate minerals.The buried soils have provided approximate ages of human artifacts through radiocarbon dating of humic horizons. Conversely, identification of artifacts found in buried soils has helped to bracket their ages.Paleosols that are relicts are chiefly members of a Red-Yellow group, many of which seem to be Udults (Ultisols). The soils apparently began forming in warmer past periods but still persist on the land surface. Such soils are strongly acid and very low in plant nutrients, with resulting low productivity when used for forestry or farming. Moreover, such soils are readily subject to erosion because of their landscape positions and poor plant cover.     

Distribution of Zinc,Manganese, Copper,Cobalt, and Nickel in Andosols Profiles

The distribution of zinc, manganese, copper, cobalt, and nickel in Andosols was investigated. Sixty nine soil samples were collected from different horizons of an Andosols profile in Miyakonojo Basin in south Kyushu, Japan, The total contents of heavy metals were determined by digestion and four extraction solutions, 1 M NH₄Ac (ammonium acetate) pH 4.5, 0.1 M HCl, 0.01 M EDTA (ethylenediaminetetraacetic acid) pH 6.5, and 0.005 M DTPA (diethylenetri-aminepentaacetic acid) pH 7.3 were used to determine the contents of available Zn, Mn, Cu, Co, and Ni in Andosols in relation to the organic carbon content. The results of the extraction analysis showed that by the use of 0.1 M H Cl high value of extracted heavy metals in the upper layers of the humus horizons were obtained while EDTA extraction yielded a large amount of the above mentioned metals in the high humus horizons. The extractable heavy metals contents were high and these metals closely related to the organic carbon content mostly in the humus horizons in the profile. Where, biocycling process may play an important role in the concentration of heavy metals. Based on the study, it was found that the total content of Zn increased towards the C horizons or pumice layers in the soil profile. Such a trend was also found in the case of the Mn content. While the Cu content in the humus horizons was much higher in the upper part of each humus horizon. According to this study the distribution of heavy metals, Cu (organic matter complexes) in the Andosols profile was more stable than that of Zn (organic matter complexes) in soils. It was shown that Zn in the surface humus horizon was enriched but that some amount was leached under buried conditions. The same phenomenon was also observed in the distribution of Mn in the profile. The movement of Co and Ni in the soil profile was limited, as evidenced by the sharp reduction in the concentrations of these two metals in buried soils.

Hence, it is concluded that the distribution of Zn, Mn, Cu, Co, and Ni was considerably higher in the humus horizons of the Andosols profiles.     

Mycological complexes in Holocene and Late Pleistocene paleohorizons and in fragments of paleosols

Fragments of buried Late Pleistocene (30000-year-old) and Early Holocene (10000-year-old) paleosols contained viable complexes of microscopic fungi. The mycobiota of these paleosols represents a pool of fungal spores that is lower in number and species diversity as compared to that in the recent humus horizons and higher than that in the inclosing layers. The central part of the paleosol profiles is greatly enriched in microscopic fungi. In the intact humus horizons of the Late Holocene (1000–1200 years) paleosols, actively functioning fungal complexes are present. These horizons are characterized by their higher level of CO₂ emission. The buried horizons, as compared to the recent mineral ones, contain a greater fungal biomass (by several times) and have a higher species diversity of microscopic fungi (including fungi that are not isolated from the recent horizons). Nonsporulating forms are also present there as sterile mycelium. The seasonal dynamics of the species composition and biomass of the fungal complexes were more prominent and differed from those inherent to the surface soil horizons. In the buried humus horizons, the dynamics of the fungal biomass were mainly due to the changes in the content of spores. The data on the composition of the fungal complexes in the buried soils confirm (due to the presence of stenotopic species) the results of paleobotanic analyses of the past phytocenoses or do not contradict them.     

Nonhydrolyzable Part of Soil Organic Matter in Buried and Modern Soils

Eurasian Soil Science - Results of the study of humus composition in about 200 modern soils of different genesis and more than 100 buried Pleistocene and Holocene paleosols have been collected and...     

The development of chernozems on the Dniester-Prut interfluve in the Holocene

The development of forest-steppe and steppe chernozems on the Dniester-Prut interfluve in the Holocene was studied on the basis of data on the paleosols buried under archaeological monuments of different ages. The parameters of the mathematic models of the development of the soil humus horizons in different subtypes of chernozems were calculated. They were used to determine the rate of this process and the age of the soils formed on the surface of Trajan’s lower rampart. The climate-controlled changes in the character of the soil’s development in the Late Holocene were differently pronounced in the different subtypes of chernozems. The suggested differentiation of the trends in the development of the humus horizon in the studied chernozems corresponds to the differences in the soil-forming potential of particular areas (as judged from the energy consumption for pedogenesis).     

Revealing of directed temporal changes in soils of short-term chronosequences upon the high spatial variability in the background soil properties

The properties of paleosols buried under the Filippovka group of kurgans in Orenburg oblast dating back to the second half of the fifth and to the fourth centuries BC were analyzed with the use of multivariate statistical methods. This made it possible to establish the relative chronology of construction of the kurgans, which was confirmed by the results of radiocarbon dating of the soil humus.     

Paleosols from the groups of burial mounds provide paleoclimatic records of centennial to intercentennial time scale: A case study from the Early Alan cemeteries in the Northern Caucasus (Russia)

Buried soil chronosequences under a series of Early Alan kurgans (burial mounds) in the Vladikavkazkaya depression of the Northern Caucasus, Russia, were studied to derive a high-resolution paleoclimatic record from the variations of the selected paleosol properties. Haplic Chernozems occur under kurgans and on the actual land surface. Three kurgan cemeteries, Brut 1, Brut 2 and Beslan, dated from the end of the second to the beginning of the seventh centuries AD have been studied. The cemeteries are situated close to each other under similar lithological and geomorphological conditions but differed in the paleosols' preservation. The Brut 2 site has been recently altered due to annual ploughing and intensive irrigation for more than 30 years. The background soils and paleosols of the Brut 2 site have been compared with synchronous soils of non-irrigated Brut 1 and Beslan sites to detect pedogenic properties that are less changed by irrigation and thus comprise the “soil memory”. Stronger black color of humus horizon, increase of humus content and decrease of humus δ¹³C values; clear signs of biological activity, absence of morphological and analytical signs of solonetz properties; diffused carbonate white soft spots in the Bca horizon and decreasing carbonate content are thought to be related to the comparatively humid climatic conditions in the region. On the contrary, relatively low humus content, tongue-like lower boundary of humus horizon, increase of humus δ¹³C values, morphological signs of solonetz properties together with high content of exchangeable Na, relatively large and clearly shaped carbonate white soft spots in the paleosols of the Brut 2 site, as well as increase of density, thickness of the carbonate pseudomicellium and high carbonate content in the upper part of profiles in the paleosols of the non-irrigated Brut 1 site are assumed to be xeromorphic features, indicating comparatively drier climatic conditions. The paleosols of the earliest chronointerval of burial (the end of the second to the beginning of the third centuries AD) demonstrate clear xeromorphic properties which indicate a relatively dry climate with a mean annual precipitation 50–100 mm less than today. The estimated duration of the period with such climatic conditions is thought to be not less than 100 years. In addition, those paleosols have some weak signs of humid conditions indicating that between the end of the first and the middle of the second centuries AD the climate was getting more moist, mean annual precipitation became equal or slightly higher than today. The paleosols buried in the first half of the fifth century AD again demonstrate the gradual enhancement of xeromorphic properties reflecting the next stage of droughts. Thus, the period with favourable humid climate when the Early Alan culture flourished in the Northern Caucasus was relatively short (about 400 years). Studying the detailed chronosequence in the non-irrigated Brut 1 site the records of intercentennial time scale soil properties variability produced by comparatively “fast” pedogenic processes typical for the steppe zone i.e., humus formation and accumulation, bioturbation, carbonate accumulation and transformation and solonetzization, have been provided.     

Paleosols of kurgans of the Early Iron Age in the Transural steppe zone

Paleosol studies of archaeological monuments of different ages have been conducted on the Transural Plateau. The morphological and physicochemical properties of paleosols under burial mounds (kurgans) of the Early Iron Age (the fifth and fourth centuries BC) were compared with the properties of background surface soils. A paleosol of the Savromat epoch (2500 BP) is characterized by high contents of gypsum and soluble salts. The presence of humus tongues in its profile attests to the aridity and continentality of the climatic conditions during that epoch. Paleosols buried under kurgans of the Late Sarmatian epoch and the Hun epoch (about 1600 BP) are characterized by a higher content of humus and greater depth of the carbonate horizon, which attests to the humidization of climatic conditions. The evolution of soils as related to climate dynamics in the first millennium BC and the first millennium AD is characterized.     

Buried late holocene paleosols of the nienshants cultural-historical monument in St. Petersburg

Buried Late Holocene paleosols of the Nienshants historical monument at the junction of the Neva and Okhta rivers (St. Petersburg) have been studied. These soils developed from estuary deposits of the Littorina basin with abundant artifacts of the Neolithic and Early Iron ages (7–2 ka BP). The soil cover of the area consists of the mature dark-humus profile-gleyed soils on elevated elements of the mesotopography (3.0–3.5 a.s.l.) and dark-humus gley soils in the local depressions (2.0–2.6 m a.s.l.). The soils are characterized by the low to moderate content of humus of the fulvate-humate type. The beginning of humus formation in the dark-humus gley soil on the slope facing the Neva River is estimated at about 2600 yrs ago; for the darkhumus profile-gleyed soils of the studied paleocatena, at about 2000 and 1780 yrs ago; and for the darkhumus gley soil, at about 1440 years ago. Judging from the spore-pollen spectra, the development of these soils took place in the Subatlantic period under birch and pine-birch forests with the admixture of spruce and alder trees. The gleyed horizons of the buried soil at the depth of 1.6–1.2 m on the Neva-facing slope date back to the Late Subboreal period (2500–2600 yrs ago), when pine-birch-spruce forests were widespread in the area. The new data contribute to our knowledge of the environmental conditions during the Neolithic and Iron ages.     

Land-use/cover change effects and carbon controls on volcanic soil profiles in highland temperate forests

The stabilization of SOM by Al–humus complexes and non-crystalline minerals is a key issue to explain the soil-C variability and the biogeochemical processes that determine the fate of soil C following land-use/cover change (LUCC) in volcanic landscapes. In an altitudinal gradient of volcanic soils (2550–3500 masl), we quantified the total soil C (C_T) concentrations and stocks in soil pits sampled by genetic horizons. We performed analyses at landscape and local scales in order to identify and integrate the underlying environmental controls on C_T and the effects of LUCC. We selected four sites, two on the upper piedmont, one on the lower mountain slope and one on the middle mountain slope at Cofre de Perote volcano (eastern central Mexico) where temperate forests are the natural vegetation. At each site we selected three to five units of use/cover as a chronosequence of the LUCC pathways. In each soil horizon chemical characteristics (i.e. N, C/N ratio, pH, exchangeable bases) were determined and mineralogical properties were estimated from selective Al, Fe and Si oxalate and pyrophosphate extractions (i.e. the Alp/Alo ratio, the active Al related to non-crystalline minerals as Al_o ? Al_p, the allophane concentration, and the non-crystalline Al and Fe minerals as Al_o + 1/2Fe_o). At landscape scale, the Al–humus complexes were strongly related to the C_T concentration in topsoil (A horizons) but this relationship decreased with depth. In turn, the non-crystalline minerals and the C/N ratio explained the variability of the C_T concentrations in C horizons. At local scale, C_T concentrations and stocks were depleted after conversion of forest to agriculture in Vitric Andosols at the upper piedmont but this was not observed in Silandic Andosols. However, in Vitric Andosols the reduction of the C_T stocks is partially recovered throughout the regeneration/reforestation processes. The results suggest that the lower vulnerability of Silandic Andosols than Vitric Andosols to changes in the C_T after LUCC is due to the higher levels of SOM stabilized by Al–humus complexes and non-crystalline minerals in the Silandic soils. Furthermore, the importance of the allophane to explain the C_T stocks in the Silandic Andosols of the middle slopes suggests that the C_T stabilized by this mineral fraction in the subsoil adds an important fraction of the C_T to the estimates of the stocks.     

白垩纪钙质古土壤的发生学特征及古环境意义

古土壤形成于过去环境,是揭示环境变化历史的重要材料。新近纪(23.03 M a)以前形成的古土壤,年代久远、埋藏深、受成岩作用改造强烈,其发生学特征研究是古环境重建的基础。本文通过对白垩纪时期不同地点的钙质古土壤的发生学研究,拟恢复研究区域古环境。研究表明,古土壤剖面中的A层和B层形态分别产生变化,但层次差异依然明显,且表层土壤有机质含量一般高于表下层,钙积层(Bk)普遍发生并富含碳酸盐结核。可以观察到古土壤中方解石沿根孔淀积特征以及具滑擦面。钙质古土壤质地偏粗,为壤质砂土和砂质壤土。古土壤Bk层中的Ca、Mn、Sr相对富集,其余常量元素与Ba、Sc、Nb、Th、U、Cr、V、Co、N i等元素降低;δCe和δEu负异常以及相对富集重稀土元素。分别按照中国土壤分类系统和美国土壤系统分类两种分类体系进行了古土壤分类。由古土壤类型和特征可以推断白垩纪不同时期,在四川盆地梓潼—巴中地区、辽宁金岭寺—羊山盆地和松辽盆地出现过半湿润至半干旱的气候环境。     

Soils of the subtaiga landscapes on the northern spurs of the Tsagan-Daban Ridge in the Selenga Mountains

The soil cover patterns in the subtaiga landscapes on the northern spurs of the Tsagan-Daban Ridge in the Selenga Mountains have been studied. Gray-humus lithozems and bedrock outcrops are typical of the steep south-facing slopes under herbaceous pine forests. Soddy iron-illuvial podburs are formed under forest vegetation on gentle slopes of northern and western aspects with a thick mantle of loose colluvial deposits. Dark-humus metamorphic soils occur on the slopes of western and northwestern aspects below 700 m a.s.l. under secondary forb-grassy communities that replaced the initial herbaceous pine forests. Windblown hollows (yardangs) are occupied by humus psammozems under steppe pine forests. The morphological and physicochemical characteristics of these soils are discussed in the paper.     

Soils, vegetation, and climate of the southern Transural region in the Middle Bronze Age (by the example of the Arkaim fortress)

Paleosols of the unique fortress of Arkaim located in the steppe zone of the southern Transural region (Chelyabinsk oblast) were investigated. The dating of the buried soils was performed using the radiocarbon method. The time of building this archeological monument is the Middle Bronze Age (the Sintashta culture; the calibrated dating with 1σ confidence is 3700–4000 years ago). Seven pits of paleosols and ten pits of background ordinary chernozems were studied. The soils are loamy and sandy-loamy. The morphological and chemical properties of the buried and background ordinary chernozems are similar; they differ by the lower content of readily soluble salts in the paleosols as compared to the background ones. The sporepollen spectrum of the Arkaim paleosol is transitional from the steppe to the forest-steppe type. During the existence of this settlement, pine forests with fern ground cover grew, and hygrophytic species (alder and spruce) that nowadays are not recorded in the plant cover occurred. The main feature of the paleosols is the presence of pollen of xerophytic and halophytic herbaceous plants there. The few pollen grains of broad-leaved species testify to a higher heat supply as compared to the current one. Judging by the results of the spore-pollen and microbiomorphic analyses, the climate during the time of building the walls of the settlement was somewhat moister and warmer (or less continental) than the present-day climate. The duration of this period appeared to be short; therefore, soil properties corresponding to the changed environment could not be formed. They reflect the situation of the preceding period with the climatic characteristics close to the present-day ones.     

Soil formation in the technogenic forest-steppe landscapes of the Nazarovskaya Depression in western Siberia

The soil formation was studied in the 21- to 35-year-old pine plantations created on the overburden dumps of the Nazarovskaya Depression without applying the material of the humus horizon. The surface technogenic formations under the pine plantations belong to the group of naturfabricats (surface formations devoid of the humus horizon and composed of natural substrate). The morphological characteristics, bulk chemical and particle-size compositions, and labile properties of the soils indicate that the accumulation and transformation of organic matter are dominant processes in the artificially planted forests. The accumulation of organic residues and destruction and humification are tightly related to the environmental conditions transformed by the technogenesis and conceal other processes forming the soil profiles. Quasizems created for agricultural production purposes were the objects of the study. They were formed by covering the technically planned overburden rocks with the material of humus layers. The thickness of the humus horizons of the quasizems varies greatly (25–64%); the variation of the humus reserves in them is 34–122%. Middle-profile horizons have not been formed by the present time.     

The solonetzic process in surface soils and buried paleosols and its reflection in the mineralogical soil memory

The development of the solonetzic process in paleosols buried under kurgans and in the modern surface soils has been studied on the basis of the analysis of the clay (<1 μm) fraction. The revealed changes in the textural differentiation of the soils and the mineralogical composition of the clay fraction during 4500 years are assessed from the viewpoint of the “memory“ of the solid-phase soil components. The mineralogical characteristics show that the solonetzic process in the modern background soil is more developed. The mineralogical approach allows us to reveal the long-term changes in the soil status; it is less useful for studying the effect of short-term bioclimatic fluctuations. In the latter case, more labile soil characteristics should be used. The mineralogical method, combined with other methods, becomes more informative upon the study of soil chronosequences. Our studies have shown that the data on the clay minerals in the buried paleosols may contain specific information useful for paleoreconstructions that is not provided by other methods.