Analysis on the viscosity of six different compound smelting reduction slag

In combination with Huimin high-phosphorus iron smelted by smelting reduction and HIsmelt ironmaking technologywhich have the advantages of high efficient dephosphorizationCaO-SiO2-Al2O3-MgO-FeO-P2O5 slags with basicity R (mass ratio of CaO to SiO2)ranging from 0.8 to 1.4Al2O3 ranging from 6.4% to 15.4%P2O5 ranging from 0 to 3% and the content of MgO and FeO fixed as 4% and 6% respectivelyare studied.The slags are synthesized by reagent grade.The mineral composition and microstructure of the slags are studied with scanning electron microscope and the effects of changes in the composition of smelting reduction slags on its viscosity are studied by RTW-10 melt comprehensive physical properties measuring apparatus.Results show that the mineral structure of slags are mainly composed of melilite(gehlenite and akermanite)which is characterized by square and thick skeleton form.The viscosity decreases with the increasing of the slag basicity at fixed P2O5 or Al2O3 mass fractionincreases with the increasing of Al2O3 mass fraction at fixed slag basicity or P2O5 mass fractionand increases with the increasing of P2O5 mass fraction at fixed slag basicity or Al2O3 mass fraction.     

Experiment of the Influence of Manganese Oxide on the Prosperities of High Alumina Content BF Slag

Alumina content in Nanjing Steel blast furnace slag is up to 19%, which results in worse slag fluidity, higher furnace operating temperature and higher silicon content of hot metal. Therefore blast furnace strengthening is reduced. Aiming at this problem, an by laboratory experiments the viscosity of simulating Nanjing Steel BF slag samples are measured after adding MnO, which are made up of analytically pure chemical reagents. And according to the experimental results, the influence of MnO on the properties of high alumina content BF slag is analyzed and the methods of reducing silicon content of hot metal in Nanjing Steel is educed. The results showed that the addition of MnO in high Al2O3 content slag has stronger effects on viscosity decreasing, and the decreasing of slag viscosity would make it possible to reduce the operating temperature of the blast furnace, which would result in decreasing of silicon content of hot metal.     

ROLE OF BaO IN MOLD POWDER USED IN CHNTINUKUS CASTING KF STEEL

In this paper, the role of BaO in mold powder used in continuous casting of steel is studied. The pricipal content of the study is about the effect of BaO on melting temperature, Viscosity, and capacity of absorbing inclusion and glassing of molten mold powder. Experiment results reveal that to add BaO into mold powder can decrease the melting temperature and viscosity, and prevent the formation of high melting point particle and crystallizing of mold powder, suitable BaO content in mold powder is quite helpful to increase the capacity of absorbing inclusion of molten mold powder, and to improve the lubrication effect of molten powder film between mold and billet.     

Researches on Melting point and Viscosity of Mould Fluxes Containing SrO

The melting point and viscosity of SrO SiO 2 CaO Al 2O 3(5%) Na 2O(10%) CaF 2(10%) flux system have been measured,and the curve charts of the melting point and viscosity are drawn.Moreover,the mathematical relations of properties with chemical composition are founded.The best range of chemical composition for mould flux containing SrO is presented via analyzing the curve charts.     

CaO-B2O3-SiO2-TiO2系保护渣配位结构的计算模拟

针对新型无氟保护渣CaO-B2O3-SiO2-TiO2四元渣系,采用分子动力学模拟的方法,对该保护渣系的微观结构进行了模拟计算,分析了CaO-B2O3-SiO2-TiO2渣系的配位结构,并考察了TiO2含量对保护渣配位结构的影响规律。研究表明：该渣系中硼的配位结构只存在三配位的三角体和四配位的四面体,而Ti与O之间主要以六配位的八面体结构形式存在;随着TiO2含量的增加,保护渣微观结构中Si、B、Ti的配位形式将发生明显变化,分别向四配位结构、三配位结构及五配位结构转化。     

含铈耐热钢凝固过程中的夹杂物行为

建立了稀土耐热钢凝固过程中夹杂物析出与溶质元素微观偏析的耦合热力学模型,并通过工业试验与高温模拟实验验证了模型的准确性。利用该模型,依次考察了铈添加量,初始氧含量,初始硫含量对253MA耐热钢凝固过程中夹杂物析出行为的影响作用规律。在本模型条件下,随着铈添加量的增加,钢中的SiO2与MnS消失,且凝固过程中开始析出CeN;随着初始氧含量的增加,钢中开始析出Ce2O3,SiO2及MnS,其中SiO2与MnS在凝固过程中析出;随着初始硫含量的增加,钢中的Ce2O3消失,钢中开始析出Ce3S4与MnS,在凝固过程中析出的Ce3S4逐渐在液相线温度以上析出。研究工作对于稀土耐热钢连铸水口结瘤问题的解决具有理论指导意义。     

Quantitative study on solid slag film’s crystallinity of mould fluxes by using DSC method

The method to determine the crystallinity of solid slag film is established by analyzing the DSC curve of solid slag film and corresponding quenched slag. The accuracy of the method is investigated by measurements of prepared samples whose crystallinity is given. In addition, the solid slag films of mold slags used to cast medium carbon steel and low carbon steel are obtained by heat flux simulator in laboratory, and the crystallinity of the two kinds of slag film are also measured by DSC method. Experimental results indicates that the crystallinity of solid slag film can be determined by comparing the crystallization enthalpy of solid slag film and corresponding quenched slag during heating process, and the relative error is within 5.03%. For medium carbon steel, the crystalline fraction of solid slag film is 88.6%, while the crystalline fraction of solid slag film corresponding to low carbon steel is 55.0%. The results are consistent with actual structure of solid slag films.     

MgO对高铝高炉渣脱硫的影响及其动力学分析

随着廉价高铝铁矿石的不断使用,高炉炉渣内Al₂O₃含量也随之升高,这势必会影响高炉炉渣的各项冶金性能。为深入研究高铝高炉渣脱硫性能,明确MgO含量对高铝渣脱硫性能的影响,笔者通过改变高铝渣中MgO的含量,分别设定渣中MgO含量为5%、9%、13% MgO,研究不同MgO含量高炉高铝渣的脱硫性能及其脱硫动力学。结果表明：MgO含量不仅对高铝渣的黏度、脱硫能力有不同的影响,还使炉渣的脱硫速率发生了很大的改变。MgO含量越高对应的黏度越低,脱硫能力越大;但脱硫速率却表现出了不同规律,9% MgO的脱硫速率表现为最大;经过综合比较,当碱度固定为1.1、Al₂O₃含量固定为17%时,MgO含量为9%的炉渣同时具有较好的粘度和脱硫性能。     

Alumina-based Composite Materials for Prefabricated Iron Runner

The relationship between the properties of the composite and the addition of the preventing crack additives, dispersion agent, SiC, graphite, stainless steel fiber have been researched. Finally, alumina-based composite materials used for prefabricated iron runner with better ratio of properties and price has been developed by the studying of the properties and microstructure of alumina based composite materials. The best composition for the iron line is Al 2O 3-14%SiC-5%G-4%SiO 2-2%micropoeder-1%white clay-6%cement;the best composition for the slag line is Al 2O 3-16%SiC-5%G-4%SiO 2-2%micropoeder-1%white clay-6%cement;addition of both is 0.15%Na 5P 3O 10-3B aluminum powder-2%stinless steel fiber. The mechanism on the composite materials eroded by molten iron has also been discussed.     

A simulated experiment on the high titanium slag rheological behavior

The rheological property of high titanium slag is a main factor to influence the vanadium titanomagnetite smelting in blast furnace. It plays a great role in discharging slag, separating iron and slag and even the life of blast furnace hearth. The acrylonitrile-butadiene-styrene multipolymer(ABS) dense suspension is taken to simulate the system of high titanium slag. Apparent viscosity is measured by a NXS-11A rotating cylinder viscometer. The impact of temperature, volume fraction and particle sizes on the suspension apparent viscosity is studied. The results show that temperature and volume fraction have a strong influence on the suspension apparent viscosity, while the particle size has a weak effect. The suspension shows Bingham behavior within a wide concentration range. The dependence of the appear viscosity on temperature and amount of solid addition can be described by a binary function equation.     

四种因素对晚粳稻糊化特性和脂肪酸值的影响研究

采用正交试验方法和RVA粘度测定仪,研究稻谷温度、储藏时间、稻谷含水量和磷化氢浓度四种因素对粳稻储藏期间糊化特性的影响。结果显示:温度是晚粳稻糊化特性和脂肪酸值最主要的影响因素,磷化氢对晚粳稻峰值粘度和崩解值影响显著,储藏时间和稻谷含水量对晚粳稻糊化指标影响不显著。     

Current Status of DIMOX in Synthesizing Al/Al2O3 by Aluminum Alloy

The processes, microstructures, properties and mechanisms of DIMOX in synthesizing Al/Al 2O 3 by Al-Mg-Si alloy are reviewed and their problems are considered mainly as following:non_homogeneous oxidation growth of Al/Al 2O 3 at the surface of melts and the porosity of Al/Al 2O 3 limites structural application of Al/Al 2O 3 composite. The mechanisms and models of microchannel,magnesium action,silicon action,and induction are outlined. Several problems which need to be noticed are pointed out,which are diffusion and transfer of oxygen in aluminium melts;the role of MgO and MgAl 2O 4 at outer layer;the reaction feature of solid_gas in the oxidation microstructures of Al_Mg_Si alloy;SiO 2 induction mechanism of silicon and its correlation with the mechanism of magnesium action in Al_Mg_Si alloy.     

RESEARCH ON THE PLUX FOR CONTINUOUS CASTING THE STEEL CONTAINING ALUMINUM

The changes of Al2O3 and the properties, such as basicity, metting point and viscosity, of the mould flux when continuously casting the steels containg Al are discussed. In order to obtain a stable quality in the flux, the functions of content MnO are also studied. As a result, a reasonable composition of flux for this purpose is suggested.     

Researches on Melting-points and Visccoity of Mould FluxesWei Qingcheng

The testing of the melting-points and viscosity of BaO-SiO2-CaO-Al2O3(5%)-Na2O(10%)-CaF2(1 0%)six-part slag system is completed. Then the curve charts of the melting-points and viscosity are drawn. Moreover, the mathematical relations between properties andchemical compostion are found out.As a result,the proper range of chemical composition for BaO-contained mould fluxes is therefore presented.     

Thermal Barrier Properties of Gradient Coating on a Ceramic Metal

In this paper,the adherence and thermal barrier properties of A12O3-based ceramic metal gradient coating with the method of oxyacetylene-flam-spray are studied. The results show that the physical and chemical compatibilities between the coating and the substrate are improved by adding Cu,Ni/Al and the gradient coating,and to relax thermal stress and interface stress in coat and at the same time to increase adherence property of coating. Besides,the gradient coating has good spalling resistance,erosion resistance to high temperature liquid iron and the effect of thermal barrier properties is remarkable.     

不同生物降解地膜对大蒜生长发育的影响及降解效果研究

以金乡白皮蒜为试验材料,研究了“降解1号”、“降解2号”、“降解3号”3种氧化-生物双降解地膜、普通地膜及不覆膜对大蒜生长发育和产量的影响,并研究了不同降解地膜的保温保墒和降解性能。结果表明：氧化-生物双降解地膜和普通地膜处理之间,株高、植株重量、假茎粗、单叶平均叶面积以及鳞茎亩产鲜重差异均不显著,3种降解地膜比较,“降解3号”鳞茎产量较高,为28932.75 kg/hm2不覆膜处理由于低温冻害,鳞茎产量为覆膜处理平均产量的17.53%。对比不覆膜处理,不同覆膜处理均能显著提高5 cm和15 cm的土层温度以及10 cm土层的土壤含水量,尤其能够显著提高深层土壤温度,生物降解地膜与普通地膜处理之间差异不显著。降解性能对比,“降解1号”降解效果最好,至大蒜成熟期,最大拉力和断裂伸长率为0,“降解2号”和“降解3号”断裂伸长率分别为102.83%和360.28%。     

中原地区入仓高水分玉米安全度夏技术研究

介绍了中原地区堆高5 m～6 m、入仓水分最高17.8%的玉米安全度夏采取的一系列措施,从入仓控制开始,经过冬季低温储藏,春季气温回升15℃到以上时采用地上笼压入式通风、组合式多管通风系统压入式通风就仓干燥等技术,使玉米全仓平均水分降到14.0%以内,结合臭氧防霉、高浓度PH3熏蒸及排积热控仓温等措施,确保了高水分玉米的安全储藏。     

复合型缓释肥包衣剂理化性质及缓释特性研究

为了探明复合型缓释肥包衣剂的理化性质及其缓释特性,对复合型缓释肥包衣剂的粘度、成膜性、成膜时间、膜韧性、包衣脱落率、包衣肥的养分初期溶出率、养分微分溶出率、养分累积释放曲线等进行了测定。理化性质测试结果显示：缓释肥包衣剂的粘度为44.5 MPa/s、成膜性良好、成膜时间7 min、包衣膜拉长倍数达2.8倍,包衣脱落率< 5%。缓释特性测试结果显示：包衣肥养分N、P、K初期溶解率< 15%、微分溶解率< 2%,符合中国《缓释肥料》标准GB/T23348-2009。其中P的初期溶解率小于N、K的初期溶解率,而N、P、K微分溶解率相差不大。养分累积释放曲线大致呈“S”型,与作物生长需肥规律一致。表明复合型缓释肥包衣剂的理化性质良好,能有效控制普通复合肥养分的缓释。     

不同覆膜处理对土壤水分温度及春玉米产量的影响

为了研究可降解地膜的农用特性以及对不同种可降解地膜进行择优,试验通过对比研究的方法,对一般大田条件下普通地膜,不同可降解地膜以及露地栽培条件下土壤的温度、水分以及产量性状进行了对比研究。结果表明：在玉米生育前期,各地膜组均可以有效提高地下0~40 cm土壤水分含量,地下5~25 cm土壤温度,保温作用持续65天,其保水保温作用均表现为普通地膜与可降解地膜1差异不大,可降解地膜2次之,露地处理最差。普通地膜、可降解地膜1、可降解地膜2玉米增产率分别为19.5%,22.0%和13.1%,说明可降解地膜1和普通地膜对玉米产量影响显著且差异不大。由此可得,可降解地膜1代替普通地膜从事农业活动具有实际可操作性。     

Smelting AlMnSi alloy by Using High-bearing Manganese Slag

First smelting MnSi alloy by using high-bearing manganese slag of BF by electric smelting process in a 25 kVA arc furnace in lab has been introduced. In order to increase the content of manganese and silicon in MnSi alloy , a little amount of MgO is added into the slag and the lower alkalinity has been adapted. Then smelting AlMnSi alloy using MnSi alloy containing high silicon that obtained by experiments and waste Al with an induction furnace has been studied. The controlling of temperature is the key in smelting process. The high quality AlMnSi alloy has been obtained successfully,Which can be extensively used for the compound oxygen removal agent for making steel and the metal alloy additive.