我国4种土壤磷素淋溶流失特征

磷素是水体富营养化的主要限制因子,地表水磷的污染负荷主要来源于农业面源污染。采集黑土、潮土、红壤和水稻土4种土壤,采用土柱模拟的试验方法,研究磷素在4种土壤剖面中空间分布特征,以及土壤渗漏液中TP、TDP的含量、动态变化以及流失量特征。结果表明:(1)不同类型土壤全磷和有效磷含量差异性显著,由高到低依次为水稻土潮土黑土红壤;黑土、红壤和水稻土土壤全磷和有效磷含量都表现出,随土壤深度的增加,不断降低;而潮土剖面呈上下层高,中间低的分布格局。(2)4种土壤渗漏液中占主导的磷形态不一致,潮土以MRP占主导,黑土和水稻土以DOP为主,而红壤则以PP为主。土壤磷素动态变化方面,潮土表现为TP含量先减后增再减,TDP含量先增后减;黑土表现为TP含量先增后减,TDP含量持续下降;红壤和水稻土TP和TDP含量变化不显著。(3)相关分析表明,4种土壤中Olsen-P与渗漏液中TP呈指数关系,具有极显著相关性。(4)4种土壤TP、TDP下渗流失量都以潮土最高,其次是黑土和水稻土,红壤流失量最小,磷素流失以TDP为主。     

土壤积累态磷研究:Ⅰ.一次大量施磷的产量效应

试验表明，在红壤和石灰性潮土上，一次大量施磷的总产量（红壤为６季，潮土为３季），在总施磷量相等的情况下，都高于或至少等于分次施磷，但其增产作用主要表现在前１－２季作物上，随着时间的延长，一次施磷的产量逐渐下降直至低于分次施磷，说明了随土壤和磷肥作用时间的延长、积累态磷的有效性逐渐下降，积累态磷的有性不仅决定于与土壤接触的时间，以及土壤磷素吸附位的饱和度，还与作物类型有密切关系，如试验中的萝卜菜，利     

再生水灌溉对不同类型土壤磷形态变化的影响

在温室条件下采用盆栽试验方法在4类典型土壤上种植小白菜,以自来水灌溉作为对照,研究再生水灌溉对小白菜生长、土壤磷形态转化特征以及不同类型土壤间的差异性。结果表明,全再生水灌溉:①显著增加红壤、潮土、塿土小白菜生物量,分别为9.1%,16.1%,9.9%;黑土小白菜生物量增加不显著;②显著增加4类土壤小白菜地上部磷含量和土壤速效磷含量,红壤、潮土、塿土和黑土的小白菜地上部磷含量分别增加17.6%,20.0%,18.8%和15.8%,土壤速效磷含量分别增加16.7%,32.2%,34.4%,16.8%;③显著增加红壤、潮土、塿土的活性有机磷和无机磷组分中活性较高的Ca2-P,黑土的Ca2-P含量显著增加,但其活性有机磷含量变化不大。再生水灌溉能促进土壤稳性较高的有机、无机磷组分向活性较高的组分转化,但不同类型土壤间存在差异性。     

不同土壤类型对硫酸钾镁肥中钾、镁、硫吸附特性研究

在水稻土、红壤、潮土中分别加入不同浓度的硫酸钾镁肥溶液,研究3种土壤在不同浓度硫酸钾镁肥下pH值的变化及对K、Mg、S吸附的能力。结果表明:在3种土壤中加入硫酸钾镁肥都使土壤pH值下降,下降速度是红壤>水稻土>潮土。3种土壤对K的吸附能力较强,可用一元线性方程拟合,在0~354 mg kg-1的K加入量范围内,吸附率在50.4%~74.1%;对S的相对吸附率居中,可用一元二次方程拟合,在0~311 mg kg-1的S加入量范围内,吸附率在35.6%~88.1%;对Mg的吸附能力极弱。3种土壤对K、S吸附能力大小顺序为:潮土>红壤>水稻,对镁吸附能力大小顺序为:潮土>水稻土>红壤。土壤田间施用硫酸钾镁肥量应根据不同土壤对养分的吸附能力大小进行相应的调整。     

长期施肥对我国6种旱地小麦磷肥回收率的影响

为阐明长期施肥下小麦磷肥回收率的时间及空间变化特征,对我国6种旱地土壤（红壤、黑土、均壤质潮土、轻壤质潮土、塿土和黄棕壤）长期不同施肥下的磷肥回收率及相关指标进行了分析。结果表明,长期施用NPK化肥（NPK）,均壤质潮土、轻壤质潮土、塿土、黄棕壤上小麦当季磷肥回收率随时间增加而显著升高,每年平均分别上升 0.80、0.60、1.30和0.44个百分点;化肥有机肥配施（NPKM）,每年平均上升0.25～1.72个百分点。黑土上小麦磷肥回收率长期施用NPK的变化不大,施用NPKM的显著升高,平均每年上升 0.50个百分点;红壤上磷肥回收率NPK处理呈下降趋势,平均每年下降 0.86个百分点,而NPKM处理保持平稳,说明施用有机肥有利于提升磷肥回收率。不同土壤上小麦当季磷肥回收率的变化速率与土壤磷的形态密切相关,以无机钙磷为主要形态的土壤（均壤质潮土、轻壤质潮土、塿土）小麦磷肥回收率均高于以有机磷为主要形态的黑土和以无机闭蓄态磷为主要形态的红壤。小麦当季磷肥回收率受土壤性质的影响,与土壤全磷和pH值之间具有显著的正相关关系（P0.05）。     

长期施肥对我国典型土壤活性有机质及碳库管理指数的影响

对我国重点农区的6种典型土壤红壤、灰漠土、垆土、潮土、褐土、黑土长期耕作施肥后的活性有机质及碳库管理指数(CMI)进行了研究,探讨施肥对不同土壤活性有机质和CMI的影响。土壤活性有机质用KMnO4氧化法测定,采用3种浓度KMnO4(33、1673、33.mmol/L)将土壤活性有机质分为高活性有机质、中活性有机质和活性有机质3部分。结果表明,只耕作不施肥(CK)10年后土壤活性有机质含量降低,CMI下降11.1～63.6,其中垆土、褐土下降幅度最大、黑土最小。施用化肥也使土壤活性有机质下降,其中单施氮(N)的潮土活性有机质下降最大,达31.3%;化肥配合施用(NPK)的红壤活性有机质下降最大,其余土壤相对较小。施肥使土壤活性有机质和总有机质含量增加,高于初始土壤和CK。施用有机肥或有机肥配施化肥,土壤活性有机质含量和CMI均显著增加,CMI以红壤上升最大,达91.4,潮土最小,仅为4.6。土壤活性有机质的数量及CMI变幅大于土壤总有机质的变化幅度,以CMI变化为大,说明CMI是评价施肥耕作对土壤质量影响的最好指标。土壤活性有机质分组结果表明,红壤活性有机质组成以高活性有机质为主;垆土、灰漠土活性有机质以高活性和中活性两部分为主;潮土以中活性有机质为主。施肥对红壤、灰漠土活性有机质组分影响明显,对垆土、潮土影响相对较小。     

南方典型土壤水力特征差异性分析

为探究南方地区典型土壤水力性质的差异,采用压力膜法、定水头渗透法和一维水平土柱吸渗法对粘性潮土、沙性潮土、红壤、水稻土和紫色土5种南方典型土壤的水动力学参数进行室内测定,对比分析了各土壤水力特征的差异及其产生的原因。结果表明:土壤质地和粘粒含量是影响土壤水力特征的主要因素;粘性潮土、沙性潮土属于级配良好土,而红壤、紫色土、水稻土属于级配不良土,粘性潮土、沙性潮土、红壤、紫色土、水稻土饱和导水率依次增大,分别为1.75×10~(-3),3.15×10~(-3),4.77×10~(-3),11.02×10~(-3),11.87×10~(-3) cm/min;相对水稻土和沙性潮土而言,其他3种试验土持水性较高。土壤有效水含量为沙性潮土粘性潮土水稻土紫色土红壤,其有效水孔隙体积分别占其总孔隙体积的48%,29%,27%,18%和17%。非饱和条件下,沙性潮土和红壤中的水分运动速率较快,远高于粘性潮土中的水分运动速率,约为其6.8倍。土壤质地、颗粒级配、粘粒和有机质含量不同是造成土壤水力特性差异的因素,其中土壤质地和颗粒级配为南方典型土壤水力特性差异的主要影响因素。     

不同土壤磷的固定特征及磷释放量和释放率的研究

通过加入不同浓度的P(水土比为 2 0∶1 )并利用连续提取法 ,对三种土壤P的固定特征以及磷的释放进行了研究。结果表明 ,红壤对P的固定能力高于潮土 ,而潮土高于水稻土 ,在加入P量为 2 97gkg- 1土壤的条件下 ,三种土壤对P的固定量分别为 2 84gkg- 1、2 5 3gkg- 1和 2 0 8gkg- 1。三种土壤对P的固定率则随着加入P量的增加而降低。在P的释放研究中 ,随着提取次数的增加 ,P的释放量减少 ,并在提取 8次后 ,以后各次P的释放量不发生显著变化。三种土壤中 ,水稻土P的最大释放量 (1 2 4 0 7mgkg- 1)显著高于红壤 (60 46mgkg- 1)和潮土 (1 9 74mgkg- 1) ,水稻土P的总释放量 (1 6次 )也大于红壤和潮土 ,三种土壤P的总释放量分别为 2 0 6 0 2 (1 98gkg- 1土壤P处理 )和 2 71 91mgkg- 1(2 97gkg- 1土壤P处理 )、1 0 0 48和2 60 5 3mgkg- 1、1 1 6 0 6和 1 3 1 91mgkg- 1。三种土壤P的释放率随着提取次数的增加而增加 ,并逐渐达到稳定。水稻土的释放率显著高于红壤和潮土。水稻土和潮土中 ,1 98gkg- 1土壤P处理的土壤P的释放率高于2 97gkg- 1土壤P处理的土壤 ,红壤则相反     

不同有机培肥方式对红壤性水稻土磷素的影响

基于红壤性水稻土有机肥长期定位试验,分析了红壤双季稻种植模式下,不施肥、NPK、紫云英+猪粪+化肥、紫云英+猪粪+秸秆+化肥、紫云英+秸秆+化肥处理耕层土壤全磷、Olsen-P、磷素有效性和磷素利用率35年的变化特征,以及Olsen-P与水稻产量的响应关系。结果表明:不施肥处理土壤全磷含量显著降低,有效磷含量及磷素有效性略微下降。配施猪粪显著提高全磷、Olsen-P含量和磷素有效性,但显著降低磷肥利用率,增加磷的环境污染风险。化肥配合紫云英及稻草还田处理土壤全磷、有效磷含量以及磷素有效性保持稳定,但显著提高磷肥利用率。Olsen-P的产量农学阈值为16.36 mg kg-1。     

退化红壤肥力障碍特征及重建措施Ⅲ. 典型地区红壤磷素积累及其环境意义

本文研究了红壤典型地区土壤磷素的不断积累情况 ,并初步提出了可能造成面源磷污染水体的土壤有效磷临界参考水平。这一水平在以泾流为主和以下渗水流为主的不同土壤上临界值不同 ,在旱地土壤和水稻土上数值也不同。作者认为红壤区目前的土壤有效磷水平大部分都处于上述临界值以下 ,但在冲积土区的水稻土上 ,特别是高产水稻土区 ,以及城郊蔬菜区都有数量不等的土壤已达到或超过这一临界值 ,面源磷的污染在这类土壤上已成为现实威胁。作者建议应开展我国不同地区面源磷对环境影响的研究。     

Interaction of NPK fertilizers during their transformation in soils: Ⅲ. Transformations of monocalcium phosphate

Interactions of N, P and K fertilizers in soil-plant systems are widely recognized. This study focused on the transformations of monocalcium phosphate (Ca(H2PO4)2) (MCP) with co-application of ammonium and potassium fertilizers in three different soils. The results showed that after 1 d incubation a large portion of the MCP applied in the paddy,calcareous and red soils became the water-insoluble form and the recoveries of P applied as Olsen P varied greatly in these three soils. Application of ammonium sulfate ((NH4)2SO4) (AS) or potassium chloride (KC1) reduced WSP significantly in the soils with AS more effective than KC1 in the calcareous soil, while the reverse occurred in the red soil. Meanwhile, in the paddy soil, co-application of the two fertilizers reduced WSP more than when the fertilizers were applied individually. The co-application of AS with MCP in the paddy and calcareous soils significantly reduced Olsen P, but the opposite occurred in the red soil. The experiment on the effect of different accompanying anions showed that the ammonium fertilizers (PNC1 and PNS) reduced WSP more effectively than the corresponding potassium fertilizers (PKC1 and PKS) in the calcareous soil due to the difference of the cations, whereas in the red soil, the chlorides reduced WSP more effectively than the sulfates. Overall, co-application of ammonium or potassium fertilizers with MCP significantly decreased availability of P from MCP during its transformation in soils, especially when MCP was applied in combination with ammonium in the calcareous soil.     

土壤中氮磷钾肥转化中的交互作用: Ⅰ.土壤pH的动态变化

Dynamic changes of soil pH as influenced by ammonium sulfate (AS), monocalcium phosphate (MCP),potassium chloride (KCl) and their interaction in soils were evaluated in incubation experiments. Applyingthese fertilizers significantly reduced soil pH values in all cases and followed sequences of AS ＞ MCP ＞KCl, MCP ＞ KCl ＞ AS and KCl ＞ AS ＞ MCP for the paddy, calcareous and red soils, respectively. TheAS-induced reduction of pH in the three soils followed the sequence of red soil ＞ paddy soil ＞ calcareous soil,while in MCP and KCl systems the reduction of pH followed the sequences of calcareous soil ＞ paddy soil ＞red soil and red soil ＞ calcareous soil ＞ paddy soil, respectively. The interactions of the NPK fertilizers on pHwere significant. MCP plus KCl or MCP plus AS reduced pH values more than the fertilizers applied solelyin the paddy soil, but AS partly counteracted the effect of MCP on pH in the 1 d sample of the calcareoussoil. The effect of MCP on pH was trivial when MCP was applied in combination with KCl or AS in the redsoil. When applied in combination with AS, KCl did not affect soil pH initially, but suppressed the reductionof pH at the later incubation stage, which was related to inhibition of nitrification by KCl in the soils.     

应用穆斯堡尔谱和X射线法研究红壤性水稻土的氧化铁矿物

应用穆斯堡尔谱和X射线法分析研究红壤性水稻土的氧化铁矿物,研究结果表明,红壤性水稻土的氧化铁矿物组成、特性及其形成转化与起源土壤具有明显的差异。水稻土的成土条件不利于赤铁矿的形成。红壤的粘粒氧化铁矿物以赤铁矿和高铝替代(>20摩尔%)的针铁矿为主。经淹水种稻后,赤铁矿逐渐被转化为低铝替代的针铁矿或其它形态氧化铁。渗育型水稻土P层的赤铁矿含量比相应的母土低,其针铁矿铝替代量较其它水型的水稻土高。而潴育型水稻土W层和潜育型水稻土G层粘粒氧化铁矿物均以针铁矿为主,其铝同晶替代量低(<15摩尔%),且颗粒细小,结晶度较低。这些结果反映了水稻土的成土条件和发生特点,同时对水稻土发生分类具有重要的意义。     

不同水分状况及施磷量对水稻土中速效磷含量的影响

通过室内培养试验研究了不同水分(淹水和60%田间持水量)及施P量对水稻土速效P及水层含P量的影响。结果表明,无论水分状况如何,土壤速效P含量随施P量的增加而呈明显增加趋势。土壤速效P出现富集的转折点因供试土壤而异,第三纪红壤性水稻土大致为P2O560~120mg/kg,而第四纪红壤性水稻土和黄泥土为P2O5120~180mg/kg。P肥施入土壤后,水溶性P主要存在于土壤溶液中,而分布于水层中的P相对较少。但在过量施P(P2O5>180mg/kg)时,施肥后短期内(0~30天),水层中P浓度较高(0.05~0.3mg/kg),如水分管理不当,则会造成P的损失。     

石灰用量对污染红壤和黄泥土中有效态铜锌含量的影响

采用外源加入重金属铜锌硝酸盐的方法,制成铜、锌单一及复合污染的三级污染红壤和黄泥土（Cu 200mg/kg、Zn 400 mg/kg）,稳定一个月,施入低（0.50 g/kg）、中（1.50 g/kg）和高（2.50 g/kg）3种不同用量的石灰,稳定两个月后测定土壤有效态铜、锌含量和pH值,以阐明石灰用量对不同污染土壤中重金属有效态含量的影响。结果表明,随石灰用量的增加,复合污染红壤中有效态铜含量较对照依次降低31%、76%和87%;而石灰用量对黄泥土中有效态铜影响的差异不显著;两种土壤中有效态锌含量均随石灰用量的增加而显著减少;复合污染较单一污染相比,有效态铜及有效态锌的含量差异不显著。在复合污染下,低、中量石灰使黄泥土中有效态铜含量较红壤减少89%和63%,有效态锌减少27%和65%。但加入高量石灰,两种土壤差异不显著。石灰能够降低单一与复合污染铜、锌有效态的含量,但其效果因土壤类型而异,在红壤上选择施用高量石灰而在黄泥土上则适宜施用低中量石灰,以取得最佳的修复效果和效益。     

Phosphorus sorption,supply potential and availability in soils with contrasting parent material and soil chemical properties

Soil phosphorus (P) management requires a more targeted and soil‐specific approach than is currently applied for agronomic recommendations and environmental evaluation. Phosphorus buffering capacities control the supply of P in the soil solution and were measured across Irish soils with contrasting parent material and chemical properties. Langmuir sorption buffer capacities (MBCs) and binding energies (b) were strongly correlated with soil pH and extractable aluminium (Al). A broken‐line regression fitted to the relationship between MBC and Al derived a change‐point value for Al above which MBC increased linearly. Soils above the change point were predominantly acidic to neutral with non‐calcareous parent material, with larger buffering capacities and binding energies than calcareous soils. Ratios of Mehlich3‐Al and P (Al:P) were used to relate buffering capacity to supply potential in non‐calcareous soils. Large ratios of Al:P were associated with poor P availability, characteristic of strongly P‐fixing soils. Threshold values of iron‐oxide paper strip P (FeO‐P) and Morgan's P revealed Al:P ratios where soils began to supply P in available form. The change‐point for Morgan's P fell within the current target index for P availability; however, the confidence interval was more compatible with previous agronomic P indices used in Ireland. Relationships between Morgan's P and measures of extractable P, M3‐P and Olsen P, deviated in calcareous soils at large soil P contents, indicative of P precipitation processes dominating in these soils. Identifying differences in soil P buffering capacity at the laboratory scale would improve agronomic and environmental assessment at field and catchment scales.     

Speciation of phosphorus in temperate zone forest soils as assessed by combined wet‐chemical fractionation and XANES spectroscopy

Phosphorus availability in terrestrial ecosystems is strongly dependent on soil P speciation. Here we present information on the P speciation of 10 forest soils in Germany developed from different parent materials as assessed by combined wet‐chemical P fractionation and synchrotron‐based X‐ray absorption near‐edge structure (XANES) spectroscopy. Soil P speciation showed clear differences among different parent materials and changed systematically with soil depth. In soils formed from silicate bedrock or loess, Fe‐bound P species (FePO₄, organic and inorganic phosphate adsorbed to Fe oxyhydroxides) and Al‐bound P species (AlPO₄, organic and inorganic phosphate adsorbed to Al oxyhydroxides, Al‐saturated clay minerals and Al‐saturated soil organic matter) were most dominant. In contrast, the P speciation of soils formed from calcareous bedrock was dominated (40–70% of total P) by Ca‐bound organic P, which most likely primarily is inositol hexakisphosphate (IHP) precipitated as Ca₃‐IHP. The second largest portion of total P in all calcareous soils was organic P not bound to Ca, Al, or Fe. The relevance of this P form decreased with soil depth. Additionally, apatite (relevance increasing with depth) and Al‐bound P were present. The most relevant soil properties governing the P speciation of the investigated soils were soil stocks of Fe oxyhydroxides, organic matter, and carbonate. Different types of P speciation in soils on silicate and calcareous parent material suggest different ecosystem P nutrition strategies and biogeochemical P cycling patterns in the respective ecosystems. Our study demonstrates that combined wet‐chemical soil P fractionation and synchrotron‐based XANES spectroscopy provides substantial novel information on the P speciation of forest soils.     

湖北恩施几种典型土壤对氟的吸附与解吸特性

采用室内试验方法,研究了恩施六种土壤氟吸附的特性。结果表明:(1)不同土壤的吸附量差异很大,表现为黄粘泥水田土>红粘壤土>泥质岩黄壤土>红砂泥水田土>中性紫色土>黑色石灰土;同一土壤的吸附量随氟离子初始浓度的增大而增大。不同土壤的解吸量在低浓度时差异不明显,高浓度时表现为黄粘泥水田土、红粘壤土、泥质岩黄壤土、红砂泥水田土>中性紫色土>黑色石灰土;同一土壤的解吸量随氟离子初始浓度的增大而增大。(2)Langmuir公式可以很好地描述土壤氟吸附的特性,Freundlich公式能够较好地描述土壤对氟的吸附。(3)去除铁、铝氧化物后土壤氟吸附量明显降低;草酸能够促进土壤对氟的吸附;共存PO43-能够抑制土壤对氟的吸附。     

Interaction of silicon,iron, and manganese in rice (oryza sativa L.) rhizosphere at low ph in relation to rice growth

Rice (Oryza Sativa L.) nutrition is influenced by the interactions of (Iron) Fe, (Manganese) Mn, and (Silicon) Si in the rhizosphere. A greenhouse experiment was carried out with rice grown in four low‐pH soils (a granitic lateritic red earth, a paddy soil from the red earth, a basaltic latosol, and a paddy soil from the latosol). Rice was grown in pots with the roots confined in rhizobags and the rhizosphere soil and nonrhizosphere soil were analyzed separately for active Si, Fe, and Mn by Tamm's solution. Silicon and Mn concentrations were lower in the rhizosphere soil indicating a depletion which was higher for the basaltic soils and for the paddy soils. Iron concentrations were higher in the rhizosphere soil indicating an accumulation that was higher for granitic soils and for the upland soils. Plant growth response was due mostly to Mn with the basaltic soils supplying toxic amounts and the granitic soils being deficient. Iron accumulation in the rhizosphere caused lower plant uptake of Si, phosphorus (P), and calcium (Ca) and higher Fe and aluminum (Al) absorption leading to the conclusion that Fe deposition on plant roots and in rhizosphere may block the uptake of other nutrients.