Impact of contaminants bound to suspended particulate matter in the context of flood events

Purpose  

The presented study investigated on contamination of suspended particulate matter (SPM) in rivers that was sampled long-term and with higher frequency during a flood event at the river Rhine. It was conducted to determine in vitro biological effects as well as to identify and quantify compound classes and effective contaminants. Research was part of investigation on hazards of contaminants bound to SPM to inundated sites and retention areas that are inundated during flood events.     

Density-driven underflows with suspended solids in Lake Constance

Purpose

In Lake Constance, on average, underflows occur several times a year due to flood events in the River Rhine. During these events, large amounts of sediments as well as oxygenated riverine water are transported into the hypolimnion of the lake. The purpose of this study was to quantify the effect on deep water renewal and study the factors that influence the occurrence of underflows.

Materials and methods

A three-dimensional hydrodynamic model was set up. To calibrate the model, the flood event of August 2005, whose peak discharge was slightly below the discharge with a return period of 100 years, was simulated and results compared to measurements. The model was then validated simulating several further, smaller underflow events. In a model study of the flood event of June 2012, the influence of underflows to deep water renewal was investigated by using different tracers to mark the inflowing water as well as the epilimnic water. By varying the discharge, suspended solid concentration, and water temperature of the River Rhine in the model, the influence of these factors on the occurrence and spreading of underflows was studied.

Results and discussion

The simulations show that the model was able to reproduce the occurrence and spreading of under-flows satisfactorily. The tracer study indicates that a fair amount of epilimnic water was entrained into the underflow and therefore enhances deep water renewal. It was shown that the main influence factor on the occurrence of underflows was the concentration of suspended solids, followed by the discharge. Water temperatures have a relatively small influence. These results are confirmed by two underflow events in 2013 which occurred due to extreme high concentrations of suspended sediments without any increase in discharge. Although not part of the model study, it was suspected that the grain size distribution of the suspended solids also exerts a significant effect on the underflow.

Conclusions

The hydrodynamic model was able to reproduce the main processes involved in the occurrence of underflows and therefore is a suitable tool for the investigation of influence factors on the build-up of underflows as well their effects on the lake’s sedimentation and erosion processes and water quality.

     

The Rhine delta—a record of sediment trapping over time scales from millennia to decades

Purpose  

At the land–ocean interface, large river deltas are major sinks of sediments and associated matter. Over the past decennia, many studies have been conducted on the palaeogeographic development of the Rhine delta and overbank deposition on the Rhine floodplains. This paper aims to synthesise these research results with special focus on the amounts and changes of overbank fines trapped in the Rhine delta and their controls at different time scales in the past, present and future.     

Sediment management and the renewability of floodplain clay for structural ceramics

Background, aim, and scope  

The Netherlands has vast resources of clay that are exploited for the fabrication of structural ceramic products such as bricks and roof tiles. Most clay is extracted from the so-called embanked floodplains along the rivers Rhine and Meuse, areas that are flooded during high-discharge conditions. Riverside clay extraction is—at least in theory—compensated by deposition. Based on a sediment balance (deposition versus extraction), we explore the extent to which clay can be regarded as a renewable resource, with potential for sustainable use. Beyond that, we discuss the implications for river and sediment management, especially for the large engineering works that are to be undertaken to increase the discharge capacities of the Rhine and Meuse.     

Contamination history of suspended river sediments accumulated in oxbow lakes over the last 25 years

Background, aims, and scope  Embankment of meandering river systems in many industrial areas results in the formation of artificial oxbow lakes that may act as perennial or intermittent traps for river sediments. Their deposits can be dated using a combination of historical and stratigraphic data, providing a good means to study historical records of contamination transported by rivers. Contamination history over the last few decades is of special significance for Central and Eastern Europe as it can reflect high pollutant levels in the second half of the twentieth century and the subsequent improvement after the fall of the Iron Curtain. The purpose of this study was to investigate recent sediments of an oxbow lake of the Morava River, Czech Republic, their stratigraphic records, sediment architecture, and history of contamination. Materials and methods  Seven ground-penetrating radar (GPR) profiles and three sediment cores up to 4 m deep were studied. The stratigraphy of the cores was inferred from visible-light spectrophotometry, X-ray radiography, grain size analysis, and semiquantitative modal analysis of sandy fractions. The sediments were dated using the ¹³⁷Cs mass activity and combinations of stratigraphic and historical data. The cores were sampled for concentrations of heavy metals and persistent organic pollutants. Wet sampled, lyophilized, and sieved sediments were extracted and analyzed for heavy metals by inductively coupled plasma mass spectrometry (ICP-MS) of aqua regia leachate and for persistent organic pollutants by gas chromatography (GC-ECD and GC-MS). Results  Three distinct sedimentary sequences (S1, S2, and S3) were identified. The basal sequence S1 represents river channel sediments deposited before the formation of the oxbow lake, most likely before the 1930s. The boundary between the S1 and S2 sequence correlates with the level of sediment dredging from 1981 evidenced from historical data. The overlying sequences S2 and S3 represent a postdredging sediment wedge, which progrades into the lake. ¹³⁷Cs dating revealed a distinct Chernobyl 1986 peak at ∼150 cm depth inferring sedimentation rates up to 7.7 cm/year. Sediment contamination abruptly increased from the pre-1930s deposits to the post-1981 deposits. The concentration levels increased two to five times for Pb, As, Zn, and Cu, about 10 to 15 times for Cr, Sb, and Hg, up to 34 times for Cd, and 25 to 67 times for DDTs, PCBs, and PAHs. The concentrations of most contaminants remained approximately constant until the late 1980s when they started to decrease slowly. The decreasing trends were most prominent for heavy metals and anthracene, less prominent for DDTs, and almost absent for PCBs and most PAHs. Discussion  Different temporal and spatial patterns for various contaminants make it possible to distinguish between anthropogenic point sources from local industry (anthracene, Cr, Cd), possible diffuse sources (most PAHs), and geological background (V, Co, Ni, and Mo). The observed recent trends in heavy metal and persistent organic pollutant contamination are generally consistent with data from other Central European rivers. The roughly balanced contamination levels in sediments from the lake and the adjacent river channel suggest that the oxbow lake deposits reflect immediate levels of the contamination bound to suspended particulate matter passing through the river. Conclusions  The investigated oxbow lake accumulated suspended sediment from Morava River, developing a thick sedimentary body. The sediments offer a good time framework to study historical contamination of the river on a decade time scale. Continuous contamination trends can be traced back to the early 1980s. The results show that stratigraphic analysis of cores has a good potential for identification of uninterrupted historical trends and unconformities, e.g., due to dredging. Recommendations and perspectives  Oxbow lakes may provide an alternative to floodplains and reservoir deposits when studying river contamination history. High sedimentation rates of up to 7.7 cm/year offer a very good stratigraphic resolution, making it possible to study contamination patterns on annual or even seasonal time scales. On the other hand, oxbow lakes may represent long-term contamination stores, which are unlikely to be redistributed by river erosion and, hence, may possess significant environmental risks for the farther future.     

Consequences of hydrological events on the delivery of suspended sediment and associated radionuclides from the Rh?ne River to the Mediterranean Sea

Purpose

Almost 20 nuclear reactors are situated along the Rh?ne valley, representing Europe??s largest concentration of nuclear power plants. The fate of suspended sediments and natural and artificial particle-bound radionuclides in relation to extreme hydrological events was assessed at the lower course of the Rh?ne River, which provides the main source of water and sediment inputs to the northwestern Mediterranean Sea.

Materials and methods

We sampled water at a high frequency over the period 2001?C2008 and measured suspended particulate matter (SPM) loads and particle-bound natural and artificial radionuclide concentrations at the SORA observatory station in Arles, France. We monitored various hydrological events (either natural or anthropogenic origin) and characterize their influence on concentrations and fluxes.

Results and discussion

The relationship between SPM concentration and the very wide range of water discharges did not differ significantly from previous periods, indicating no significant shift in the average sediment delivery over the last 20?years. Unexpected hydrological events of anthropogenic origin, in particular those associated with flushing of reservoirs that are generally not captured by sampling strategies, were recorded and were shown to transfer significant additional sediment and associated contaminants towards the marine environment. Concentrations of anthropogenic radionuclides associated with sediment (i.e., ¹³⁷Cs, ⁶⁰Co, ⁵⁴Mn, ^110mAg, and Pu isotopes) varied over two to three orders of magnitude during periods of low and moderate flow due to variations in the liquid release from nuclear facilities. Except for Pu isotopes, the concentrations of the various particle-bound radionuclides generally showed a decreasing trend with increasing discharge, revealing the geochemical or anthropogenic background values, and providing a useful flood fingerprint for this large fluvial system before its entry into the marine environment.

Conclusions

Our approach produced key data on the level and fate of suspended solids and radionuclide concentrations during flood events occurring in a large river system that could be contaminated by chronic or accidental radioactive releases. These results are of fundamental importance for further interpretations of sediment dynamics at the river mouth.     

Modeling desorption kinetics of a persistent organic pollutant from field aged sediment using a bi-disperse particle size distribution

Purpose  

With the predicted climate change, it is expected that the chances of river flooding increase. During flood events, sediments will resuspend and when sediments are polluted, contaminants can be transferred to the surrounding water. In this paper we discuss a numerical intraparticle diffusion model that simulates desorption of dieldrin from a suspension of contaminated porous sediment particles with a well-characterized particle size distribution. The objective of this study was to understand the desorption rate (flux) of dieldrin from a suspension of field-aged sediment at different hydraulic retention times (HRT) of the aqueous phase and to elaborate the effect of particle-size distribution on mass transfer.     

Spectral fingerprinting: characterizing suspended sediment sources by the use of VNIR-SWIR spectral information

Purpose

Knowledge of sediment sources is a prerequisite for sustainable management practices and may furthermore improve our understanding of water and sediment fluxes. Investigations have shown that a number of characteristic soil properties can be used as “fingerprints” to trace back the sources of river sediments. Spectral properties have recently been successfully used as such characteristics in fingerprinting studies. Despite being less labour-intensive than geochemical analyses, for example, spectroscopy allows measurements of small amounts of sediment material (>60 mg), thus enabling inexpensive analyses even of intra-event variability. The focus of this study is on the examination of spectral properties of fluvial sediment samples to detect changes in source contributions, both between and within individual flood events.

Materials and methods

Sediment samples from the following three different origins were collected in the Isábena catchment (445 km²) in the central Spanish Pyrenees: (1) soil samples from the main potential source areas, (2) stored fine sediment from the channel bed once each season in 2011 and (3) suspended sediment samples during four flood events in autumn 2011 and spring 2012 at the catchment outlet as well as at several subcatchment outlets. All samples were dried and measured for spectral properties in the laboratory using an ASD spectroradiometer. Colour parameters and physically based features (e.g. organic carbon, iron oxide and clay content) were calculated from the spectra. Principal component analyses (PCA) were applied to all three types of samples to determine natural clustering of samples, and a mixing model was applied to determine source contributions.

Results and discussion

We found that fine sediment stored in the river bed seems to be mainly influenced by grain size and seasonal variability, while sampling location—and thus the effect of individual tributaries or subcatchments—seem to be of minor importance. Suspended sediment sources were found to vary between, as well as within, flood events; although badlands were always the major source. Forests and grasslands contributed little (<10 %), and other sources (not further determinable) contributed up to 40 %. The analyses further suggested that sediment sources differ among the subcatchments and that subcatchments comprising relatively large proportions of badlands contributed most to the four flood events analyzed.

Conclusions

Spectral fingerprints provide a rapid and cost-efficient alternative to conventional fingerprint properties. However, a combination of spectral and conventional fingerprint properties could potentially permit discrimination of a larger number of source types.     

Investigation on soil contamination at recently inundated and non-inundated sites

Purpose  

This study was carried out to determine hazards of particle-bound contaminants in rivers to retention areas close to public well fields in the context of flood events. The focus was on the assessment of soil contamination at a planned retention area. Soil core samples were chemically and biologically analyzed. Samples were fractionated to identify and compare contaminant loads and biological effects of soil and flood suspended particulate matter (SPM).     

Vertical distributions of PAHs in the sediments of four lakes in Japan

Purpose

The purpose of this study was to elucidate historical trends, spatial variations, and the sources of polycyclic aromatic hydrocarbons (PAHs) pollution in several Japanese lakes.

Materials and methods

The vertical distributions of PAHs in the core samples of sediments taken at several points in lakes Kasumigaura, Suwa, Kizaki, and Shinji were determined using a gas chromatograph equipped with a mass selective detector and combined with chronological information and the physical/elemental properties of the sediment.

Results and discussion

Seventeen related compounds (congeners) typically had concentration peaks at sediment depths corresponding to the 1960s to 1970s. In Lake Shinji and one bay of Lake Kasumigaura, there was a tendency for PAH concentrations to increase downstream; in contrast, another bay of Lake Kasumigaura showed the reverse trend. During big flood events, the fluxes of PAHs increased due to large inputs of particulate matter, although PAH concentrations were reduced. For the four study lakes and other similar lakes, PAH concentrations of surface sediments were approximately proportional to population densities in the respective watersheds, while the total input of PAHs to the lakes were correlated with their population and watershed area. The source apportionment analysis using isomer ratios for the congener profiles indicated that the principal sources of the PAHs in the lake sediments were gasoline and/or diesel engine exhausts and biomass burning.

Conclusions

The observed concentration peaks showed a deterioration of the chemical quality of atmospheric conditions around 1960?C1970 and a recent tendency for their amelioration. Between-lake differences suggest that the influence of human activity in the watersheds influences sediment PAH concentrations. The PAH sources were identified to be of pyrogenic origin.     

Water infiltration in urban soils and its effects on the quantity and quality of runoff

Purpose  

Urban soil characteristics, especially soil physical properties, are subject to dramatic changes due to compaction by intensive human activities, which may cause frequent flood events during the rainy seasons. The aim of this study was to explore the water infiltration characteristics of urban soils with different degrees of compaction and to determine the effects of infiltration on environmental problems in urban areas.     

Delayed immobilization of heavy metals in soils and sediments under reducing and anaerobic conditions; consequences for flooding and storage

Purpose  

The consequences of permanent inundation and storage of flood plain soils and aquatic sediments on metal mobility were studied. The main goal was to quantify kinetic mobilisation processes in order to pinpoint the conditions that pose emission risks to groundwater and surface waters.     

Responses of flood peaks to land use and landscape patterns under extreme rainstorms in small catchments - A case study of the rainstorm of Typhoon Lekima in Shandong,China

Investigations of the formation mechanisms of flood peaks in small catchments facilitate flood prediction and disaster prevention under extreme rainstorms. However, there have been few studies on the responses of flood peaks to land use landscape patterns using field surveys during extreme rainstorm events. Based on field data from 17 small catchments near the rainstorm center of Typhoon Lekima, 7 landscape indices were chosen. The flood peak and its sensitivity to the land use landscape were investigated by combining remote sensing interpretation and related analysis. The conclusions are as follows: (1) The peak discharge of the small catchment was 2.36–56.50 m³/s, the peak modulus was 8.00–48.89 m³/(s·km²), and the flood index K ranged from 3.61 to 4.55. (2) Under similar rainfall conditions, the flood peak modulus, K and the proportion of sloping cropland had significantly positive correlations (p < 0.05). The flood peak modulus was significantly negatively correlated with the proportion of forest-grassland and terrace (p < 0.05), and K and the proportion of forest-grassland and terraced land exhibited a negative correlation. (3) The flood peak modulus and K were positively correlated with the landscape fragmentation. (4) The sensitivities of small catchments to floods were evaluated to be moderate compared to K values from other studies. The ability of small catchments to cope with extreme rainstorms can be improved by increasing the areas of forest-grassland, and terraces and reducing landscape fragmentation. Our results could be applied to provide a basis for land use planning and support for the response against disasters caused by extreme floods.     

Factors controlling sediment trapping in two freshwater tidal wetlands in the Biesbosch area,The Netherlands

Purpose

A thorough understanding of mechanisms controlling sedimentation and erosion is vital for a proper assessment of the effectiveness of delta restoration. Only few field-based studies have been undertaken in freshwater tidal wetlands. Furthermore, studies that measured sediment deposition in newly created wetlands are also sparse. This paper aims to identify the factors controlling the sediment trapping of two newly created freshwater tidal wetlands.

Materials and methods

Two recently re-opened polder areas in the Biesbosch, The Netherlands are used as study area. Field measurements of water levels, flow velocities, and turbidity at both the in- and outlet of the areas were carried out to determine the sediment budgets and trapping efficiencies under varying conditions of river discharge, tide, and wind in the period 2014–2016.

Results and discussion

Short-term sediment fluxes of the two study areas varied due to river discharge, tide, and wind. A positive sediment budget and trapping efficiency was found for the first study area, which has a continuing supply of river water and sediment. Sediment was lost from the second study area which lies further from the river and had a lower sediment supply. The daily sediment budget is positively related to upstream river discharge, and in general, export takes place during ebb and import during flood. However, strong wind events overrule this pattern, and trapping efficiencies decrease for increasing wind strengths at mid-range river discharges and for the highest river discharges due to increased shear stress.

Conclusions

Delta restoration, based on sedimentation to compensate for sea-level rise and soil subsidence, could only be effective when there is a sufficient supply of water and sediment. Management to enhance the trapping efficiency of the incoming sediment should focus on directing sufficient river flow into the wetland, ensuring the supply of water and sediment within the system during a tidal cycle, creating sufficiently large residence time of water within the polder areas for sediment settling, and decreasing wave shear stress by the establishment of vegetation or topographic irregularities.

     

Sediment dynamics and the role of flash floods in sediment export from medium-sized catchments: a case study from the semi-arid tropical highlands in northern Ethiopia

Purpose  

The Ethiopian highlands are a fragile environment characterized by steep slopes, intense rainfall, a sparse vegetation cover, and the occurrence of flash floods. Although important efforts have been made to mitigate the ongoing soil erosion and land degradation problems, the sediment dynamics at medium-sized catchment scale (100–10,000 km²) are not fully understood. Therefore, this study aims to provide a better understanding of sediment export processes and the importance of flash flood events in semi-arid tropical catchments.     

A mid–late Holocene flood record from the alluvial reach of the Mahi River, Western India

Flooding of rivers in India is linked with the peak monsoons. Investigating the linkage between monsoonal patterns and flood history of various rivers is therefore of fundamental importance in the Indian context. In the present study, the slackwater deposits in the alluvial reaches of the Mahi river basin, western India have been documented. These occur in the ravines incised during the early Holocene on an alluvial surface comprising sediments of Late Pleistocene age. The slackwater deposits occur at elevations up to 20 m from the present river level and extend to about 500 m inland. The carbonate rich sediments forming the ravine cliffs have provided bank stability and the dissections in the ravines have helped in the accumulation of slackwater deposits due to backflooding of the floodwater from the main channel. Recent gullies have incised the sediments and exposed deposits related to major flood events. The best exposures of slackwater deposits have been observed at Dodka. The sediment succession of the slackwater deposits is dominated by bedsets and laminasets of silt and sand separated by colluvial sediments. Four events of flood deposition occurred during the mid to late Holocene. Two units of slackwater deposits, SWD 2 and 4 have been dated by IRSL at 4.6 ± 1 ka and 1.7 ± 0.5 ka. The stratigraphy of these deposits indicates that the first two slackwater units (SWD1 and SWD2) have resulted due to flooding in a regime of intense monsoon. The other two units, however, represent extreme high magnitude floods in a period of low average precipitation.     

Effects of flood events on the genetic structure of riparian populations of the grassland plant Origanum vulgare

River regulation results in the disconnection and increased fragmentation of habitats in the river corridor. In this study, we investigated the within-population genetic variability and among-population genetic differentiation of 21 populations of Origanum vulgare along the River Meuse, using dominant AFLP markers, in order to asses the restoration potential of this species in the context of current river restoration efforts. The average observed within-population genetic diversity was high and suggests that river regulation and associated fragmentation of the populations have not strongly affected genetic diversity. The genetic differentiation between populations was high (Φ_ST = 0.24) and can be explained by founder effects, rather than by genetic drift in isolated populations. We also detected a pronounced hierarchic spatio-temporal structure in genetic variation. This structure can be related to the irregular patterns in the flow regime of the River Meuse. Large floods are the major vector of genetic structure, but geographic upstream proximity, probably mediated by small floods, also has an important effect on genetic structure. Three distinct groups of populations were observed, two of which could be related to the extreme flood events of the mid-nineties of last century. Assignment tests revealed occasional long-distance seed dispersal with extreme flood events and local colonisation with more regular floods. Our study species optimally took benefit of the opportunities offered by the river restoration programme, with a strong colonisation after floods, and illustrates the need for maintaining river dynamics to conserve and restore genetic diversity.     

Radionuclides and stable elements in the sediments of the Yesa Reservoir,Central Spanish Pyrenees

Purpose  

The sediments accumulated in the Yesa Reservoir (Central Spanish Pyrenees) have greatly decreased its water storage capacity and are a major threat to the sustainability of water resources in the region. This study examines the contents of radionuclides and stable elements in the reservoir sediments and relates their variations with the sediment composition and local sedimentary dynamics, particularly flood frequency and intensity, which are responsible for changes in the main supply and distribution of radionuclides in the basin.     

Hydrosedimentology of nested subtropical watersheds with native and eucalyptus forests

Purpose

Information on the effects of eucalyptus forests on hydrosedimentological processes is scarce, particularly at the catchment scale. Monitoring and mathematical modeling are efficient scientific tools used to address the lack of information for natural resource management and the representation and prediction of those processes. This study evaluates the effects of eucalyptus cultivation on hydrosedimentological processes in watersheds and to use the Limburg soil erosion model (LISEM) to represent and predict hydrological processes.

Material and methods

The study was conducted in two forested watersheds: the main watershed (94.46 ha) and a nested sub-watershed (38.86 ha), both cultivated with eucalyptus and residual riparian native forest, located in southern Brazil. Hydrosedimentalogical monitoring was conducted from 16th February 2011 to 31st December 2012, and LISEM model calibrations were performed on the bases of six storms events.

Results and discussion

The sediment yield for 2011 was 41.6 Mg km^?2 and 38.5 Mg km^?2 for the watershed and sub-watershed, respectively. An extreme event in 2012 provided greater sediment yield for the sub-watershed (99.8 Mg km^?2) than that for the watershed (51.7 Mg km^?2). Rainfall events with a greater maximum intensity generated rapid discharge and suspended sediment concentration responses in the sub-watershed due to the smaller drainage area and steeper landscape. In the main watershed, the accumulation of flood waves occurred for most events, with less steep hydrographs, and a later occurrence of the discharge peak after that of the sub-watershed. The LISEM adequately reproduced the peak discharge and runoff for the calibrated events; however, the peak time and the shape of the hydrograph were not adequately represented.

Conclusions

The hydrosedimentological patterns of the watershed and sub-watershed, both cultivated with eucalyptus, was characterized by sedimentographs preceding hydrographs during rainfall–runoff events where scale effects occur, with maximum discharge and specific sediment yield greater in the watershed than that in the sub-watershed. Empirical models based on hydrologic variables may be used for estimating the suspended sediment concentration and sediment yield. Therefore, LISEM may be used for the prediction of hydrological variables in these forested watersheds.     

The impact of environmental changes on the sediment loads of Norwegian rivers

The impact of unusual events on the sediment dynamics in rivers is discussed in this paper. The increase in the number of extreme precipitation events and other unusual weather events in Norway strongly suggests that weather conditions are changing. It is difficult to monitor sediment transport during large magnitude floods. It is however well known that they may deliver substantial amounts of sediment. The suspended sediment load in the upper Atna river during the springflood in 1995 was 44 times the mean load measured during the preceding years. The recurrence interval of this flood was estimated to be 100–200 years. The conditions during the occurrence of a particular flood event may also be of considerable importance and measurements during rainfall on frozen ground have indicated unusually high runoff and erosion rates.The seasonal distribution of runoff in several parts of Norway has changed in recent years and higher winter temperatures have produced an increase in the frequency of flood events. A very long lasting flood caused by a prolonged period of rain occurred in the Vikka stream during September to December 2000. The availability of sediment increased with the increasing soil moisture content in the area. As the ground became saturated, more active slope processes caused erosion rates to increase markedly. The combined effects of climate change and human impact on sediment transport in rivers appear to enhance downstream sediment delivery. Flood protection works along river channels prevent sediment from being deposited on the floodplain. River channels that have been lowered in order to reduce groundwater levels in agricultural floodplain areas will experience the same effect. During the last decade extensive ecological changes have taken place in the coastal areas of southern Norway as 90% of the sugar kelp forest has been lost. This change has been attributed to an apparent increase in sediment delivery to the sea along with a rise in sea temperatures.