A new approach to evaluate the effect of moisture on heat transfer of thermal protective clothing under flashover

It’s urgent to investigate moisture effect on thermal protection of thermal protective clothing in simulated fire scene as accurately as possible. The current bench top tests can’t evaluate thermal protective performance (TPP) of fabrics under microclimate with high temperature and relative humidity (RH). In this paper, to well investigate effect of different RH under microclimate on thermal protective performance of flame-retardant fabrics exposed to flashover, a new modified TPP testing apparatus was developed. It consisted of a typical TPP tester and RH adjustable microclimate chamber. Three kinds of air gaps under fabrics were also employed to simulate different spaces between skin and clothing. The results showed that the temperature increment under microclimate of 35 % RH was highest, and that of 95 % RH was lowest. There was significant temperature difference found among above three adjusted environment. Time required of temperature rise to 12 oC highly prolonged as RH became higher. It could be deduced that the effect of RH on heat transfer became significant as air gap increasing; if the air gap width still increased, the moisture effect diminished. The newly developed testing apparatus could be well used to evaluate the moisture effect on thermal protective performance of flame-resistant fabrics.     

Effects of air gap entrapped in multilayer fabrics and moisture on thermal protective performance

Thermal protection of firefighter protective clothing is greatly influenced by the air gap entrapped and moisture in clothing. In this paper, the effects of air gap size and position on thermal protective performance exposed to 84 kW/m² heat source were investigated. Water was also added to thermal liner to understand the effect of air gap coupled with moisture on thermal protection. It was indicated that the TPP of fabrics system increased with the air gap size. The air gap position also greatly influenced the heat transfer during exposure to flash fire. Moisture added weakened the positive effect of air gap size when the air gap exists far from heat source, and almost eliminated the favorable effect of air gap position. However, when there is no air gap or small air gap between outer shell fabric and moisture barrier, moisture increased the thermal protection performance of multilayer fabrics system. The results obtained suggested that certain air gap entrapped in fabrics system and clothing microclimate could improve thermal protection, and the complicated effect of moisture should also be considered.     

Mathematical simulation and experimental measurement of clothing surface temperature under different sized air gaps

The influence of air gap thickness on clothing surface temperature is analyzed by means of experimental and simulated methods. A three-dimensional body scanner is used to determine the air gap distribution between different-sized garments. The clothing surface temperature is measured by an infrared thermal camera to evaluate the heat transfer through air gap layer. The combination of two non-contact measuring techniques is a novel way to investigate the relationship between air gap thickness and clothing surface temperature. A mathematical model is set up to simulate the heat and moisture transfer from skin to environment by including the sensible and latent heat transfer through air gap layer under clothing, fabric layer and boundary air layer adjacent to the fabric. The established mathematical model is used to forecast the surface temperature and evaluate the heat transfer capacity of different sized garments.     

The relation between thermal protection performance and total heat loss of multi-layer flame resistant fabrics with the effect of moisture considered

Eight multi-layer, flame resistant fabrics were tested for thermal protective performance (TPP) and total heat loss (THL) under four levels of moisture content of the fabrics. Moisture level in the fabrics was statistically significant correlated with both TPP and THL values. With moisture level taken into account, there was no significant negative correlation between TPP and THL. The relation between thermal protection and total heat loss performances of multi-layer fire resistant fabrics was much more complicated considered with variable factors of user situation.     

Application of electrospun polyurethane web to breathable water-proof fabrics

Electrospun web may possibly be widely applied to protective garments or specialty textiles due to its high level of protection as well as comfort. Of particular interest in this study is to develop waterproof-breathable fabric by applying electrospun web of polyurethane directly onto the substrate fabric. The optimal electrospinning condition was examined with regards to the concentration, applied voltage and tip-to-collector distance. Solvent-electospinning of polyurethane was performed at the optimum condition, using N,N-dimethylacetamide as solvent. The thickness of 0.02 mm of electrospun web was applied onto the polyester/nylon blended fabric. For comparison, the polyester/nylon fabrics were coated with 0.02 mm thickness of polyurethane resin membranes adopting four different conditions. The electrospun PU web/fabric was compared to resin coated fabrics in terms of water-proof and breathable properties. The electrospun web applied fabric showed higher air permeability, vapor transmission, and thermal insulation properties than resin coated fabrics, which can be translated as greater comfort sensation of electrospun applied fabrics. However, water resistance value of electrospun web applied fabric did not reach that of resin coated fabrics.     

Protective performance of thermal protective clothing assemblies exposed to different radiant heat fluxes

Three layered clothing assemblies were constructed from commercial heat protective textile clothing materials for outer, middle and inner layers. Thermal liners, used as middle layer, were prepared from Nomex fibres of two different fineness keeping other parameters constant. Different three layered combinations of fabrics were compared for radiant heat protective performance based on the estimate of burn injury time using Stoll’s curve. Analysis of experimental results showed that characteristics of the outer layer fabric and its interaction with applied heat flux are important factors that affect thermal response of the clothing assemblies. Fineness of the constituent fibres of nonwoven thermal liner was found to significantly affect the protective performance. Thermal properties, porosity, optical properties of the clothing layers found to affect heat protection provided by clothing assembly.     

Comfort characteristics of fabrics made of compact yarns

Comfort is one of the most important aspects of clothing. Thermal comfort is related to fabric’s ability to maintain skin temperature and allow transfer of perspiration produced from the body. Properties like thermal resistance, air permeability, water vapor permeability, and liquid water permeability are suggested as critical for thermal comfort of clothed body. In this study the fabrics developed from the EliTe compact yarns are compared with the fabrics made from normal yarns. The thickness of the fabrics made from EliTe® compact yarns is also slightly less than the fabrics made from normal yarns. Fabrics made from EliTe® compact yarns have shown greater air permeability as compared to the fabrics made from normal yarns. It is observed that, thermal resistivity values of the fabrics developed from EliTe® compact yarns are lower than the fabrics made from normal yarns indicating they are cooler fabrics compared to normal fabrics. Fabrics developed from the EliTe® compact yarns have shown slightly higher values of MVTR (moisture vapor transmission rate) as compared to the fabrics made from the normal yarns. The wicking characteristic of fabrics developed from EliTe® compact yarns was slightly higher than the fabrics developed from normal yarns.     

Transport properties of layered fabric systems based on electrospun nanofibers

Layered fabric systems with electrospun polyurethane fiber web layered on spunbonded nonwoven were developed to examine the feasibility of developing protective textile materials as barriers to liquid penetration using electrospinning. Barrier performance was evaluated for layered fabric systems, using pesticide mixtures that represent a range of surface tension and viscosity. Air permeability and water vapor transmission were assessed as indications of thermal comfort performance. Protection performance and air/moisture vapor transport properties were compared for layered fabric systems and existing materials for personal protective equipment (PPE). Layered fabric systems with electrospun nanofiber web showed barrier performance in the range between microporous materials and nonwovens used for protective clothing. Layered fabric structures with the web area density of 1.0 and 2.0 g/m² exhibited air permeability higher than most PPE materials currently in use; moisture vapor transport was in a range comparable to nonwovens and typical woven work clothing fabrics. Comparisons of layered fabric systems and currently available PPE materials indicate that barrier/transport properties that may not be attainable with existing PPE materials could be achieved from layered fabric systems with electrospun nanofibrous web.     

Study on heat and moisture vapour transmission characteristics through multilayered fabric ensembles

A detailed study on the heat and moisture vapour transmission characteristics of different types of single and multi-layered fabric ensemble by using sweating guarded hot plate (SGHP) has been reported in the present paper. A comparison has been made on thermal and moisture vapour transmission properties of five different insulative fabrics, namely, knitted-raised fabric, needle punched nonwoven, through air bonded nonwoven, spunbonded-through air bonded sandwich nonwoven and warp knitted spacer fabric and three different coated fabrics, namely, plain woven rubber coated, plain woven polyester polymer coated and plain woven polytetrafluoroethylene (PTFE) coated fabric, used for thermal insulation purpose. ANOVA has been conducted to analyse the significance of type of insulative and coated fabrics used. Sandwich nonwoven fabric which has higher thickness and porosity shows higher thermal resistance followed by through air bonded fabric, raised fabric, needle punched fabric and spacer fabric. Spacer fabric shows lesser evaporative resistance due to its lesser thickness and larger aperture size, which increases the diffusion of moisture vapour. Needle punched fabric shows slightly higher evaporative resistance than spacer fabric, followed by raised fabric, through air bonded fabric and sandwich nonwoven fabric. Permeability index of different multilayered fabric ensembles are also compared.     

Evolution of moisture management behavior of high-wicking 3D warp knitted spacer fabrics

Moisture management behavior is a vital factor in evaluating thermal and physiological comfort of functional textiles. This research work studies functional 3 dimensional (3D) warp knitted spacer fabrics containing high-wicking materials characterized by their profiled cross section. These spacer fabrics can be used for protective vest to absorb a user’s sweat, to reduce the humidity and improve user’s thermal comfort. For this reason, different 3D warp knitted spacer fabrics were produced with functional fiber yarns in the back layer of the fabric (close to the body) and polyester in the front and middle layers (outer surface). Comfort properties such as air and water vapor permeability and wicking and other moisture management properties (MMP) of different fabric samples were measured. It is demonstrated that by using profiled fibers such as Coolmax fiber, moisture management properties of spacer fabrics can be improved, enabling them to be use as a snug-fitting shirt worn under protective vests with improved comfort.     

Effects of athletic T-shirt designs on thermal comfort

This paper reports on an experimental investigation of the effects of T-shirts design on clothing thermal comfort measured in terms of clothing thermal insulation and moisture vapour resistance. Ten short sleeved T-shirts of varying opening styles and mesh styles were designed and produced for testing on the sweating fabric manikin-Walter. Clothing thermal insulation and moisture vapour resistance of the T-shirts were measured when the manikin simulates walking motion and standing posture. The results showed that, the positions of openings and ventilation panels affects the total thermal insulation and vapour resistance; among the various designs tested, openings applied at two vertical side panels along the side seams can most effectively release heat and moisture from the body.     

Effect of low temperature plasma treatment on wool fabric properties

Low temperature plasma (LTP) treatment was applied to wool fabric with the use of a non-polymerizing gas, namely oxygen. After the LTP treatment, the fabric properties including low-stress mechanical properties, air permeability and thermal properties, were evaluated. The low-stress mechanical properties were evaluated by means of Kawabata Evaluation System Fabric (KES-F) revealing that the tensile, shearing, bending, compression and surface properties were altered after the LTP treatment. The changes in these properties are believed to be related closely to the inter-fiber and inter-yarn frictional force induced by the LTP. The decrease in the air permeability of the LTP-treated wool fabric was found to be probably due to the plasma action effect on increasing in the fabric thickness and a change in fabric surface morphology. The change in the thermal properties of the LTP-treated wool fabric was in good agreement with the above findings and can be attributed to the amount of air trapped between the yarns and fibers. This study suggested that the LTP treatment can influence the final properties of the wool fabric.     

Structural characterization of LbL assembled multilayers by using different polyelectrolytes on cotton fabrics

An alternative approach to application of chitosan based on layer by layer (LbL) assembled technique is studied in this paper. For this aim, chitosan (CHT) was used as a bio-based cationic polyelectrolyte and pentasodium tripolyphosphate (TPP) and poly(sodium 4-styrene sulfonate) (PSS) were selected as anionic polyelectrolyte. TPP/CHT and PSS/CHT based bilayers were fabricated on the cationized woven cotton fabrics via layer-by-layer self-assembly technique. The characterization of coatings on the fabric surface in terms of surface appearance, atomal content, and chemical bondings were made in detail through SEM, XPS, and FTIR-ATR analysis. Also, the antibacterial activity, air permeability, and water contact angle were measured. Surface analyses demonstrate the interaction between TPP, PSS and chitosan separately. XPS spectra also showed the existence of LbL deposition over cotton substrates in terms of both elemental composition and the presence of different types of bondings on the fabric surface. The antibacterial activity analysis revealed that the modified cotton fabric with the addition of CHT/TPP and CHT/PSS bilayers could increase the degree of inhibition on K. pneumanie and S. aureus bacteria.     

Synthesis and Characterization of Waterborne Polyurethane Modified by Acrylate/nano-ZnO for Dyeing of Cotton Fabrics

Waterborne polyurethane modified by acrylate/nano-ZnO (PUA/ZnO) was synthesized and used to improve the wet rubbing fastness of reactive dyed cotton fabric. The reaction conditions were optimized and the products were characterized by FT-IR, TG, DSC, SEM, and particle size distribution. The dyed cotton fabrics were finished with PUA/ZnO emulsion and the rubbing fastness, ultraviolet resistant property, and wearability of treated fabrics were measured. The wet rubbing fastness of treated fabrics was increased by about 0.5–1 rate to achieve 3–4 rate, and the ultraviolet protection factor (UPF) achieved 50+ level. The whiteness, air permeability, and elongation at break of treated fabric were not decreased significantly. SEM showed that the smooth and reticular coating on the surface of treated fabric reduced the mechanical friction force between dyed fabric and rubbing cloth, and thus improved the rubbing fastness. The decomposition temperature of finished fabric was increased by 50–80 °C.     

Evaluation of anti-stabbing performance of fabric layers woven with various hybrid yarns under different fabric conditions

Various types of special fibers are used for human body protection, mostly in the form of fiber-reinforced composites. These composites are made of special fibers and matrix resin; however, they are often not comfortable for the wearer due to the lack of flexibility and air permeability. This study focuses on an evaluation of human body protective performance against stabbing for various special fibers such as aramid, basalt, and steel fibers, being utilized in cotton hybrid forms. These hybrid forms are designed to improve wearer comfort, while maintaining adequate anti-stab resistance. Specimens prepared with various fabric densities are tested in terms of anti-stabbing performance, according to the NIJ standard. In addition, we investigate the influence of factors such as fiber type, the number of fabric layers, fabric weight, and fabric density on anti-stabbing performance. Results show that the penetration depth of the impactor, which punctures and protrudes through the specimens, decreases with the number of layers, the thickness, and the mass of the armor sample; however, these factors have different relationships according to the material type. Consequently an objective evaluation of anti-stabbing performance is needed. We suggest an anti-stabbing index that can be applied as a criterion to evaluate the antistabbing performance of various specimens woven with special fibers under different fabric conditions. Using the new index, anti-stabbing performances of various specimens can be compared and raw material and fabric conditions that offer the most efficient anti-stabbing performance can be selected.     

Immobilization of TiO2 nanoparticles on PET fabric modified with silane coupling agent by low temperature hydrothermal method

PET fabric was first modified with silane coupling agent KH-560, and then was loaded with a layer of nano-scaled TiO₂ particles using tetrabutyl titanate as precursor by low temperature hydrothermal method, followed by dyeing with Disperse Blue 56. The morphology, crystalline phase, chemical modification, thermal stability and optical property of PET fiber before and after treatments were studied by scanning electron microscope, X-ray diffraction, X-ray photoelectron spectroscopy, thermal gravimetric and diffuse reflectance spectrum techniques. The properties of tensile, air permeability, luster, ultraviolet (UV) protection, photocatalytic activity, K/S value and color fastness were also measured. It was found that compared with the TiO₂-coated fabric without modification with KH-560, the loading of TiO₂ nanoparticles on the surface of the TiO₂-coated fabric modified with KH-560 was obviously improved. The pure anatase TiO₂ nanoparticle was grafted onto the fiber surface. The onset decomposition temperature increased. The absorbing capability to ultraviolet radiation was enhanced. The properties of tensile, air permeability, luster, K/S value and color fastness changed slightly. The UV protection ability and photodegradation of methyl orange under UV illumination were enhanced to some extent.     

Evaluation of the contact coolness of fabric using infrared thermogram imagery

This study develops a method to evaluate the contact coolness of fabric using the infrared thermal image of a small test specimen. By using infrared thermal images of 7 types of fabrics developed as cool fabric, the average temperature difference on the surface of the human palm and a heating plate, with and without fabric was measured and this was used for the scale of the ability of the fabric to cool by touch. By comparing the average temperature differences with the Qmax of a fabric, absorption coolness, subjective contact coolness, and correlations were investigated. More heat is transmitted via fabric when the Qmax value is higher and average temperature difference of thermogram image is smaller, which means the coolness perceived by the skin becomes stronger. Fabric with a small average temperature difference in infrared thermal imaging had a high Qmax value and it was evaluated as having strong coolness in subjective evaluation too. However, it was found that there was no relationship between average temperature differences and absorption coolness. Therefore, it can be concluded that the evaluation of fabrics’ coolness using infrared thermal image is useful when evaluating contact coolness at the point of physical contact. In addition, by comparing the methods using the palm and heating plate, the method using the palm showed higher correlation with Qmax (-.828, p<0.05). Therefore, we confirmed that evaluating the coolness of small test specimens using an infrared thermal camera and the palm is effective.     

Investigation on hydrostatic resistance and thermal performance of layered waterproof breathable fabrics

Waterproof breathable layered fabrics allow water vapor passing through, but resist liquid water to pass. This ability of the fabrics to protect rain and snow water while allowing sweat vapor to evaporate from inside to outside atmosphere, leads them to be used as outdoor sportswear or protective clothing. The big challenge of enhanced hydrostatic resistance of these fabrics with proper breathability and thermal comfort has widened the research scope. This study presents an experimental investigation on hydrostatic resistance and thermal behavior of layered waterproof breathable fabrics. Six different types of hydrophobic and hydrophilic membrane laminated layered fabrics were evaluated by varying different fabric parameters in the experiment. Hydrostatic resistance and water vapor permeability of the laminated fabrics were measured by SDL ATLAS Hydrostatic Head Tester and PERMETEST respectively. Thermal properties were evaluated by ALAMBETA instrument. Moreover, FX-3300 air permeability tester was used to measure air permeability which represents the porosity of the fabrics and computer based See System software was used for water contact angle measurement on the outer fabric surface in order to determine the hydrophobic and hydrophilic properties. This experiment clearly discusses the influence of different fabric characteristics and parameters on hydrostatic resistance and thermal properties of the breathable laminated fabrics. The results show that fabric material composition, density, thickness, and hydrophobic and hydrophilic membranes have significant effects on hydrostatic resistance, breathability and thermal properties of different laminated fabrics.     

Application of the real fabric frictional speeds to the fabric sound analysis using water repellent fabrics

This study aims to determine fabric frictional speeds between the arm and the trunk when people walk (1.3 m/s), jog (2.5 m/s) and run (4.5 m/s), and to apply the measured speeds to setting a sound generator for each motion to obtain fabric rustling sounds. By analyzing body motions captured by the Falcon motion analysis system and a camcorder, it was identified that the friction between the arm and trunk occurred within 10° of shoulder angle along the center line of the trunk in the sagittal plane and the maximum frictional speed occurred at the elbow within the shoulder friction range. The averages (SDs) of maximum frictional speed at the elbow were found 0.63 m/s (0.17) at walking, 1.1 m/s (0.25) at jogging, and 1.98 m/s (0.35) at running. The frictional sounds of three coated nylon fabrics were obtained using these predetermined speeds. We calculated sound characteristics such as the sound pressure levels (SPL) and Zwicker’s psychoacoustic parameter using 1/3 octave band analysis. The SPL values ranged from 74.2 dB at running to 79.0 dB at jogging, which was about the same noise level as in the busy street. The values of loudness (Z) at walking and jogging were higher than that at running, but the fluctuation strength (Z) increased in the order of walking, jogging, and running.     

Climate change effects on paddy field thermal environment and evapotranspiration

The effect of air temperature increase from meteorological data on thermal microenvironment of irrigated paddy field is simulated using energy balance model. Statistical test was used to determine the existence of the trend in temperature change of data from meteorological stations in Indonesia. The temperature was tested to have positive trend, and it was used to generate future and past increase of temperature for the simulation. According to the simulation, the change in energy balance occurs following additional heat contributed by the increase of air temperature. The results show that irrigated paddy field seems to have function of decreasing effect of temperature increase whereas, evapotranspiration increases. However, increasing air temperature also increases temperature in paddy system, but seems to be more moderate than in nonpaddy field.