A portable NMR sensor for moisture monitoring of wooden works of art, particularly of paintings on wood

It is proposed the use of a mobile device based on a NMR single-sided sensor for in situ non-invasive determination of the moisture content (MC) of wood items, especially items of Cultural Heritage interest. The MC is obtained through the moisture volume fraction, which is an appropriate quantity for the sensor and corresponds to the fraction of its measurements sensitive volume occupied by water. The device has been used here to track changes in MC of wood specimens caused by changes over time of the environmental relative humidity. The kinetics of water adsorption has been related to results obtained with the gravimetric method. Measurements on an old painting, the Pietà (1516–1517), oil on a poplar wood panel by Sebastiano del Piombo (1485 Venice, 1547 Rome), Civic Museum, Viterbo, Italy, have shown, conclusively, the good sensitivity of the sensor and its capability to behave as a non-invasive and in situ utilizable device. Results of in situ painting measurements show that the NMR sensor can track moisture fluctuations that are outside the sensitivity range and precision of electro-hygrometric approach.     

Introducing an overall mass-transfer coefficient for prediction of drying curves at low-temperature drying rates

The aim of this study is to justify that the drying rate of wood can be represented by a phenomenological model defining a driving force expressed as the difference between the average wood moisture content and the equilibrium wood moisture content. The results show that the mathematical relation proposed is valid when introducing an overall mass transfer coefficient, K, at low temperature wood-drying rates.     

Influence of coating system on the moisture buffering capacity of panels of Pinus sylvestris L.

Abstract

The indoor relative humidity in dwellings and offices is an important factor in building physics. The ability of hygroscopic materials and especially wood materials to store and release moisture helps to regulate the indoor climate naturally and to avoid extremes of humidity. In the present study, cyclic sorption experiments with coated Scots pine were performed. Materials with different coating compositions were exposed to day-to-day relative humidity changes. The moisture buffering capacity was estimated by a gravimetric method and the moisture buffer value was computed. The results show that the coating has a significant impact on the moisture buffering capacity of the underlying Scots pine. The moisture distribution in the wood sample was appraised for each coating system using a proton magnetic resonance imaging technique. This study confirmed that the dynamics of moisture exchange between the indoor environment and the wooden material during typical daily moisture fluctuations is confined to a few millimetres behind the air–wood interface.     

Improved methodology of measuring moisture content of wood by a vibrational technique

Abstract

A method of measuring moisture content of wood is introduced. This method uses a vibrational technique. A shaker driven by swept sine signals was used for the accurate generation of vibration. A cylindrical wood sample was used to verify the method of measuring the moisture content. Resonance frequencies of the wood sample decreased as its moisture content increased. An experiment was performed by measuring the vibration of a tree to explore the feasibility of applying the method to the measurement of the moisture content of trees. The circumferential mode, which is independent of the height of a tree, was identified using a white oak tree.     

Modeling moisture absorption process of wood-based composites under over-saturated moisture conditions using two-part equations

The objective of this study was to investigate the moisture absorption process for wood-based composites subjected to over-saturated moisture conditions. Two stages are comprised in the moisture transfer process at the over-saturated moisture conditions, an initial stage which is the moisture transfer process mainly under fiber saturation point (FSP), and a second stage which is the moisture transfer process beyond the FSP. A model was developed based on two-part equations to describe the process, from which three coefficients (k ₁ , k ₂₁ , and k ₂₂) can be used to quantitatively describe the moisture transfer process under the conditions. Two different wood-based composites, wood fiberboard and wood fiber/polymer composites (polymer content: 30%), were used to test the model at four different ambient temperatures (30, 45, 62, and 80°C). It was shown that the two-part equation can accurately describe the moisture absorption process under over-saturated moisture conditions. The moisture absorption rate in the initial stage was about 30–60% greater than that in the second stage for most of the cases evaluated in this study. The higher the temperature, the greater moisture absorption parameters were obtained. At both moisture absorption stages (below FSP and above FSP), the calculated activation energy for the moisture absorption rate of wood fiberboard was very close to that of wood fiber/polymer composites.     

Treatment of Softwoods with CCA at High Moisture Levels

A literature study on the feasibility of treating wood with aqueous solutions at high moisture levels revealed a positive indication. The objective of the present study was to determine treatability of Pinus radiata and P. pinaster lumber at high moisture levels with commercial CCA in controlled experiments. The wood samples were treated at levels of moisture content ranging from 20 to 100%.

A statistical analysis of the data showed that specific gravity and moisture content influence solution-absorption, the effect being different for different species. Chemical analyses showed a screening out of copper- and arsenic compounds. The effect of higher moisture contents on screening out was negligible. The results indicated that certain wood species can be treated satisfactorily with CCA at moisture levels higher than 25%.     

Assessment of high-frequency technologies for determining the moisture content of comminuted solid wood fuels

Industries that trade in biomaterials require new and reliable methods for rapidly determining the moisture content (MC) of solid biomass. It is therefore important to develop and test alternative technologies that can fulfil the requirements of all parties in the wood fuel trading chain and provide real-time, accurate and representative MC measurements. The aim of this study was to evaluate the accuracy of a commercial high-frequency (HF) technology (originally developed to analyse potting soils) as a tool for determining the MC of comminuted solid biofuels. The measurements obtained using the HF technology were compared to measurements obtained using the gravimetric method from the European standard EN 14774-2:2009. The HF measurements were most accurate for feedstocks with homogeneous particle size distributions such as wood chips, sawdust and peat [root mean square error (RMSE) 3.1–4.5%]. Less accurate results were achieved for wood fuels with large particles and gaps between particles, such as crushed stem wood (RMSE 8.4%). If the system was adapted to improve its performance for heterogeneous particle size distributions, it should yield acceptably accurate MC estimates. Because of its potential in online analysis, it should therefore be regarded as a potential alternative to existing methods for MC measurement and merits further investigation.     

Determining moisture-dependent elastic characteristics of beech wood by means of ultrasonic waves

The present study investigates the influence of moisture content on the elastic characteristics of beech wood (Fagus sylvatica L.) by means of ultrasonic waves. A set of elastic engineering parameters (i.e. three Young’s moduli, three shear moduli and six Poisson’s ratios) is determined at four specific moisture contents. The results reveal the significant influence of the moisture content on the elastic behaviour of beech wood. With the exception of some Poisson’s ratios, the engineering parameters decrease with increasing moisture content, indicating a decline in stiffness at higher moisture contents. At the same time, wood anisotropy, displayed by the two-dimensional representation of the velocity surface, remains almost unchanged. The results prove that the ultrasonic technique is suitable for determining the elastic moduli. However, non-diagonal terms of the stiffness matrix must be considered when calculating the Young’s moduli. This is shown experimentally by comparing the ultrasonic Young’s moduli calculated without, and allowing for, the non-diagonal terms. While the ultrasonic technique is found to be reliable to measure the elastic moduli, based on the measured values, its eligibility to measure the Poisson’s ratios remains uncertain.     

Investigation of wood properties that influence the final moisture content of air-dried sugi (Cryptomeria japonica) using principal component regression analysis

Sugi (Cryptomeria japonica D. Don) lumber is known to have a large variability in final moisture content (MC_f) and is difficult to dry. This study investigated the variability in MC_f of sugi in relation to wood properties. The wood property variables included initial moisture content (MC_i), basic density (BD), annual ring orientation (ARO), annual ring width (ARW), heartwood ratio (HR) and CIE L ^* color (L ^*). Sugi samples were cut from flat-sawn lumbers and air-dried; a principal component regression (PCR) model for predicting MC_f was developed with the wood property variables. The wood properties that contributed to the prediction of MC_f were evaluated by PCR analysis. Significant positive regression coefficients of the PCR model were observed in the MC_i, BD, ARO and HR, whereas negative ones in the L ^*. There were no significant regression coefficients in the ARW. These results suggest that the MC_i, BD, ARO and HR had a positive influence, the L ^* had a negative influence, and the ARW had little influence on the MC_f of air-dried sugi wood. This finding is in line with the general view on the drying characteristics in relation to these wood properties.     

Moisture content profiles and uptake kinetics in wood cladding materials evaluated by a portable nuclear magnetic resonance spectrometer

Abstract

This study evaluated the capability of nuclear magnetic resonance (NMR) technology based on small portable magnets for in situ studies of the local moisture content in wood. Low-field and low-resolution [¹H]NMR with a unilateral permanent magnet was used to monitor and map the moisture content of wood cladding materials of various types in a spatially resolved manner. The results show that portable NMR equipment based on small open-access permanent magnets can be successfully used for non-invasive monitoring of the moisture content in various extended wood specimens. The moisture content was measured with a depth resolution of 0.2 mm and a maximum penetration depth of 3 mm. This makes the technique suitable for in situ local moisture content measurements beneath a coating layer in the cladding, for example, and it is also possible to relate the moisture level to specific properties of the wood material.     

Correction of moisture effects on near infrared calibration for the analysis of phenol content in eucalyptus wood extracts

? Methods based on near infrared spectroscopy used to assess wood properties are susceptible to variations in physical parameters (temperature, grain size, etc.). As wood is a hygroscopically sensitive material, we studied the effects of moisture on near infrared absorbance and calibration to accurately determine the application potential of this technique under routine.

? A collection of Eucalyptus urophylla × E. grandis hybrid wood pieces were analysed to obtain reference calibration of polyphenol contents in wood extracts via NIR spectra acquired under constant moisture conditions. Other specimens from the same source were assessed to obtain spectra for eight moisture contents spanning a broad variation range. The effects of moisture on absorption and on estimates based on a reference model were analysed.

? An increase in moisture content prompted a rise in near infrared absorption over the entire spectrum and for water O-H absorption bands. The polyphenol content estimates obtained by assessing specimens against the reference calibration at variable moisture contents revealed prediction bias. Five correction methods were then tested to enhance the robustness relative to moisture.

? In-depth calibration and external parameter orthogonalization (EPO) were found to be the most efficient methods for offsetting this factor.

     

The frequency dependence of hygro-expansive scaling of oak

ABSTRACT

Fluctuations in the ambient relative humidity are often cyclic of nature, composed of a wide variety of frequencies. Variations may be as fast as one minute or as slow as a complete season. A wooden object exposed to these fluctuations exchanges moisture with the air, resulting in a change in the local moisture content of the wood. Since moisture penetration is affected by the timescale of the changes in ambient conditions, so are processes caused by moisture content variations. Moisture content variations cause dimensional changes of a wooden object, which, if mechanically restrained, lead to a buildup of stresses and ultimately to damage. It is therefore important to predict the frequency behavior of moisture content and expansion in wood. In the presented study, experiments are conducted in which the moisture content and expansion of oak cubes with different sizes is measured during sinusoidal relative humidity fluctuations with different frequencies. The amplitude in moisture content and expansion is shown to be simply scalable based on sample size only. Derived diffusion coefficients are in agreement with literature values, although the experimental frequency behavior is shown to deviate qualitatively from diffusive frequency behavior.     

Experimental determination of the convective heat and mass transfer coefficients for wood drying

The knowledge of the convective heat and mass transfer coefficients is required for the characterization of the boundary conditions of the heat and mass transfer equations of a wood drying model based on water potential. A new experimental method for the determination of the convective mass transfer coefficient is presented. This method is based on the measurement of the moisture content, and indirectly the water potential, at the surface of a wood specimen at different drying times. Drying experiments were performed on red pine (Pinus resinosa Ait.) sapwood from nearly saturated to dry conditions at 56 °C, 52% relative humidity and air velocities of 1.0, 2.5 and 5.0 m s⁻¹. The results show that the convective mass transfer coefficient is constant until the wood surface moisture content reaches about 80% and then decreases more or less gradually as the moisture content decreases further. The convective mass transfer coefficient increases with air velocity. A regression analysis shows that there is no significant improvement in considering the water potential gradient near the wood surface when the difference in water potential between the surface and the surrounding air (ψ_s − ψ_∞) is used to determine the convective mass flux at the surface. Also, ψ_s − ψ_∞ is more appropriate than the water vapour pressure difference (pv_s − pv_∞) as the responsible driving force of the moisture flux leaving the wood surface. The convective heat transfer coefficient was determined during the same experiments. A plateau is observed at high values of moisture content corresponding to the constant drying rate period. Received 27 February 1998     

异叶南洋杉人工林木材生材性质研究

为合理利用异叶南洋杉人工林木材,通过排水法、质量法和数值法对异叶南洋杉人工林的生材性质展开研究,结果表明,异叶南洋杉人工林木材树皮体积百分率、质量百分率、生材密度、基本密度和生材含水率的平均值分别为11.39%、13.78%、0.842 g/cm³、0.394 g/cm³和121.43%。随异叶南洋杉树高的增加,树皮体积百分率和质量百分率总体呈增大趋势;生材密度和基本密度总体呈下降趋势;生材含水率总体呈先升高后降低的趋势。以期为异叶南洋杉人工林木材的合理利用提供数据支持和理论支撑。     

Normalization of wood density in biomass estimates of Amazon forests

Wood density is an important variable in estimates of biomass and carbon flux in tropical regions. However, the Amazon region lacks large-scale wood-density datasets that employ a sampling methodology adequate for use in estimates of biomass and carbon emissions. Normalization of the available datasets is needed to avoid bias in estimates that combine previous studies of wood density that used wood sampling at diverse positions in the bole or with various methods of density determination. This paper examines the question of whether regressions for radial variation and for variation in wood density along the bole, both developed in dense forest in central Amazonia (CA), are suitable for the open forests in southern Amazonia (SA) that are currently the target of most of Amazonia's deforestation activity. The wood density of the heartwood and density of full disks or slices (bark, sapwood and heartwood) in each tree were measured to assess the radial variation. For variation along the length of the bole, wood densities at breast height and at the top of the bole were used. Moisture content of the bole was measured in SA and compared with values reported by studies from CA in similar dense forest. Comparing regressions that predict full-disk density from heartwood density, the pattern of radial variation differs slightly and significantly between the two forest types (ANCOVA p = 0.006); the slopes have similar values but the intercepts differ. Variation along the bole in the two forest types does not differ significantly (p = 0.144), so the CA model for predicting mean bole density from the density of a slice at breast height gives an unbiased estimate of the mean bole density when applied to SA trees. In SA the mean moisture content of the bole was 0.416 (±0.068 S.D.; n = 223 trees). Moisture content of the bole had a strong inverse relationship with basic wood density (r = −0.77), which explains the lower moisture content in the trees in CA relative to SA. A much weaker inverse relationship was found between moisture content and green wood density (r = −0.292). The relationship between wood basic density and green (‘fresh’) density presented in this study provides an alternative means of obtaining basic wood density directly in the field when oven drying of samples is not possible.     

A new method for nondestructive evaluation of solid wood moisture content based on dual-energy X-ray absorptiometry

This paper presents a new method to determine the moisture content of solid wood based on the principle of dual-energy X-ray absorptiometry. The study investigates the theoretical relationship between X-ray wavelength and mass attenuation coefficients of wood, water, and reference substance. In accordance with this relationship, a theoretically obtained equation is proposed to calculate the moisture content in wood. The proposed equation is compared to experimental results using small blocks of sugi wood, which showed that the change in mass attenuation coefficient of wood with X-ray tube voltage increased with increasing moisture content as expected from the theoretical equation. A regression equation for moisture content estimation was determined based on the experimental results, and the standard error of estimate in the 0–120 % dry-basis moisture content range using the regression equation was determined to be 21.9 % with the most appropriate pair of tube voltages, 15 and 40 kVp. The accuracy of the method will be improved by reducing the duration of X-ray radiography and by increasing the disparity between paired tube voltages. This method has the potential to determine moisture content of solid wood using X-ray without oven-drying or assuming oven-dry density.     

Moisture-dependent orthotropic viscoelastic properties of Chinese fir wood in low temperature environment

The influence of moisture content (MC) on the orthotropic viscoelasticity of Chinese fir wood (Cunninghamia lanceolata [Lamb.] Hook.) has been examined in low temperature environment. Storage modulus E′ and loss modulus E″ of wood with six different levels of MC ranging from 0.6 to 22.0% were determined from ??120 to 40 °C and at multi-frequency range of 0.5, 1, 2, 5, and 10 Hz using a TA instruments^® Dynamic Mechanical Analyzer (DMA 2980). The results showed that a distinct moisture dependency is exhibited by the orthotropic viscoelastic behaviour of Chinese fir wood. With the exception of some apparent activation energy (ΔE) for β-relaxation process, the E′ decreased and the E″ peak temperatures moved towards lower temperature and the ΔE for α-relaxation process became lower with MC increasing in all orthotropic directions, whereby individual decline of E′ and the E″ peak temperatures were affected by MC to different degrees. Besides, a little E″ peak at around 0 °C was only seen in L direction, which could be attributed to the melting of frozen water. Furthermore, the dynamic viscoelastic behavior of wood is also dependent on the measurement frequency. The findings suggest that the orthotropic structure and moisture content have an important influence on the viscoelastic performance in low temperature environment.     

Moisture diffusion coefficient of reaction woods: compression wood of Picea abies L. and tension wood of Fagus sylvatica L.

The moisture diffusion coefficient of compression wood in spruce (P. abies) and tension wood in beech (F. sylvatica) was examined. The results indicated that the diffusion coefficient measured under steady-state condition (cup method) could well characterize the drying kinetics of the reaction woods. The compression wood offered more resistance to the moisture diffusivity when compared with the corresponding normal wood. The thick cell wall rich in lignin explains the small mass diffusivity in compression wood. In contrast, the mass diffusivity in beech is almost always higher in tension wood than in normal wood, in spite of similar density values. The high moisture diffusion in tension wood can be explained by the ease of bound water diffusion in the gelatinous layers (G-layers).     

Using drill resistance to quantify the density in coarse woody debris of Norway spruce

To evaluate the mass of coarse woody debris (CWD), it is necessary to quantify its density. Drill resistance measurements are introduced as a approach to estimate the density of CWD in different stages of decay. Dead logs of Norway spruce [Picea abies (L.) Karst.] from a Central European mountainous site were used as a test system to compare the new method with conventional predictors of wood density such as fast quantitative field estimates (e.g., knife probe) and classification of decay classes based on a set of qualitative traits and quantitative estimates. The model containing only drill resistance as a predictor explained 65% of the variation in wood density and was markedly better than models containing one or more of several conventional predictors. However, we show that the relationship between drill resistance and gravimetric wood density relationship is sensitive to the decay status. Therefore, the best model combines drill resistance and decay class (adj. R2 = 0.732). An additional experiment showed that drill resistance is also sensitive to the moisture state (fresh vs. oven-dry) of the sample. The major potential of the method lies in its non-destructive nature which allows repeated sampling in long-term ecosystem studies or in protected areas where destructive sampling is prohibited. The limitations of the method are discussed and recommendations for applications are given.     

Determination of wood moisture properties using a CT-scanner in a controlled low-temperature environment

Abstract

The aim of the present work was to examine an advanced image-processing algorithm for moisture content (mc) calculation and also to use this algorithm to analyse moisture loss data for low temperature drying. Since wood starts to shrink below the fibre saturation point during drying, the geometrical shape of the wood piece will change. The dry wood image was thoroughly transformed to the shape of the wet wood image prior to calculating the dry weight mc. The results show that the algorithm for the dry weight mc on density data from the CT-scanning during low-temperature drying in the climate chamber is a powerful tool for analysing the moisture loss inside the wood piece. This method can make it possible to get a higher quality on the product.