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1.
A series of random copolyesters having various compositions were synthesized by bulk copolymerization of bishydroxyethyl terephthalate (BHET) with 1,4-cyclohexane dimethanol (CHDM) or dimethyl isophthalate (DMI). CHDM and DMI content was less than 10 wt%. For the synthesized copolyesters, isothermal crystallization rate, melting behavior, and equilibrium temperature were investigated by calorimetry and by Avrami and Hoffman-Weeks equation. Crystalline lattice and morphology were studied by WAXD and SEM. Regardless of the composition, the value of the Avrami exponent was about 3, which indicates that crystallization mechanism of the copolyester was similar to those of PET homopolymer. Incoporation of CHDM or DMI units in PET backbone decreased the crystallization rate of the copolyesters. Surface free energy of copolyesters was evaluated using the newly proposed equation. The value of surface free energy was about 189×10−6 J2/m4 regardless of comonomer contents. This result is in good agreement with that of PET homopolymer.  相似文献   

2.
A series of copolyesters (Co-PETs) containing poly(ethylene glycol) (PEG), 5-sodiumsulfodimethyl isophthalate (DMS), and dimethyl isophthalate (DMI) were synthesized via the conventional two-step melt-polycondensation method. The synthesized Co-PETs were characterized by 1H-NMR spectroscopy, FT-IR spectroscopy, differential scanning calorimeter (DSC), and thermogravimetric analyzer (TGA). The DSC results showed that the melting temperature (T m) and the heats of fusion (ΔH m) of Co-PETs decreased with increasing the DMS content in Co-PET, while the inclusion of PEG did not affect their thermal properties significantly. The water absorption and the water contact angle of the Co-PET films were found to be significantly affected by the DMS content rather than PEG content. The moisture-related cooling properties of the fabric samples made of Co-PET 5 as well as PET were evaluated by using liquid moisture management tester (MMT) and Q max measurements. The MMT and Q max results indicated that Co-PET 5 fabric containing DMS 1.0 mol% and PEG 10.0 wt% in Co-PET seemed to be a good candidate for the fabric having durable cooling effects.  相似文献   

3.
We have prepared a series of polypropylene/exfoliated graphene (PP/EG) nanocomposite films via efficient meltcompounding and compression, and investigated their morphology, structures, thermal transition behavior, thermal stability, electrical and mechanical properties as a function of EG content. For the purpose, EG, which is composed of disordered graphene platelets as reinforcing nanoscale fillers, is prepared by the oxidation/exfoliation process of natural graphite flakes. SEM images and X-ray diffraction data confirm that the graphene platelets of EG are well dispersed in PP matrix for the nanocomposites with EG contents less than 1.0 wt%. It is found that thermo-oxidative degradation of PP/EG nanocomposites is noticeably retarded with the increasing of EG content. Electrical resistivity of the nanocomposite films was dramatically changed from ∼1016 to ∼106 Ω·cm by forming electrical percolation threshold at an certain EG content between 1 and 3 wt%. Tensile drawing experiments demonstrate that yielding strength and initial modulus of PP/EG nanocomposite films are highly improved with the increment of EG content.  相似文献   

4.
Alternatives need to be addressed for reducing losses in elephant grass (EG; Pennisetum purpureum) silages. Furthermore, smallholders lack information on the nutritional aspects of dairy farms. The aim of this study was to evaluate total mixed ration silage (TMR) combining fresh EG and concentrate ingredients, creating the following treatments: (i) EG silage (control); (ii) EG, corn and soya bean meal; (iii) EG, corn, soya bean meal and molasses; (iv) EG, citrus pulp and soya bean meal; and (v) EG, citrus pulp, soya bean meal and molasses. Five replicates of each treatment were ensiled in 15‐L plastic jars. The fermentation profile, chemical composition, microbial counts and aerobic stability were assessed. Three contrasts were tested, as follows: (i) control vs. TMR; (ii) TMR with corn vs. TMR with citrus pulp; and (iii) TMR with molasses vs. TMR without molasses. Variables were analysed through the PROC MIXED procedure of the SAS at the 5% level. The TMR had better fermentation profile, lower effluent production and longer aerobic stability compared to control. When the effect of corn was compared to citrus pulp among the TMR, silages with citrus pulp showed lower fermentation losses, non‐protein nitrogen and effluent production. The aerobic stability also improved with citrus pulp. Molasses did not affect the fermentation profile. Overall, lactic acid was the primary acid in all TMR. Nitrogen source (e.g., soya bean meal) can be used without compromising the fermentation process. TMR with citrus pulp showed better results than corn. TMR may be an alternative to optimize the use of EG on smallholdings.  相似文献   

5.
增铵营养对玉米品质影响初探   总被引:2,自引:1,他引:2       下载免费PDF全文
李彩凤 《玉米科学》2003,11(3):082-084
试验利用盆栽,选用远征808(收敛型)和四单19(平展型)作试验材料,研究了增铵营养对玉米子粒中蛋白质、淀粉和可溶性糖含量的影响.在氮素水平一致的条件下,设6个处理,NO3--N和NH4+-N比例分别是3:0、2:1、1:1、1:2、0:3及对照(不施氮).试验表明,增铵营养可以提高玉米子粒中蛋白质含量,但不同类型品种表现有差异,远征808在NO3--N和NNH4+-N比例为2:1时蛋白质含量最高,而四单19在1:2时  相似文献   

6.
The effect of offering a total mixed ration of silage and concentrate (proportionately 0·44 silage) system [indoor feeding system (IF)] was compared with grazing at a high daily herbage allowance with a low level of concentrate supplementation [early grazing system (EG)] in early spring on the performance of spring‐calving dairy cows in Ireland. Sixty‐four spring‐calving Holstein–Friesian dairy cows (mean calving date, 2 February) were allocated to one of two systems between 16 February and 4 April 2004. An equal number of primiparous and multiparous cows were assigned to each system. The dairy cows on the IF system were housed for a 7‐week period and offered a diet of 10·9 kg DM cow?1 d?1 (s.d. 2·3) of concentrate, the remainder of the diet was 8·6 kg DM cow?1 d?1 (s.d. 1·9) of grass silage. The dairy cows on the EG system were offered a mean daily herbage allowance of 15·1 kg DM cow?1 d?1 (s.d. 3·7) and were supplemented with 3·0 kg DM cow?1 d?1 (s.d. 1·0) of concentrate. There was no difference in milk yield between the two systems but the cows in the EG system had a higher milk protein concentration (2·9 g kg?1) and a higher milk protein yield than in the IF system. Milk fat concentration was higher for cows in the IF than EG system (3·0 g kg?1). There was no difference in total daily dry‐matter intake between the systems, measured in week 6 of the study. Mean live weight of the cows in the IF system was greater than in the EG system. The results of the study suggest that a slightly greater performance can be achieved by a system offering a high daily herbage allowance to spring‐calving dairy cows in early lactation compared with a system offering a total mixed ration containing a high proportion of concentrate with grass silage.  相似文献   

7.
An experiment involving forty-five British Friesian cows in mid-late lactation was carried out to evaluate the effects of ensiling on herbage digestibility, dry-matter intake and milk production. The herbage from the primary growth of a predominantly perennial ryegrass sward that had received 123 kg N ha?1 was zero grazed (ZG) from 27 April to 24 May 1992. Before going onto the experimental diets all animals were offered a common silage as the sole diet and dry-matter intakes and milk yields were recorded. The herbage was mown, picked-up with a precision-chop harvester and offered as the sole diet, twice daily, 10 fifteen cows that were on average 176 days into lactation. On May 20 herbage from the same sward was harvested identically to the ZG herbage and ensiled, alternative loads being untreated (UT) or treated with formic acid (2.4 l?1) (FA). For silages UT and FA respectively, pH values were 3.94 and 3.92 and ammonia nitrogen concentrations were 95 and 75 [g(kg total N?1)]. Forty-two days after ensiling, the silages were fed twice daily as the sole diet to thirty cows which were on average 166 days into lactation. The feeding interval was 28 days and the last 7 days was the main recording period for each treatment. For diets ZG, UT and FA, dry-matter intakes (DMI) (kg d?1), milk yields (kg d?1), fat plus protein yields (kg d?1). milk fat concentration (g kg?1), milk protein concentration (g kg?1)and fat plus protein yields [kg (kg DMI)?1] were 12.70, 11.51 and 12.07 (Av s.e.d. = 0.458); 12.79, 10.01 and 10.18 (Av s.e.d. = 0.346); 0.900, 0.649 and 0.682 (Av s.e.d. = 0.026); 39.8, 33.7 and 36.7 (Av s.e.d. = 0.174); 32.9, 29.9 and 30.0 (Av s.e.d. = 0.83); 0.073, 0.055 and 0.055 (Av s.e.d. = 0.003). UT treatment significantly increased dry matter (DM), organic matter (OM). energy and crude fibre digestibilities and the digestible OM concentration. UT and FA compared with ZG altered rumen fermentation patterns, significantly decreasing butyrate and increasing valerate concentrations. FA treatment significantly decreased the non-glucogenic ratio. It is concluded that ensiling using formic acid had no effect on forage DMI relative to the parent fresh herbage. Ensiling either untreated or with formic acid significantly decreased milk yield and milk fat plus protein yield, resulting in a lower efficiency of conversion of DMI to milk fat plus protein.  相似文献   

8.
The effect of adding Lactobacillus buchneri 40788, a heterofermentative lactobacilli, to whole‐plant maize and its effect on fermentation and aerobic stability of the resulting silage were evaluated. Whole‐plant maize (380 g DM kg–1 fresh weight) was ensiled in laboratory silos after the following treatments: untreated, L. buchneri 40788 at 1 × 105, 2·5 × 105, 5 × 105, and 1 × 106 colony forming units g–1 of fresh forage or, a commercial inoculant containing homolactic acid bacteria, a single species of propionibacteria and enzymes. Addition of L. buchneri 40788 resulted in a decrease in lactic acid concentration but increased the concentration of acetic acid in silage and markedly decreased the numbers of yeasts present in the silage. All levels of L. buchneri 40788, increased the aerobic stability of silages but the effect was greatest for the two highest levels of inoculation. Treatment with the commercial inoculant had no effect on the fermentation or aerobic stability of silage. On‐farm treatment of maize silage with L. buchneri 40788, stored in a bag silo, resulted in changes in fermentation that were similar to those observed in laboratory silos. Treatment decreased the numbers of yeast in silage and increased aerobic stability (+25 h) of the silage when exposed to air. Treatment had no effect on the dry‐matter intake of silage fed to sheep. These results showed that treating silage with L. buchneri 40788 can increase the aerobic stability of maize silage in laboratory and farm silos.  相似文献   

9.
为了探明河北不同品质类型冬小麦的适宜施氮量,在十年定位试验的基础上,研究了不同施氮水平(0、60、120、180、240和360 kg·hm-2)下小麦中筋品种济麦22、中强筋品种石优20、强筋品种藁优2018和超强筋品种师栾02-1的产量和品质以及农田氮素平衡和土壤氮素盈余状况。结果表明,产量和品质在不同类型小麦品种间及氮肥处理间均差异显著。不施氮和施氮60 kg·hm-2处理的产量和品质显著低于其他处理。长期不施氮肥时各小麦品种的蛋白质含量、湿面筋含量、稳定时间等品质指标降至弱筋麦水平。济麦22、石优20、藁优2018和师栾02-1实现高产高效的适宜施氮范围依次是120~240、180~240、120~300和120~240 kg·hm-2,济麦22达到品种本身品质水平的适宜施氮量范围为120~300 kg·hm-2,其他品种为180~240 kg·hm-2。不同品质指标对施氮量的反应有差异,强筋品种的蛋白质含量和面团稳定时间在施氮120 kg·hm-2条件下能达到较高水平,而湿面筋含量、面团形成时间和延伸性则需要更高施氮量才能达到较高水平。济麦22、石优20、藁优2018和师栾02-1达到农田氮素表观平衡的适宜施氮量分别为197、166、199和218 kg·hm-2,土壤氮素表观平衡的施氮量均为212 kg·hm-2。过量施氮不能提高小麦产量和品质,降低施肥效益,会造成土壤氮素盈余。可见,施氮180 kg·hm-2为最优施氮处理,能实现小麦高产、高效、优质和生态安全的统一。  相似文献   

10.
Abstract

Aromatic rice variety, Mentikwangi, was crossed with high-yielding upland rice variety, Poso, and the pedigree was selected to obtain lines with high yielding and aromatic characters. The objectives of the research were to study the yield stability of aromatic upland genotypes across different locations and to select aromatic upland rice genotypes having wide adaptability, and or specific location adaptability. Yield stability of genotypes was estimated by using regression lines proposed by Finlay and Wilkinson. Some genotypes showed high yield stability and wide adaptability in different locations, and others showed good adaptability to a specific location. The lines having high yield stability and wide adaptability were G10 (405 g m-2), G19 (400 g m-2), G39 (418 g m-2), and G136 (411 g m-2), which may be considered as candidates of new aromatic upland rice cultivars. Situpatenggang had specific adaptability at the fertile locations; and Poso and G13 at the infertile locations. Genotype x location interactions for the yield and its components performance were observed.  相似文献   

11.
为明确外源硒酸盐对小麦各器官硒含量的影响以及硒酸盐的残效,通过两年连续盆栽试验,设置了0、0.02、0.04、0.08、0.16mg·kg-1五个施硒水平,第一年施硒,第二年不施硒且在原土中继续种小麦,测定和分析了两年小麦不同器官(叶、茎、籽粒和颖壳)和土壤硒含量及产量和生物量。结果表明,施硒当季能够增加小麦产量及地上部生物量,显著提高各器官硒含量,各器官硒含量与施硒量均呈显著的线性正相关。器官中叶片对硒的富集能力最强,其次为籽粒、茎和颖壳。小麦不同器官硒强化指数大小与富集系数表现一致,施硒量每增加1 mg·pot-1,叶片、籽粒、茎、颖壳的硒含量分别增加8.9、6.2、4.6和3.6mg·kg-1。外源硒酸盐具有残效,尤其在硒施用量较高时,小麦对外源硒的利用率两年均随施硒量的增加而增加,当季硒的利用率最高值为33.7%,两年累积利用率最高值为34.7%。施硒在第二年对小麦各器官硒的含量、土壤硒含量仍有显著的增加效应,尤其在施硒量较高时,但其对小麦硒含量的影响大于对土壤有效硒、总硒含量的影响。在农业生产应用中应选择适宜的...  相似文献   

12.
A novel phosphorus-containing flame retardant plasticizer (PFRP) derived from castor oil acid methyl ester (COME) was synthesized to substitute dioctyl phthalate (DOP) for plasticizing polyvinyl chloride (PVC) products. The chemical structures of PFRP were confirmed by fourier transform infrared spectroscopy (FTIR) and 1H nuclear magnetic resonance (1H NMR). Meanwhile, the plasticizing effect, flammability and thermal stability of plasticized PVC films were investigated by dynamic mechanical analyzer (DMA), limiting oxygen index (LOI) test, scanning electron microscope (SEM) and thermogravimetric analysis (TGA). As the PFRP content increasing from 0 wt% to 50 wt% amount of plasticizers, the plasticizing efficiency and the mechanical properties showed a slightly decreasing tendency compared with that of DOP, while the LOI value of plasticized PVC increased remarkably from 21.5 % to 25.2 %, showing a combined plasticizing efficiency and flame retardancy. SEM and TGA analysis indicated that PFRP had little effect on thermal stability but was effective to promote the formation of compact carbon residue.  相似文献   

13.
为明确安徽大田生产环境下软质小麦籽粒和终端产品品质表现,评价优质软麦品种的加工适用性,本研究选取该区当前推广种植的24个软质小麦品种,对其籽粒和面粉的主要品质性状及其制品南方馒头和曲奇饼干的品质进行差异性、相关性分析,并以美国软白麦近五年的主要品质性状平均值为理想指标进行灰色关联度比较。结果表明,供试材料的硬度、面粉色泽b*、湿面筋含量、面团形成时间、稳定时间等籽粒品质性状变异系数较大,而容重、面粉L*值和吸水率变异系数较小。南方馒头品质性状中,白度差异最小,比容差异最大;曲奇饼干品质性状中,感官评分变异系数较大,饼干直径均值和变异系数都较小。蛋白质含量、湿面筋含量、稳定时间均符合弱筋标准(GB/T 17320-2013)的样品数为0。相关分析表明,容重、降落值、面粉L*、b*、白度与大部分性状间相关性不显著;籽粒硬度与水SRC和乳酸SRC均呈显著正相关,与湿面筋含量和面粉a*值均呈显著负相关。蛋白质含量与面粉a*值等7个指标均呈显著正相关,与面粉b  相似文献   

14.
为了解赤霉病对小麦脱氧雪腐镰刀菌烯醇(DON)毒素水平和品质指标的影响,通过喷雾及单小花滴注接种,田间弥雾保湿,对10个陕西省主栽小麦品种进行了赤霉病抗性鉴定,并对其DON毒素水平和品质相关指标进行了测定。结果表明,病情指数与千粒重呈显著负相关。喷雾接种条件下,对赤霉病表现中抗、中感的品种分别有1个、5个,其千粒重分别下降了2.84%和1.49%~8.20%;病情指数与籽粒、颖壳中的DON毒素含量呈极显著正相关,中抗品种西农511的籽粒、颖壳、穗轴中的DON毒素含量分别为14.63、24.33和56.15 mg·kg-1,5个中感品种的籽粒、颖壳、穗轴中的DON毒素含量平均值分别为21.67、45.35、62.81 mg·kg-1。单小花滴注接种条件下,筛选出中抗品种3个,中感品种2个,千粒重分别下降了1.38%~12.25%和2.66%~9.51%;平均严重度与籽粒、颖壳、穗轴中的DON毒素含量呈极显著正相关;3个中抗品种籽粒、颖壳、穗轴中的DON毒素含量平均分别为15.50、32.44和14.59 mg·kg-1,2个中感品种籽粒、颖壳、穗轴中的DON毒素含量平均分别为19.98、33.80和16.41 mg·kg-1。除苏麦3号外,喷雾接种下麦穗组织中的DON含量高于单小花滴注接种。喷雾接种条件下,病情指数与容重呈显著负相关,与蛋白质(干基)含量呈显著正相关,千粒重与容重呈极显著正相关,与蛋白质(干基)含量、稳定时间呈显著负相关,与沉降值极呈显著负相关。单小花滴注接种条件下,平均严重度、千粒重与品质指标无显著相关性,但赤霉病导致容重、蛋白质(干基)含量、湿面筋含量、沉降值、稳定时间、延展性和拉伸面积7项指标不同程度的下降。GGE双标图分析表明,7项指标中除容重外,其余指标关系密切。西农3517、西农899和西农511的综合品质表现较优。  相似文献   

15.
The moderately halophilic strain Salinivibrio sp. EG9S8QL was isolated among 11 halophilic strains from saline mud (Emisal Salt Company, Lake Qarun, Fayoum, Egypt). The lipopolysaccharide was extracted from dried cells of Salinivibrio sp. EG9S8QL by the phenol–water procedure. The OPS was obtained by mild acid hydrolysis of the lipopolysaccharide and was studied by sugar analysis along with 1H and 13C NMR spectroscopy, including 1H,1H COSY, TOCSY, ROESY, 1H,13C HSQC, and HMBC experiments. The OPS was found to be composed of linear tetrasaccharide repeating units of the following structure: →2)-β-Manp4Lac-(1→3)-α-ManpNAc-(1→3)-β-Rhap-(1→4)-α-GlcpNAc-(1→, where Manp4Lac is 4-O-[1-carboxyethyl]mannose.  相似文献   

16.
钙对铬胁迫下玉米幼苗生长及生理特性的影响   总被引:1,自引:0,他引:1  
采用含有CrCl3及CaCl2的培养液培养,研究了不同浓度钙和铬处理对玉米幼苗的叶片、株高、根长、鲜重、含水量、叶绿素、保护酶系统(SOD、POD、CAT活性)以及丙二醛(MDA)含量的影响。结果表明,单一铬处理,随着铬浓度增加,玉米植株生长明显受到抑制,株高、根长、鲜重、含水量、叶绿素含量以及CAT活性下降,SOD、POD活性上升,MDA含量增加。单一钙处理,当浓度小于160 mg/L时,明显促进植株生长,株高、根长、鲜重、含水量、叶绿素含量增加,CAT活性上升,POD活性和MDA含量下降;当钙浓度大于160 mg/L时促进效果则开始下降。钙、铬混合处理,一定浓度的钙有抑制或者缓解铬毒害的作用,减轻铬胁迫对株高、根长、鲜重和含水量的抑制,提高叶绿素含量和CAT活性,降低SOD、POD活性和MDA含量。  相似文献   

17.
Silk fibroin (SF)/Cellulose Acetate (CA) blend nanofibrous membranes were prepared by electrospinning and their heavy metal absorbabilities were examined in an aqueous solution after ethanol treatment. The electrospun nanofibrous membranes were comprised of randomly oriented ultrafine fibers of 100–600 nm diameters. As a result of field emission electron microscope (FEEM), the anti-felting properties of the blend nanofibrous membranes were markedly improved after treatment with 100 % ethanol when SF was blended with CA. Metal ion adsorption test was performed with Cu2+ as a model heavy metal ion in a stock solution. The SF/CA blend nanofiber membranes showed higher affinity for Cu2+ in an aqueous solution than pure SF and pure CA nanofiber membranes. Especially, the blend nanofibrous membranes with 20 % content of CA had an exceptional performance for the adsorption of Cu2+, and the maximum milligrams per gram of Cu2+ adsorbed reached 22.8 mg/g. This indicated that SF and CA had synergetic effect. Furthermore, the parameters affecting the metal ions adsorption, such as running time and initial concentration of Cu2+, had been investigated. The results showed that the adsorption of the Cu2+ sharply increased during the first 60 min, the amount of metal ions adsorbed increased rapidly as the initial concentration increased and then slope of the increase decreased as the concentration further increased. This study provides the relatively comprehensive data for the SF/CA blend nanofibrous membranes application to the removal of heavy metal ion in wastewater.  相似文献   

18.
为探究C、N供给时期和供给水平对小麦籽粒建成及蛋白质含量的影响,以冬小麦品种济麦22为材料,采用离体穗培养的方法,设置了三个蔗糖浓度(C1:20 g·L-1;C2:40 g·L-1;C3:80 g·L-1)和四个硝酸铵水平(N1:0.57g·L-1;N2:1.14g·L-1;N3:2.28 g·L-1;N4:4.56g...  相似文献   

19.
The objective of this investigation was to evaluate the mechanical, thermal stability and viscoelastic behaviors of experimental PP composites made from wheat straw and PP-g-MA coupling agent. Four levels of wheat straw, 10, 20, 25 and 30 wt % and two levels of coupling agent, 0 and 3 % wt were mixed with PP in rotary type mixer and injection molding process, respectively. Tensile characteristics and impact strength, thermal gravity and dynamic mechanical and thermal analysis of the samples were evaluated. Based on the results, it was observed that the tensile properties increased and impact strength decreased with the increase in the fiber loading from 10 % to 30 %. Further, the composites treated with PP-g-MA exhibited improved mechanical properties which confirmed efficient fiber-matrix adhesion. DMT analysis showed that the PP composites made of 30 % wheat straw containing 3 % PP-g-MA showed the highest E’ and lowest tan δ than the untreated ones. Also, the thermal stability of wheat straw was lower than PP and as filler content in the composites increased, the thermal stability decreased and the ash content increased.  相似文献   

20.
为探究陕西关中地区小麦HMW-GS亚基与品质性状间的关系,采用SDS-PAGE法对57份陕西关中地区小麦品种(系)HMW-GS亚基组成及相关品质性状进行了分析。结果表明,供试品种(系)中共检测出7种HMW-GS亚基类型和8种HMW-GS亚基组合;Glu-A1位点上有3种亚基类型,分别为1、2*和Null,以1亚基为主(78.95%);Glu-B1位点上检测到7+8(61.40%)与7+9(38.60%)两个类型;Glu-D1位点上检测到5+10(70.18%)和2+12(29.82%)两个类型。3个HMW-GS基因位点编码亚基共组成8种亚基组合,品质得分6~10分,其中1/7+8/5+10组合品质得分10分,出现频率最高。就HMW-GS不同位点对品质性状效应进行分析发现,Glu-D1位点对b*值、形成时间、稳定时间、弱化度和粉质质量指数的影响达到极显著水平(P<0.01);对面团流变学特性的影响,Glu-D1>Glu-B1。不同类型亚基对小麦品质的效应存在差异,7+8亚基对蛋白质含量、湿面筋含量和容重具有正效应,7+9和5+10亚基对形成时间和稳定时间的影响显著高于其他亚基(P<0.05);携带1/7+8/5+10亚基组合小麦的蛋白质、湿面筋含量和容重最高;携带1/7+9/5+10亚基组合具有较高面粉L*值和面团流变学特性指标值。  相似文献   

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