Properties of solonetzes on terraces of salt lakes Bulukhta and Khaki in the Caspian Lowland

A comparative assessment of pedogenetic processes in solonetzes (Calcic Gypsic Salic Solonetzes (Siltic, Albic, Cutanic, Differentic)) developing on terraces of lake depressions within the Volga–Ural interfluve of the Caspian Lowland has been performed on the basis of data on their macro- and micromorphological features and chemical, physicochemical, and physical properties. The studied soils have number of common characteristics shaped by the humus-accumulative, solonetzic, eluvial–illuvial, calcification, and gypsification processes. However, it is shown that macro- and micromorphological indicators of solonetzic processes (the development of clay–humus coatings and the character of structural units in the solonetzic (B) horizon) do not always agree with the modern physicochemical conditions of the development of this process. This is explained by differences in the degree and chemistry of the soil salinization and the depth and salinity of the groundwater. Solonetzes developing on the second terrace of Playa Khaki are distinguished by the highest water content and maximum thickness of the horizons depleted of soluble salts. They are characterized by the well-pronounced humus-accumulative process leading to the development of the light-humus (AJ) horizon. In other solonetzes, the accumulation of humus is weaker, and their topsoil part can be diagnosed as the solonetzic-eluvial (SEL) horizon. Active solodic process and illuviation of organomineral substances with the development of thick coatings and infillings in the B horizon are also typical of solonetzes on the second terrace of Playa Khaki. Micromorphological data indicate that, at present, layered clayey coatings in these soils are subjected to destruction and in situ humification owing to the active penetration of plant roots into the coatings with their further biogenic processing by the soil microfauna. The process of gleyzation (as judged from the number of Fe–Mn concentrations) is most active in solonetzes developing on the first terrace of Playa Khaki. These soils are also characterized by the highest degree of salinization with participation of toxic salts. The maximum accumulation of gypsum is typical of the heavy-textured horizons.     

Morphological and chemical properties of the meadow-semidesert soil complexes of the Khaki playa (the Caspian Lowland) and the influence of the biogenic factor on them

The initial stage of the development of the complex soil cover pattern in the Caspian Lowland was studied. The obtained data made it possible to reveal the specific features of the morphological and chemical properties of the soils on terraces of the Khaki playa and the role of burrowing animals in the formation of the microtopography and complex soil cover patterns on the youngest surfaces. The soil cover of the studied area consists of three-component complexes: light-humus quasi-gley solonetzes on relatively flat background surfaces, zooturbated solonetzes on microhighs, and humus quasi-gley soils in microlows. The layered deposits of the Khaki playa terraces and the shallow depth of the saline groundwater are responsible for the specificity of the modern salinization of the studied solonetzes. The distribution of the salts in their profiles has a sawshaped patter, which is related to the nonuniform texture of the deposits. On the microhighs composed of the earth extracted from 5- to 7-year-old suslik burrows, specific zooturbated solonetzes are formed. The known age of these formations makes it possible to determine the rate of the desalinization of the gypsum- and salt-bearing material extracted onto the soil surface and the rate of the salt accumulation in the lower part of the solonetzic horizon and in the subsolonetzic horizons in comparison with the data on the solonetzes of the background flat surfaces. The specific features of the soils in the closed microlows suggest that these soils have a polygenetic origin. The features of the recent hydromorphism predetermine the specificity of their morphology.     

Anthropogenic transformation of soils in the northern Ergeni Upland (studies at the first experimental plot of the Arshan’-Zelmen Research Station)

The results of soil studies performed in 2005–2009 at the first experimental plot of the Arshan’-Zelmen Research Station of the Institute of Forest Science of the Russian Academy of Sciences are discussed. The post-reclamation state (about 55 years after reclamation) of the soils under forest shelterbelts and adjacent croplands in the rainfed agriculture was studied. The long-term efficiency of forest reclamation and crop-growing technologies developed in the 1950s by the Dokuchaev Soil Science Institute and the Institute of Forest to reclaim strongly saline solonetzic soils was proved. In 55 years, strongly saline sodic solonetzes with sulfate-chloride and chloride-sulfate composition of salts were replaced by agrogenic soils with new properties. Under forest shelterbelts, where deep (40–60 cm) plowing was performed, the soils were transformed into slightly saline solonetzic agrozems with slight soda salinization in the upper meter and with dealkalized plowed and turbated horizons (0–20(40) cm). Under the adjacent cropland subjected to the influence of the shelterbelts on the soil water regime, strongly saline solonetzes were transformed into solonchakous agrosolonetzes with slight soda salinization in the upper 50 cm. In the plow layer, the content of exchangeable sodium decreased to 4–12% of the sum of exchangeable cations. An increased alkalinity and the presence of soda were found in the middle-profile horizons of the anthropogenically transformed soils.     

Solonetzic process in postagrogenic and postameliorative conditions of the Kamennaya Steppe area

The physicochemical conditions and morphological features of solonetzic process in soils of chernozemic solonetzic complexes were studied in the area of solonetzic experimental station no. 1 in the Kamennaya Steppe area in 55 years after a single application of ameliorative measures (earthening, gypsuming, and manuring) and cessation of the annual plowing. It was found that the modern soil-forming factors favor the development of soil processes inherent in native chernozems and solonetzes prior to their plowing and amelioration. They cause the restoration of the humus horizon in chernozems and the morphological differentiation of solonetzes after the cessation of plowing. Active postameliorative and postagrogenic restoration of solonetzic features is related to the preservation of the physicochemical conditions (the low concentration of salts and the presence of exchangeable sodium) in the soil profile. The humus horizon of chernozems applied over the surface of solonetzes is characterized by the appearance of solonetzic features under hydromorphic conditions.     

Zonal,provincial, lithological,and geomorphic features of soil salinization in the Southern federal okrug of Russia

The relationships between soil salinization and the zonal and provincial bioclimatic conditions, the lithological composition of the sediments, and the geomorphic features of the territory have been analyzed for the Southern federal okrug of Russia. It is shown that the lithological and geomorphic conditions (relief, salinity of parent materials, degree of drainage, and the depth of saline groundwater) play an important role in the distribution of salt-affected soils against the background of the more general regularities specified by the climate. The participation of salt-affected soils in the soil cover of the Southern federal okrug increases in the eastward direction from the forest-steppe zone to the semidesert zone in agreement with an increase in the aridity and continentality of the climate. The chemical composition of soil salts also changes: the sulfate and soda-sulfate types predominate in the forest-steppe zone; the sulfate type or the sulfate type with the participation of soda, in the steppe zone; the sulfate-chloride type, in the dry steppe zone; and the chloride type, in the semidesert zone. The lithological and geomorphic conditions within the particular zones and provinces affect the distribution pattern of the salt-affected soils and the degree and chemistry of the soil salinization. The areas of salt-affected soils were calculated with the use of a digital version of the Map of Salt-Affected Soils of Russia (1: 2.5 M scale) with due account for the participation of these soils in the soil cover of the particular delineations and the data on the depth of the upper boundary of the salt-bearing horizons, the degree and chemistry of the soil salinization, and the area of solonetzes and solonetzic soils.     

Saline-alkali soils of Russia

Diagnostics, methods of evaluation, and geography of saline-alkali (soda) soils are discussed. The saline-alkali soils include soils of different genetic types with the following chemical properties: the pH of the water suspensions equal to or higher than 8.5; the total alkalinity exceeding 1.4 meq/100 g of soil and the sum of water-soluble calcium and magnesium; and the presence of soluble “alkaline” salts in the soil profiles, the hydrolysis of which results in the alkaline reaction of the soils. The chemical properties of the saline-alkali soils are largely related to the presence of soda (Na₂CO₃, NaHCO₃) in the soils. According to their morphological properties, saline-alkali soils are divided into two groups: alkaline soils with an undiferentiated profile and without a morphologically pronounced solonetzic (natric) horizon, and alkaline soils with a pronounced natric horizon (solonetzes). Solonetzes, in turn, are divided into (a) alkaline solonetzes (with soda or with soda and neutral salts), (b) solonetzes salinized with neutral salts (saline soils) with increased alkalinity in the solonetzic and lower lying horizons, (c) saline solonetzes throughout the profile, and (d) leached solonetzes containing no soluble salts in the profile and almost no exchangeable sodium in the soil exchange complex (SEC) (“dead” solonetzes). The latter two groups of solonetzes cannot be ranked among the alkaline soils. The alkalinity of the saline-alkali soils under study is due to carbonate and bicarbonate ions (carbonate alkalinity), organic acid anions (organic alkalinity), and borate ions (borate alkalinity). The carbonate alkalinity is due to both soda (Na₂CO₃, NaHCO₃) and CaCO₃.     

Modern state of soil salinity in solonetzic soil complexes at the Dzhanybek Research Station in the North Caspian Region

Variations in the salinity of virgin soils of solonetzic soil complexes at the Dzhanybek Research Station are characterized on the basis of field materials obtained by the author in 2002–2004. The soil salinity is characterized with respect to the depth of the upper boundary of salt-bearing horizons, the total amount of salts, the content of toxic salts, and the chemical composition of salts. Changes in the soil salinity under dry farming conditions are estimated for the following soil management practices: (1) agroforest amelioration with additional moistening of virgin soils owing to snow retention by the adjacent shelterbelts and forest plantations, (2) intense grazing, (3) soil fallowing after normal tillage to a depth of 20–25 cm, and (4) soil fallowing after deep tillage to a depth of 40–50 cm. It is shown that normal tillage and considerable grazing pressure do not affect the salinity of the studied soils. No definite effect of the shelterbelts on the salt status of the adjacent virgin soils of the solonetzic complex has been revealed. Deep soil tillage strongly affects the salt status of solonetzes: the content of toxic salts in the upper meter considerably decreases. Virgin solonetzes are usually moderately or strongly saline soils, whereas deeply tilled solonetzes are slightly or moderately saline soils.     

Salinization dynamics in irrigated soils of the Svetloyarsk irrigation system,Volgograd oblast

On the basis of soil surveys performed by the Volgograd hydrogeological reclamation expedition in 1998 and 2006, published data, and original materials obtained by the authors, the dynamics of soil salinization within the Svetloyarsk irrigation system in Volgograd oblast during the irrigation and post-irrigation periods have been traced. It is found that high irrigation rates under conditions of poor drainage and closed drainage basins upon both shallow (within the Caspian Lowland) and relatively deep (on the Ergeni Upland) occurrence of saline groundwater and the presence of natural salts in the soils and subsoils lead to the rise in the groundwater level above the critical level and the development of secondary salinization in the previously surfacesaline, deeply saline, and even nonsaline soils. During the post-irrigation period (15–18 years) under modern climatic conditions, the groundwater level has been descending to a depth of more than 3 m, and the degree of salinity in the upper meter of light chestnut and meadow-chestnut soils has decreased owing to the leaching of salts with atmospheric precipitation.     

Diagnostics of solonetzes according to the clay profile differentiation

The classification of solonetzes (including the scheme developed by Fridland et al.) does not take into account the thickness of the solonetzic horizon and the depth of the lower boundary of the illuvial horizon. The degree of solonetzicity is only judged from the content of absorbed sodium in the illuvial horizon. For the diagnostics of solonetzes, the authors propose two additional characteristics: the degree of illuviation (weak, medium, strong, and very strong (for solonetzes)) and the depth and kind of illuviation (typical medium-profile, lithogenic medium-profile, deep-profile, and high-profile). As an example, data on some soils of Ukraine are presented.     

On the manifestation of solonetzic properties in soils of the steppe and dry steppe zones in the south of Ukraine

Solonetzic soils are widespread in the south of Ukraine; some of them are represented by low-sodium solonetzes whose diagnostics is complicated by the absence of correspondence between the low content of exchangeable sodium and the clearly pronounced features of the illuvial solonetzic horizon. The statistical treatment of available literature, personal materials, and the materials of soil surveys in the south of Ukraine demonstrated that the diagnostics of low-sodium solonetzes should be based on the assessment of the degree of illuviation in the soil profile. It was shown that the degree of correlation between the content of exchangeable sodium and the degree of illuviation of the soil profile varies in dependence on the size of the statistical sample and differs for the low-sodium and medium-sodium solonetzes. Two scales characterizing the degree of soil illuviation were developed for these soil groups. It is suggested that these scales should be applied during soil surveys in the areas with solonetzic soils.     

Modern tendencies of changes in the properties of virgin and post-irrigational soils of solonetzic complexes on the Privolzhskaya ridge

The study of post-irrigational and virgin soils of solonetzic complexes on the Privolzhskaya sandy ridge has shown that the morphological features of paleohydromorphism and the features acquired during the 30-year-long irrigation period are well preserved in the soil profiles. After the cessation of irrigation, the upper boundary of effervescence has shifted closer to the soil’s surface; fine-crystalline gypsum has appeared in channel pores. When the groundwater level is deeper than 4 m, the boundary of effervescence is higher than the boundary of the gypsum concentrations. When the groundwater level is about 3 m, these two boundaries coincide. If the groundwater level is higher than 2.5 m, the boundary of the effervescence is found deeper than the boundary of the gypsum concentrations. Salinization and solonetzization of the post-irrigational soils have not been identified. In the virgin soils with the groundwater level of 2.3–3.0 m, the content of exchangeable sodium in the upper 30 cm is similar to that in the post-irrigational soils. In the deeper layers, the exchangeable sodium content in the solonetzes and chestnut soils rises up to 25% and more; in the meadow-chestnut soils, it constitutes up to 4% of the sum of exchangeable bases.     

On the dynamics of salts in solonetzic soil complexes of the Pallas irrigation system in relation to fluctuations in the groundwater level and changes in the regime of irrigation

Changes in the salt status of solonetzic soil complexes within the Pallas irrigation system were estimated for a field surveyed in 1990 and 2003. The irrigation of this field was stopped in 2000. In 2003, the depth of the groundwater table lowered by 1 m, and the groundwater salinity decreased considerably in comparison with the corresponding values obtained in 1990. The concentrations of Na⁺ and SO ₄ ^2? ions in water extracts, as well as the ESP values in the upper horizons of solonetzes, became lower. In meadow-chestnut soils, dealkalization processes were active in the entire profile.     

Estimation of the areas of salt-affected soils in the European part of Russia on the basis of a digital map of soil salinization on a scale of 1 : 2.5 M

A digital version of the map of salt-affected soils on a scale of 1 : 2.5 M has been used to calculate the areas of these soils in the four federal okrugs (the Southern, Central, Volga, and Northwestern) of European Russia. The total area of soils with soluble salts in the upper meter reaches 23.3 million ha. More than half of them are solonchakous soils (with soluble salts in the layer deeper than 30 cm), and about 25% are saline from the surface. Soils of sulfate and chloride-sulfate salinization predominate (>50% of the area of salt-affected soils). Alkaline soda-saline soils and soils with the participation of soda comprise about 6%. We consider this value to be underestimated and requiring refinement, because soils of solonetzic complexes with neutral salts in the upper horizons may also contain soda in the solonetzic and subsolonetzic horizons, which was not always taken into consideration upon assessing the chemical composition of the salts. Solonetzes proper and solonetzic soils predominate among the salt-affected soils in the European part of Russia. The area of solonetzes is up to 9.4 million ha. The area of solonetzic soils (including solonetzic soils with salts in the layers of 0–100 and/or 100–200 cm) is 15.5 million ha. The highest percentage (32.2%) of salt-affected soils is in the Southern federal okrug.     

Factors and mechanisms of soil salinization under vineyards of southern Taman

The spatial distribution of saline soils under vineyards in the south of Taman Peninsular is discussed. The Paleogene–Neogene clays of the Komendantskaya Mount serve as the source of salts. Vineyards were planted on an inclined plain at the foot of this mount. At present, their state on salt-affected soils worsens. In the upper part of the plain, solonchakous or deep-solonchakous slightly saline and nonsaline (within the upper 2 m) dark quasigley vertic soils (Vertisols) are formed. The salts are of the sulfate–sodium composition. Their vertical distribution has an eluvial pattern with a quick rise in the salt content from the surface layer to the depth of 50–100 cm and with a gradual increase in the salt content in the deeper layers. The absence of chlorides in the soils of flat areas within the slope attests to the predominance of lateral leaching of salts down the slope over their vertical leaching in the soil profiles. In the lower part of the slope, soil salinization mainly takes place in the hollow crossing the plain and the vineyard from the north to the south. In the middle part of the slope, nonsaline (to a depth of 2 m) agrohumus quasigley soils (Haplic Chernozems (Clayic, Aric, Stagnic)) are formed. Slight chloride–sulfate sodium salinization is only seen in the soils of the hollow, which contain fine-crystalline gypsum in the solid phase and display the accumulation of sodium chlorides in the middle part of the soil profile (in the 60–150-cm-thick layer). Heavy loamy agrochernozems with migrational and segregational forms of carbonates (Haplic Chernozems (Loamic, Aric, Pachic) are developed in the lower part of the slope; they are nonsaline to the depth of 2.5 m. In the area of transition from the humusquasigley soils to chernozems, specific horizons are formed in the hollow at the depth of more than 250 cm. Their soil solutions contain sodium, calcium, and magnesium chlorides against the background of the presence of fine-crystalline gypsum in the solid phase, which is typical of secondary salinization.     

Soils and the soil cover of the arkaim reserve (Steppe Zone of the Trans-Ural Region)

Soils of the Arkaim Reserve in the area around a unique settlement-fortress of the Bronze Age in Chelyabinsk oblast have been studied. These soils are generally typical of the entire Trans-Ural Plateau. The soil properties are characterized in detail on the basis of factual data on 170 soil pits and four soil catenas. The soil cover of the reserve is specified into six geomorphic groups: (a) denudational surfaces of the low mountains, (b) accumulative-denudational surfaces of the low mountains, (c) denudational-accumulative plain surfaces, (d) lacustrine-alluvial plain surfaces, (e) floodplain surfaces, and (f) slopes and bottoms of the local ravines and hollows. Chernozems occupy about 50% of the reserve; solonetzes and saline soils, 32%; meadow chernozems, 7%; and forest soils, 1%. The soils of the reserve are relatively thin; they have a distinct tonguing of the humus horizon and are often saline and solonetzic. The latter properties are inherited from the parent materials and are preserved in the soils for a long time under the conditions of a dry continental climate. The genetic features of the soils differ in dependence on the composition and age of the parent materials. With respect to the thickness of the soil profiles and the reserves of soil humus, the soils can be arranged into the following lithogenic sequence: the soils developed from the eluvium of igneous rocks-redeposited kaolin clay-montmorillonite-hydromica nonsaline and saline loams and clays. The content of C_org in the upper 20 cm varies from 2.5 to 5.6%, and the reserves of C_org in the layers of 0?C0.5 and 0?C1.0 m reach 57?C265 and 234?C375 t/ha, respectively. The soils of pastures subjected to overgrazing occupy two-thirds of the reserve. Their humus content is 10?C16% higher in comparison with that in the analogous plowed soils. Another characteristic feature of the humus in the soils of the pastures is its enrichment in the labile fraction (28?C40% of C_org).     

Changes in the properties of solonetzic soil complexes in the dry steppe zone under anthropogenic impacts

Long-term studies of changes in the properties of solonetzic soil complexes of the dry steppe zone under anthropogenic impacts (deep plowing, surface leveling, irrigation, and post-irrigation use) have been performed on the Privolzhskaya sand ridge and the Khvalyn and Ergeni plains. The natural morphology of solonetzic soils was strongly disturbed during their deep ameliorative plowing. At present, the soil cover consists of solonetzic agrozems (Sodic Protosalic Cambisols (Loamic, Aric, Protocalcic)), textural (clay-illuvial) calcareous agrozems (Eutric Cambisols (Loamic, Aric, Protocalcic)), agrosolonetzes (Endocalcaric Luvisols (Loamic, Aric, Cutanic, Protosodic), agrochestnut soils (Eutric Cambisols (Siltic, Aric)), and meadowchestnut soils (Haplic Кastanozems). No features attesting to the restoration of the initial profile of solonetzes have been found. The dynamics of soluble salts and exchangeable sodium differ in the agrosolonetzes and solonetzic agrozems. A rise in pH values takes place in the middle part of the soil profiles on the Khvalyn and Ergeni plains.     

The boron content in soils of solonetzic complexes in the Irtysh Region of Omsk oblast and the boron resistance of plants

Data on the boron content in the main soil types of solonetzic complexes in the Irtysh Region of Omsk oblast are given. They attest to the boron salinization of the soils. It is shown that there is a risk of excessive boron accumulation in natural plants and crops. The boron resistance of crops cultivated on the boronsaline soils has been examined in the field and in pot experiments. Approximate normal and toxic levels of the boron content in soils and in plants and the corresponding Ca-to-B ratios in the aboveground phytomass are suggested. Amelioration of solonetzes with application of gypsum and phosphogypsum reduces the degree of their boron salinization and the boron uptake by plants.     

Distribution of exchangeable cations in a soil catena in the area of Baer mounds

The soil cover of the Baer mounds in Astrakhan oblast consists of brown solonetzes on the tops of the mounds, solonetzic brown and meadow brown soils on the slopes, and solonchaks at the footslopes. The exchangeable sodium percentage in the brown soils on the tops and slopes varies from 7 to 42%. However, the morphological features of the solonetzic process are weakly pronounced in these soils, except for some cementation of the soil mass and the poorly developed columnar structure in the B horizon. This is probably related to the coarse soil texture and the relatively low exchange capacity (<10 meq/100 g of soil). The portion of exchangeable sodium reaches 2–9%. A direct correlation between the sodium concentrations in the water extracts and in the soil exchange complex is clearly seen.     

Early stages of pedogenesis at the bottom of a 30-year-old artificial depression under semidesert conditions

Initial soils that developed at the bottom of an artificial hollow 30 × 40 m in size and 3 m in depth have been studied. The hollow was dug on a plot with a predominance of solonetzic complexes in the soil cover on the territory of the Dzhanybek Research Station in 1979. A soil with a shallow but clearly differentiated profile composed of a litter, a humus-accumulative W horizon leached from carbonates, and an underlying C1ca horizon with a high content of dispersed carbonates formed in the hollow over 30 years. The total thickness of these horizons is 7–10 cm. The morphology of the profile corresponds to the slightly alkaline humus-accumulative calcareous soil type of the order of immature soils in the current classification of Russian soils. The soil-sediment layer to a depth of >80 cm contains little soluble salts, predominantly sulfates; the content of exchangeable Na does not exceed 1 meq/100 g. Groundwater of calcium sulfate composition occurs at a depth of ～3.8 m. These features, together with additional moistening by low-saline melt water, ensure favorable conditions for the spontaneous propagation and development of herbaceous, shrubby, and woody plants in the bottoms of artificial hollows. The development of a soil profile is accompanied by the depletion of the clay fraction from the upper W horizon, presumably due to the predominant removal of smectite minerals. In the upper W horizon, transformations of layered aluminosilicates takes place: it involves the formation of illites from smectites and from smectitic layers in illite-smectite mixed-layered minerals and partial vermiculitization of chlorites. The technology used upon the excavation of the hollow can be recommended for growing woody-shrubby plants on soils of the solonetzic complex in the clay semidesert during a relatively short time period.