A comparative study between an electrostatic and conventional methods of drying soil samples

Abstract

Drying of soil samples exposed to high fluxes of air ions of both polarity, produced by corona electrodes, were studied by a beta‐ray gauge. The conventional methods of air‐drying and oven‐drying of soil samples were compared with the new technique. Fluxes of 0.94 x 10¹² positive and 1.83 x 10¹² negative air ions cm^‐2 s^‐1 reduced drying time of samples by at least three times over the air‐drying controls. Although oven‐drying at a high temperature was the fastest drying method, air ions maintained steady‐state soil temperature during the drying process at 4.5° and 7.3°C below that of the control and ambient temperatures, respectively. There was no significant change in pH, electrical conductivity, and organic matter content values of the dried soil samples of Dalhousie clay, Macdonald sandy loam and St. Sophie sand. Electric wind produced by the ionic drag is proposed to be the principal driving force for the enhancement of evaporation rates from the soil samples. Electroconvection and electrostriction that arise due to the interactions of an external electric field with soil dielectrics may also have contributed to the drying enhancement.     

Examining the Relationships Between the Activities of 3H in Precipitation and 137Cs in Ground-Level Air in Belgrade City Area

Specific activity of tritium (³H) in precipitation and specific activity of ¹³⁷Cs in ground-level air were monitored at three locations in Belgrade (Meteorological Station of Belgrade at Zeleno Brdo (ZB), Meteorological Station Usek (USEK), and Vin?a Institute of Nuclear Sciences (VINS)). Data presented cover the period 1985?C1997 for ¹³⁷Cs for all locations and 1985?C2009 (ZB), 1988?C1997 (USEK), and 1988?C2009 (VINS) for ³H. Concentrations of ³H in precipitation have been determined using electrolytic enrichment and liquid scintillation spectrometer LKB-Wallac 1219 RackBeta. The activity of ¹³⁷Cs in air was determined on an HPGe detector (Canberra, relative efficiency 23?%). ³H concentrations in precipitation ranged from 0.40?±?0.08 to 74.6?±?5.2?Bq?l^?1 decreasing with distance from the nuclear facilities. Significantly higher tritium levels were measured in samples in VINS compared with those from an off-site location. The observed seasonal variations of tritium concentration indicate the stratospheric source of tritium. Increases in activity concentration of ¹³⁷Cs in the atmosphere were observed after the nuclear plant accident at Chernobyl in April 1986. The concentrations obtained for ¹³⁷Cs in 1986 were compared with the integrated air concentrations of ¹³⁷Cs in the region. The increases of ¹³⁷Cs air concentrations in 1987 and 1988 were attributed to local resuspensions from the ground. Since 1989, the activity level before the accident has been obtained. The average monthly concentrations of ¹³⁷Cs in ground-level air were shown spread maximum in spring?Csummer period and pronounced maximum during winter. The obtained results were statistically analyzed, i.e., the following parameters were determined: tritium deposition, monthly activities of ³H and ¹³⁷Cs, seasonal indices, radionuclide loading indices, and linear correlation coefficients.     

Polydopamine Nanoparticles as a New and Highly Selective Biosorbent for the Removal of Copper (II) Ions from Aqueous Solutions

The adsorption and desorption of copper (II) ions from aqueous solutions were investigated using polydopamine (PD) nanoparticles. The nanoscale PD nanoparticles with mean diameter of 75?nm as adsorbent were synthesized from alkaline solution of dopamine and confirmed using scanning electron microscopy and X-ray diffraction analysis. The effects of pH (2?C6), adsorbent dosage (0.2?C0.8?g?L^?1), temperature (298?C323?K), initial concentration (20?C100?mg?L^?1), foreign ions (Zn²⁺, Ni²⁺, Cd²⁺, Fe²⁺, and Ag⁺), and contact time (0?C360?min) on adsorption of copper ions were investigated through batch experiments. The isotherm adsorption data were well described by the Langmuir isotherm model. The maximum uptake capacity of Cu²⁺ ions onto PD nanoparticles was found to 34.4?mg/g. The kinetic data were fitted well to pseudo-second-order model. Moreover, the thermodynamic parameters of the adsorption (the Gibbs free energy, entropy, and enthalpy) were studied.     

Response of water-soluble salt accumulation in weathered gneiss spoil substrate to the addition of superabsorbent polymer under a semiarid climate

Purpose

Superabsorbent polymer (SAP) has been widely used to improve soil moisture conditions in the ecological restoration of mining land. The effect of SAP on water-soluble salt movement in SAP-modified gneiss spoil in a semiarid region was studied in this experiment.

Materials and methods

Weathered gneiss spoil, dress soil, SAP, and turf were mixed via the L₂₅(5⁶) orthogonal test, and the semiarid environmental conditions were controlled for 1 year in a climate chamber.

Results and discussion

The results showed that bulk density, field water-holding capacity, and daily average evaporation rate of the substrate were dominated by the proportions of the soil and turf contents but were not significantly influenced by the SAP. The water-soluble salt in the top layer of the substrate increased significantly as the SAP concentration increased; i.e., it increased by 36.5% per 0.1% increase in the SAP within the range of 0 to 1%. The major ions influenced by the SAP were Na⁺, Mg²⁺, Ca²⁺, Cl^?, and SO₄^2?. The SAP decreased the pH of the substrate before the experiment, but only the top layer was influenced by the increase in the SAP after 1 year. The electrical conductivity (EC), which reflects the content of soluble ions in different substrate layers, was significantly influenced by the SAP in the following order: EC-middle layer < EC-bottom layer < EC-top layer.

Conclusions

Based on the above results, we can conclude that the strong water and salt ion absorption ability of the SAP may limit the leaching of water-soluble ions and aggravate the accumulation of surface salts under semiarid environmental conditions. This study will be helpful for understanding the salt accumulation caused by the use of SAP in the remediation of mine spoil with high soluble salt contents.

     

Genotype-by-environment interaction of elite heat and drought tolerant bread wheat (Triticum aestivum L.) genotypes under non-stressed and drought-stressed conditions

ABSTRACT

The selection of relatively high and stable yielding genotypes is key in wheat breeding programs to improve yield performance under heat and drought-stressed environments. This study determined grain yield response and stability among elite heat and drought tolerant bread wheat genotypes under simulated drought-stressed (DS) and non-stressed (NS) environments to select promising parents for breeding. Twenty-four elite bread wheat genotypes selected from the International Maize and Wheat Improvement Centre (CIMMYT) drought and heat tolerant nursery were assessed under NS and DS conditions using a 7?×?4 alpha-lattice design under rainout shelter (RS) and glasshouse (GH) environments. Grain yield data was subjected to analysis of variance (ANOVA), the additive main effect and multiplicative interaction (AMMI) and genotype and genotype-by-environment (GGE) biplot analyses. ANOVA and AMMI revealed highly significant (p?≤?0.001) differences among test genotypes (G), environments (E) and G?×?E interaction effects suggesting differential responses for selection. The GGE biplot explained 83.76% of total variation and aided in selection of high-yielding and stable heat and drought tolerant wheat genotypes such as LM13, LM22, LM95 and LM100. These selections are recommended for breeding for yield gains under heat and drought-stressed environments.     

An electrohydrodynamic technique for removal of moisture from soil samples

Abstract

Removal of moisture from soil is of great importance in research, and any attempt in improving the existing soil drying techniques would be desirable. Evaporation rates of water from six soil samples of varying organic matter content were determined gravimetrically while exposed simultaneously to bipolar ions produced by corona electrodes and a thallium‐204 beta‐ray source. These devices produced ion fluxes of 2.63 × 10¹² positive and 2.68 × 10¹² negative ions cm^‐2 s^‐1 in air at the soil surface. Argon (A), dry air, and nitrogen (N) gases were used as ionization media for moisture loss studies. The rate of moisture loss was found to be the lowest in N. The water vapour fluxes from the exposed soil samples were enhanced by a factor of at least three compared to control samples under ambient conditions.     

Changes in the chemical properties of acid soil and aggregate stability in the whole profile under long-term management history

ABSTRACT

The effects of long-term (1959–2005) liming in combination with cattle manure application on the chemical properties and aggregate stability of acid soil were investigated in the whole soil profile to a 100 cm depth. Investigations were performed in a long-term liming and fertilizing field trial at Vezaiciai Branch of Lithuanian Research Centre for Agriculture and Forestry situated in West Lithuania. The soil of the study site is Bathygleyic Distric Glossic Retisol (WRB 2014) with a texture of moraine loam. Acid soil had been periodically limed and manured at different intensity for 47 years. The experiment involved the following treatments: (1) unlimed and unfertilized (control); (2) unlimed and 60 t ha^?1 manure; (3) limed and unfertilized; and (4) limed and 60 t ha^?1 manure. During the 47-year period, liming was performed using pulverized limestone at a rate 1.0 (by hydrolytic soil acidity) every 7 years. During the whole study period, the soil received 38.7–36.5 t ha^?1 CaCO₃; 840 t ha^?1 cattle manure, 2740 kg ha^?1 mineral nitrogen; 3030 kg ha^?1 phosphorus and 3810?kg?ha^?1 potassium. The data showed that long-term (47 years) periodic liming of different intensities in combination with cattle manure application significantly changed the chemical properties of the whole soil profile. The soil acidification was neutralized in the topsoil and subsoil to the 60?cm depth when the soil had been systematically limed with 1.0 rate every 7 years in combination with 60?t?ha^?1 manure application every 3–4 years. Periodic long-term liming in combination with manuring had a positive effect on the improvement of chemical properties of acid soil profile in the ElB₁ and ElB₂ horizons. The data of the soil structure in the topsoil and subsoil showed that such liming practice together with manuring had a positive effect on soil aggregate stability.     

Effects of green synthesized zinc and copper nano-fertilizers on the morphological and biochemical attributes of basil plant

Abstract

In the present study, the green synthesis of Zn and Cu nanoparticles (NPs) was carried out via Zn and Cu ions reduction during their exposure to basil extract. The shape, size and chemical identity of the Zn and Cu NPs were determined using SEM and XRD analysis. To investigate the effects of the Zn and Cu NPs on the morphological and biochemical traits of basil plant, an experiment was conducted as a factorial based on completely randomized design with 4 levels of Zn NPs (0, 1000, 2000, and 4000?ppm) and 4 levels of Cu NPs (0, 1000, 2000, and 4000?ppm). Based on the results, nutrient treatments, especially 4000?ppm Zn NPs + 2000?ppm Cu NPs caused a significant increase in most morphological parameters. The application of the Zn and Cu NPs significantly affected concentrations of chlorophyll a, chlorophyll b, total chlorophyll and carotenoid in the leaves of basil plants. The highest total phenolic and flavonoid content was obtained for 4000?ppm Zn NPs + 2000?ppm Cu NPs treatment. Plants treated with 4000?ppm Zn NPs + 0?ppm Cu NPs showed the highest antioxidant activity followed by 4000?ppm Zn NPs + 2000?ppm Cu NPs and 2000?ppm Zn NPs + 0?ppm Cu NPs. It can be concluded that foliar application of the Zn and Cu NPs is necessary for obtaining better quantity and quality in basil.     

Removal of Uranium(VI), Lead(II) at the Surface of TiO2 Nanotubes Studied by X-Ray Photoelectron Spectroscopy

A thin film of well-ordered anatase TiO₂ nanotubes prepared by anodic oxidation of titanium metal were synthesised and used as adsorbent medium for the purification of water from aqueous uranium and lead. The amount of subtracted metal ions was quantified by using X-ray photoelectron spectroscopy at the surface of the reacted TiO₂ surface. Batch experiments for the sorption of U and Pb at the surface of the titania substrate were carried out in separated solution equilibrated with air of uranyl acetate and lead nitrate, in the pH range 3?C9. For uranium, the experiments were also repeated in anoxic (N₂) atmosphere. The amount of metal ions adsorbed onto the titania medium was quantified by measurements of the surface coverage expressed in atomic percent, by recording high-resolution XPS spectra in the Ti2p, U4f and Pb4f photoelectron regions. Adsorption of the uranyl species in air atmosphere as a function of pH showed an adsorption edge near pH 4 with a maximum at pH 7. At higher pH the presence of very stable uranyl?Ccarbonate complexes prevented any further adsorption. Further adsorption increased until pH 8.5 was obtained when the uranyl solution was purged from dissolved CO₂. Lead ion showed a sorption edge at pH 6, with a maximum uptake at pH 8. The results showed that the uptake of uranium and lead on the selected titania medium is remarkably sensitive to the solution pH. This study demonstrates the reliability of this type of material for treating water polluted with heavy metals as well as leachates from radioactive nuclear wastes.     

Risk assessment,spatial distribution,and source identification of heavy metal(loid)s in paddy soils along the Zijiang River basin,in Hunan Province,China

Purpose

This study aimed to reveal spatial distribution of As, Cd, Cr, Cu, Mn, Ni, Pb, Sb, V, and Zn in paddy soils in the Zijiang River basin and to evaluate its pollution status and potential ecological risks, and thus to provide basic information for rational utilization of paddy soils in the study area.

Materials and methods

The heavy metal(loid) concentrations in one hundred and thirty-five paddy soil samples (these samples were collected from the top 0–20 cm layer) were measured by inductively coupled plasma-optical emission spectrometry. The spatial distribution characteristics of the heavy metal(loid)s were depicted by the Ordinary Kriging interpolation analysis. The contamination degree and potential ecological risks of the heavy metal(loid)s in paddy soils were assessed by Nemerow’s comprehensive index, geoaccumulation index, potential ecological risk factor, and potential ecological risk index. The potential sources of the heavy metal(loid)s were deduced by Pearson’s correlation analysis, hierarchical cluster analysis, and principal component analysis.

Results and discussion

The mean concentrations of the heavy metal(loid)s decreased in the order of Mn?>?V?≈?Zn?>?Cr?>?Ni?≈?Pb?>?Cu?≈?Sb?>?As?>?Cd. Except for Cd and Sb, the mean concentrations of As, Cr, Cu, Mn, Ni, Pb, V, and Zn were close to the background reference values. The concentration of Cd in 94.8% of samples exceeded the soil quality standard value (grade II, 5.5?<?pH?<?6.5, GB 15618–1995). According to the assessments of pollution and potential ecological risks for the heavy metal(loid)s, 45.2% and 46.7% of samples were severely polluted and moderately polluted, respectively. The potential sources analysis indicated that Cd, Sb, and Zn mainly originated from agricultural, mining, and smelting activities; As, Cu, and Pb mainly originated from agricultural activities, while coal combustion by-products was another major source of these heavy metal(loid)s in paddy soils near the thermal power plant in the southwest corner of the study area; Cr, V, Mn, and Ni mainly originated from natural source.

Conclusions

Cadmium and Sb are the main contaminants in paddy soils in the study area, and there are hot-spot pollution areas.

     

Chemically Modified Silica Gel with N-(2-aminoethyl)-Salicylaldimine for Simultaneous Solid Phase Extraction and Preconcentration of Cu(II), Ni(II), Cd(II) and Zn(II) in waters

In this study, N-(2-aminoethyl)salicylaldimine bonded silica gel was synthesized and characterized using Fourier transform infrared and C, H, N elemental analysis. The analytical conditions such as the pH and volume of the solution, flow rates of the sample solution and the type of eluent to achieve the simultaneous preconcentration of Cu(II), Ni(II), Cd(II) and Zn(II) were optimised using the modified silica gel loaded column using a solid phase extraction technique. Samples (50?C500?ml) containing metal ions at optimal pH of 8 were passed through the column filled with the modified silica gel at 7?ml min^?1 and then elution was achieved using 5?ml of 0.25?M HCl. The concentrations of metal ions in the eluates were determined using flame atomic absorption spectrometry (FAAS). The effects of matrix ions were also studied and none of the major ions interfered to the proposed method. The accuracy of the developed method was validated using a certified reference water sample (Ontario Lake water, NWTMDA-54.4). The method was successfully applied to the analysis of various natural water samples. The adsorption capacities of the modified silica gel for Cu(II), Ni(II), Cd(II) and Zn(II) ions were determined and found to be 0.332, 0.261, 0.130 and 0.375?mmol g^?1, respectively.     

Soil matric potential and salt transport in response to different irrigated lands and soil heterogeneity in the North China Plain

Purpose

In the lowland area of the North China Plain (NCP), increasing utilization of brackish water could promote the transformation of precipitation into available water resources, and alleviate the conflict between increase food production and freshwater scarcity. However, the processes of soil water movement and salt migration might be altered, because utilization of brackish water results in frequent changes in groundwater depth and thickness of vadose zone. Thus, it was necessary to understand soil water movement and salt migration when using brackish water for irrigation.

Materials and methods

In this study, soil matric potential (SMP) and total dissolved solids (TDS) at multiple depths were measured in situ to investigate the mechanisms of soil water movement and salt migration at one grassland (site 1) and at three typical irrigated croplands (sites 2, 3, and 4) with different soil textures and groundwater depths in a lowland area of the NCP.

Results and discussion

The study showed that deep soil water and groundwater were recharged generally following heavy precipitation during rainy season. SMP values increased quickly at site 4 due to relatively homogeneous soils, followed by site 3?>?site 2?>?site 1 with an obvious hysteresis response of SMP at multiple depths to precipitation. Soil water mainly moved downward in piston flow, and preferential flow also existed in the soil above 100 cm in the percolation process at four sites. Generally, SMP values followed the order of site 4?>?site 1?>?site 2?>?site 3 and exhibited an inverse trend for TDS, which was mainly due to soil heterogeneity and soil texture in vertical profiles. The differences in SMP among the four sites were mainly due to land use and groundwater depth. There were significantly differences in spatiotemporal distribution of water and salts between homogenous and heterogeneous soils. The processes of infiltration and water redistribution ended quickly in relatively homogeneous soils after heavy rains. However, there was obvious hysteresis in SMP with an increase in soil depth in heterogeneous soils.

Conclusions

Homogenous soils favored water infiltration, salt leaching, and groundwater recharge, and the flow of soil water flow was blocked and salt accumulated significantly in layered soils. The soil water movement and the transformation relationship between water and salt in the vadose zone provided a basis for utilization of brackish water irrigation in lowland region of the NCP.

     

Comparison of postharvest practices used for cereal straw decomposition in a clay loam soil

ABSTRACT

During 2008–2011, model field experiments were carried out at the Joni?k?lis Experimental Station of Lithuanian Research Centre for Agriculture and Forestry on a clay loam Endocalcaric Endogleyic Cambisol. The study was aimed to establish the comparison of various postharvest practices (mineral nitrogen fertiliser alone or together with a bioactivator Penergetic k, livestock slurry, red clover biomass and straw incorporation in the soil by a stubble cultivator at a 10 cm depth) on the acceleration of the initial (nine-month period) decomposition of winter wheat straw. During this period, straw mass decomposition intensity was 20.7–29.1%, carbon (C) concentration decreased by 6.5–22.8%, while an increase in nitrogen (N) by 1.1–2.2 times was observed. The highest straw decomposition rate was recorded when after straw incorporation autumn was warm and humid. That year straw mass C to N ratio (C/N) was 38–46. Under less-favourable autumn conditions, the highest decomposition of straw was achieved, having applied mineral N (with and without Penergetic) and livestock slurry and having incorporated the straw in the soil (C/N = 40–55). A slower decomposition rate was observed for the straw spread on the soil surface with mineral N addition or on undersown red clover.     

Application of Organic Wastes to Primary Saline-alkali Soil in Northeast China: Effects on Soil Available Nutrients and Salt Ions

ABSTRACT

Soil available nutrients and soil salt ions are considered to play a significant role in soil fertility. A two-year field experiment was conducted to investigate the effects of different agricultural organic wastes on soil available nutrients and soil ions in a primary saline soil, located in the west of Jilin Province, China. The treatments were granular corn straw (GS), coarse corn straw (CS), sheep manure (SM), fodder grass (FG), and control (CK). The results showed that agricultural organic wastes effectively decreased soil pH by 1.28%-3.83%. The application of agricultural organic wastes also improved soil available nutrients, of which the available nitrogen (AN) increased by 23.64%-32.54%, the available phosphorus (AP) increased by 16% ?19.93%, and the available potassium (AK) increased by 2.78% – 8.42%. In contrast, the content of soil salt ions decreased significantly with the exception of potassium ions. Linear dependence suggests that, with the decrease of soil pH, the soil available nutrient content was higher. From the correlation analysis, the relationship between other salt ions and soil available nutrients showed an extremely significant negative correlation with the exception of potassium (K+). The redundancy analysis (RDA) showed that calcium (Ca²⁺) and potassium (K⁺) are the main factor affecting soil available nutrient content in 2a (about 12 months after organic wastes were applied) and 3a (about 24 months after organic wastes were applied), respectively. In conclusion, treatment GS is recommended for improving soil available nutrients and decreasing the pH and content of soil salt ions in primary saline-alkali soils.     

Physiological responses and adaptive strategies of wheat seedlings to salt and alkali stresses

Abstract

Effects of salt (NaCl?:?Na₂SO₄) and alkali (NaHCO₃?:?Na₂CO₃) stresses on the contents of inorganic ions and organic solutes in wheat shoots were compared to explore the physiological responses and adaptive strategies of wheat to these stresses. Wheat significantly accumulated Na⁺ and simultaneously accumulated Cl^?, soluble sugars and proline to maintain osmotic and ionic balance under salt stress. Compared with salt stress, the high pH from alkali stress enhanced Na⁺ accumulation and affected the absorption of inorganic anions. To maintain ionic and osmotic balance, wheat accumulated organic acids, soluble sugars and proline. The accumulation of Cl^? and organic acids was the main difference in the physiological responses and adaptive mechanisms to salt and alkali stresses, respectively.     

Surface mulching and a sandy soil interlayer suppress upward enrichment of salt ions in salt-contaminated field

Purpose

The suppression effect of a sandy soil interlayer on topsoil enrichment of salt ions was investigated. However, whether this suppression effect was enhanced by surface mulching was little documented. The objectives of this study were to compare the suppression effects under different materials mulching, and to investigate an innovative method to suppress the soil salt ions down-to-top enrichment.

Materials and methods

In this study, the sandy soil layer was pre-positioned at 60–100 cm depth in a salt-contaminated site in advance, achieving the suppression effect on surface enrichment of salt components as expected. Three treatments were herein designed as bare field (CK), plastic film mulching (PM), and maize straw mulching (SM) to examine the dynamics of water and salt movement across soil profiles during the summer with strong evaporation.

Results and discussions

Results showed that total salt content was increased by 21.3 and 8.0% in CK and SM respectively, while decreased by 24.9% in PM at the end of strong evaporation period, comparing with the beginning. Thus, surface mulching further strengthened this suppression effect, but PM displayed better performance than SM did. The data also demonstrated that vertical transport of soil water was much restrained in PM and SM, accordingly inhibiting upward transfer of salt ions. Particularly, sodium adsorption ratio (SAR) ranged from 14.3–265.7, 17.9–147.1, 38.4–147.2 mmol^1/2 kg^?1/2 at a shallow soil layer (0–60 cm) in CK, PM, and SM, respectively.

Conclusions

The results suggested that sandy soil interlayer settings with plastic mulching are a critical technical strategy for salt-contaminated land reutilization and management.

     

An Application of Geographic Information System (GIS) to a Fictitous Thermal Power Plant in Mersin,Türkiye: An Application of Dispersion Modelling Coupled with GIS

In this study, local air quality impacts of a proposed conventionalcoal-fired power plant in the ?çel region has been investigated using numerical dispersion modeling studies coupled with a GIS application. Within the impact area of the facility, Industrial Source Complex Short Term (ISCST2) dispersion model has been used to estimate ground-level concentrations of air pollutants originating from the power plant. For the same impact area, GIS applications have been utilised to determine the agricultural yield distribution. For this purpose, relevant satellite images were digitised, classified and statistically analyzed. Based on the predicted ground-level pollutant concentrations and sensitivity of the agricultural crops to the pollutants, agricultural yield loss was estimated for the impact area.The results have been quantified and valuated in monetary terms for the purpose of performing an environmental cost benefit analysis. Comparison of the conventional cost benefit analysis with the environmental cost benefit analysis showed the significance of the external cost of the proposed facility, resulting from the environmental damages.

     

The Effect of High Concentration of Negative Ions in the Air on the Chlorophyll Content in Plant Leaves

This research was done on the effectof high concentration of negative ions in the air onchlorophyll contents and photosynthetic efficiency in leavesof Zea mays L. In vivo reflectance and chlorophyllfluorescence were measured in intact maize leaves before andafter exposing to the high concentration of negative ions inthe air. Reflectance, yield of chlorophyll fluorescence, redshift in chlorophyll fluorescence and blue shift inreflectance are observed in exposed species. These resultsindicate that high concentrations of negative ions inair cause significant change in: a) chlorophyll content andb) photosynthetic efficiency.     

On-farm comparisons of soil organic carbon under no-tillage and chisel-plow systems

Purpose: Role of no-tillage (NT) in soil conservation has been already established but its influence on soil organic carbon (SOC) is still under debate.

Materials and methods: Three paired sites, with NT and chisel-plow (CT) fields adjacent to each other were selected for this study. Fields were under the same tillage practices for more than 20 years. Fields were sampled up to 90?cm depth to determine SOC and different C pools based on soil CO₂ flux during 86?d of incubation.

Results and conclusion: Significant differences in SOC and its pools were limited within the surface 0–15?cm depth only. Profile SOC did not vary between NT and CT. Tillage had a significant influence on soil C pools but the effect was not consistent across sites.     

Sorption of cupric,dichromate and arsenate ions in some New Zealand soilds

Concentrated solutions of copper (Cu²⁺), dichromate (Cr₂O^2? ₇) and aresenate (AsO₄ ^3?) ions (CCA solutions) are used extensively in the New Zealand timber preservation industry. These ions are therefore, potential soil pollutants at timber treatment sites. Sorption of these three ions was examined by the surface and sub-surface horizons of two free-draining New Zealand soils over a range of soil solution pH values. Copper sorption by both soils increased substantially with increasing pH and was greater in the surface compared with the sub-surface horizons. Less dichromate was sorbed than the other two ions and wa similar in both surface and sub-surface horizons for each soil. Dichromate sorption increased with decreasing pH. Arsenate sorption from solutions containing all three ions was not greatly different to influenced by changes in soil solution pH. Arsenate sorption was generally greater in the sub-surface horizons of both soils. Sorption from solutions containing all three ions was not greatly different to sorption from solutions containing the single metal ions. Sorption behaviour for each ion is related to its chemistry and the soil chemical properties of each horizon. Results suggest that in the event of soil contamination by CCA solution, the immediate leaching potential of the initial ions species present would increase in the following order: Cu²⁺ < HAsI ₄ ^? ? Cr₂O ₇ ^2? .