Phosphordüngewirkung eisenhaltiger Klärschlämme

<?show $38#Bo;>Phosphorus fertilization effect of sewage sludges treated with iron compounds The result of waste water treatment with iron salts are sewage sludges with higher P but also Fe contents. The effect of such sludges on P availability in soils is not clear and was, therefore, compared with CaHPO₄ as a P mineral fertilizer. In experiments (Mitscherlich pots, 6 kg soil) two sandy soils (pH 4.3 and 4.9), two luvisols ( pH 6.3 and 7.2), a loess (13 % CaCO₃), and quartz sand all differing in their P status were treated with two sewage sludges which differed in their molar Fe:P ratios (sludge Gö: 1:0.3, sludge Sh: 1:1.2). For sludge Gö the P elimination had been carried out with FeSO₄ and the sludge was stabilized with FeCl₃ + Ca(OH)₂ (filter press). For sludge Sh P was eliminated by FeCl₃ in the aerobic basin. The first crop was maize (total shoot dry matter), the second red clover. In case of sludge Sh both crops took up in comparison to CaHPO₄ the same amount of P from all substrates with the exception of quartz sand. The effect of sludge Gö was quite different: from the neutral luvisol soils maize was able to take up only 64—82 % P and red clover 77—82 % P only as compared to CaHPO₄. On the sandy soils maize and red clover grew after sludge Gö as good or better than after CaHPO₄ application and P uptake was quite similar (83—106 %). This result was concomitant to an increase of pH values (from 4.3 to 4.9, 4.9 to 5.6, respectively). The negative efficiency of P uptake in heavy soils after application of sludge Gö resulted from an increase of P sorption and decrease of orthophosphate concentration in soil solution. This sludge contains a high proportion of iron hydroxides/oxides with free sorption sites for P. In future P elimination from waste water should be done without iron salts. At least during the process of conditioning no Fe salts should be used.<?show $6#>     

Ermittlung der Gesamtsäuredeposition in nordrheinwestfälischen Fichten- und Buchenbeständen

Measurement of total acid deposition into spruce and beech forests in Northrhine-Westfalia During one year the deposition of H⁺, NH₄⁺, Al³⁺, Fe³⁺ and the acidity (BNC_8,2) in bulk precipitation and throughfall of spruce and beech stands was measured in Northrhine-Westfalia. It is shown that the calculation of acid deposition as the sum of the H⁺-equivalents of (H⁺ + NH₄⁺ + Al³⁺ + Fe³⁺ + Mn²⁺) underestimates total deposition of acidity. A simple and useful alternative is the calculation of H⁺-equivalents from (BNC_8,2 + 0.9 NH₄⁺ + Mn²⁺).     

Maßstabsabhängige räumliche Variabilität mikrobieller Bodenkenngrößen in einem Buchenwald

Scale-dependent spatial variability of microbiological characteristics in soil of a beech forest The spatial variability of the microbial biomass content (C_mic), the microbial respiration rate (basal respiration) and the metabolic quotient (qCO₂) was analyzed in sandy Cambisols and Luvisols in a beech forest in Northern Germany. Highest variability of microbiological features and, thus, the distance of independent samples was around 10 m that is discussed with reference to spatial hierarchy. Structural changes between the 10 m and 50 m grid were suggested for the Ah horizon due to the break of correlations of C_mic content and the contents of C_org and plant-available Ca, Mg, K and N_t. The C_mic content correlated with the C_org content close to tree trunks and ecotones like borders of the forest and clearings. The qCO₂ did not generally increase with declining pH value. High H⁺ concentrations and C_org content in the litter layer near to the tree trunk indicated retarded microbial mineralization rates. High proportion of microorganisms that are resistant to low pH value and adjusted ro readily-degradable substrates seems to dominate in the soil close to the tree.     

Stärkegehalte von Kartoffelknollen in Abhängigkeit von Kalium-Ernährung und Knollenentwicklung

Starch content of potato tubers in relation to K nutrition and tuber growth In a pot experiment with potato (cv Saturna) K content in tubers increased from 1.0 to 2.6 % of tuber-DM due to increasing rates of K fertilizer. Simultaneously starch in tuber fresh matter decreased from 21 to 15 %. Highest starch content in tuber dry matter was obtained in that K treatment which gave the highest yield in dry tubers. Measuring starch accumulation during tuber growth revealed that already in the flowering stage differences exist in the starch contents of the tuber dry matter between the lowest and highest K treatments, namely 69 % for K₁ as compared with 64 % for K₅. The rate of starch accumulation between flowering and final harvest, however, was similar in all K treatments. This suggests that K supply affects the storage tissue at an early stage of tuber development probably via different water relations of tubers.     

Bemerkungen zur Ermittlung der ungesättigten Wasserleitfähigkeit unter nichtstationären Bedingungen

On the Determination of Capillary Conductivity at Unsteady-State Conditions . Therefore it is stated that for obtaining the effective k_u-values. Considering the importance of capillary conductivity for the soil water regime the large differences up to 2 orders of magnitude between determinations on core samples from the same soil using the double-membrane-method (Henseler and Renger 1969) and the evaporation-method (Becher 1971a) initiated a study concerning the error caused by a possible nonlinearity of suction changes between two measuring levels using the latter method. The study was carried out on disturbed and undisturbed core samples from the three textural classes sand, silt and clay and with modified evaporation method. Comparing the geometric means of the obtained k_u-values calculated at unsteady-state and quasisteady-state conditions for different suctions resulted in that with usual application of the method the measured k_u-values must be diminished for obtaining the effective k_u-values. This correction factor increased with suction and is considered to be more important in laboratory than in field use.

• 1 For sandy soils a correction factor of 2 at 150 cmH₂O increasing to 6 at 1000 cm H₂O must be applied. The coarser the sand would be, at the lower suction nonlinearity will start and the more rapidly the correction factor will increase;.
• 2 For silty soils a correction factor of 2–4 must be applied for suctions > 300 cm H₂O;.
• 3 For clayey soils a correction factor of 2 rapidly increasing to 10 must be applied for suctions > 150 cm H₂O, but depending on soil cracks.

. The overestimation of water through-put resulting from the uncorrected k_u-values amounts to 1.5–4.0 [l/m² · d] at 100 cm H₂O, but these values are within the variation of the effective k_u-values. For 800cm H₂O the overestimation amounts to 0.002–0.065 [l/m² · d], but this makes up 300–1000 % of the effective water through-put.     

Schwefelausstattung ausgewählter europäischer Waldböden in Abhängigkeit vom atmogenen S-Eintrag

Sulfur status of selected European forest soils as dependent on the atmospheric S deposition Along a transect from the Pyrenees (SP), over the Vosges Mountains (FR), the Black Forest and the Bavarian Forest (D). and the eastern Ore Mountains to the Iser-Mountains (CR) 10 representative forest soil forms derived from granite regolith and 1 developed from gneiss debris (Dystric Cambisols, Leptic and Ferro-Humic Podzols) at montane and high-montane elevation were analyzed for their concentrations and amounts of total sulfur and various S fractions in order to study the impact of the atmospheric sulfur input, increasing from SW to NE, on the soil sulfur characteristics. Soils receiving low S inputs are generally characterized by low amounts of inorganic (especially water soluble) sulfate. Most of their total S amount consists of organic sulfur. With increasing S deposition, the concentrations of total S and C-S and the ratios S_t/C_org, C-S/C_org and SO₄?S_tor/C_org in the L-. Of- and Oh-horizons increase. The Aeh- and Ah-horizons of Cambisols and Podzols under different sulfur load do not differ with regard to the S parameters. The B horizons of the northeastern soils affected by high sulfur deposition, however, are markedly enriched with adsorbed and water-soluble sulfate and show comparably high ratios of sulfate S versus dithionite-extractable iron.     

Der Einfluß unterschiedlicher Kalium- und Nitraternährung auf pH-Änderungen in der Rhizosphäre

The Influence of potassium and nitrate nutrition on pH changes in the rhizosphere Seedlings of winter wheat, barley, sunflower, peanut and field bean were grown in soils differing in K and nitrate content. pH changes of the rhizosphere soil were measured periodically with antimony electrodes. In soils relatively poor in K the lowest pH values were measured at the root surface of the dicots (maximum pH decrease from 5 to 4.2), while soil pH increases from 5 to 5.4 in contact with roots of the monocots. Increasing K addition caused decreasing pH near peanut and field bean roots. In soils fertilized with K, monocot roots also decreased soil pH. In a K-rich soil the roots of the dicots decreased pH even after addition of 6.6 mg NO₃-N/100 g soil, while the roots of the monocots did not change pH. The pH changes are explained by an imbalance between anion and cation uptake, causing release of protons or hydroxyl ions. The reason for the differences in behaviour between monocots and dicots may be due to the differing cation-exchange capacity of the plant roots, causing a higher cation uptake by dicots and therefore greater proton release.     

Bodenphysikalische Untersuchungen zum Nachweis der spätpleistozänen Bodenbildung in rheinisch-westfälischen Lößgebieten

Soil physical investigations proving the late pleistocene pedogenesis in loess areas of Northrhine-Westfalia Balancing the structure of typical Braunerde- and Parabraunerde-profiles in the loess-regions of Northrhine-Westfalia soil physical investigations had confirmed that the biggest part of the solum has been clearly compacted als related to parent material. Above C-horizon there has been found a small part of Bv-horizon without compaction, characterized by distinctly increasing pore volume, especially by that of the 10–50 μm fraction, following the carbonate losses. This horizon represents an important mark in soil genesis, probably dating the border between preholozene and holozene soil forming processes. Because the disturbing effects of permafrost conditions the preholozene soil genesis is of definite importance in soil mapping and describing properties of the soils.     

Zelluloseabbau während der Heißrotte von Siedlungsabfällen

Degradation of cellulose during high-temperature composting of municipal wastes Model experiments were carried out to investigate the breakdown of cellulose during the decomposition of municipal wastes at high temperatures. At 70°C only small amounts of cellulose were decomposed. But a very considerable breakdown of cellulose was observed at temperatures of 65°C and below, i.e. at temperatures suitable for the growth and activity of thermophilic microorganisms.     

Erodibilität repräsentativer Böden der Hallertau

Erodibility of representative soils of the Hallertau (South Bavaria) Differences between the USA and the Federal Republic of Germany in geology, soil types, and climate necessitate to verify the erodibility of the soils estimated according to Wischmeier and Smith (1978), when using the Universal Soil Loss Equation under local conditions. The erodibility of 5 representative soils of the region Hallertau within the so-called “Unterbayerisches Hügelland” was checked by measuring soil losses using a laboratory rainfall simulator. The estimated and measured erodibilities for two Aquic Hapludalfs from loess and one Ruptic-Alfic Eutrochrept from Tertiary sand compared very well as shown by coefficients of regression of 1. The estimated erodibilities for a Typic Eutrochrept and an Aquic Chromudert, both from Tertiary materials, however, underestimated the soil losses by a factor of 1.5. For all regressions the coefficients of correlation were 0.90. Due to the small number of soils checked, it is only possible to suggest causes for the observed deviations, particularly since the aggregate stability could not be the only property, as demonstrated by measurements.     

Zur räumlichen Variabilität der Gehalte ausgewählter Schadstoffe in Stadtböden Gelsenkirchens

On the spatial variability of selected contaminations in urban soils in Gelsenkirchen Principle aspects of the distribution characteristics of soil contaminations are shown by the examples of lead, benzo(a)pyren and the polychlorinated dibenzodioxins and -furans. Regions of different contamination levels are distinguishable, but are found inhomogeneous inside. The variability of contamination in urban soils can be explained by differences in the superpositon of input paths into the soil in very small areas, analytical inaccuracies, and the influence of the way of presentation respectively of the units used.     

Die Abschätzung von Nitratausträgen aus landwirtschaftlichen Nutzflächen mit Hilfe von Nmin-Daten

Development and application of a method for the estimation of nitrate leaching from agricultural land For two locations in the Rhine Valley in the State of Baden- Württemberg research on the nitrate leaching from agricultural fields was carried out. The investigated sites are located on aquifers that are pumped for drinking water. A new procedure was developed in order to estimate the nitrate losses by leaching from the rooting zone of agricultural fields. The procedure uses seepage estimates from a soil water simulation model and measured nitrate contents in the soil. It is found that for both sites large amounts of nitrate are washed out and that high nitrate concentrations occur in the seepage water. The simultaneous use of the investigated areas for intensive agriculture and for drinking water supply is questioned.     

Ein autoregressives Verfahren zur Bestimmung der gesättigten und ungesättigten hydraulischen Leitfähigkeit

An autoregressive procedure to predict the hydraulic conductivity — Comparison of measured and predicted results An instantaneous profile method was used to measure the unsaturated hydraulic conductivity. Relatively new techniques involving undisturbed soil samples instrumented with minitensio-meters and Time-Domain-Reflectometry (TDR) mini-probes were used for the experiments. The laboratory method allows a high spatial and temporal resolution. Laboratory measurements were carried out for 40 soil horizons with a wide spectrum of texture and bulk density. In addition, retention curves were measured using the standard pressure plate apparatus. Using this homogeneous set of data, an autoregressive model was developed which allows a stepwise calculation of the hydraulic conductivity for a water potential range of —30 up to —600 hPa. This model was developed for loamy sands, sandy, silty and clayey soils in conjunction with data from the retention curves. The calculation procedure starts with the determination of an initial unsaturated conductivity (k) close to field capacity, i.e., for water potential from —60 hPa up to —100 hPa. This first value is then used to predict other conductivity values using appropriate changes in soil water content corresponding to a defined range of the soil water potential. Subsequently, the hydraulic conductivities for higher and lower potentials were estimated considering the k value of the previous step in combination with the data of the retention curve of the next water potential range. The advantage of this empirical model is the indirect consideration of soil structure, in contrast to the closed-form van Genuchten-Mualem (vGM) model. To demonstrate these effects on different fitting procedures, the vGM model was also used to describe soil hydraulic functions. The accuracy of both, the vGM model and the autoregressive one, were compared for various fitting procedures and soils.     

Stickstoffernährung und Al-Toxizität bei Buchenjungpflanzen. I: Entwicklung von Buchenjungpflanzen in Abhängigkeit von der Form der Stickstoffernährung und dem Aluminiumgehalt der Nährlösung

Nitrogen nutrition and Al toxicity with young beech plants. I: Development of young beech plants in relation to the source of nitrogen and the Al content of the nutrient solution Young beech plants were grown in aerated nutrient solutions with different Al concentrations over a period of 14 weeks. Nitrogen was supplied in either NO₃- or NH₄-form. pH-changes of the solutions were either corrected to the initial pH of 4 after two days, or not corrected over a period of two weeks. Root growth of the beech seedlings was inhibited by Al. Reduction of root length and dry matter production was more severe if the plants were fed with ammonium nitrogen compared to nitrate nitrogen. Detrimental effect of Al on root growth was also influenced by the pH of the solution. NH₄-N-nutrition led to pH decrease and therefore to increased solubility and toxicity of aluminium. On the contrary, NO₃-N-nutrition weakened Al toxicity because of pH increase at the root surface and in the AFS. This led to an inactivation of Al in the form of insoluble hydroxy aluminium polymers. Compared to NO₃-N-nutrition NH₄-N promoted shoot growth. During 14 weeks no detrimental effect of Al on shoot growth was observed.     

Stickstoffernährung und Al-Toxizität bei Buchenjungpflanzen. II: Mineralstoffgehalte junger Buchen in Abhängigkeit von der Form der Stickstoffernährung und dem Al-Gehalt der Nährlösung

Nitrogen nutrition and Al toxicity with young beech plants. II: Mineral contents of young beech plants in relation to the source of nitrogen and the Al content of the nutrient solution Young beech plants were grown in aerated nutrient solutions with different Al concentrations over a period of 14 weeks. Nitrogen was supplied in either NO₃ or NH₄-form. pH-changes of the solutions were either corrected to the initial pH of 4,0 after two days, or not corrected over a period of two weeks. The cation contents of the roots and shoots were greater if the nitrogen was supplied in NO₃-form. Increasing Al concentrations in the nutrient solutions led to an increase in Al contents and a decrease in Ca- and Mg-contents in roots and shoots.