土壤中磷、钾、钙、镁的同时提取以及对巴西南部作物的钾肥推荐

Simultaneous multi-element extraction has been increasing worldwide to improve soil laboratory testing quality and effciency. This study sought to investigate the applicability of the Mehlich-1, Mehlich-3, and resin methods for simultaneous extraction of soil available P, K, Ca, and Mg as well as the effect of using conversion equations on nutrient recommendations for crops. Topsoil (0-20 cm) samples were taken from the most representative soil types used for crop production in southern Brazil with a wide range of chemical, physical, and mineralogical properties. Soil P, K, Ca, and Mg were simultaneously extracted using 1.0 mol L-1 KCl, Mehlich-1 and Mehlich-3 solutions, and membrane resin. The amounts of P extracted with the Mehlich-1 method were, on average, 50% lower than those extracted with the resin and Mehlich-3 methods. However, the resin method extracted the lowest amounts of K, Ca, and Mg. The use of conversion equations was suitable and it did not a?ect negatively the K recommendations for crops grown on soils of southern Brazil.     

Comparison of the ammonium acetate,Mehlich 3, and sodium tetraphenylboron as extractants to evaluate crop available potassium

ABSTRACT

The 1 M ammonium acetate (NH₄OAc) (AA) is the most widely used method for soil-test potassium (K), but other methods have been also suggested to estimate crop available K. The accuracy of these extractants may be influenced by soil texture and clay mineralogy. This study evaluated the relationships among AA, Mehlich-3 (M3), and sodium tetraphenylboron (TPhB) methods using soils differing in texture and clay minerals from the agricultural area of Uruguay. The M3 and AA extractable K concentrations were highly correlated (R² > 0.97) across soils, although AA extracted slightly higher amount of K than M3. The TPhB method extracted more K than AA and M3, indicating that extracted K from different pools. The slopes of the relationships between TPhB and AA or M3 varied among soils being higher in fine-textured and illitic soils than in coarse soils. These results would be useful for evaluating the feasibility of incorporating M3 into a test program using the existing calibrations of the AA method. In addition, TPhB could be considered a complementary tool to improve the interpretations of the extractants to estimate soil-test K along with other characteristics such as the texture and clay mineralogy.     

Evaluation of universal extractants for determining plant available potassium in intensively cultivated soils

Abstract

Eighteen soils from northwestern Switzerland were used to study the value of seven universal extractants (CaCl₂; DB‐DTPA; Mehlich 1, 2, and 3; Morgan‐Wolf; and NH₄OAc‐EDTA) for predicting plant available potassium (K) as compared to a bioassay (a modified Neubauer test with winter rye). These extractants were evaluated on the basis of K uptake by the bioassay test and the soil K status. In order to create the sufficiency level of exchangeable K for plant growth, soils were treated with 0, 20, 40, 80, and 160 mg K/kg of soil. The range of K uptake by the bioassay tests was between 89.2 and 403.0 mg/kg of soil for the control pots, and 136.6 to 495.8 for the K treatments with optimal conditions for plant growth. The average amounts of K extracted by the seven universal extractants, in ascending order, were: CaCl₂ < Morgan‐Wolf < Mehlich 1 < Mehlich 2 < NH₄OAc‐EDTA < Mehlich 3 < DB‐DTPA. The highest simple correlation with K uptake versus the bioassay test was obtained with the DB‐DTPA (r = 0.89) extractant and the lowest with the Mehlich 1 (r = 0.53) extractant. The DP‐DTPA, NH₄OAc‐EDTA and Mehlich 3‐K procedures showed an advantage over K procedures based on water soluble and exchangeable K pools in the investigated soils in order to predict the amount of plant‐available K. A simple regression and the Cate‐Nelson graphic method offer the possibility of assessing the soil‐K status using K values obtained by these universal extractants and to calibrate them against K forms as follows: exchangeable, water soluble, and non‐exchangeable.     

Testing for calcium,magnesium, and potassium in soilless potting media: Differences and similarities between extractants

Abstract

Interpretation guidelines for the availability of calcium (Ca), magnesium (Mg), and potassium (K) in soilless media have been developed through plant growth studies and comparisons amongst extractants. The extractants used were 70% ethanol (EtOH), water, DTPA, ammonium acetate (NH₄OAc) and silver thiourea (AgTu). Ethanol, which removes ions in pore water, extracted only 4.5, 13, and 26% of the Ca, Mg, and K, respectively, that could be extracted by AgTu from Pinus radiata bark of pH 5.66 and CEC of 11.2 cmol⁺/L. Acidification to pH 4.62 increased these proportions to 22, 40, and 38%. Correlations between water and DTPA for 39 media were excellent for both individual elements and the ratios Ca/Mg, K/Mg, and Ca, Mg, and K/(the sums of their concentrations in the extractants) (r² = 0.88–0.98). Correlations between these extractants and AgTu and NH₄OAc were poor for individual elements (r² = 0.37–0.75) but high for ratios (r² = 0.71–0.96). For Petunia ’Celebrity Salmon’ growing in peat media of similar pH but widely different Ca, Mg, and K proportions, the ratios of these elements in the shoots were highly correlated with their ratios in 2 mM DTPA extracts of the media. Similarly high correlations were obtained between the Ca/Mg ratios of the shoots of three Asplenium species growing in pinebark media and this ratio for DTPA, NH₄OAc, and AgTu extracts of the media. The results indicate that the ratios of Ca, Mg, and K to one another in water and DTPA extracts of soilless media are good indicators of the availability of these elements to plants. Healthy specimens of the test plants grew in media whose DTPA extracts had a minimum Ca/Mg mole ratio of 1 or 2, depending on the Ca requirements of the species. The upper limit for good growth was deduced to be about 6. Limits for NH₄OAc and AgTu extracts were similar to those found for crop plants in soils, at 1.6 or 3 to about 9. Minimum amounts of Ca, Mg, and K extracted by water and DTPA that were adequate for short‐term growth in the absence of further inputs were about 9,2.5, and 5 cmol⁺/L medium, respectively, at pH 6.0. The effect of pH on cations removed by water and DTPA raises the minima to about 19, 5, and 7.5 cmol⁺/L at pH 5.0.     

A simplified method for the extraction and analysis of available nitrogen,phosphorus, and potassium in soils

Abstract

Sodium bicarbonate (NaHCO₃) and calcium chloride (CaCl₂) are proposed as simultaneous extractants of available nitrate‐nitrogen (NO₃ ^‐‐N), phosphorus (P), potassium (K) in soils. Flow Injection methods were used for the determination of NO₃ ^‐ and P, and atomic emission spectroscopy for K. Parameters, such as reproducibility, precision, and recovery of the different extraction processes were studied. The usefulness of the proposed extractants was tested by applying them to different samples from the Spanish Soil Collection. The results obtained were compared with those provided after using the extractants recommended by the official methods. Sodium bicarbonate turned out to be suitable for the simultaneous extraction of NO₃ ^‐, P, and K in alkaline soils, whereas CaCl₂ was only advisable for NO₃ ^‐.     

Comparison of four extractants and chemical fractions for assessing available zinc and copper in soils of India

Abstract

Relative suitability of different extraction procedures for estimating available zinc (Zn) and copper (Cu) in soils was assessed using DTPA, 0.1 N HCl, ammonium acetate+EDTA, and double acid (HCl+ H₂SO₄) as extractants and rice as a test crop in Neubauer experiment. The relationships between Zn concentration and uptake of Zn by rice plants and Zn extracted by the different methods showed that DTPA‐TEA, pH 7.3, could very suitably be used to assess Zn availability in soils. However, 0.1 N HCl was better for assessing the Cu availability in soils to the rice plants. Water‐soluble and exchangeable fractions of Zn and Cu had significant positive correlations with Zn and Cu concentrations, respectively obtained by all the four extractants tested. The results also showed that DTPA and ammonium acetate+EDTA extracted organically bound Zn, whereas DTPA, 0.1 N HCl and ammonium acetate+EDTA extracted organically bound Cu. Water‐soluble, exchangeable and organic matter bound fractions exhibited significant relationships with Zn and Cu concentrations, their uptake and rice dry matter yield.     

Evaluation of some chemical extractants for determination of exchangeable ammonium in tropical rice soils

Abstract

Seven rice soils varying in texture, pH, organic matter and total nitrogen content were extracted with 1N and 2N KCl, 1N and 2N Nacl, 10% Nacl at pH 2.5, N CH₃ CooNa at pH 3.0, and Morgan's reagent using a soil: solution ratio of 1:10. The ammonium in the extracts was determined by steam distillation with MgO.

The normality of KCl or Nacl had no significant effect on the amount of NH₄ ⁺ ‐N extracted but KCl proved a better extractant than Nacl. However, Nacl at pH 2.5 generally extracted significantly higher amounts of NH₄ ⁺ ‐N as compared to the neutral salt solution. N CH₃ CooNa at pH 3.0 did not extract more NH₄ ⁺ than Morgan's reagent. Overall, KCl appeared to be better than Nacl; Nacl at pH 2.5 N CH₃ CooNa and Morgan's reagent were either equally effective or better for some of the soils as compared to KCl. However, when recovery of the known amount of NH₄ ⁺‐N applied to soils was used as a criterion, the efficiency of these chemicals were in the following descending order: KCl > NaCl, pH 2.5 > NaCl > CH₃CooNa, pH 3.0 > Morgan's reagent.     

Simplified flow injection slurry method for direct flame atomic absorption spectrometric determination of calcium,magnesium, sodium and potassium in fruits

A rapid, direct flow injection slurry atomization flame atomic absorption spectrometric procedure for Ca, Mg, Na and K determination is shown to give reproducible and accurate results for a variety of tropical fruits. The optimized conditions obtained for instrumental, slurry formation and manner of calibration graphs preparation are detailed. Ground fruit is simply suspended by being shaken in a Triton X-100 solution. Statistical evaluation of results from certified and non-certified materials indicate that the flow injection slurry method is both accurate and comparable in precision to a traditional wet acidic sample digestion procedure.     

Comparison of ammonium lactate,sodium bicarbonate and double calcium lactate methods for extraction of phosphorus from wetland peat soils

Procedures for routine analysis of soil phosphorus (P) have been used for assessment of P status, distribution and P losses from cultivated mineral soils. No similar studies have been carried out on wetland peat soils. The objective was to compare extraction efficiency of ammonium lactate (P-AL), sodium bicarbonate (P-Olsen), and double calcium lactate (P-DCaL) and P distribution in the soil profile of wetland peat soils. For this purpose, 34 samples of the 0–30, 30–60 and 60–90 cm layers were collected from peat soils in Germany, Israel, Poland, Slovenia, Sweden and the United Kingdom and analysed for P. Mean soil pH (CaCl₂, 0.01 M) was 5.84, 5.51 and 5.47 in the 0–30, 30–60 and 60–90 cm layers, respectively. The P-DCaL was consistently about half the magnitude of either P-AL or P-Olsen. The efficiency of P extraction increased in the order P-DCaL<P-AL≤P-Olsen, with corresponding means (mg kg^?1) for all soils (34 samples) of 15.32, 33.49 and 34.27 in 0–30 cm; 8.87, 17.30 and 21.46 in 30–60 cm; and 5.69, 14.00 and 21.40 in 60–90 cm. The means decreased with depth. When examining soils for each country separately, P-Olsen was relatively evenly distributed in the German, UK and Slovenian soils. P-Olsen was linearly correlated (r=0.594, P=0.0002) with pH, whereas the three P tests (except P-Olsen vs P-DCaL) significantly correlated with each other (P=0.0178≤0.0001). The strongest correlation (r=0.617, P=0.0001) was recorded for P-AL vs P-DCaL) and the two methods were inter-convertible using a regression equation: P-AL=?22.593+5.353 pH+1.423 P-DCaL, R ² =0.550.     

Evaluation of three calcium extractants for coastal plain soils

Abstract

Mehlich 1‐Ca is used as an index to predict the Ca requirement for peanut (Arachis hypogaea L.) fruit development in major peanut growing states. Recently, some concern has been raised about the inadequacy of Mehlich 1 extractable Ca for that purpose. Possible use of alternative extractants for soil Ca has been suggested. In this study, relationships among Mehlich 1, 0.2 M NH₄Cl and 0.01 M NaNO₃ extractable Ca were examined in several Coastal Plain soils to which gypsum or lime had been applied. Variability in extractable Ca was much greater following lime treatment than following gypsum treatment. In Bonifay soil, the quantity of Ca extractable by the three extractants was similar in a gypsum treatment, but in a lime treatment (at an application rate equivalent to the gypsum treatment) Mehlich 1‐Ca was 2 and 5‐fold greater than NH₄Cl‐ and NaNO₃‐Ca, respectively. In Greenville soil, Mehlich 1‐Ca was 3 to 4‐fold greater than NaNO₃‐Ca regardless of gypsum or lime amendment.

For soil samples from a field experiment on Lakeland sand, where lime or gypsum was applied prior to planting, Mehlich 1‐Ca was 7.5 and 2.2‐fold greater than NaNO₃‐Ca for the lime and gypsum treatments, respectively. Greater variability in Mehlich 1‐Ca in lime than in gypsum treatments was due to possible inclusion of undissolved limestone in the soil samples, resulting in overestimation of Ca available for peanut fruits. Mehlich 1‐Ca appears to be an adequate index of soil Ca for prediction of supplemental Ca requirement for peanut if lime has not been applied or has been applied well in advance of planting, thus minimizing the inclusion of undissolved limestone with the soil sample taken from the fruiting zone (0–8 cm depth) 10–14 d after planting.     

Seasonal patterns of nitrogen,phosphorus, potassium,calcium and magnesium in the leaves of the massachusetts cranberry

Abstract

Leaf samples from cranberry plants in Wareham, Massachusetts were collected during the 1980–82 growing seasons and analysed for N, P, K, Ca and Mg. The seasonal patterns which emerged allowed the proposal of normal ranges for the elements and optimum times for sampling. The foliar nutrient levels obtained were compared to those for cranberries grown in other areas as well as to those for crops which are grown under similar conditions.     

Comparison of different extractants for the determination of inorganic sulphate in gypsum‐free agricultural soils

Four frequently used extractants (H₂O, 0.1 M NaCl, 0.016 M KH₂PO₄, and 0.5 M NaHCO₃) as well as different extraction conditions have been tested for sulphate extraction from gypsum‐free agricultural soils. Water is the preferable extractant for soils with pH > 6. Two extraction steps have to be carried out for complete extraction (> 95%). A 0.016 M KH₂PO₄ solution was found to be the most efficient extractant for soils with a pH < 6 within a single extraction step. A shaking frequency of 170 min^‐1 and a duration of extraction of 4 hours are the optimized conditions for the sulphate extraction with H₂O and KH₂PO₄ solution.     

Comparison of some methods for determination of sulfate in soils

Abstract

Sulfate (SO₄ ^2‐) is present in soils as salts of various metals, and the different metals associated with sulfate may influence adsorption of SO₄ ^2‐by soils. The analytical method used for determination of SO₄ ^2‐could be affected by the type of metal associated with the SO₄ ^2‐. Four analytical methods based on different principles were evaluated for determination of SO₄ ^2‐in different metal salts and in soil extracts obtained with three extractants {0.1M lithium chloride (LiCl), 0.15% calcium chloride (CaCl₂), and 500 mg P/L as calcium phosphate [Ca(H₂PO₄)2]}. The analytical methods were: (i) a methylene blue (MB) colorimetric method after the reduction of SO₄ ^2‐to hyrogen sulfide (H₂S), (ii) an ion Chromatographie (IC) method, (iii) a turbidimetric (TD) method, and (iv) an indirect barium (Ba) atomic absorption spectrophotometric (SP) method. The recovery of SO₄ ^2‐associated with various mono‐, di‐, and tri‐valent metals was quantitative by the MB method. But, trivalent metals, such as aluminum (Al), indium (In), lanthanum (La), and scandium (IC), decreased the recovery of SO₄ ^2‐by the other three methods. The MB and IC methods gave similar values for SO₄ ^2‐in soils by using the three extractants. The TD and SP methods gave variable results and, in general, underestimated the amounts of SO₄ ^2‐in soils. Among the four methods, the MB and IC methods were the most accurate and precise.     

振荡浸提电感耦合等离子体发射光谱法同时测定土壤中速效钾及交换性钙、镁

采用振荡浸提法对土壤样品进行前处理，电感耦合等离子发射光谱法对样品试液中速效钾及交换性钙、镁含量进行测定。该方法简单、快捷，测定结果准确可靠，重复性、稳定性好，明显提升了分析检验工作效率。     

Evaluation of multi-nutrient extractants for determination of available P,K, and micronutrient cations in soil

Sixty soil samples (0–0.15 m depth) collected randomly from different districts of Himachal Pradesh were used to evaluate ammonium bicarbonate-diethylenetriaminepenta acetic acid (AB-DTPA) and acid ammonium acetate-ethylene diamine tetra acetic acid (AAAc-EDTA) over standard methods for P, K, and micronutrient cations. Among Olsen P, Bray P1, AB-DTPA P, and AAAc-EDTA P, available P (kg ha^?1) varied from 7.8 to 44.3, 9.5 to 61.1, 6.5 to 38.8, 10.5 to 52.1; available K (kg ha^?1) among NH4OAc, AB-DTPA, and AAAc-EDTA ranged from 103.6 to 372.3, 86.6 to 364.9, and 74.6 to 362.5. In case of micronutrients cations, AB-DTPA in general, extracted more amounts as compared to DTPA alone. AAAc-EDTA correlated highly with the Olsen P. AB-DTPA-K and AAAc-EDTA-K correlated well with standard method (NH4OAc) however; AAAc-EDTA had higher correlation with AB-DTPA for K extractability. Among methods for micronutrients highest significant correlations were observed between AB-DTPA and DTPA for Cu, Fe, and Zn.     

Preliminary nitrogen,phosphorus, potassium,calcium and magnesium DRIS norms and indices for apple orchards in Canterbury,New Zealand

Abstract

Diagnosis and Recommended Integrated System (DRIS) norms and indices for N, P, K, Ca and Mg were developed for apple trees in Canterbury, New Zealand, based on surveys of nutrient levels of apple leaves in field experiments before and after N and K fertiliser applications and in four orchard surveys over a period of three years. Comparisons were made between calculated norms based on mean sufficiency nutrient levels and published norms. Results obtained showed that calculated norms and indices from sufficiency range provide a good indication of the order of apple nutrient requirements. High N and low Ca were identified as major nutrient problems. The best period for sampling leaves for nutrient analysis is at 3 to 5 months after blossom (i.e., December to January in New Zealand).     

Effects of potassium nutrition on the absorption of sodium,calcium, and magnesium by intact tomato plants

Abstract

Tomato plants (cv. VF145 B 7879) were grown in a greenhouse by the water culture technique with six levels of K nutrition. The absorptions of Na, Ca, and Mg were not affected greatly by the K nutritional status of the intact tomato plants, except when the plants were extremely K deficient. The rates of absorption by the intact plants were slow initially when the plants were small, and then increased rapidly as the growth rates increased.

At the onset of K deficiency, the rate of growth and water use by the tomato plant decreased. A linear function of water use and plant size was obtained, indicating that water use was a function of plant size and hence a function of the plant's nutritional status.

Waterlogging, simulated by aeration cut‐off of the culture solution for two days, had only a small effect on water use, but concurrently interrupted the absorption of K, Ca, and Mg.     

Comparison of extractants for available sludge-borne metals: A residual study

To study the availability of sludge-borne Zn, Cu, Cd, Ni and Pb over time, a field study was conducted. Anaerobically digested sewage sludge (dried on sandbeds) from Huntsville and Chicago were applied to a Decatur silty clay loam soil (clayey, kaolinitic, thermic, Rhodic Paleudult), pH 6.2, for 5 consecutive yr. The sludges were applied at rates of 0, 20 (annual application for 5 yr) and 100 mt ha^?1 (single application). Corn (Zea mays L.) and sudangrass (Sorghum sudanenses) were grown on the sludge-treated plots as test crops in 1987. Plant tissue samples were collected at different growth stages. Soil samples collected from the sludge-treated plots were extracted for Zn, Cu, Cd, Ni and Pb by 0.1 M HCI, DTPA, Mehlich 1 and Mehlich 3 extractants. Statistically, Mehlich 1, Mehlich 3, DTPA and 0.1M HCI extractants all gave highly significant correlations with the plant accumulation of Zn, Cu, Ni and Cd, with DTPA giving the highest at any growth stage for both corn and sudangrass, but they gave poor correlations for Pb. Zinc removed by four extractants was more highly correlated with Zn accumulation by corn (r=0.72^** to 0.93^** p=0.01) and sudangrass (r=0.50^** to 0.96^**, p=0.01) than other metals. Based on higher significant linear correlation coefficients (r), DTPA would be the extractant of choice for both crops; however the advantage to using the Mehlich 3 extractant is that, with a shorter shaking time of 5 min (compared to 2 hr for DTPA), it may be better suited for routine analysis of large numbers of soil samples.

     

不同类型的离子交换树脂对土壤速效钾测定的影响

通过室内模拟试验研究,结果表明不同类型的离子交换树脂膜在饱和溶液中的吸附曲线基本相同,但对钾的吸附数量差异很大,国产树脂膜对钾离子的平均饱和吸附量为8303.6μg/cm2,而进口树脂膜对钾离子的平均饱和吸附量为2209.8μg/cm2,仅是国产膜的26.6%.在土壤中,离子交换树脂膜对钾的吸附量随时间呈对数关系,在开始2小之内,二者的吸附量差异不大,以后随时间的延长,二者的吸附量差异逐渐增大.在钾离子的测定中,进口膜通过接触交换至膜上的钾离子数量占总比例为25%,而国产膜为38.5%,土壤含水量对土壤钾的测定有很大影响.     

造纸厂污水对不同品种大豆中钾、钙、钠和镁浓度的影响

A field experiment was conducted on a sandy loam soil at an Experimental Farm in Taejon, South Korea, to determine the effects of paper mill sludge compost application rates on K, Na, Ca and Mg concentrations of soybean (Glycine max (L.) Merr.) aboveground tissues and the genotypic effects on the concentrations of these elements. Sludge compost treatments of 0, 75, and 150 t ha-1 were applied to 30 diverse soybean cultivars. Concentrations of K, Na, Ca, and Mg in aboveground tissues harvested 69 days after planting (DAP) varied with the genotype and the application rate of paper-mill sludge compost, with the sludge compost application rate exerting stronger influence on these concentrations than the genotype. The magnitude of variation caused by both genotype and sludge compost application was in the order of Mg > K > Ca > Na. Significantly positive correlations were observed between K and Na (P < 0.01), Na and Ca (P < 0.05), and Ca and Mg (P < 0.01). Also, the lower the sludge compost application rate, the larger the variation in the concentrations of K, Na, and Ca. From this several cultivars were identified for use as an accumulator for one or more of these elements.