Evaluation of phosphorus availability from three phosphorus sources in Nigerian soils

Abstract

In an attempt to search for a cheaper source of phosphorus (P), both for direct application and industrial use, three P fertilizers were evaluated in incubation and greenhouse studies. Indigenous Sokoto rock phosphate (SRP) imported, Togo rock phosphate (TRP), and conventional single superphosphate (SSP) were applied on three soil types namely Oxisol, Ultisol, and Alfisol at rates ranging from 0–800 mg P kg^‐1 soil. Evaluation of the P sources was conducted for 12 weeks in incubation study, and five weeks in the greenhouse using maize as test crop. Evaluation of direct application of SSP and SRP on an oxic paleudult was carried out in the field for three years. The results of incubation studies revealed in general, that P availability increased as fertilizer rates increased. The P availability was, however, greater when SSP was applied on the Alfisol than on the Oxisol and Ultisol. The rock phosphates on the other hand were more efficient on acid soils than on soils neutral in pH. Optimum P availability from the fertilizers was observed to occur predominantly between four and eight weeks of incubation. In the greenhouse study, SSP gave the highest cumulative P uptake and optimum rate of application was 200 mg P kg^‐1 soil, while optimum rate for rock phosphate was 400 mg P kg^‐1 soil. The agronomic effectiveness (EA) of the rock phosphates was about 40% relative to SSP on the Alfisol. The EA, however, for TRP and SRP was 120% and 160%, respectively, on the Oxisol, while on the Ultisol, SRP was equally effective as SSP and TRP had 65% effectiveness. The results of the field trial indicated that the SRP had 54%, 83%, and 107% agronomic effectiveness of SSP, respectively, in the first, second, and third year of cropping. Optimum rate for SSP and SRP application was considered to be 50 and 75 kg P₂O₅ ha^‐1, respectively.     

RESIDUAL EFFECTS OF PHOSPHORUS SOURCES IN GRAIN AMARANTH PRODUCTION

Productivity of grain amaranth can be improved at a reduced cost through combined use of low-cost rock phosphate (RP) phosphorus sources as well as selection of amaranth varieties with high phosphorus (P) use efficiencies. Rock phosphate sources are known to exhibit differences with respect to grain yield, disease tolerance and P use efficiency (PUE) in amaranth varieties. However, very little is known about their residual release of P. It is probable that the differential performances exhibited by the RPs might be a function of their P residual properties after cropping. Based on these premises this study was carried out to evaluate the residual effects of P sources under continuous croppings for grain amaranth production. The study was a factorial experiment with four replications. Four P sources: single super phosphate – SSP, ogun rock phosphate – ORP, sokoto rock phosphate – SRP, and control; three amaranth varieties: NH84/493, NH84/445 and NH84/452 were factorially combined with two soil types: Kandiudult and Haplustalf. In order to monitor the residual effects of the P sources the experimental plots were cropped consecutively three times. Results from the study revealed that sandy loam Haplustalf was better than the clayey Kandiudult soil in improving grain amaranth yield under continuous cropping system. Grain yield and relative agronomic efficiency (RAE) decreased with continuous cropping for SSP but increased with continuous cropping for ORP and SRP till second cropping, thereafter there was a decrease. Averaged over the three continuous consecutive croppings, SRP and ORP were 68.9% and 73.5% as effective as SSP in increasing grain yield respectively. It was concluded therefore that ORP and Haplustalf soil are best options for grain amaranth production under continuous cropping system.     

Phosphate rock and a phosphate rock/superphosphate mixture as fertilizers for crops grown on a calcareous soil

Abstract

The agronomic effectiveness of Mussoorie phosphate rock (MPR) from India and a 2:1 mixture of MPR and single superphosphate (SSP) was compared against SSP as phosphate fertilizers for crops. The experiment was conducted for three seasons and was designed to study the response of crops to current application as well as residual effects of the various P fertilizers. Three crops were grown in sequence: finger millet (Eleusine coracana), maize (Zea mays L.), and blackgram (Phaseolus mungo) on a calcareous soil under irrigated conditions. The phosphate fertilizers were applied to finger millet and/or maize but not to the blackgram. Soil samples were collected at intervals and analysed for Olsen bicarbonate‐extractable P. The agronomic effectiveness of fertilizers relative to SSP (RAE) were calculated from the fertilizer substitution ratios. When used on finger millet, the RAE of MPR, calculated at a yield which corresponded to 90% of calculated maximum yield on applying SSP, was 42%. For the mixture of MPR and SSP the RAE was 68%. On maize, yield in MPR treatment plateaued at too low a level (about 80% of calculated maximum yield for SSP) to calculate RAE but for MPR/SSP the RAE was 80%. The residual effectiveness of fertilizers on the second crop, compared against freshly applied SSP was 41% for SSP, 49% for MPR, and 73% for MPR/SSP. Olsen bicarbonate‐extractable P values determined one month after fertilizer application increased over control by about 55% in MPR and 86% in MPR/SSP treatments relative to SSP. Economic calculations indicated that, application of MPR is of equal value to SSP for the cropping sequence whereas MPR/SSP for the cropping sequence as well as for individual crops.     

Effect of two moisture regimes on P-release from P treated soils

Understanding phosphorus (P) release under different climatic or moisture regimes will facilitate effective management of plant nutrition. The objective of this study is to evaluate the effect of two soil moisture regimes on P release from Ogun rock phosphate (ORP) and Sokoto rock phosphate (SRP) in two soil types. Soil was poured into soil columns to form lower and top layers. Top layer was mixed with 400 kg ha^?1 P from ORP, SRP, single super phosphate (SSP) and leached with 35.4 cm³ water representing low moisture regime (LMR; 400 mm rainfall) and 106.1 cm³ water for high moisture regime (HMR; 1200 mm rainfall). P concentrations of leachates, available P in soil and soil pH were determined. Cumulative P leached was higher under HMR than LMR in both soils. There was more leaching with SSP (0.41–0.97 mg P) than both phosphate rocks (0.008–0.19 mg P) indicating leaching potential of SSP. Cumulative P leached from SSP treated Olokemeji soils was twice that of acidic Sapoba under LMR while they were similar (Olokemeji, 0.97 mg P; Sapoba, 0.94 mg P) under HMR suggesting that LMR enhances fixation of P in acidic soils. Irrigation of P fertilized soils may reduce P sorption in acidic soils.     

Relative Agronomic Effectiveness of phosphate rocks and P adsorption characteristics of an Oxic Rhodustalf in Eastern India

The Relative Agronomic Effectiveness (RAE) of rock phosphates as compared to water soluble Triple Super Phosphate was measured on direct, residual, and cumulative application of the P fertilizers in a field experiment with rice on an Oxic‐Rhodustalf in the eastern plateau region of India. The fertilizers were Morocco Rock Phosphate (MORP), Mussoorie Rock Phosphate (MRP), Partially Acidulated Rock Phosphate (PARP), and Triple Super Phosphate (TSP). The RAE of the rock phosphates were lower for direct application (54–80 %) and cumulative application (70–93 %) of P but roughly equal or larger for the residual effect (92–142 %) as compared to TSP. The P adsorption characteristic of the experimental soil conformed to the linear relationship of both Freundlich and Langmuir isotherm equation. The adsorption data when plotted according to Langmuir equation deviated from a single linear relationship at higher concentration (10 μg ml^–1), thereby giving two adsorption maximum values ( 68.49 μg g^–1 and 256.41 μg g^–1) and binding energies ( 2.86 ml μg^–1 and 0.089 ml μg^–1) for the soil. Two populations of P adsorption site with widely different affinity for P probably existed in the soil.     

Long‐term field fertilization affects soil nitrogen transformations in a rice‐wheat‐rotation cropping system

Mineralization and nitrification are the key processes of the global N cycle and are primarily driven by microorganisms. However, it remains largely unknown about the consequence of intensified agricultural activity on microbial N transformation in agricultural soils. In this study, the ¹⁵N‐dilution technique was carried out to investigate the gross mineralization and nitrification in soils from a long‐term field fertilization experiment starting from 1988. Phospholipid fatty acids (PLFA) analysis was used to determine soil microbial communities, e.g., biomasses of anaerobic bacterial, bacterial, fungi, and actinobacteria. The abundance of ammonia‐oxidizing bacteria (AOB) and archaea (AOA) were measured using real‐time quantitative polymerase chain reaction. The results have demonstrated significant stimulation of gross mineralization in the chemical‐fertilizers treatment (NPK) ([6.53 ± 1.29] mg N kg^–1 d^–1) and chemical fertilizers–plus–straw treatment (NPK+S1) soils ([8.13 ± 1.68] mg N kg^–1 d^–1) but not in chemical fertilizers–plus–two times straw treatment (NPK+S2) soil when compared to the control‐treatment (CK) soil ([3.62 ± 0.86] mg N kg^–1 d^–1). The increase of anaerobic bacterial biomass is up to 6‐fold in the NPK+S2 compared to that in the CK soil ([0.7 ± 0.5] nmol g^–1), implying that exceptionally high abundance of anaerobic bacteria may inhibit gross mineralization to some extent. The gross nitrification shows upward trends in the NPK+S1 and NPK+S2 soils. However, it is only significantly higher in the NPK soil ([5.56 ± 0.51] mg N kg^–1 d^–1) compared to that in the CK soil ([3.70 ± 0.47] mg N kg^–1 d^–1) (p < 0.05). The AOB abundance increased from (0.28 ± 0.07) × 10⁶ copies (g soil)^–1 for the CK treatment to (4.79 ± 1.23) × 10⁶ copies (g soil)^–1 for the NPK treatment after the 22‐year fertilization. In contrast, the AOA abundance was not significantly different among all treatment soils. The changes of AOB were well paralleled by gross nitrification activity (gross nitrification rate = 0.263 AOB + 0.047 NH ‐N + 2.434, R² = 0.73, p < 0.05), suggesting the predominance of bacterial ammonia oxidation in the fertilized fields.     

Long‐term effects of organic manure and manufactured fertilizer additions on soil quality and sustainable productivity of finger millet under a finger millet–groundnut cropping system in southern India

In a 20‐yr‐old long‐term experiment, the impact of continuous application of organic manures and inorganic fertilizers on soil quality and the sustainability of finger millet production was conducted on two cropping systems: finger millet and finger millet–groundnut on an Alfisol of semi‐arid southern India. The study was conducted from 1992 to 2011 at the All India Coordinated Research Project for Dryland Agriculture, UAS, Bangalore, using a randomized block design. The treatments comprised of T₁: control [no fertilizer and no farmyard manure (FYM) applied], T₂: FYM 10 t/ha, T₃: FYM 10 t/ha + 50% of recommended NPK (50:50:25 kg/ha), T₄: FYM 10 t/ha + 100% of recommended NPK and T₅: 100% recommended NPK. Comparison of long‐term yield data between treatments was used to calculate a ‘sustainability yield index’ (SYI), which was greatest for T₄ (FYM 10 t/ha + 100% of recommended NPK), in both rotational (0.68) and monocropping (0.63) situations. Soil quality indices were determined using principal component analysis linear scoring functions. The key indicators which contributed to the soil quality index (SQI) under rotation were organic C; potentially available N; extractable P, K and S; exchangeable Ca and Mg; dehydrogenase activity and microbial biomass C and N. The largest SQI (7.29) was observed in T₄ (FYM 10 t/ha + 100% NPK), and the smallest (3.70) SQI was for the control. Application of 10 t/ha FYM together with NPK (50:50:25 kg/ha) sustained a mean yield of 3884 kg/ha.     

Corn Monoculture Yield Response to Fertilization and Nitrate Nitrogen Distribution

The objectives of this study were to determine the effects of fertilization system, nitrate (NO₃)– nitrogen (N) distribution along soil profile, and their interaction on corn yield. The study was conducted at the experimental field of Institute of Field and Vegetable Crops in Novi Sad (Serbia) during 2001–2004. Corn monoculture included four fertilization variants: control (Ø), nitrogen–phosphorus–potassium (NPK) mineral fertilizers, mineral fertilizer + corn stalks (NPK + S), and mineral fertilizers + manure (NPK + M). The greatest yield was found in the variant NPK + M (9.25 t ha^?1). Path coefficients showed that greatest direct positive effects on corn yield were exhibited by NO₃-N levels at soil depths of 60–90 cm and 30–60 cm. The path analysis showed that winter precipitation (WP) had a direct negative effect on yield performance. However, the effect of the downward movement of NO₃-N from the topsoil to deeper soil layers of WP on yield was positive.     

Nutrient concentrations and NH4+‐N mineralization under different soil types and fallow forms in southern Cameroon

To evaluate the soil‐fertility sustainability of the fallow systems, nutrient concentrations and NH₄⁺‐N mineralization were determined in different soil and fallow types in the humid forest zone of southern Cameroon. Two experiments were conducted, the first comprised planted leguminous tree Calliandra calothyrsus, planted leguminous Pueraria phaseoloides, and regrowth mainly composed of Chromolaena odorata on the Typic Kandiudult. The second experiment made up of a fallow dominated by C. odorata, a fallow with C. odorata removed, and a P. phaseoloides fallow on the Rhodic Kandiudult, Typic Kandiudult, and Typic Kandiudox. In the first experiment, available P, Ca²⁺, K⁺ concentrations and effective CEC under C. calothyrsus were, respectively, 40%, 22%, 45%, and 15% lower when compared to P. phaseoloides but no differences were found between soils under P. phaseoloides and C. odorata. Mineralization of NH₄⁺‐N was higher under C. calothyrsus than under C. odorata‐ and P. phaseoloides‐fallow types, indicating the impoverishment of organic material under the former. In the second experiment, the beneficial effect of P. phaseoloides was found in the Rhodic Kandiudult in the 0–10 cm layer throughout its low NH₄⁺ release from mineralization. In the Typic Kandiudult, no differences in NH₄⁺‐N mineralization were found between C. odorata and P. phaseoloides fallows. In the Typic Kandiudox, there was no difference in NH₄⁺ mineralization between the three fallow types. According to the nutrient concentrations and NH₄⁺ mineralization, the fertility sustainability of the different fallow types may be ranked as follow: P. phaseoloides ≥ C. odorata > C. calothyrsus > fallow without C. odorata.     

Effects of Boron and Lime on Productivity of Garden Pea under Acidic Soils in Northwestern Himalayas

An experiment comprising seven treatments was conducted to study the effect of boron and lime integrated with organic manures and nitrogen, phosphorus, and potassium (NPK) fertilizers on garden pea productivity. Seed yield along with growth parameters were significantly influenced by combined use of farmyard manure and NPK fertilizers either alone or in combination with boron and lime. Treatment combination of 20 t farmyard manure / ha + 100% NPK + borax (T₄) resulted in 37% increase in seed yield over recommended practice of 20 t farmyard manure / ha + 100% NPK (T₃). In addition, recommended practice supplemented with granubor (T₅) and lime (T₆) also significantly surpassed T₃ with respective increase of 14 and 10% in seed yield. Similarly, maximum nutrient was observed in T₄. Hence, application of boron along with farmyard manure and NPK fertilizers could be the best option to maximize pea productivity in acidic soils under humid subtemperate climate.     

Potassium→ammonium exchange of two benchmark soils from Botswana and its implication for nitrogen economy of the soils

Ion exchange preferences for NH₄⁺ and K⁺ by soil exchanger surface can greatly affect the NO₃^? leaching into groundwater and nitrogen-use efficiency in agricultural production. Since NH₄⁺ and K⁺ salts are usually applied together as fertilizers, the binary K→NH₄ exchange of two benchmark Botswana soils, Pellustert and a Haplustalf, was studied to determine the selectivity coefficients and the thermodynamic exchange constant with special reference to N economy. The Vanselow and the Gaines and Thomas coefficients indicated preference for NH₄⁺ by the Pellustert and K by the Haplustalf across the exchanger phase composition. The equilibrium constant (K_ex) was 1.807 for the Pellustert and 0.174 for the Haplustalf. The exchange free energy (ΔG_ex⁰) was ?1.467 kJ mol^?1 for the Pellustert and 4.334 kJ mol^?1 for the Haplustalf. Negative ΔG_ex⁰ for the Pellustert is consistent with preference for NH₄⁺ to K⁺ in contrast to positive ΔG_ex⁰ for the Haplustalf. The greater stability of NH₄X than KX complex in the Pellustert, and KX than NH₄X in the Haplustalf, would mean increased residence time of NH₄⁺ in the Pellustert than the Haplustalf. The implication of short residence time of NH₄⁺ in soil is rapid nitrification, thereby leading to NO₃^??N leaching losses and possible groundwater contamination.     

Polyhalite as a sulfur source for fresh market tomato production in Brazil

Abstract

Polyhalite (PH), a naturally occurring multinutrient fertilizer containing potassium (K), calcium (Ca), magnesium (Mg), and sulfur (S), has improved tomato (Solanum lycopersicum L.) production in Brazil but a specific response by tomato to the S in PH is not confirmed. We compared four S sources – PH, sulfate of potash (SOP), sulfate of potash magnesia (SOPM), and single super phosphate (SSP) – applied at a target application rate of 40?kg?S?ha^?1 to fertilizers with no S (muriate of potash, MOP), and no K or S at commercial application rates in three commercial fields in Brazil with nitrogen (N), phosphorus (P), and K applied at recommended rates of 355, 500, and 200–300?kg?ha^?1, respectively. Consistent across locations, PH increased total yields over the control, MOP, and SSP, with SOP and SOPM higher than the control but not MOP or SSP. Only PH increased marketable yields compared to the control. Yields increased linearly with fruit numbers per plant which were higher for PH than the control or MOP, indicating higher fruit set in PH contributed to yield differences. While fertilizers increased leaf K and S concentrations and soil test K and SO₄–S, yield differences did not appear to be related solely to either K or S fertilization, nor to Mg fertilizers to which there was no response. Leaf and fruit Ca concentrations were higher in PH than the control and MOP at some locations suggesting Ca improved fruit set in PH. Results suggest tomato likely responded to the multinutrient content or solubility pattern of PH.     

Agronomic effectiveness of partially acidulated phosphate rock fertilizers in an allophanic soil at near‐neutral pH

Abstract

The agronomic effectiveness of five partially acidulated phosphate rocks (PAPRs) and an unground phosphate rock (PR) were compared against single superphosphate (SSP) in a glasshouse experiment using a high phosphorus (P) retention soil at a near‐neutral pH (pH 6.5), and corn (Zea mays L.) as the test crop. The PAPRs were prepared by acidulating unground North Carolina PR with either phosphoric or sulphuric acid (expressed as Phos‐PAPR and SA‐PAPR, respectively) and at three levels of acidulation (20, 33, and 50%). The relative agronomic effectiveness (RAE) and substitution value (SV) of the test fertilizers, calculated with respect to SSP using the standard “vertical”; and “horizontal”; comparisons, showed that 50% phosphoric acidulated PAPR performed as effectively as SSP whereas the other fertilizers were less effective. The PR treatment showed a small yield response. The dry matter yield and P uptake were linearly related to water‐soluble P of the fertilizers up to 66% of total P and there was no advantage in acidulating fertilizers above this level of water‐soluble P using reactive PR. Whereas very little of the directly‐applied PR dissolved (3.4% of PR applied), PR applied as a component of PAPRs dissolved up to 22%. The dissolved proportion of added PR component increased with increasing water‐soluble P content of the fertilizer. The results suggest a greater efficiency of PAPR than SSP as a P supplier to plants.     

Maize growth and yield responses to seed‐inoculated N2‐fixing bacteria under Dryland production conditions

Maize (Zea Mays L.) seeds were inoculated with the N₂‐fixing bacteria, Azospirillum brasilense and Azorhizobium caulinodans. Shoot growth, shoot nitrogen (N) concentration, and grain yield was determined under dryland production conditions in a silt loam. Fertilizer N was applied according to soil test recommendations at either 0, 50, 75, or 100% of the recommended N requirements for a 7,500 kg ha^‐1 yield goal. Both A. brasilense and A. caulinodans increased shoot dry matter production, shoot N concentration, and grain yield somewhat at the lower N recommended rates. There was no agronomic benefit with either A. brasilense and A. caulinodans inoculations under dryland conditions for high N fertility soils under dryland production conditions in a subhumid or semi‐arid moisture regime.     

Biochar‐Based Fertilization with Liquid Nutrient Enrichment: 21 Field Trials Covering 13 Crop Species in Nepal

Biochar produced in cost‐efficient flame curtain kilns (Kon‐Tiki) was nutrient enriched either with cow urine or with dissolved mineral (NPK) fertilizer to produce biochar‐based fertilizers containing between 60–100 kg N, 5–60 kg P₂O₅ and 60–100 kg K₂O, respectively, per ton of biochar. In 21 field trials, nutrient‐enriched biochars were applied at rates of 0·5–2 t ha⁻¹ into the root zone of 13 different crops. Treatments combining biochar, compost and organic or chemical fertilizer were evaluated; control treatments contained same amounts of nutrients but without biochar. All nutrient‐enriched biochar substrates improved yields compared with their respective no‐biochar controls. Biochar enriched with dissolved NPK produced on average 20% ± 5·1% (N  = 4 trials) higher yields than standard NPK fertilization without biochar. Cow urine‐enriched biochar blended with compost resulted on average in 123% ± 76·7% (N  = 13 trials) higher yields compared with the organic farmer practice with cow urine‐blended compost and outcompeted NPK‐enriched biochar (same nutrient dose) by 103% ± 12·4% (N  = 4 trials) respectively. Thus, the results of 21 field trials robustly revealed that low‐dosage root zone application of organic biochar‐based fertilizers caused substantial yield increases in rather fertile silt loam soils compared with traditional organic fertilization and to mineral NPK or NPK‐biochar fertilization. This can be explained by the nutrient carrier effect of biochar, causing a slow nutrient release behaviour, more balanced nutrient fluxes and reduced nutrient losses, especially when liquid organic nutrients are used for the biochar enrichment. The results open up new pathways for optimizing organic farming and improving on‐farm nutrient cycling. Copyright © 2017 John Wiley & Sons, Ltd.     

Effect of Mycorrhiza,Organic Sources,Lime, Secondary and Micro-nutrients on Soil Microbial Activities and Yield Performance of Yam Bean (Pachyrhizus erosus L.) in Alfisols

Effect of integrated use of mycorrhiza, lime, inorganic fertilizers, and organic manures on microbial activities and yield performance of yam bean (Pachyrhizus erosus L.) was studied for two consecutive kharif (rainy) seasons during 2013–14 and 2014–15 in an acid Alfisol. The experiment was laid out with 16 treatments consisting of graded doses of soil test–based nitrogen, phosphors, and potassium (NPK); lime; mycorrhiza; organic sources, that is, farmyard manure (FYM), vermicompost, and green manure; secondary magnesium sulfate (MgSO₄) and micronutrients zinc sulfate (ZnSO₄ and borax). Significantly highest mean tuber yield (29.61 t ha^?1) was recorded due to integrated application of lime + FYM + NPK + ZnSO₄. Graded doses of NPK showed a mean yield response of 65%, 134%, and 191% due to addition of 50%, 100%, and 150% of NPK over control, respectively. Inoculation of vesicular–arbuscular mycorrhiza (VAM) combined with NPK and FYM recorded a mean tuber yield of 25.14 t ha^?1. Highest mean dry matter (18.85%) was recorded due to application of 150% NPK, whereas highest starch content on fresh weight basis was recorded due to integrated use of lime + FYM + NPK + MgSO₄ (11.11%). Application of 150% NPK has recorded highest dehydrogenase activity (2.018 µg TPF h^?1 g^?1) and fluorescein diacetate hydrolysis assay (2.012 µg g^?1 h^?1). Fungal inoculation of VAM in combination with lime + FYM + NPK recorded highest acid and alkaline phosphatase activities (82.20 and 67.02 µg PNP g^?1 soil h^?1, respectively). Soil biological activities and phosphatase activities had highly significant relationship with tuber yield and biochemical constituents of yam bean. The study emphasized the conjunctive use of soil test–based inorganic fertilizers, lime, and organic manures to enhance the enzymatic activities and to realize higher crop yields of yam bean in acid Alfisols.     

Response of wheat seedlings to Mn‐lignosulfonate adhered to granular NPK

Manganese (Mn) deficiency is a widespread crop micronutrient disorder. The aim of this work was to evaluate two NPK fertilizers coated with Mn that eliminate the specific labor cost for applying Mn and that allow the correction of Mn deficiency in wheat (Triticum aestivum L.). Two Mn sources [MnSO₄ and Mn‐lignosulfonate (MnLS)] were compared as NPK coatings at doses of 0.1, 0.3, and 1.0% (w/w) in hydroponic, perlite, and soil pot cultures under growth chamber and greenhouse conditions with wheat to evaluate the effects on dry matter production and Mn concentrations. For the NPK+MnLS product, 52–63% of the total Mn remained in solution at calcareous conditions. However, the NPK+MnSO₄ product was able to maintain only 14–25% of the total Mn added in solution. As expected, the MnLS product resulted in higher Mn concentrations in shoots than the MnSO₄ product due to the Mn complexation by lignosulfonate which preserved Mn from precipitation and maintained it available for plants. In the experiment with perlite as growth substrate, at low Mn dose (0.1% Mn) a similar Mn concentration in wheat shoots was found (57 mg kg^?1 DW for the MnSO₄ coating versus 72 mg kg^?1 DW for MnLS coating), but at the highest dose (1.0% Mn) the NPK+MnLS showed a significant increase in shoot Mn concentration (167 versus 132 mg kg^?1 DW). Soil application of coated NPK products showed similar Mn concentrations in shoots with both Mn sources (29–37 mg kg^?1 DW), except for the NPK+MnSO₄ (0.1%) treatment (only 18 mg kg^?1 DW). Based on the recommended Fe/Mn values (Fe : Mn ratio = 1.5–2.5) given in the literature for plants with a correct nutrition, only the NPK+MnLS (0.3%) fulfilled this ratio (Fe : Mn = 2.5).     

Long‐term effects of fertilizer and manure applications on soil quality and yields in a sub‐humid tropical rice‐rice system

Widespread yield stagnation and productivity declines in the rice–rice cropping system have been reported and many of the associated issues are related to soil quality. A long‐term experimental study was initiated in 1969 to assess the impact of continuous cultivation of rice as a single crop grown in wet as well as dry seasons using varying levels of chemical fertilizer and manure applications on soil quality indicators (physical, chemical and biological), a sustainable yield index (SYI) and a soil quality index (SQI). The treatments comprised chemical fertilizers and farmyard manure (FYM) either alone or in combination viz. control, N, NP, NK, NPK, FYM, N+FYM, NP+FYM, NK+FYM and NPK+FYM, laid out in a randomized complete block design with three replications. Soil samples were collected after the wet season rice harvest in 2010 and were analysed for physical, chemical and biological indicators of soil quality. A SYI based on long‐term yield data and SQI using principal component analysis (PCA) and nonlinear scoring functions were calculated. Application of NPK fertilizers in combination with FYM significantly increased the average grain yield of rice in both wet and dry seasons and enhanced the sustainability of the system compared to the control and plots in receipt of fertilizers. The SYI for the control was higher in the wet season than in the dry one, whereas the reverse was true for NPK+FYM treatment. The value of the dimensionless SQI varied from 1.46 in the control plot to 3.78 in the NPK+FYM one. A greater SYI and SQI in the NPK+FYM treatment demonstrated the importance of using a chemical fertilizer in combination with FYM. For the six soil quality indicators selected as a minimum data set (MDS), the contribution of DTPA‐Zn, available‐N and soil organic carbon to the SQI was substantial ranging from 59.4 to 85.7 per cent in NPK+FYM and control plots, respectively. Thus, these soil parameters could be used to monitor soil quality in a subhumid tropical rice–rice system.