Soil development on the Crimean Peninsula in the Late Holocene

The study of soils of different ages in different physiographic regions of the Crimean Peninsula made it possible to reveal the main regularities of pedogenesis in the Late Holocene (in the past 2800 years). With respect to the average rate of the development of soil humus horizons, the main types of soils in the studied region were arranged into the following sequence: southern chernozems and dark chestnut soils > mountainous forest brown soils > gravelly cinnamonic soils. In the newly formed soils, the accumulation of humus developed at a higher rate than the increase in the thickness of humus horizons. A sharp decrease in the rates of development of soil humus profiles and humus accumulation took place in the soils with the age of 1100-1200 years. The possibility for assessing the impact of climate changes on the pedogenetic process on the basis of instrumental meteorological data was shown. The potential centennial fluctuations of the climate in the Holocene determined the possibility of pulsating shifts of soil-geographic subzones within the steppe part of the Crimea with considerable changes in the rates of the development of soil humus horizons in comparison with those in the Late Holocene.     

Trends of the natural evolution of chernozems on the East European Plain

A generalized chronosequence of changes in the morphometric parameters of chernozems in the past 5100 years is analyzed. It is shown that the development of chernozems in the center of the East European Plain is characterized by both long-term (interglacial, encompassing the entire Holocene) and short-term (within separate climatic periods of the Holocene) trends. The long-term trend of the evolution of ordinary chernozems developed from the loess-like calcareous loam consists of a continuous increase in the thickness of the soil humus profile and an oscillating increase in the depth of the carbonate accumulations. The Late-Holocene short-term trends of the natural evolution of chernozems are characterized by the high spatial heterogeneity related to the patterns of climatic fluctuations and to the lithological composition of parent materials. In that period, the thickness of genetic horizons in the forest-steppe chernozems was increasing faster than that in the steppe chernozems.     

The regularities of the late Holocene soil formation in the lower don steppes

The direction and stages of pedogenesis, rate and scales of changeability, and type of evolution of chernozems in the steppes of the Lower Don are ascertained by studying the archaeological monuments of the Bronze Age, Early Iron Age, and Middle Ages. It is shown that the soil formation process was characterized by cyclicity, and evolutional soil transformations took place at the level of subtype. The paper ascertains the polygenetic character of modern chernozems, whose evolution during the second half of the Holocene was predominantly low-contrast, inheriting, and transforming. The processes forming the humus, salt, gypsum, and carbonate profiles, as well as the processes of solonetzization-desolonetzization, were the most dynamic. The fundamental differences in the genesis of different parts of the humus profile are revealed. The role of climatically pulsing solonetzicity in forming the specific Azov chernozems is for the first time ascertained.     

Specificity of the physical properties of soils in locally waterlogged landscapes in the lower reaches of the Don River

We studied the physical properties of chernozems subjected to local waterlogging because of different reasons. The secondary soil hydromorphism resulted in insignificant changes in the soil’s texture related to some redistribution of the elementary soil particles by the particle-size fractions. The physical clay content somewhat increased in the lower part of the soil profiles (in the B2 and BC horizons) at the expense of the clay particles. The bulk density of the waterlogged soils somewhat increased, particularly in the B2 horizon. The regular soil waterlogging worsened the soil’s structural status with a decrease in the content of the silt-size aggregates and an increase in the content of the coarse blocky aggregates. The changes in the soil’s structure can be considered a diagnostic feature of the locally waterlogged chernozems. The water stability of the aggregates increased due to the higher contents of the major cementing agents, including the soil humus and carbonates.     

Evolution of forest pedogenesis in the south of the forest-steppe of the Central Russian Upland in the Late Holocene

The Late Holocene stage of forest pedogenesis has been studied on the interfluves along river valleys in the forest-steppe zone of the Central Russian Upland. The development of gray forest soils from the former chernozems as a result of the Late Holocene advance of forest vegetation over steppes is discussed. It is argued that the climatic conditions of the Subatlantic period were unstable, so that multiple alternation of forest and steppe vegetation communities took place. This specified a complex character of soil evolution upon contrasting substitution of forest pedogenesis for steppe pedogenesis. On the interfluves near the natural drainage network (balkas, ravines, and steep slopes of river valleys), the climate-driven dynamics of forest and steppe vegetation with corresponding changes in the character of pedogenesis could take place during the entire Holocene, which is reflected in a lower thickness of humus profiles and deeper leaching of carbonates from chernozems of the Early Iron Age in comparison with their analogues formed under steppe cenoses in central parts of the interfluves. Two variants of the evolution of gray forest soils can be suggested: the pulsating evolution typical of balkas and interfluves near river valleys and the continuous progressive evolution typical of automorphic (plakor) positions in central parts of the interfluves.     

Biological mineralization of organic matter in the modern virgin and plowed chernozems,buried chernozems,and fossil chernozems

The phenomenon of mineralization (biological mineralization) of organic matter in chernozems has been studied. A decrease in the content of C_org with time can be considered an index of the organic matter mineralization. It is suggested that the humus horizons of modern chernozems contain the pools of organic matter of different ages: easily decomposable organic matter, labile biologically active humus, stable biologically active humus, and relatively inert humus. The composition and mean residence times of these pools and their contribution to the total organic matter content have been estimated. The particular types of the biological mineralization have been determined on the basis of the comparison between the velocities of mineralization (M) and humification (H) processes: total unidirectional mineralization (M ≫ H), equilibrium mineralization (M ∼ H), nonequilibrium mineralization (M> <H), and zero mineralization. The separation of subtypes is based on data on the relative rates (%) of the organic matter mineralization. On the basis of available experimental data on chernozems buried under kurgans and in loess sediments (with the age of up to 800 ka), the quantitative relationship of the humus content in the buried soils on their age has been found; it has an exponential shape. During the first 100 ka after the soil burial, the soil humus content gradually (with a slowing intensity) decreases from 100–75 to 6.5% of its content in the virgin chernozems. Then, 100–1000 ka after the soil burial, the soil humus content remains approximately constant (6.5% of the initial level, or 0.3% of the soil mass). The rates of mineralization have been estimated. It is shown that the elemental composition (C, H, N, O) of humic acids remains relatively stable for a long time due to the regeneration of the chemical structure of humus (matric restoration of humus). It is suggested that several different forms of humus related to pedogenesis should be distinguished in the biosphere. The renewable humus in the equilibrium state with the environment is typical of the open biospheric (soil) systems. The fossil humus, whose content decreases with time, and whose composition remains stable, is typical of the semiclosed and closed systems. With time, it transforms into residual humus, whose content and composition remain stable. The fossilized organic matter in the fossil soils and sediments of the past geological epochs (Mesozoic and Paleozoic) considerably differs from the renewable, fossil, and residual humus.     

Genesis and age of mineralogical profiles of Moldavian chernozems

In chernozems developed in the autonomous positions in Moldova, the mineralogy of their silicate component has some features indicative of stronger transformations than those that could be expected for the chernozems formed by the Holocene pedogenesis. The mineralogical profiles testify to the eluvial nature of the main subtypes of chernozems. It is suggested that the revealed changes are not due to the Holocene pedogenesis. According to the probable age of the mineralogical profiles calculated from the volumes of aluminosilicates removed, these profiles originated in the early and middle Late Pleistocene, i.e., about 50 000–120 000 years ago. The effect of forest pedogenesis in the past epochs on the mineralogy of the northern subtypes of chernozems also cannot be excluded. The presented data characterize the chernozems under study as polygenetic soil formations.     

Modeling of the evolution of steppe chernozems and development of the method of pedogenetic chronology

Geoarchaeological methods were used to study chronosequences of surface soils in the steppe zone and to trace soil evolution during the Late Holocene in northwestern Crimea. It was found that the morphological and functional “maturity” of the humus horizons in steppe chernozems of the Late Holocene was reached in about 1600–1800 yrs. After this, their development decelerated irreversibly. The maximum concentration of trace elements accumulated in these horizons in the course of pedogenesis was reached in 1400 yrs. A new method of pedogenetic chronology based on the model chronofunction of the development of irreversible results of pedogenesis over time is suggested. Original pedochronological data and growth functions—the most suitable models for simulating pedogenesis over the past three thousand years—suggest that the development of morphological features of soil as an organomineral natural body follows growth patterns established for biological systems.     

Solonetzic process in postagrogenic and postameliorative conditions of the Kamennaya Steppe area

The physicochemical conditions and morphological features of solonetzic process in soils of chernozemic solonetzic complexes were studied in the area of solonetzic experimental station no. 1 in the Kamennaya Steppe area in 55 years after a single application of ameliorative measures (earthening, gypsuming, and manuring) and cessation of the annual plowing. It was found that the modern soil-forming factors favor the development of soil processes inherent in native chernozems and solonetzes prior to their plowing and amelioration. They cause the restoration of the humus horizon in chernozems and the morphological differentiation of solonetzes after the cessation of plowing. Active postameliorative and postagrogenic restoration of solonetzic features is related to the preservation of the physicochemical conditions (the low concentration of salts and the presence of exchangeable sodium) in the soil profile. The humus horizon of chernozems applied over the surface of solonetzes is characterized by the appearance of solonetzic features under hydromorphic conditions.     

Fractional composition of humus in leached chernozems and gleyed podzolized chernozem-like soils of the northern forest-steppe zone

The composition of humus in leached chernozems differs from that in gleyed podzolized chernozem-like soils in the northern forest-steppe zone of European Russia. Leached chernozems have the fulvate-humate humus. Gleyed podzolized chernozem-like soils have the humate-fulvate humus. A more aggressive composition of humus in the latter soils is caused by their overwetting and the development of gley processes under conditions of a stagnant-percolative soil water regime.     

Temporal changes of eroded soils depending on their agricultural use in the southern Cis-Ural region

Temporal changes of eroded soils in the southern Cis-Ural region (Republic of Bashkortostan) depending on their agricultural use during the period from 1975 to 2011 were studied. In the northern foreststeppe zone, the development of erosion processes was retarded upon the use of soil-saving management practices and grain-fallow-grass crop rotations. In slightly eroded light gray forest soils (Eutric Retisols (Cutanic)), the thickness of humus-accumulative horizons and the content of humus increased; the conversion of cropland into permanent fallow was found to be the most efficient measure to control soil erosion. In podzolized chernozems (Luvic Greyzemic Chernic Phaeozems) and typical chernozems (Haplic Chernozems) of the Cis-Ural steppe, the content of humus in the plow layer under grain-row crop rotation and classical soil management decreased, especially in moderately eroded soils. The development of water and wind erosion on slopes depended on the slope shape: the texture of soils at different degrees of erosion on slopes with free runoff became coarser by one gradation after 35 years; in the presence of linear obstacles in the lower part of slopes, the content of fine fractions in moderately and strongly eroded soils increased.     

The humus formation and humus in forest-steppe and steppe chernozems of the southern Cisural region

The ecological features of the humus formation in typical, ordinary, and southern chernozems of the Orenburg Cisural region were considered. The fractional-group composition and amphiphilic properties of the forest-steppe and steppe chernozem subtypes were studied in relation to the dynamics of the hydrothermal regime, the vegetation, and the biological (enzymatic) activity of these zonal soils. The particular properties of the humus in virgin and arable landscapes were established. Arguments were presented for the probable existence of a genetically controlled relationship between the fractional-group composition of the humus and its amphiphilic properties     

Soil evolution on the low terraces of Lake Nero

The soil evolution in the depression of Lake Nero was driven by climate changes in the Holocene and by the history of the relief’s development in this region. In the Alleröd period, dark-colored soils were formed; in the Late Dryas period, they were cryoturbated and covered by colluvial deposits from the adjacent slopes. These specific paleosols are found on relatively high ancient surfaces. In the Early and Middle Holocene (10000–3700 BP), dark-colored horizons of soils with high stability of the organic matter were formed. The properties of humus in these soils are close to the properties of humus in forest-steppe soils. In the past 3500–3700 years, under conditions of some cooling and humidization of the climate with the development of taiga pedogenesis, these soils have evolved into soddy-podzolic soils. Their dark-colored horizons have degraded, though their lower parts are partly preserved in many places as the second humus horizons, the most distinctive feature of the soil polygenesis in the studied region. The soils of the low terrace (100–103 m a.s.l.) are younger than the soils of the higher and more ancient surfaces. Their evolution followed the same stages, though the Alleröd paleosols have not been found on this surface. In the coastal zone, at the heights below 97 m a.s.l., the soil formation began later, about 7000 years ago. Afterwards, the soils of this surface were subjected to the influence of fluctuations in the lake’s level. During the regression phase (7000–3500 BP), which corresponded to the dark-colored pedogenesis, these soils and the habitation deposits of the Bronze Age were formed on the dried bottom of the lake below its modern lake level of 93.2 m a.s.l. In the Late Holocene, these soils in the coastal zone were subjected to waterlogging rather than to podzolization due to the rise in the lake’s level; they have evolved into the soddy gley soils.     

Soil development in anthropogenically disturbed forest-steppe landscapes

The results of long-term studies of chernozem development in anthropogenically disturbed landscapes of the forest-steppe zone are discussed. Parameters characterizing the formation of the humus horizon of chernozems and the rate of this process are presented. Critical points and characteristic times of the formation of humus horizons are determined. The regeneration of soil properties as dependent on the degree of anthropogenic disturbance of chernozems is estimated.     

Comparative assessment of the biological tolerance of chernozems in the south of Russia towards contamination with Cr, Cu, Ni, and Pb in a model experiment

The biological properties of chernozems in the south of Russia worsen under the impact of contamination with Cr, Cu, Ni, and Pb compounds. The tolerance of chernozems towards contamination decreases in the following sequence: ordinary chernozems > typical chernozems > southern chernozems > leached vertic chernozems. This sequence is specified by the soil reaction and the organic matter content. The high humus content determines the high buffer capacity of chernozems towards contamination with chromium, whereas the high pH values ensure the soil tolerance towards contamination with copper, nickel, and lead. With respect to their adverse effect on the biological properties of the chernozems, the studied heavy metals can be arranged into the following sequence: CrO₃ > CuO > PbO ≥ NiO.     

Specific features of organic matter in urban soils of Rostov-on-Don

Data on the fractional and group composition of humus in urban soils of Rostov-on-Don are discussed. We have compared the humus profiles of chernozems under tree plantations and those buried under anthropogenic deposits (including sealed chernozems under asphalt). It is shown that the type of humus in these soils remains stable despite a decrease in its total content after the long-term burial under asphalt. Under the impact of the trees, the organic matter of the chernozems acquired some features typical of gray forest soils, i.e., the humate-fulvate type of humus in the humus horizon and the sharp drop in the humus content down the soil profile.     

Soddy-Podzolic Soils with a Complex Organic Profile in the Right-Bank Part of the Lower Vyatka River Basin

Data on soddy-podzolic soils with the second humus horizon in the southwestern part of Kirov oblast are discussed. These soils were first studied by the authors on mantle calcareous loams of the Yarano- Kokshagskaya Plain in the eastern part of the Central Russian southern-taiga province of medium-humus soddy-podzolic soils of European Russia. The aim of this study is to reconstruct the history of the development of soil properties and soil cover in automorphic landscapes of this region. Morphology, substantive properties of mineral and organic components, soil genesis and evolution are analyzed using a set of physical, chemical, physicochemical, biochemical, and geochronological methods. The results of our study attest to the relict character of second the humus horizon and polygenetic nature of the studied soils. These soils have passed through two essentially different evolutionary stages in the Holocene: the accumulative stage in the first half of the Holocene and the accumulative-eluvial stage of erasing evolution with preservation of some inherited features in the second half of the Holocene. According to their properties, the studied soils are analogous to the earlier studied southern-taiga Vyatka–Kama province of high-humus soddy-podzolic soils of the northeast. At present, plowing of these soils leads to a partial or complete destruction of the second humus horizon; thus, spontaneous degradation processes are complemented by the human-induced soil degradation. A tendency for a gradual disappearance of these soils from the soil cover under the influence of natural and anthropogenic factors has been noted. The materials presented in this paper may be useful for organization of specially protected soil areas in the southwestern part of the Vyatka River basin.     

Radiocarbon ages of humic substances in chernozems

Data on radiocarbon ages of different fractions of humus (humic acids, fulvic acids, and humin) in the profiles of chernozems are analyzed. A chronoecological grouping of humus in modern and buried (fossil) soils is suggested. An increase in the radiocarbon age of humic substances down the soil profile has a stepwise character. It is shown that the ¹⁴C content in chernozems decreases down the soil profile more somewhat slower than the ¹²C content. The dependence of a decrease in the humus content of buried soils on the age of burying is traced for a time span of 800 ka.     

Composition of humus in chronosequences of buried soils in the tundra zone

The humus characteristics in buried Holocene and Late Pleistocene paleosols of the tundra zone have been studied. It is shown that the paleosol sequences encompassing the time span from 55 to 2.5 ka BP contain paleosols with analogous types of humus, attesting to the cyclic repeatability of the corresponding stages of soil formation. A tendency for an increase in the degree of humification in the course of soil development has been revealed. Within the ultracontinental areas of East Siberia, the accumulation of salts accompanied soil formation in the Late Pleistocene and Holocene.     

Humus status and distribution of the underground phytomass in eroded chernozems of the Cis-Salair region

It is shown that humus loss may reach 1.7 t/ha per year as a result of plowing of leached chernozems and erosion development. Distribution of underground phytomass in uneroded and eroded chernozems and slightly aggraded meadow-chernozemic soils of dissected areas in the Cis-Salair region is analyzed. It is shown that an increase in the degree of soil erosion is accompanied by a decrease in the total phytomass reserves, whereas the average depth of the root zone increases.