Soil Inorganic Phosphorus Fractionation and Availability under Greenhouse Subsurface Irrigation

Inorganic phosphorus (P) fractions and their availability under subsurface irrigation were investigated in a greenhouse planted for 5 years with tomato. Irrigation was applied when soil water conditions reached the predefined maximum allowable depletion (MAD) for different treatments, e.g., ?10 kPa, ?16 kPa, ?25 kPa, ?40 kPa, and ?63 kPa. Concentrations of five inorganic P fractions, which include of soluble / loosely bound P, aluminum (Al) P, iron (Fe) P, calcium (Ca) P, and occluded P, were obtained by following a sequential chemical fractionation procedure. Results showed that the effect of subsurface irrigation and schedules on inorganic P fractions was more pronounced in topsoil layers than in deep soils. The concentrations of soluble / loosely bound P, Al P, and Fe P generally decreased with soil depth, having the largest values at the depths of 0–10 cm and 10–20 cm. In all the irrigation treatments, Al P and Fe P were the dominant fractions at the depths of 0–10 cm, 10–20 cm, and 20–30 cm, whereas Ca P and occluded P were most predominant at the depths of 30–40 cm and 40–60 cm. Soluble or loosely bound P, Al P, and Fe P were the main sources contributing to plant-available P, whereas Fe P and Al P were the two most important sources for contribution to plant-available P. Frequent irrigation with small amounts of water (e.g., irrigation with MAD of ?16 kPa and ?25 kPa) yielded larger concentrations of soluble / loosely bound P, Al P, and Fe P, which are the main sources of plant-available P. However, infrequent irrigation with larger amounts of water in each irrigation event led to greater concentrations of Ca P and occluded P, which are relatively less available to plants.     

长期施肥对砂姜黑土有机磷组分及其有效性的影响

应用Bowman和Cole的有机磷(P)分组方法,研究23年田间定位试验下不同有机肥对土壤有机P组分及其有效性的影响.结果表明:与休闲、不施肥对照和长期单施化肥处理相比,无机肥与有机肥配施能显著增加土壤有机P的总量,不同有机肥对有机P的累积效应是牛粪>猪粪>麦秸.长期施肥主要是提高中活性有机P的含量,活性和中稳性有机P的增幅相当,高稳性有机P的含量几乎没有变化.相关分析表明活性有机P是土壤有效P的直接P源,中活性有机P是活性有机P的有效补充,而中稳性有机P和高稳性有机P的有效性较低.     

不同磷肥调控措施下红壤磷素有效性和利用率的变化

南方红壤区磷肥当季利用率仅为10%～25%,提高磷肥利用率是亟待解决的问题。通过两年田间试验,分析了不同磷肥品种（过磷酸钙、猪粪、钙镁磷肥、磷酸一铵、磷酸二铵）、磷肥梯度（常规施磷、减磷20%、减磷30%）以及调控措施（石灰、钙镁磷肥配施磷酸二铵、钙镁磷肥配施秸秆）对红壤磷素有效性和作物生长的影响,探索提高磷肥利用率的途径。结果表明,各磷肥品种间,以猪粪处理土壤有效磷、地上部生物量、磷肥累积利用率等指标最高,土壤有效磷较不施磷处理两年分别提高了32%和241%,地上部生物量较不施磷处理两年分别提高了73%和510%,两年的磷肥累积利用率分别为16.4%和26.5%;伴随磷肥用量的减少,土壤有效磷含量显著降低,而对油菜生长、磷肥利用率及磷肥农学效率无显著影响;与单施钙镁磷肥相比,钙镁磷肥配施磷酸二铵能显著提高油菜籽粒产量、土壤有效磷含量、磷肥累积利用率、磷肥农学效率、土壤磷素盈余量等指标。添加石灰可提高作物产量及土壤有效磷含量。油菜产量与土壤有效磷呈极显著正相关关系。上述结果表明,猪粪替代化学磷肥可达到减施增效、促进作物生长的目的,且以减磷30%为宜;钙镁磷肥配施磷酸二铵可推荐为磷肥调控...     

Relationship between Soil Phosphorus Availability and Phosphorus Loss Potential in Runoff and Drainage

Abstract

Elevated soil phosphorus (P) content is common in the central coastal valleys of California, the result of decades of the intensive vegetable production. Undesirably high P concentration in surface water in this region stimulated interest in evaluating techniques to rank the potential for soil P loss to the environment. Phosphorus availability of 25 representative soils from fields in vegetable rotations were evaluated by the following techniques: bicarbonate‐extractable P (P_bc)–calcium chloride, extractable P (P_cc), P extractable by iron‐impregnated paper (P_Fe), P extractable by anion exchange resin (P_ae), and the degree of P saturation (P_sat). A column study was conducted in which these soils were evaluated for soluble P concentration in runoff and leachate from two simulated irrigation events. There were strong correlations among all measures of soil P availability (r=0.66–0.90). Runoff soluble P was most strongly correlated with P_cc, P_ae, and P_bc (r=0.98, 0.93, and 0.91, or 0.98, 0.90, and 0.85 in the first and second irrigation, respectively). The relationship of runoff soluble P to P_bc, P_ae, and P_cc was characterized by a change point; runoff soluble P from soils <50 mg kg^?1 P_bc was minimal, whereas at higher P_bc runoff P reached levels of environmental concern. Leachate soluble P was also correlated with P_cc, P_ae, and P_bc (r=0.84–0.99). Across soils, leachate soluble P averaged 1.4 mg L^?1, compared to 0.11 mg L^?1 for runoff P. We conclude that P_cc, P_ae, and P_bc are useful tests to rank the potential for P loss in irrigation runoff or drainage. Given the relative complexity of the P_ae technique, P_bc and P_cc appear to be the most practical soil tests for this purpose.     

长期施肥条件下潮土有效磷的演变及其对磷盈亏的响应

为探明土壤有效磷的演变规律与磷平衡状况,在河南潮土区冬小麦-夏玉米轮作制度下,于1998年始在河南省不同区域开展田间定位试验,共设置常规施肥(CF)和不施肥(CK)2个处理,对土壤全磷、速效磷累积和土壤有机质等进行监测和分析。结果表明,长期不施肥,土壤磷素常年处于亏缺状态,有效磷处于耗竭状态;长期施肥即常规施肥,有12个监测点的有效磷随年份显著上升,2个监测点显著下降,其余持平。土壤有效磷的变化量与磷的盈亏量呈极显著正相关(P0.01),不施肥条件下,土壤每亏缺100 kg P·hm-2,土壤有效磷下降2.7 mg·kg-1;常规施肥下,土壤每盈余100 kg P·hm-2,土壤有效磷可以增加1.2 mg·kg-1。土壤有机质含量与有效磷随磷盈亏的变化量呈极显著正相关(P0.01,CF的R2=0.5542,CK的R2=0.4039)。由此可见,通过施肥措施来调控土壤有效磷含量,可达到培肥地力和作物高产的效果。本研究结果为指导磷肥施用以及土壤磷素管理提供了科学依据。     

Phosphorus Amendment of a Lead-Spiked Soil with Low Phosphorus Availability: Roles of Phosphorus on Soil and Plant Lead

Phosphorus (P) is both a macronutrient for plants and an effective amendment to reduce lead (Pb) toxicity in soil. Thus, in Pb-polluted soil with low P availability, P will act as a nutrient as well as a Pb-immobilizing agent. However, this has not been fully investigated. A soil with 2.50 mg kg^?1 Olsen P was spiked with soluble Pb and then amended with superphosphate to examine the effect of P on soil Pb availability and ryegrass (Lolium perenne L. cv. Aubisque) growth. It was found that P/Pb = 2 increased ryegrass yield by 804% and decreased root Pb concentration and soil diethylenetriaminepentaacetic acid (DTPA)–extractable Pb concentration by 25.6% and 1.0%, respectively. As P amendment increased to P/Pb = 4, both plant yield and root Pb concentration declined compared with P/Pb = 2. Results of the sequential extraction indicated that the proportion of carbonate phase Pb decreased, while that of the manganese oxide phase increased as P was added. The proportion of residual Pb was little affected by the amendment. The results suggest that in soils with low P availability and high Pb availability, availability of soil Pb and root concentration of Pb are less affected, whereas the toxicity of Pb is greatly depressed by the P amendment; P/Pb = 2 is high enough to alleviate the stresses of low P availability.     

滴灌条件下不同磷肥品种对土壤磷有效性及玉米产量的影响

通过模拟试验及田间试验研究不同磷肥施用后对土壤磷有效性的动态变化和分布特点,以及玉米磷吸收和产量响应的影响。田间和模拟试验包括4个处理,分别为对照(不施磷肥)、MAP(磷酸一铵)、UP(磷酸脲)和AAP(水溶性聚磷酸铵)。模拟试验中,不同磷肥均提高土壤中有效磷含量,APP处理10—15 cm土层有效磷含量增加最多。在均匀的养分投入和管理水平下,3种磷肥品种均有土壤酸化效果,其中UP处理最为显著。田间试验中,玉米生长后期,APP处理的土壤有效磷含量在深层土壤分布较高,UP处理土壤pH较低,均有利于改善土壤的供磷能力,提高土壤有效磷含量;APP处理对根系发育有显著的促进作用,玉米组织磷含量和磷吸收量最大,产量最高(14.40 t/hm^2)。3种磷肥中,APP处理移动性较好,土壤深层有效磷含量增加,利于根系生长和养分的吸收,提高产量。水溶性聚磷酸铵(APP)是一种适合于玉米灌溉施肥的肥料。     

Corn and Soybean Grain Phosphorus Content Relationship with Soil Phosphorus,Phosphorus Fertilizer,and Crop Yield

Most fertilizer phosphorus (P) rate recommendations for the north-central United States are based on combination of a critical soil-test P value and a mass-balance calculation of fertilizer P required to maintain critical soil-test P. Accurate estimates of grain P removal are an essential component of P mass-balance calculation. Current north-central extension service guidelines recommend that estimates of corn and soybean grain P removal should be calculated using constant grain P concentrations. We reviewed research from the north-central region to determine the extent to which variation in grain P concentration accounts for differences in crop P removal and to determine whether predictions of grain P concentration can be improved through consideration of soil-test P, crop yield, and fertilizer P application. We found that soil-test P, grain yield, and fertilizer P are predictor variables that may significantly improve estimates of grain P concentration for corn and soybeans.     

施肥对马尾松土壤磷形态的影响

采用室内盆栽试验研究了不同施肥处理下马尾松土壤磷形态,结果表明:施入P肥后土壤中无机磷的含量产生了变化,施入PK后根际土和非根际土土壤中的速效磷含量都有增加;除施入K、PK外,施肥后根际土和非根际土中Al-P的含量都比未施肥的高;施肥后Fe-P的变化比较大,而Fe-P的减少是由于南方土壤中的铁大多是以高价存在,易发生氧化还原反应;O-P是一种无效磷,施肥后土壤中的O-P含量均沉积于土壤而比对照的高;施入N、P、K、PK、NK、NPK后降低了两种土壤中Ca-P的含量。因此,为了促进马尾松的生长发育,可以给马尾松增施NP、PK、NPK肥。     

The Effect of Legume Species Grown as Cover Crops in Olive Orchards on Soil Phosphorus Bioavailability

Some legume species are able to utilize phosphorus (P) from sparingly soluble P sources benefiting companion crops or those following in the rotation. Lupinus albus, Vicia villosa, and a mixture of eleven annual pasture legumes were used in olive orchards as mulched cover crops as a means of increasing the soil P availability. By soil testing and growing bioindicator P plants in the next season, it was possible to detect a slight but consistent increase in soil P availability. The results indicated that the increase in soil P availability was mainly due to the mineralization of the high P content legume residues, rather than the direct effect in the rhizosphere of the living plants. The results also suggested that the good adaptation of white lupine to low P environments might be due to a high internal P use efficiency of this species, producing high dry matter yields with low P concentration in their tissues.     

大沽河流域农田土壤磷有效性及全磷淋失影响因素试验

以青岛市大沽河流域砂壤、河潮土、砂姜土 3种农田土壤为研究对象,开展室内土柱试验,研究土壤pH、温度、含水率等理化性质与生物炭和氮肥配施对土壤有效磷(Olsen—P)和全磷(TP)淋失的影响,以期为提高农田土壤磷素有效性、减少全磷淋失提供参考依据.结果表明:3种土壤的pH在偏中性或弱碱性时磷素有效性最高,pH偏酸性时,...     

低分子量有机酸对石灰性土壤有机磷组成及有效性的影响

为探索提高土壤磷素有效性的途径,采用室内培养的方法,研究不同有机酸对土壤速效磷含量及有机磷组分的影响。结果表明,添加有机酸后土壤速效磷含量发生显著变化,其中草酸处理下土壤速效磷含量显著高于其他处理,而柠檬酸和苹果酸对土壤速效磷含量具有抑制作用,其活化量为负值;随着培养时间的延长,速效磷含量缓慢降低。速效磷含量随着草酸浓度的升高而升高,随着苹果酸、柠檬酸浓度的升高而降低;有机酸处理后,土壤活性、中活性、中稳性有机磷升高,高稳性有机磷降低,这说明有机酸能促进土壤有机磷由有效性低的形态逐步向有效性高的形态转化,其中草酸的作用效果总体上较柠檬酸和苹果酸强。     

Phosphorus Availability and Early Corn Growth Response in Soil Amended with Turkey Manure Ash

Incinerating turkey manure is a new option in the USA to generate renewable energy and to eliminate environmental problems associated with manure stockpiling. Incineration produces turkey manure ash (TMA) with a nutrient content of 43 g phosphorus (P) kg^?1 and 100 g potassium (K) kg^?1. We conducted a greenhouse pot study using a low P (6 mg kg^?1) and high K (121 mg kg^?1) soil/sand mixture with a 7.0 pH to evaluate early growth response of corn (Zea mays L.) to TMA. A control and five rates based on P (5.6, 10.9, 16.5, 21.9, and 27.2 mg kg^?1) and respective K contents in TMA were compared with triple-superphosphate and potassium chloride fertilizer. Plant height and stalk thickness at 24 and 31 days after emergence (DAE) were greatest with the fertilizer, but no differences were detected at the final sampling (52 DAE). Regardless of nutrient source, plant biomass increased with P rate. Because of faster initial plant development, corn dry matter 52 DAE was 15 to 20% greater with fertilizer than with TMA. Corn tissue P concentration was greater with TMA than with fertilizer, but P uptake was similar. Tissue micronutrient concentrations were greatest for the control. Bray 1 P appeared to extract excessive amounts of P in TMA-amended soil, whereas soil P levels with the Olsen extractant provided an estimate of plant-available P that was consistent with plant response. Based on this first approximation, we conclude that TMA is a potential source of P for field crops. Field studies are required to determine recommended application rates.     

调控措施对滨海盐渍土磷素形态及作物磷素吸收的影响

滨海盐渍化土壤存在磷素有效性低的问题。本试验采用根袋法盆栽试验,共设不施磷肥、常规磷肥、磷肥+生物质炭、磷肥+腐殖酸、磷肥+商品有机肥5个处理,分析不同调控措施对非盐渍土、轻度盐渍土和中度盐渍土有效磷含量、磷素形态以及大麦磷素吸收利用的影响。结果表明:①盐碱障碍降低根区内外土壤有效磷含量,表现为非盐渍土>轻度盐渍土>中度盐渍土。添加生物质炭能显著提高轻度、中度盐渍土根区内外土壤有效磷含量,较常规磷肥对照处理分别提高40.72%、84.80%。②盐碱障碍降低大麦产量,抑制地上部对磷素的吸收,不同调控措施均能促进盐渍土上大麦对磷素的吸收,提高磷肥利用率。轻度盐渍土上不同调控措施的增产效果不显著,中度盐渍土上添加生物质炭处理显著提高大麦产量,较常规磷肥对照处理提高63.20%。③盐碱障碍降低土壤活性无机磷、NaOH-Pi、NaHCO₃-Po、NaOH-Po比例,增加HCl-Pi比例。添加生物质炭处理能显著提高盐渍土活性无机磷比例,提高土壤磷的有效性。添加生物质炭和商品有机肥处理对中度盐渍土上HCl-Pi比例的降低效果优于轻度盐渍土。     

夏玉米和冬小麦秸秆对石灰性土壤磷吸附特性及磷素形态的影响

本文对夏玉米秸秆(MR)和冬小麦秸秆(WR)单施或者与P肥混施(在等P量条件下)对石灰性土壤P的吸附特性及其形态转化进行了为期15周的室内模拟培养研究,结果表明,无论是MR和WR单施,还是秸秆与P肥混施,都可以减少土壤对P的吸附量,提高土壤P的活性,其中秸秆单施处理的活性无机磷(Pi)和有机磷(Po)(NaHCO3-P或者NaOH-P)提高较大,夏玉米秸秆单施时,比对照(CK)增加Pi、Po的量分别达6.0、5.6mgkg-1(NaHCO3-P),增加NaOH-Po为12.7mgkg-1。并通过Langmuir方程求得P的最大吸附量(b)、P吸附结合能常数(k)、P素最大缓冲量(MPBC)、标准需P量(SPR)的值,进一步说明了两种秸秆均可使土壤对P的吸附能力降低,增加土壤中P的活性。     

施肥对采煤塌陷区复垦土壤理化性质和磷分级的影响

以山西省晋城市采煤塌陷区复垦土壤为研究对象,连续3年定位施肥研究施用有机肥(M)、无机肥(NPK)、有机肥+无机肥(NPK+M)对土壤理化性状、土壤磷分级的影响。结果表明:试验结束后,不同施肥处理土壤的pH、容重、全氮、全磷含量差异均不显著;单施有机肥处理的有机质含量显著高于单施化肥处理;有机肥+无机肥处理土壤速效磷含量高于其余处理,但处理间差异不显著。有机肥+无机肥处理能够明显提高土壤无机磷组分Ca_8-P含量;不同施肥处理均显著提高了Fe-P,处理间差异不显著;各处理的O-P、Ca_(10)-P增幅不明显;对照处理的不同无机磷组分含量总体保持下降趋势,其中Ca_8-P、Fe-P降幅较为明显。有机肥处理对活性、中活性组分,有机肥+无机肥处理对活性、中稳性有机磷效果明显,无机肥对有机磷组分效果不显著。相关性分析表明,Ca_2-P、Ca_8-P、Al-P、Fe-P、中活性、中稳性有机磷与速效磷均呈显著正相关性,Ca_8-P、中活性有机磷与速效磷极显著相关。     

长期施肥对旱地土壤有机磷及其组分的影响

通过15年长期定位试验,采用Bowman和Cole提出的土壤有机磷分级方法,研究了不同耕作施肥措施对旱地耕层土壤有机磷及其组分的影响。结果显示旱地土壤各个处理的活性有机磷含量低,占有机磷总量的比例低于3.6%,中活性有机磷为有机磷的主体,约占有机磷总量的73.37%-91.54%。休闲、撂荒及磷肥与其它肥料配合使用,均增加了耕层土壤的中活性有机磷含量,增加了中稳性有机磷含量及其比重;休闲、撂荒及磷钾提高了高稳性有机磷含量及比重,而氮磷钾及其与有机肥配合处理则降低了高稳性有机磷的含量。尽管不同耕作施肥管理均影响旱地土壤有机磷含量,但是施用有机肥对有机磷的增加贡献最大;撂荒与休闲相比,前者更有利于土壤有机磷的积累。     

长期磷肥不均投入下黄土高原土壤磷素有效性及与土壤性质关系分析

由于科学施肥指导工作和生产实际的脱节,过量施用磷肥的现象普遍存在,进而造成大量磷素在土壤中累积。准确评价土壤中磷素的有效性是土壤磷素科学管理的基础。国际上梯度扩散薄膜技术(DGT)和传统方法相比可以更为准确地反映土壤中元素的生物有效性。以黄土高原具有代表性的60个土壤样品为研究对象,采用传统Olsen法和DGT技术评价多年磷肥投入不均条件下黄土高原地区土壤磷储量及其有效性现状,研究了DGT技术测定的DGT-P与全磷、Olsen-P之间的关系,并利用通径分析探究了土壤磷素有效性和土壤相关理化指标之间的关系。结果表明:黄土高原地区土壤磷素分布不均匀,缺磷与富磷现象并存,富磷土壤主要是耕地样品。磷素活化系数(Olsen-PAC)小于2.0%的土壤样品占76.67%,绝大部分土壤样品磷素有效性低。耕地磷肥投入量过高,活化土壤中的无效磷是黄土高原地区磷素科学管理的主要目标。土壤DGT-P与全磷、Olsen-P呈显著相关性(P0.01)。黏粒对土壤磷素有效性的直接影响最大,对Olsen-PAC的影响为正效应,对DGT法测定的磷素活化系数(DGT-PAC)的影响为负效应。土壤黏粒含量越高,有效磷库越大,土壤中供植物吸收利用的磷反而越少。     

长期施肥对灰漠土无机磷组分的影响

以国家灰漠土土壤肥力与肥料效益长期监测站为平台,采用蒋柏藩-顾益初土壤无机磷分组方法,对23年长期定位施肥条件下、不同施肥处理土壤无机磷总量(IOP)及组分(Ca_2-P、Ca_8-P、Al-P、Fe-P、O-P、Ca_(10)-P)进行测定,以掌握长期施肥对干旱区灰漠土无机磷组分的影响规律并指导合理施肥。结果表明,长期不施肥(CK)处理土壤无机磷总量无显著变化,组分间主要发生Ca_2-P、Ca_8-P向Ca_(10)-P的转化;长期施肥(NPK、NPKM、NPKS)处理IOP极显著增加,其增加量主要为Ca_2-P、Ca_8-P、Al-P和Fe-P,其中前三者增加作用极为显著;长期施肥条件下,土壤无机磷组分中Ca_8-P转化率最高、占土壤无机磷转化总量的39%~50%,其次是Al-P、占16%~30%,再次是Ca_2-P、占10%~29%,三者合计占78%~88%,其余三种组分Fe-P、O-P、Ca_(10)-P占12%~22%。     

Effects of Long-Term Fertilization on the Form of Inorganic Phosphorus and the Characteristic of Adsorption and Desorption in Black Soil

Changes of inorganic phosphorus forms and the characteristics of phosphorus adsorption and desorption were studied under a long-term fertilization experiment in black soil. Results showed that the forms of inorganic phosphorus ranged as O–P < Ca₂–P < Ca₈–P < Al–P < Ca₁₀–P < Fe–P. Therefore, Fe–P was the main inorganic phosphorus form in this study. The capacity of phosphorus adsorption with phosphate treatments was higher than with no-phosphorus treatments. The optimal fitted equation was the Langmuir equation. Phosphorus desorption was related to the binding energy. Positive correlation between phosphorus adsorption and desorption without phosphorus addition was found; however, negative correlations among the phosphate treatments had been observed.