畜禽舍粪便污水及废气净化的研究

猪场污水经文中所述工艺系统处理以后,污水中的化学耗氧量(COD_Cr)达到98.4mg/L;生物需氧量(BOD₅)达到49.6mg/L;悬浮物(SS)达到51.49mg/L以下;硫化物达1.0mg/L以下:铜和铜化物达到0.6mg/L以下。畜舍中的废气净化,选择挥发性的药材制成“姜满净化剂”,能使畜舍的氨(NH₃)降解率达到73.9％,舍内含氟量为15.0mL/m³;硫化氢(H₂S)降解率达到85.8％,舍内的硫化氢浓度为2.8mL/m³;细菌降低率达到70.7％。     

集约化猪场废水强化生化处理工艺试验研究

该文采用新型厌氧反应器技术和强化生物脱氮及硝化技术处理猪场废水。试验结果表明：新型厌氧反应器容积COD_Cr负荷可达8 kg/(m³·d)以上,稳定运行COD_Cr平均去除率为75％;生物脱氮及硝化采用一体式A/O反应器,缺氧段水力停留时间为1 h,好氧段水力停留时间为3 d,氨氮浓度可控制在10 mg/L以下。总出水COD_Cr平均550 mg/L,BOD₅平均53.0 mg/L,NH₃-N平均8.8 mg/L,总COD_Cr去除率87%,总BOD₅去除率96%,NH₃-N总去除率在98％以上;采用原水碳源优化分配强化生物脱氮,TN去除率为77.11%左右。总出水BOD₅/COD_Cr约0.10,出水COD_Cr中难生物降解成分占绝大多数,需经过后续物化处理才能达到广东省水污染物控制标准(DB44/26-2001)。     

模拟潜流人工湿地处理猪场废水的实验研究

采用盆栽试验模拟潜流型人工湿地，研究了土壤、蛭石、煤渣和碎石四种人工湿地基质不同组合净化养猪场污水的能力。结果表明：以上层蛭石土混合物、下层煤渣和碎石的组合处理效果最佳，14d内COD_Cr、NH₄⁺-N、T-P的去除率分别达到了95.3%、90%、91.6%。试验前期，四种不同组合基质的COD_Cr、NH₄⁺-N、T-P去处率有明显差异，但试验后期除T-P的去除率仍有明显差异外，COD_Cr和NH₄⁺-N去除率已无明显差异。     

中国陕西省施有机肥黄土NH4+固定的热力学性质

Some thermodynamic properties of NH₄⁺ fixation by loess soil in plowing and clay layers are discussed. The results indicate that the four ion adsorption equations commonly used can describe the properties of NH₄⁺ fixation in these soils under constant temperature. Among the four adsorption equations, the single-surface Langmuir equation is the best. When the concentration of NH₄Cl solution is 10^-1 mol below, the Freundlich equation can be used. The changes of apparent standard free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) illustrate that NH₄⁺ fixation in soil is an endothermic adsorption and spontaneous reaction, and the process can be enhanced by a higher temperature and clay content in soil. The "proper value of NH₄⁺ fixation by soil (K₁ × q_m) increased with increasing clay content and temperature. The heat of NH₄⁺ fixation in soil (Q_m) confirms the conclusions made in this paper.     

二价锰离子对柠檬酸还原六价铬的催化作用

The catalysis of manganese(Ⅱ) (Mn²⁺) on chromium(Ⅵ) (Cr⁶⁺) reduction by citrate was studied through batch experiments with the concentration of citrate greatly in excess of Cr⁶⁺ at 25℃ and in pH ranges of 4.0 to 5.0. Results showed that at pH 4.5 within 22 h direct reduction of Cr⁶⁺ by citrate was not observed, but for the same time when Mn²⁺ (50 to 200μmol L^-1) was added, nearly all Cr⁶⁺ was reduced, with the higher initial Mn²⁺ concentration having faster Cr⁶⁺ reduction. In the initial stage of the reaction, the Cr⁶⁺ reduction could be described with a pseudo-first-order kinetics equation. In the later stage of the reaction, plots of lnc(Cr⁶⁺) versus t, where c(Cr⁶⁺) is the Cr⁶⁺ concentration in the reaction and t is the reaction time, deviated from the initial linear trend. The deviations suggested that the pseudo-first-order kinetics did not apply to the whole experimental period and that some reaction intermediates could have greatly accelerated Cr⁶⁺ reduction by citrate. The catalysis of the intermediates increased with the reaction time and gradually reached stability. Then, the plot of lnc(Cr⁶⁺) versus t in the presence of Mn²⁺ was linear again, with the rate constant increasing by 102 times compared with the absence of Mn²⁺. Complexation between Mn²⁺ and citrate was likely a prerequisite for the catalysis of Mn²⁺ on the reaction. Additional experiments showed that introducing ethylenediaminetetraacetic acid (EDTA) into the reaction system strongly suppressed the catalysis of Mn²⁺.     

硝态氮促进水稻生长和氮素吸收的生理机制

Rice is being increasingly cultivated in intermittently irrigated regious and also in aerobic soil in which Nitrate (NO₃^-) plays important role in nutrition of plant. However, there is no information regarding the influence of nitrate on the overall growth and uptake of nitrogen (N) in rice plant. Solution culture experiments were carried out to study the effects of NO₃^- on the plant growth, uptake of N, and uptake kinetics of NH₄⁺ in four typical rice (Oryza sativa L.) cultivars (conveutioual indica, conventional japonica, hybrid indica, and hybrid japonica), and on plasma membrane potential in roots of two conventional rice cultivars (indica and japonica) at the seedling stage. The results obtained indicated that a ratio of 50/50 NH₄⁺-N/NO₃^--N increased the average biomass of rice shoots and roots by 20% when compared with that of 100/0 NH₄⁺-N/NO₃^--N. In case of the 50/50 ratio, as compared with the 100/0 ratio, total N accumulated in shoots and roots of rice increased on an average by 42% and 57%, respectively. Conventional indica responds to NO₃^- more than any other cultivars that were tested. The NO₃^- supply increased the maximum uptake rate (V_max) of NH₄⁺ by rice but did not show any effect on the apparent Michaelis-Menten constant (K_m) value, with the average value of V_max for NH₄⁺ among the four cultivars being increased by 31.5% in comparison with those in the absence of NO₃^-. This suggested that NO₃^- significantly increased the numbers of the ammonium transporters. However, the lack of effect on the K_m value also suggested that the presence of NO₃^- had no effect on the affinity of the transporters for NH₄⁺. The plasma membrane potential in the roots of conventional indica and japonica were greatly increased by the addition of NO₃^-, suggesting that NO₃^- could improve the uptake of N by roots of the rice plant. In conclusion, the mechanisms by which NO₃^- enhances the growth and N uptake of rice plant was found by the increased value of V_max of NH₄⁺ and increased plasma membrane potential. Thus promotion of nitrification in paddy soil is of great significance for improving the production of rice.     

甘肃省小陇山林区降雨型浅层滑坡汇水面积-坡度关系及其影响因素

沟头发生侵蚀的地形临界模型可有效预测侵蚀沟的形成条件,浅层滑坡失稳形成的洼地也是沟头形成的方式之一。为探究浅层滑坡临界起动模型的特点,以甘肃省天水市小陇山林区的降雨型浅层滑坡为研究对象,运用汇水面积-坡度关系,构建临界起动模型,与黄土高原典型侵蚀沟(浅沟、切沟)的临界起动模型进行对比分析,并探讨土地利用类型、植被类型和土壤质地对该模型的影响。结果表明:(1)浅层滑坡临界起动模型为S=3.50A_s^-0.34,其侵蚀阈值为3.50,大于黄土高原典型浅沟(0.96)和切沟(1.54)的侵蚀阈值。研究区浅层滑坡一般发生于土层较薄的陡坡地带,其平均坡度(S=1.26)大于浅沟(S=0.35)与切沟(S=0.46),单位汇水面积(A=89.08 m²/m)小于浅沟(A=920.93 m²/m)和切沟(A=1 129.82 m²/m)。(2)汇水面积与坡度平方的乘积(AS²)代表了沟头产生侵蚀的能量指标值。研究区浅层滑坡AS²值在269.1~5 703.2 m²,平均值为1 772.97 m²,黄土高原浅沟AS²值在4.74~892.66 m²,切沟在41~814 m²,启动能量值方面,浅沟<切沟<浅层滑坡。(3)土地利用类型、植被类型和土壤质地通过影响土壤的抗冲力、渗透性和黏粒含量,从而对浅层滑坡的起动难易程度产生影响。在不同的土地利用方式中,农地最易发生侵蚀,其次是林地。油松林附近浅层滑坡的抗侵蚀能力高于日本落叶松林。研究结果为探究浅层滑坡的起动条件提供理论依据。     

淡水湿地不同围垦土壤非耕季节呼吸速率差异

选择何种湿地利用方式,使得土壤固碳能力及CO₂气体排放受到的影响最小,是合理利用湿地、减少温室气体排放的关键所在,湿地土壤呼吸不仅受环境条件的影响,还受土壤本身性状的影响。以皖江地区为研究区域,利用定位试验对天然湿地及不同围垦利用方式下土壤在非耕季节CO₂排放通量、大气温度及表层土壤温度进行测定,并对其土壤TOC含量进行分析。结果表明,CO₂排放通量:水稻田[700.70 mg/(m²·h)]> 旱地[433.80 mg/(m²·h)]> 天然湿地[302.66 mg/(m²·h)],天然湿地土壤TOC含量明显高于围垦旱地及水稻田(0-30 cm),说明天然湿地较围垦旱地和水稻田对大气中CO₂浓度贡献最小,能存储更多的碳。探讨了CO₂排放通量与温度的相关性,得出3种土壤类型CO₂排放通量与大气温度和表层土壤温度均呈正相关关系。     

猪肉油炒过程传质参数测定及其对烹饪过程控制的影响

为提升油炒数值模拟的可靠性及准确度,揭示可控操作对烹饪过程参数的影响及关键过程参数对烹饪的影响。通过无量纲水分含量分析解法,测定了中式油炒猪里脊肉过程中的表面传质系数（surface mass transfer coefficient, h_m）和有效水分扩散系数（effective moisture diffusion coefficient, D_eff）,分析了预热油温及样品比表面积Ω对h_m及D_eff的影响;基于已构建的油炒热质传递数学模型、成熟值理论,对比了h_m和流体-颗粒表面传热系数（fluid-to-particle surface heat transfer coefficient, h_fp）对烹饪成熟控制的影响。结果表明：与油炸过程类似研究的文献数据相比,该研究中h_m值偏大在5.927×10^?6～2.481×10^?5 m/s之间,D_eff在6.281×10^?9～4.148×10^?8 m²/s之间,D_eff活化能（E_a）在24.2～30.6 kJ/mol范围内;预热油温、比表面积Ω对h_m及D_eff有显著影响（P<0.05）,预热油温越高h_m和D_eff越大,比表面积Ω越大h_m越大,D_eff越小;h_m对烹饪成熟控制影响较小,而h_fp是烹饪成熟控制的关键过程参数。研究结果为油炒过程模拟提供了重要参数,为烹饪过程控制提供依据。     

半干旱黄土地区幼龄侧柏叶蒸腾的数学模型

 通过人工控制水分,形成单株幼龄侧柏的不同土壤水分梯度环境。在自然环境下对侧柏叶片定时、定位进行蒸腾速率及林冠层的光照、空气温度、空气湿度、叶水势和土壤水分等因子的同步观测。蒸腾速率与各个因子的相关分析表明:黄土半干旱地区侧柏蒸腾速率η_t/(μg·cm^-2·s^-1)与光照强度E/(μmol·m^-2·s^-1)、空气饱和差p_v/kPa、叶水势Ψ/kPa、气温t/℃的关系可以分别表示为:η_t=>αE_b,η_t=αp_vb,η_t=αψ^b,η_t=αt²+bt+c;侧柏的蒸腾速率η_t与气孔阻力R_s/(s·cm^-1)和土壤含水量W/％有密切关系,可以分别表示为:η_t=α+bW+cW₂+dW₃,R_s=α+bW+cW₂+dW₃。用气温、空气饱和差、叶水势3个因素建立了半干旱黄土地区幼龄单株侧柏蒸腾速率的非线性指数预测模型:η_t=0.6950_exp（0.03158t-14.2492/p_v+0.7606/Ψ）,经检验获得了满意的数值模拟结果。     

Absorption and transport of Na and Cl in rice cultivars differing in their tolerance to salinity: An examination of the effects of ammonium and potassium salts

The absorption and transport of Na and Cl from 0.1 mM and 10 mM ²²Na labelled NaCl or ³⁶Cl labelled KCl were examined in 15 days old seedlings of 3 cultivars of rice differing in their tolerance to salinity. Furthermore, the effects of 10, 100 and 1000 ppm (N)₂S on their uptake were studied. It was found that in general, the salt‐tolerant cultivars BR and PNL‐1 absorbed more Na and translocated a lesser proportion of it to the shoot, compared to the salt‐sensitive IR‐8, from 0.1 mM NaCl. The presence of (N)₂S reduced the uptake of Na in all the cultivars. It was also found that the presence of 100 ppm K, KN or NNreduced Na absorption from 0.1 mM NaCl significantly in all the cultivars, and the translocation to shoot in BR‐ Chloride transport from 0.1 mM NaCl was reduced by (N)₂S in all the cultivars. The 3 cultivars differed significantly in the rates of absorption and transport of Na and Cl. The results indicate that PNL‐1 which is a cross of IR‐8 X BR, has inherited the salt tolerance trait from BR. Lower rates of Na translocation to the shoot can be used as an index of salt tolerance in rice.     

An examination of the total analysis of major elements in soil samples

Recently conventional chemical analyses were mostly replaced by instrumental analysis. Although results from both methods were examined in details after the samples had been solubilized or extracted by appropriate techniques, the solubilization method was considerably altered so as to be convenient for the following analysis. In atomic absorption spectrophotometry (AAS), for example, fusion technique was mostly inadequate because of the higher salts concentration in the obtained solution. The use of H₂SO₄ must also be avoided in acid digestion for SO₄ ^2- precipitates with Sr²⁺ or La³⁺ which must be added to eliminate interferences in the succeeding procedure. Therefore, it is essential to consider the whole scheme including sample treatments to evaluate the suitability of instrumental analysis. In this experiment, the suitability of the methods which have been employed in our laboratory was examined by analyzing 9 rock standards.     

我国酸性硫酸盐土壤中铁锰形态转化及迁移

酸性硫酸盐土壤酸性很强，有机质含量高，造成了这种土壤所特有的铁锰淋洗、转化和迁移规律。研究结果表明：在酸性硫酸盐土壤中全铁含量较低，一般在３５－５０ｇ／ｋｇ（以Ｆｅ２Ｏ３计），全锰含量也低，一般在０．２５－０．５５ｇ／ｋｇ（以ＭｎＯ计），一般滩涂中全铁大于６０ｇ／ｋｇ，全锰大于１ｇ／ｋｇ。酸性硫酸盐土壤中，铁的游离度较小，一般在３７－７０％，铁的活化度较大，一般在８－２０％，而滩涂中铁的游离度一般     

Denitrification potential in a grassland subsoil: effect of carbon substrates

We examined the potential of a subsoil to denitrify nitrate under optimal anaerobic conditions in a laboratory-based incubation when supplied with a range of C substrates of increasing recalcitrance. Both topsoil and its associated subsoil were supplied with nitrate and either glucose, starch or cellulose. Microbial respiration and the evolution of N₂O and N₂ were measured. The subsoil supported low amounts of microbial activity and responded only to the glucose treatment; with less than one-fifth of the N₂O production measured in the top soil. Overall, our findings demonstrated that the denitrification potential of this particular subsoil is relatively low and that only simple carbohydrates could be utilised readily by the resident microorganisms.     

Availability and extractability of soil manganese in a liming experiment

Abstract

The availability of soil Mn to corn in relation to extractability of soil Mn by EDTA, Mg(NO₃)₂, CH₃COONH₄, hydroquinone, H₃PO₄, and NH₄H₂PO₄ as affected by liming was evaluated under field conditions on a single soil type. EDTA, Mg(NO₃)₂ and CH₃COONH₄‐extractable Mn were related inversely to available Mn. No useful relationships were found between hydroquinone, H₃PO₄, and NH₄H₂PO₄‐extractable soil Mn and Mn uptake by sweet corn.     

CO2, CH4 and N2O fluxes of upland black spruce (Picea mariana) forest soils after forest fires of different intensity in interior Alaska

Abstract

Forest fires can change the greenhouse gase (GHG) flux of borea forest soils. We measured carbon dioxide (CO₂), methane (CH₄) and nitrous oxide (N₂O) fluxes with different burn histories in black spruce (Picea mariana) stands in interior Alaska. The control forest (CF) burned in 1920; partially burned (PB) in 1999; and severely burned (SB1 and SB2) in 2004. The thickness of the organic layer was 22 ± 6 cm at CF, 28 ± 10 cm at PB, 12 ± 6 cm at SB1 and 4 ± 2 cm at SB2. The mean soil temperature during CO₂ flux measurement was 8.9 ± 3.1, 6.4 ± 2.1, 5.9 ± 3.4 and 5.0 ± 2.4°C at SB2, SB1, PB and CF, respectively, and differed significantly among the sites (P < 0.01). The mean CO₂ flux was highest at PB (128 ± 85 mg CO₂-C m^?2 h^?1) and lowest at SB1 (47 ± 19 mg CO₂-C m^?2 h^?1) (P < 0.01), and within each site it was positively correlated with soil temperature (P < 0.01). The CO₂ flux at SB2 was lower than that at CF when the soil temperature was high. We attributed the low CO₂ flux at SB1 and SB2 to low root respiration and organic matter decomposition rates due to the 2004 fire. The CH₄ uptake rate was highest at SB1 [–91 ± 21 μg CH₄-C m^?2 h^?1] (P < 0.01) and positively correlated with soil temperature (P < 0.01) but not soil moisture. The CH₄ uptake rate increased with increasing soil temperature because methanotroph activity increased. The N₂O flux was highest [3.6 ± 4.7 μg N₂O-N m^?2 h^?1] at PB (P < 0.01). Our findings suggest that the soil temperature and moisture are important factors of GHG dynamics in forest soils with different fire history.     

Sulfur dioxide inhibition of photosynthesis at different CO2 and O2 concentrations in relation to photorespiration

The mechanism of SO₂ inhibition of photosynthesis in intact leaves of tomato and maze was studied to evaluate SO₂ inhibition of photorespiration. Leaf tissues were fumigated with SO₂ under photorespiratory (low CO, and/or high O, concentrations) and non-photo-respiratory conditions. When tomato leaf disks were fumigated with 10 ppm SO₂ at 2, 21 and 100° o O., SO₂ inhibited photosynthesis at 2% O₂ in the same degrees as at 21% O₂. SO₂ inhibition of photosynthesis was depressed at higher CO₂ concentrations when the disks were fumigated with SO₂ at different CO₂ concentrations. High CO₂ concentrations also reduced the photosynthesis inhibition of maize leaf disks. These results suggest that SO₂ inhibits photosynthesis through other mechanisms than photorespiration inhibition and confirm the view that SO₂ competes with CO₂ for the carboxylating enzymes in photosynthesis     

土壤有机矿质复合体研究Ⅵ.胶散复合体的化学组成及其结合特征

本文研究水热条件渐变的地带性土壤中Ｇ１、Ｇ２组胶散复合体有机、无机物的化学组成及其结合特点。结果表明：Ｇ２组中铁有积累现象，游离态铁、铝氧化物含量为Ｇ２＞Ｇ１，但均随土壤类型变化。松结态腐殖质（Ｈ１）为Ｇ１＞Ｇ２，紧结态腐殖质（Ｈ３）则为Ｇ１＜Ｇ２。可提取腐殖质中，松、稳结态腐殖质之比值Ｈ１／Ｈ２和胡敏酸、富里酸之比值ＨＡ／ＦＡ，除个别土壤之外，都相关不大。Ｇ１、Ｇ２两组复合体中都含有一定数量的络     

Acidifying emissions in The Netherlands

The emission of acidifying compounds to air in the Netherlands, expressed as acidifying equivalents, consisted in 1992 mainly of NO_X (45%), NH₃ (35%) and SO₂ (20%). Transportation, agriculture and large combustion plants each contributed about 30% to the national total emission of acidifying compounds. The emissions from transportation activities mainly consisted of NO_X, while in agriculture NH₃ emission strongly dominated. Combustion processes in large combustion plants resulted both in SO₂ emissions (especially from refineries) and NO_X emissions (especially from public power plants). The total emission of acidifying substances decreases steadily in the Netherlands. The emission in 1992 was 24% lower than in 1985. It is expected to decrease further in future. The emission levels in 1992 and 1993 still are more than twice as high as the emission objective for the year 2000, set by Dutch environmental policy.     

Factors regulating acetylene reduction assay for measuring heterotrophic nitrogen fixation in water-logged soils

In the C₂H₂-C₂H₄ assay for measurement of heterotrophic N₂ fixation in water-logged soils, the diffusion of C₂H₂ into the soil and the recovery of C₂H₄ from it are critical factors regulating the assay result. To establish an C₂H₂-C₂H₄ assay technique suitable for waterlogged soils, the C₂H₂-reducing activities (ARA), assayed by varying the method of assay gas filling, the pC₂H₂ of the assay gas, the duration of assay incubation and of soil vibration before the gas sampling, were compared.

A maximum ARA was measured when the following set of procedures were applied to the soil sample in assay flasks: 1) a 4-fold repetition of I-min evacuation under 0.01 atmospheric pressure and the subsequent I-min filling under 1 atmospheric pressure with assay gas at pC₂H₂ of 0.1 atm, 2) an assay incubation for 3 hr, and 3) a sampling of an aliquot of the headspace gas after strongly vibrating the flask for 1 min.

The ARA measured by this technique was several times larger than those measured by the techniques hitherto applied, and corresponded to an almost 80% of the V _max of the sample. This technique was, therefore, proposed for the assay of heterotrophic N₂ fixation in waterlogged soils.

A striking depression of ARA in the soil sample prepared with agitation indicated that a microbial ecosystem established in the soil should be kept as undisturbed as possible throughout the C₂H₂-C₂H₄ assay.