Distribution of airborne heavy metals as measured in the lichens Ramalina stenospora and Parmotrema praesorediosum in Baton Rouge,Louisiana

The lichens Ramalina stenospora and Parmotrema praesorediosum were collected from 30 stations in the greater metropolitan area of Baton Rouge, Louisiana and analyzed for Al, Cu, Fe, Zn, and Pb content. A univariate analysis of the data showed a significant difference between metal concentrations and sampling stations. When the stations were separated into two groups representing those in the industrial and urban zones, a discriminant analysis was over 90% successful in correctly assigning stations based solely on metal concentrations. No significant differences in metal concentration with species could be observed. Average metal concentrations for the two lichen species were used to construct contours and three-dimensional plots of metal distribution across the study area which clearly demonstrate the effects of the industrial zone on airborne metal levels.     

Cesium-137 Concentrations in Sediments and Aquatic Plants from the Pinios River, Thessalia (Central Greece)

The levels of radioactive contamination by artificial radiocesium (¹³⁷Cs) were evaluated in sediments and the commonest species of water plants. Specimens were collected from a range of biotopes along the Pinios River and its tributaries, during the years 1998 and 2010. The ¹³⁷Cs concentrations within the above period clearly indicate that this radionuclide still decrease in the River Pinios. A marked decrease is also observed in comparison to our previous results in 1993. ¹³⁷Cs concentration activities in the sediment are higher than in the plant material. In general, roots showed greater ¹³⁷Cs concentration than leaves, while stems showed the lowest concentration. Significant differences in ¹³⁷Cs concentrations were found among different species growing under similar environmental conditions. ¹³⁷Cs content in collected aquatic plants was in the descending order: Ceratophyllum demersum L. > Myriophyllum spicatum L. > Paspalum pasalodes Scribner > Cladophora glomerata L. > Cyperus longus L. > Potamogeton nodosus Poiret. A comparison of the studied stations indicated that the southwest side of Thessalia plain, where the first two initial sampling stations of the Pinios River and the tributaries Enipeas and Kalentzis are situated, was highly contaminated. Low ¹³⁷Cs concentrations were observed in the Titarisios tributary, originated from the northeast part of Thessalia plain, behind Mt. Olympus and the last sampling stations of the Pinios River.     

Production and Bromatological Characteristics of Elephant Grass—<Emphasis Type="Italic">Cenchrus purpureus</Emphasis> (Schumach.) Morrone—Planted Under Application of Industrial Biosolid and Chemical Fertilization

Biosolid, i.e., dehydrated sludge from effluent treatment stations, has been progressively used as an agricultural fertilizer due to its high organic matter and nutrient contents. Elephant grass (Cenchrus purpureus (Schumach.) Morrone) presents easy adaptation and high yields, being used for animal feeding and for energy purposes. The objective of this work was to analyze the production and bromatological parameters of elephant grass with four different doses of biosolid, one of chemical fertilizer and a control plot, with two replicates each. A field experiment was carried out using a randomized block design with three blocks, totaling 18 plots, which received biosolid fertilization at 1×, 2×, 4×, and 8× the levels recommended by the Brazilian National Environment Council, along with conventional chemical fertilization and no fertilization, all under similar drip irrigation. Tukey’s test indicated a significant difference at p?<?0.01 for total production in the first cut and acid detergent fiber in the second cut. At p?<?0.05, significant differences were detected for total nitrogen and total protein in the first cut. The elephant grass yield under “1× biosolid” was similar to that reached with chemical fertilization. Physical and bromatological characteristics indicated potential use as animal feed and energy source. For doses higher than specified by Brazilian standards (2×, 4×, and 8×), further studies are required to verify possible contamination from heavy metals, pathogenic microorganisms, and n.     

Concentration of three toxic metals in oysters (Crassostrea virginica) of biloxi and pascagoula,Mississippi estuaries

Concentrations of three toxic trace metals, Hg, Pb, and Cd in the commercial oyster Crassostrea virginica were measured by atomic absorption spectrophotometry. Oysters were collected from the Biloxi, Ocean Springs and Pascagoula, Mississippi area. Mercury concentrations were low and appeared to be natural background levels. Lead content of the Mississippi oysters compared favorably with levels in Atlantic Coast oysters, but Cd in Atlantic Coast oysters was approximately 6.7 times greater than in the local specimens. There was no definite relation between oyster size and Pb, Hg or Cd content.     

Effects of varying air trajectories on spatial and temporal precipitation chemistry patterns

This study was designed to determine if judicious use of synoptic data and an operational trajectory model could identify probable source regions of anthropogenic pollutants in northeastern United States precipitation and thus relate receptor measurements to emissions data without consideration of the complex intervening meteorological and chemical processes. The storm event of April 8 to 10, 1979, was selected for intensive study. Precipitation chemistry data were obtained from event samples at six MAP3S sampling sites and from hourly samples at Brookhaven National Laboratory. Concentrations of hydrogen, sulfate, nitrate and ammonium ions were used as receptor data. Some emissions data for SO_x and NO_x were obtained from the MAP3S emissions inventory. Surface and upper air meteorological data were analyzed. Backward trajectories ending at each of the sampling sites during the precipitation period were computed with the Heffter Interactive-Terminal Transport Model using selected transport layers. Results show that concentrations of pollutant species in event precipitation samples were much higher at stations at end points of trajectories passing through the Ohio River valley than at stations with other trajectories. Likewise, concentrations at Brookhaven were much higher during the end period of a trajectory through the same region than with more northerly and more southerly tracks. The model produced back trajectories consistent with synoptic flows. Concentrations of air pollutants in precipitation were roughly proportional to the number of major pollutant sources along the trajectory. These results suggest that a larger number of studies might identify more restricted source areas or even establish a quantitative relationship between source emissions along a trajectory and concentrations in precipitation at receptor sites.     

Evaluation of Heavy Metal Pollution in the Arabian Gulf Using the Clam Meretrix meretrix Linnaeus, 1758

The present study is an attempt to assess the heavy metal contamination in the marine environment of the Arabian Gulf of Saudi Arabia. The concentrations of heavy metals in water and the soft tissues of the bivalve species Meretrix meretrix Linnaeus, 1758, from different stations along the Arabian Gulf coastline, were determined during the summer season of 2008. Bioaccumulation of some heavy metals (Cd, Pb, Cu, and Zn) in fresh parts of the clam (M. meretrix) was measured by an atomic absorption spectrophotometer. The average concentrations of heavy metals in the clam tissues were 0.224?C0.908, 0.294?C2.496, 3.528?C8.196, and 12.864?C24.56 mg/kg wet weight for Cd, Pb, Cu, and Zn, respectively. In water, the mean concentration values of these metals were arranged in the following descending order: Pb > Cu > Zn > Cd. The heavy metal concentrations in tissues of M. meretrix were within the acceptable standards set by the US Environmental Protection Agency, the Commission Européenne, and the Food and Drug Administration of the USA. From the human public health point of view, these results seem to show no possibility of acute toxicities of Cd, Cu, Pb, and Zn if the edible clam is consumed. It is recommended that relevant authorities should carry out a continual assessment on the levels of these pollutants in the studied area.     

Water quality along the Neapolitan coast

Two kinds of surveys on marine environment quality were carried out along the Neapolitan Bay from the winter 1977 to 1980. The first was a general investigation along 60 km of coast, embracing several municipalities. Its purpose was to identify the most consistently polluted areas. The second one was a more limited but prolonged monitoring along about 12 km of coast entirely included in the municipality of Naples. At the beginning of this latter inspection two fecally contaiminated areas were found. These showed an increase in pollution during summer. However during the three years of surveillance a general improvement of the water quality was observed, perhaps due to the use of undersea pipes for the discharge of sewage far from the coast. As a consequence in the summer of 1980, 78% of the sampling points exihibited values ofEscherichia coli below limits prescribed in the Italian standard for bathing water (100E. coli/100 ml), while only 38% of the stations in the summer of 1978 could be considered suitable for bathing.     

Can We Use Zebra and Quagga Mussels for Biomonitoring Contaminants in the Niagara River?

We compared contaminants in zebra and quagga mussels (Dreissena polymorpha and Dreissena bugensis) of two different size classes from sites within the Niagara River to determine if the two species and two size classes can be used to monitor contaminants. Composite samples (i.e., at least 50 individuals) were analysed for 7 trace metals, total PCBs, selected organochlorine pesticides, chlorinated benzenes, and dioxins and furans. ANOVAs and MANOVAs showed that metal tissue concentrations varied significantly among sites, species, and size classes (P < 0.05). At sites where metal concentrations differed between species, zebra mussels had higher concentrations than quagga mussels. Similarly, larger mussels (i.e., 16–25 mm) generally had higher tissue concentrations than smaller mussels (<15 mm length). However, differences in tissue concentrations between size classes were present only for Cd, Cu and Mn and were infrequent, making these results inconclusive. For organic contaminants ANCOVAs and MANCOVAs using lipid concentration as a covariate revealed significant differences in tissue concentrations between the three sites, whereas differences between size classes were modest (P = 0.035). The ANOVA using individual parameters did not show a significant difference in tissue concentrations between the two size classes. In general, mussel tissue concentrations among stations (up to 7 stations throughout the river), were similar for Pb, Zn, Hg and Ni using data separated by species and size class. Concentrations of Cu, Mn and Cd were variable throughout the upper and lower Niagara. Tissue concentrations of α-BHC, 1,2,3 and 1,2,4 trichlorobenzene were similar in quagga mussels collected from 8 stations from the Canadian and American side of the river, whereas concentrations of total PCBs, octachlorostyrene, 1,2,3,4-tetrachlorobenzene, pentachlorobenzene and hexachlorobenzene were higher in quagga mussels from the American side of the upper river.     

New insights into the origins and evolution of rhizobia that nodulate common bean (Phaseolus vulgaris) in Brazil

It is generally accepted that there are two major centers of genetic diversification of common beans (Phaseolus vulgaris L.): the Mesoamerican (Mexico, Colombia, Ecuador and north of Peru, probably the primary center), and the Andean (southern Peru to north of Argentina) centers. Wild common bean is not found in Brazil, but it has been grown in the country throughout recorded history. Common bean establishes symbiotic associations with a wide range of rhizobial strains and Rhizobium etli is the dominant microsymbiont at both centers of genetic diversification. In contrast, R. tropici, originally recovered from common bean in Colombia, has been found to be the dominant species nodulating field-grown common-bean plants in Brazil. However, a recent study using soil dilutions as inocula has shown surprisingly high counts of R. etli in two Brazilian ecosystems. In the present study, RFLP-PCR analyses of nodABC and nifH genes of 43 of those Brazilian R. etli strains revealed unexpected homogeneity in their banding patterns. The Brazilian R. etli strains were closely similar in 16S rRNA sequences and in nodABC and nifH RFLP-PCR profiles to the Mexican strain CFN 42^T, and were quite distinct from R. etli and R. leguminosarum strains of European origin, supporting the hypothesis that Brazilian common bean and their rhizobia are of Mesoamerican origin, and could have arrived in Brazil in pre-colonial times. R. tropici may have been introduced to Brazilian soils later, or it may be a symbiont of other indigenous legume species and, due to its tolerance to acidic soils and high temperature conditions became the predominant microsymbiont of common bean.     

Staging of Pacific flyway brant in relation to eelgrass abundance and site isolation, with special consideration of Humboldt Bay, California

Spring distributions of black brant (Branta bernicla nigricans) are closely related to that of their primary food plant, eelgrass (Zostera marina). Using historical (1931-2001) brant data from Humboldt Bay, California, we show that proportional use of two main feeding areas in the bay strongly reflects food abundance. We used multiple regression to investigate whether the spatial relationship between brant and eelgrass holds at the flyway level. We related peak brant numbers at 11 staging areas in the Pacific flyway to the sites' Z. marina abundance and isolation from other important staging areas. We explained 90% of the variation in peak brant numbers across sites with these variables; isolated bays with high eelgrass abundance supported the most brant. Our results emphasize the importance of protecting large eelgrass habitats along the Pacific Coast, particularly in bays that are geographically isolated from other large staging areas.     

Gastropod Assemblages as Indicators of Sediment Metal Contamination in Mangroves of Dumai, Sumatra, Indonesia

Impacts of heavy metal concentrations in sediments on the gastropod community structure were assessed in the coastal waters of Dumai, Sumatra, Indonesia. The objective of this study was to relate the levels of heavy metal pollution with the changes of gastropod community structure in the study area. Concentrations of Cd, Cu, Pb, Zn, Ni, and Fe in surface sediments collected from five sampling stations were analyzed and correlated with the abundance, species richness, and diversity of gastropod populations. Sediments at stations with more anthropogenic activities accumulated higher concentrations of heavy metals and consequently displayed lower abundances, lower species richness and diversity; while stations with lower heavy metal concentrations in sediments showed the opposite pattern in gastropod community metrics. The above findings are complemented by significant negative correlations p?<?0.05–0.01) between concentrations of Cd, Cu, Pb, Zn, and Ni in the sediments and gastropod abundance and species richness. Among the metals analyzed, Cu and Zn had strongest negative correlations with the gastropod diversity which suggests that these metals may be the most detrimental to gastropod populations in the mangrove area of Dumai coastal waters.     

Airborne heavy metal pollution in the environment of a danish steel plant

A survey of heavy metal deposition was carried out in the vicinity of a Danish steel plant. Bulk precipitation and transplanted lichen (Hypogymnia physodes (L.) Nyl.) were sampled at 12 stations in the environment before and after the production had been converted from open-hearth furnaces to electric-arc furnaces. The samples were analyzed for Cd, Cr, Cu, Fe, Mn, Pb and Zn. The results show that heavy metal pollution from the steelworks still is severe and that it follows a decreasing power curve when the distance to the steelworks is increased. However, a reduction in the deposition of heavy metals close to the steelworks has been observed, pointing to the conclusion that the change from a situation of emission through a 46 m stack without any filter to emission from the electric arc furnaces equipped with bag-filters has lead to changes in the emission. At the sampling stations with the highest deposition levels measured in bulk precipitation the corresponding concentrations in the lichens were relatively lower indicating a change in particle size distribution. Within each station there was a direct proportionality of metal concentrations in lichens and atmospheric fallout measured in bulk precipitation.     

Source regions of summertime ozone and haze episodes in the eastern United States

During the summer of 1979, the mobile Atmospheric Research Laboratory (ARL) was sited near the Louisiana Gulf Coast to monitor the concentrations of air contaminants in air masses moving northward from the Gulf. Using the ARL data in conjunction with O₃ and visibility measurements across the entire eastern United States as well as synoptic meteorological data and satellite photographs, major source areas were identified. The haze which was observed on the Louisiana Gulf Coast appears to be primarily due to aged sulfate aerosols. The evidence presented strongly suggests that the sulfates were largely due to SO₂ emissions in the northeastern and midwestern United States. The haze initially formed over and downwind of these source areas and was transported to the Gulf Coast area. In the last two episodes, the haze was subsequently transported back to the Midwest source region. Elevated levels of O₃ were also associated with the haze. Again, the Northeast and Midwest appear to be the most significant source areas for the regional O₃ episodes. Occasionally, O₃ formed from emissions in the east Texas area also appear to affect a large portion of the Gulf Coast. In addition, each episode appeared to have a significant stratospheric air component based on⁷Be measurements. All three episodes followed the passage of upper levels troughs which produce stratospheric intrusions due to tropopause folding.     

Temporal changes in metal levels of the lichens Parmotrema praesorediosum and Ramalina stenospora,Southwest Louisiana

Two species of lichen native to southwest Lousiana, Parmotrema praesorediosum (Nyl.) Hale and Ramalina stenospora, Mull. Arg. have been investigated as air pollution monitors. Over the period 1983–88 samples were collected at 18 stations in the Lake Charles/Westlake/Sulphur area. The samples were analyzed for A1, Fe, Cu, Pb, Cd, Hg, Cr, and Zn. When metal concentrations in lichens were plotted vs year for certain representative stations, a dramatic reduction in the concentrations of certain metals was seen after 1983. When the most recent data are compared with those previously obtained, the effects of the industrial zone, which was previously demonstrated, have now all but disappeared.     

Predictive modelling and ground validation of the spatial distribution of the New Zealand long-tailed bat (Chalinolobus tuberculatus)

The use of predictive models is continually increasing, but few models are subsequently field-checked and evaluated. This study evaluates the statistical strength and usefulness for conservation purposes of a predictive habitat use model developed for Chalinolobus tuberculatus, a threatened microchiropteran bat species found in the temperate rainforests of New Zealand. The relationship between various environmental variables and the presence/absence of the species was investigated using generalised linear modelling. The model developed was coupled with GIS data to develop maps of predicted occurrence within the West Coast region of New Zealand’s South Island. It was found that distance to forest boundary, slope, presence of Nothofagus, general land cover, variability in mean annual solar radiation, and mean ambient winter minimum temperature were significantly associated with the occurrence of the species. Evaluation of the statistical strength of the distribution model with independent data of species’ occurrence collected at 152 sites found that the C. tuberculatus model showed a moderate ability to predict both species presence and absence (τ(b) coefficient = 0.37). The field detection rate (0.45) using this model was significantly higher than that of historical surveys (0.12). The value of the species habitat model and the need to evaluate its utility in the development of conservation strategies is discussed.     

Organochlorine Pesticides and Heavy Metals in Green Mussel,Perna Viridis in Singapore

A statewide total gaseous mercury (TGM) monitoring campaign was conducted from January 1997 to December 1999 in the State of Connecticut, U.S.A. Eight monitoring sites with different characteristics of geographical location (coastal vs. interior) and land use (rural vs. urban) were included in the monitoring program. Statistical procedures were utilized to evaluate the temporal trend and spatial distribution of the TGM concentration in the State, and the influence of long-range transport from non-local sources. The statewide mean TGM concentration was 2.08 ng m^-3. The annual mean concentration had no significant differences among the three years of measurements for all the sites. Weak seasonal variations were detected in the State with higher ambient TGM concentration found in warmer seasons. Urban areas in general had higher TGM concentrations than rural areas. The effect of site location of the monitoring sites on TGM concentration was interacted with land use characteristics. Waterbury site with extremely high concentration measurements was the major cause for this interaction. The long-range transport of TGM from remote sources showed an important influence on local ambient concentrations, by explaining over 45% of the total variance of the ambient TGM concentration for most sites. Local sources were responsible for the extremely high TGM concentration in the Waterbury site. The TGM concentrations at Voluntown, Hammonasset and Avery Point in southeast Connecticut were likely to be affected by some local sources.     

The value of forest strips for understorey birds in an Amazonian plantation landscape

Remnant forest strips are frequently proposed as valuable conservation tools in fragmented tropical landscapes, yet we currently lack evidence to evaluate their potential conservation value for native biota. We examined the potential value for understorey forest birds of 30-year-old riparian and terra firme (unflooded) primary forest strips within a large silvicultural landscape in the north-east Brazilian Amazon, where the matrix is dominated by Eucalyptus plantations. We conducted mist-netting in eight forest strips connected to continuous forest (four of each forest type), with a total of 24 replicate sampling sites located near to (<1 km), far from (2.5-9 km), and within undisturbed forest controls (i.e. 16 samples within the strips, and 8 in controls). Bird communities in both strip types changed with increasing distance along forest remnants into the plantation matrix. Matrix-embedded samples were characterised by a higher representation of birds typical of secondary growth forest but not those typical of the Eucalyptus-dominated matrix. While the long-term viability of the bird populations in these remnants remains unclear, our data demonstrate that forest strips can provide important habitat for many bird species that are otherwise rarely found outside primary forest. Forest strips therefore provide an important tool to enhance biodiversity conservation in plantation landscapes. The relative practical ease with which these areas can be selected and maintained means that the protection of forest strips as part of a wider conservation strategy is likely to have particular appeal to policy makers and landscape managers working in the human-dominated tropics.     

Sediment Quality Assessment of Road Runoff Detention Systems in Sweden and the Potential Contribution of Tire Wear

Sediments from 18 different road runoff detention systems, located on the Swedish West Coast, were assessed for their ecological hazard potential. Thirteen of the sites were detention ponds, three were manholes within the same sedimentation construction, and two were detention basins handling wash water from road tunnels. Sediments from all sites were analysed for a range of physico-chemical parameters and contaminants, and screened for acute toxicity using Hyalella azteca (sediment), Daphnia magna (elutriate), and Ceriodaphnia dubia (elutriate) as the test organisms, and for chronic toxicity using C. dubia as the test organism. The benthic fauna of the thirteen detention ponds was also studied. Sediment quality guidelines probable effect levels were exceeded for one or several contaminants at half of the sites, and one third revealed toxicity in some of the bioassays. Most of the detention ponds were dominated by tolerant taxa indicating low biological quality. Relationships between contaminant concentrations, toxicity in bioassays, and benthic fauna were, however, found to be weak. Extractable organic Zn, which was used as a tire wear marker, correlated with Zn, Cu, presumably from brake linings, and W, a common component of tire studs. The highest concentration, which was found in the manholes (14 mg kg^?1 ds), corresponds to a tire wear concentration of 11 g kg^?1 ds. The results of the present study have shown that traffic related contaminants accumulate in the studied runoff treatment systems, and, therefore, the maintenance of them is crucial in order to prevent contamination of surrounding waters.     

Nitrogen compounds in atmospheric precipitation

The paper presents results of a stoichiometric calculation of a nitrogen (N) compounds in precipitation of World Meteorological Organization's Global Atmosphere Watch (WMO GAW) stations. Long-term trends of ammonium sulphate ((NH₄)₂SO₄) and ammonium nitrate (NH₄NO₃) contents i the North-West of Russia as well as in Byelorussia, Scandinavia, Western and Eastern Europe during the periods of 1958–1990 and 1972–1985 were investigated. A relatively, steady annual trend for the mean NH₄NO₃ concentrations was found typical of pure regions (5–15μeq^* 1^?1). The concentrations in industrial regions are from 4 to 5 times higher than the background close to natural. The analysis of the trend for (NH₄)₂SO₄ content in precipitation shows a wide range of a variations of mean annual concentrations with an explicit tendency to their significant decrease in some European regions in the mid-eighties. Nitric acid (HNO₃) has not been discovered in precipitation from the European WMO GAW stations while calculations based on the US data revealed its remarkable content and tendency to its increase. Nitric acid and ammonium sulphate are not contained in precipitation over ocean, ammonium nitrate is present in insignificant amounts.