热处理对MDF力学性质的影响

对市场随机购买的中密度纤维板(MDF)进行热处理,以期改善其力学性质.采用全因素试验方法,对影响MDF热处理效果的因子进行了分析.结果表明:热处理温度、时间,以及不同的生产厂家和产品厚度,对板材的主要力学性质指标可产生一定的影响.建议:当产品中的胶黏荆未完全固化时,可以采用热处理工艺以提高其内结合强度.     

无胶纤维板生产工艺的研究

研究密度为1.0g/cm~3、厚度为8mm的无胶纤维板制造工艺,结果表明其较优工艺为:板坯含水率10%,热压压力3.0MPa,热压温度200℃,板坯芯层温度140℃。以此工艺在MDF生产线上进行的试验结果表明:板材的物理力学性能达到LY/T1611—2003普通型地板基材用纤维板指标要求。     

有机膨胀型阻燃剂在桉树中纤板中的应用

桉树人工林木材已成为我国南方中密度纤维板(MDF)生产的主要原料之一,为进一步拓宽桉树MDF的应用领域和利用价值,自行研发了一种有机型阻燃剂并用于阻燃桉树MDF的生产.通过对板材阻燃性能和主要力学强度指标的测试,结果表明,阻燃桉树MDF达到难燃材料的标准要求,主要力学强度指标达到国标GB/T11718-2009的要求.     

低成本改性脲醛树脂胶的制备及应用

为降低中密度纤维板(MDF)生产成本,使用三聚氰胺对E1级脲醛树脂(UF)进行改性,并优选出适用的固化剂。生产线试验结果表明,采用一次缩聚反应制备的改性UF胶生产MDF,板材性能基本满足GB/T 11718-2009要求;按年产18万m3计,年产能和收益可分别增加约2.14万m3和342万元,节省用胶成本约351万元。     

延缓中密度纤维板(MDF)老化速度的研究

为提高MDF产品的耐老化性能,选用BS加速老化试验法对MDF素板、贴面板、浸渍板及涂饰板4种板材进行试验比较。试验结果表明,对MDF产品表面采用一定的方法进行处理,可达到延缓MDF 制品老化速度的目的。     

HA-100树脂交联剂降低MDF施胶量的生产性试验

添加HA-100树脂交联剂可显著降低MDF生产中脲醛树脂胶的施加量。本实验研究添加树脂交联剂对板材各项物理性能的影响,以及对降低生产成本的分析。     

密度对异氰酸酯胶高密度纤维板性能的影响

以桉木纤维和异氰酸酯胶为原料制备高密度纤维板,探索密度变化对高密度纤维板吸水厚度膨胀率和力学性能的影响。结果表明:高密度纤维板的主要力学性能随板材密度的增大而大幅度提高,而吸水厚度膨胀率则大幅度下降。异氰酸酯胶高密度纤维板的成功制备,对开发新型纤维板产品意义重大。     

镁铝水滑石复配三聚氰胺磷酸盐制备阻燃中密度纤维板的工艺

采用无机镁铝水滑石和三聚氰胺磷酸盐以1:1质量比复配的阻燃剂,以及异氰酸酯MDI胶制备中纤板(MDF),探讨施胶量、热压温度和热压时间对MDF力学性能的影响。结果表明:各因子对MOE、MOR和IB影响顺序为:MDI施胶量热压温度热压时间;确定较优工艺参数为:热压温度160℃,热压时间6 min,MDI施胶量10%。在此条件下,阻燃MDF的MOE、MOR与IB均达到GB/T11718-2009潮湿状态下使用的家具型产品的要求,氧指数为30.3%。     

木材纤维-铜丝网复合MDF的研究

笔者重点研究了不同目数的铜丝网和木材纤维压制具有电磁屏蔽效能的复合MDF的生产工艺。结果表明,采用异氰酸酯涂刷铜丝网,可显著改善复合MDF的胶合性能,其胶合强度可以达到国家标准的要求。铜丝网的层数对复合MDF的电磁屏蔽效能影响显著,铜丝网在MDF中的复合位置对电磁屏蔽效能影响较显著,在MDF双表面复合铜丝网,当铜丝网的目数大于60目时,在9kHz到1.5GHz频率范围内其电磁屏蔽效能可达到60dB以上。     

MDF基材表面处理对UV喷绘涂层性能的影响

UV光固化数码喷绘技术是一种高效便捷的表面打印技术,用于家居板材表面装饰可满足环保与个性化的高分辨图案定制的需求。选取木质家具常用的中密度纤维板(MDF)为对象,研究最佳的基材表面预处理,优化UV喷绘涂层的涂刷效果。首先,通过测量不同目数砂纸预处理后MDF表面的粗糙度、表面接触角,分析表面机械处理对其性能的影响;通过表征UV喷绘后涂层的性能,确定MDF表面机械处理的最佳砂纸目数。然后,采用4种不同种类的PU与PE底漆预处理MDF,再进行UV数码喷绘;通过表征喷绘涂层的光泽度、附着力、耐磨性、硬度以及板材吸水率性能,获得MDF最佳的底漆涂刷工艺。研究结果表明,经过400#砂纸打磨后,MDF表面粗糙度较低,润湿性较好,此时涂层的光泽度与附着力最好。比较不同的底漆种类与涂刷次数发现,由于UV喷绘涂层较薄,底漆性能对喷绘涂层影响较大,通过刷涂2～3道白色PU底漆预处理基材,可较好地提升UV喷绘涂层的附着力、表现力,并降低MDF基材的吸水性。     

Utilization of pine (Pinus pinea L.) cone in manufacture of wood based composite

Physical and mechanical properties of medium density fiberboards (MDF) made from various mixtures of wood fibers and stone pine (Pinus pinea L.) cones were evaluated using European standards. MDF panels were manufactured using standardized procedures that simulated industrial production at the laboratory. Six panel types were made from mixtures of wood fiber/cone flour, 100/0, 90/10, 80/20, 70/30, 60/40, and 50/50 percents, respectively. Addition of the cone flour into the MDF significantly reduced formaldehyde emission from the panel. In addition, the addition of 10% cone flour also improved water resistance of the MDF panels made using urea–formaldehyde (UF) resin. However, further addition of the cone flour into the panel negatively influenced their water resistance. Flexural properties and internal bond strength decreased with the increase of cone flour content in the panel. The UF resin is the main source of formaldehyde emission from the UF-bonded wood-based panels. Depending on addition of the cone flour in the panels, the formaldehyde emission values ranged from 2.6% to 55.3% lower than the panels made from 100% wood fiber. Based on the findings obtained from this study, pine cone can be used as a renewable biological formaldehyde catcher as an alternative to the traditional formaldehyde catchers for E1 Class MDF manufacture.     

一种脲醛树脂胶粘剂的设计

鉴于对文献的分析和实验验证,本文提出一种脲醛树脂胶粘剂的设计原则。即:1)脲醛树脂最终摩尔比应取1.40～1.20:1,这样可以使制成的板材具有足够的胶接强度;2)为了使人造板的甲醛释放量达到10mg/100g(穿孔法)以下,树脂中的游离尿素应在10%以上;3)在脲醛树脂的分子中引入尿素的环状衍生物,如三嗪环或Uron。环状化合物含量最好在10%左右。按此原则合成了三种树脂,在试验室按标准刨花板和中密度纤维板工艺制成板材,其甲醛释放量在10mg/100g左右,板材物理力学性能均超过国家标准和企业标准。     

LLM型UF树脂制造橡胶木和赤桉中密度纤维板

通过使用ＬＬＭ型ＵＦ树脂制造橡胶木和赤桉中密度纤维板的研究,评价用该树脂制造橡胶木和赤桉中密度纤维板的适应性。橡胶木和赤桉各５０％比例温和后施以ＬＬＭ型ＵＦ树脂,按照ＭＤＦ常规工艺压制９,１２,１６ｍｍ的试验板。结果表明：板材物理力学性能及甲醛释放量指标均达到ＧＢ１１７１８．２－８９标准规定的要求。     

低甲醛释放蔗渣中密度纤维板用脲醛树脂

以脲醛树脂结构形成特征为基础,研制了一种甲醛释放量低、内结合强度高的适用于蔗渣中密度纤维板生产的脲醛树脂胶粘剂。使用结果表明,所压制的蔗渣中密度纤维板物理力学性能达到国家标准要求,甲醛释放量可控制在２０ｍｇ／１００ｇ左右。     

ET03助剂降低E1级中纤板生产成本的试验

利用ET03助剂对UF树脂进行改性处理,并将改性前、后的UF树脂分别用于中密度纤维板生产.试验结果表明:改性后的UF树脂在降低10%施胶量的情况下,板材的物理力学性能指标、甲醛释放量仍可达到GB/T 1718-1999<中密度纤维板>E1级标准;每m3的中纤板可降低成本4%～5%.     

Effects of heat treatment on some properties of MDF (medium-density fiberboard)

This work investigated some mechanical, physical and free formaldehyde emission properties of heat-treated MDF. For this purpose, MDF panels were subjected to varying heat treatment temperatures (155°C, 165°C and 175°C), durations (2.5?h., 3.5?h. and 4.5?h.) and waiting times after hot pressing (30?min., 120?min. and 600?min). Thickness swelling (TS), water absorption (WA), free formaldehyde emission (FFE), bending strength (BS), modulus of elasticity (MOE), tensile strength perpendicular to fibers (TSPF) for treated and untreated samples were tested and evaluated statistically. Consequently, after the heat treatment values of tensile strength, bending strength and modulus of elasticity were almost negatively affected relatively, but the thickness swelling and water absorption and quantities of free formaldehyde were improved positively of MDF samples.     

Effect of nanoclay on some applied properties of oriented strand board (OSB) made from underutilized low quality paulownia (Paulownia fortunei) wood

In this study, the effect of nanoclay on some applied properties of oriented strand board (OSB) made from underutilized low quality paulownia wood was investigated. Organo-modified montmorillonite (MMT) at four levels (0, 1, 3 and 5?%) was added to urea formaldehyde (UF) resin. Some chemical properties of paulownia wood (holocellulose, cellulose, lignin and ash contents, pH value and hot and cold water solubility), mechanical [modulus of rupture (MOR), modulus of elasticity (MOE), internal bond strength, screw and nail withdrawal strengths], physical (water absorption and thickness swelling) properties and formaldehyde emission of the strand boards were evaluated. Mechanical properties of all panels complied with the general-purpose OSB minimum property requirements of European Norm. With increasing 5?% nanoclay to UF resin, mechanical and physical properties of the resulting panels improved and formaldehyde emission decreased. However, none of the panels satisfied the thickness swelling and water absorption requirement. The results of X-ray diffraction and transmission electron microscope analysis confirmed the good dispersion of nanoclay in the resulting OSBs. Using paulownia as a fast-growing underutilized species not only can sustain the forests but also can supply raw material to countries facing shortage of wood.     

甲醛清除触媒在清除人造板中游离甲醛的试验研究

清除人造板中甲醛的后处理试验结果表明,喷涂甲醛清除触媒后的人造板物理力学性能没有明显变化,甲醛清除触媒对不同种类人造板释放出的甲醛清除效果相同,E3级胶合板喷涂甲醛清除触媒后的甲醛释放量小于（等于）0.12mg/L,清除率大于99．08％。     

改性脲醛树脂胶低密度稻壳-木材复合材料制造工艺的研究

采用异氰酸酯(ISO)改性的脲醛树脂胶制造低密度稻壳-木材复合材料。稻壳与木质刨花的混合比例为1:1,施胶量为7%,试验结果表明,异氰酸酯改性的脲醛树脂胶黏剂适用于低密度稻壳-木材复合材料,其物理力学性能明显优于使用传统的脲醛树脂胶黏剂。低密度稻壳-木材复合材料的物理力学性能随着改性剂异氰酸酯用量的增加而提高。密度是稻壳-木材复合材料物理力学性能的重要影响因素,低密度稻壳-木材复合材料的物理力学性能随着密度的增加而提高。在设定密度为0.45g/m~3和0.5g/cm~3的条件下,3:4的ISO/UF的稻壳-木材复合材料的物理力学性能均达到日本刨花板工业标准(JIS A5908)的要求。     

The ambient aging of wood fiber and its effect on mechanical properties of MDF panels

Fourier-transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) were used to study ambient-aged wood fibers and their effects on the mechanical properties of medium-density fiberboard (MDF). It was found that MDF made with ambient-aged fibers had poorer mechanical properties than MDF made with fresh fibers; this difference resulted from the alterations of surface characteristics of wood fibers after ambient aging, which led to poor wettability of the urea–formaldehyde (UF) resin applied to the aged wood fibers. After 6 months of ambient aging, the concentration of carbonyl groups in the fibers increased by 144%, while the pH value of wood fiber decreased from 5.2 to 4.7. SEM showed that much more UF resin agglomerated on the surface of ambient-aged fibers and the breakage of MDF made with aged fiber frequently occurred at the resin-fiber interfaces, indicated the poorer wettability of UF resin to fibers due to the decrease in surface energy after aging.