叶面喷施微肥对晋南小麦产量和微量元素含量的影响

在山西临汾盆地石灰性褐土进行冬小麦田间试验,在底施NPK肥的基础上,研究了在拔节中期和抽穗前期叶面喷施锌、铁和硒对"济麦22"产量及其构成因素、成熟期地上部分各器官微量元素含量和分配比例的影响。结果表明:叶面喷施3种微肥提高了小麦产量及其构成因素,增产效果为FeSeZn,喷施铁肥与喷施清水相比差异显著;叶面喷施微肥使籽粒、茎叶和颖壳中对应微量元素的含量提高,其中喷施硒肥效果最为明显,喷施锌肥次之;籽粒对3种元素的吸收相互影响,铁对锌单向拮抗,锌与硒、铁与硒相互促进;叶面喷施微肥使锌在籽粒中分配比例稍高于茎叶+颖壳,铁在籽粒中分配比例仅6.87%~8.25%,硒在籽粒中的分配比例稍低于茎叶+颖壳。建议临汾盆地在小麦拔节中期和抽穗前期对冬小麦叶面喷施0.4%ZnSO_4·7H_2O溶液750 kg/hm~(2)和0.017%Na_2SeO_3溶液750 kg/hm~(2),可显著提高籽粒中的锌、硒含量,从而改善籽粒品质;叶面喷施0.3%FeSO_4·7H_2O溶液750 kg/hm~(2)对产量有一定的提升作用。     

Principal component analysis of biogenic amines and polyphenols in Hungarian wines

Biogenic amines, polyphenols, and resveratrol were analyzed quantitatively in 25 different Hungarian wines from the same wine-making region, harvest of 1998. Polyphenols were determined according to a spectrophotometric method, whereas other substrates were analyzed using overpressured-layer chromatography (OPLC). Principal component analyses (PCA) were performed on data matrices consisting of substrates (columns) and different sorts of wines (rows) from the region of Pécs (southern Hungary). It was found that four (unrotated) principal components account for >80% of the total variance in the data. The plots of component loadings showed significant groupings for concentrations of biogenic amines (and polyphenols). Similarly, the component scores grouped according to the different sorts of wines. The loading plots reveal that there is no need to measure all of the variables to achieve the same characterization. It is enough to measure one variable per group. Naturally, this conclusion is valid only within the limits of the present study; wines from other regions may behave differently.     

Application of ICP sector field MS and principal component analysis for studying interdependences among 23 trace elements in Polish beers.

Twenty-three metallic elements, including almost all essential and toxic metals such as lead, cadmium, mercury, arsenic, silver, and thallium, have been quantified in 35 types of bottled and canned Polish beer by using double-focusing sector field inductively coupled plasma mass spectrometry (ICP-MS) with ultrasonic nebulization. The samples were digested using concentrated HNO3 in closed PTFE vessels and applying microwave energy under pressure. The means and medians of the concentrations of Rb, Mn, and Fe were on the order of 200 ng/mL; Cu, Zn, V, Cr, Sn, As, Pb, and Ni were detected at 1-5 ng/mL; Ag, Ga, Cd, Co, Cs, Hg, U, and Sb were found at < 1 ng/mL; and In, Tl, Bi, and Th were present at < 0.1 ng/mL. The concentrations of Hg, Cd, As, Pb, and Zn were 1-3 orders of magnitude lower than proposed tolerance limits. The interdependences among determined trace elements were examined using the principal component analysis (PCA) method. The PCA model explained 74% of the total variance. The metals tend to cluster together (As, Tl, Cs, Sn, Th, Bi, and Hg; Cd and Co; Cs and Cr; Fe and Zn; Mn and V).     

樱桃品种果实品质因子主成分分析及模糊综合评价

研究不同品种甜樱桃果实品质指标差异,确定代表性品质指标,从而筛选出品质优良的甜樱桃品种。以24种甜樱桃果实为材料,测定其11项品质指标(单果质量、硬度、可食率、出汁率、p H值、总糖含量、还原糖含量、可滴定酸含量、糖酸比、维生素C含量、花色苷含量),并运用主成分分析、模糊评判法进行综合评价。结果表明:不同甜樱桃品种各项指标存在差异,其中单果质量与维生素C之间,可食率与出汁率、可滴定酸之间,花色苷与p H值、可滴定酸之间,总糖、还原糖、糖酸比与p H值之间均呈及极显著正相关。因子分析提取了甜味、口感、抗氧化、可食、质量5项主因子,累计方差贡献率为82.948%,包含了大部分指标信息,因此筛选总糖、出汁率、维生素C、可食率、单果质量作为评价甜樱桃的关键指标;利用PAST软件绘制各品种在5个主因子的分布状况,并对品种因子综合得分进行排序,得分排名前10的樱桃品种依次为"Red"(0.70)、"早露"(0.63)、"红蜜"(0.60)、"彩玉"(0.47)、"秦樱一号"(0.44)、"S2S1"(0.38)、"早大果实生"(0.35)、"13-33"(0.28)、"明珠"(0.13)、"秦林"(0.07);对11个分析指标进行模糊综合评判,综合品质表现排名前10的品种分别为"Red"(0.642)、"红蜜"(0.566)、"早露"(0.545)、"明珠"(0.524)、"彩玉"(0.521)、"秦樱一号"(0.512)、"秦林"(0.501)、"美早"(0.491)、"S2S1"(0.482)、"早大果实生"(0.470),以上结果一致表明"Red"、"早露"、"红蜜"、"彩玉"、"秦樱一号"、"S2S1"、"早大果实生"、"明珠"、"秦林"等9种樱桃综合品质较其他15种樱桃更优,其中"Red"樱桃品质最优,可作为樱桃资源开发利用、育种及品质改良的原材料。因子分析与综合评价结果基本一致,该试验初步确定排名前9位的樱桃优良品种,为樱桃品种选育和加工利用提供理论依据。     

气候变暖对春小麦籽粒痕量元素利用率的影响

为了回答温度升高是否会改变痕量元素在士壤中的溶解性,以及作物对痕量元素的生物利用率,在人工气候室模拟未来气候变化温度升高背景下,对种植在不同温度处理的3种春小麦,测定了籽粒中Cd,Cu,Fe和Zn含量.结果发现温度升高引起了土壤中Cd,Cu,Fe和Zn溶解性的显著变化,也显著地影响小麦籽粒中Cd,Cu,Fe和Zn的生物利用率.最高升温3℃处理使西旱1号、2号和3号小麦籽粒中Cd浓度相比对照分别下降43.4％、11.1％和13.4％,Cu浓度相比对照处理分别下降了30.4％、25.1％和10.8％.但Fe和Zn的情况却不同,1℃和2℃升温处理使西旱1号籽粒中Zn浓度比对照处理分别增加了28.9％和35.8％.根据未来气候变化两北地区温度升高1.9℃,估计到2050年,小麦籽粒中的质量分数范围分别在Cd(0.59-0.65)、Cu(5.91-7.64)、Zn(63.73-69.41)和Fe(185.23-202.70) mg/kg.     

Patterns in trace elements in lichens

Water, Air, & Soil Pollution - Epiphytic lichens were sampled in a Dutch national monitoring survey, which was carried out twice within 5 yr. The samples were analyzed by neutron activation...     

不同种源枫香磷响应指标的主成分分析

采用裂区砂培试验,研究枫香对 P 水平响应性状的相关性,进行了主成分分析,旨在找出影响其生物量的主导因子、不同种源的最适生长 P 浓度及优良耐 P 胁迫种源.相关分析表明,除 P 利用率具有一定的稳定性外,生物量与其他响应性状相关性显著;低 P 胁迫造成的 N 吸收利用的变化对枫香影响更大.主成分分析表明,枫香生物量差异的主导因子是 N、P 吸收性状,其次是 P 利用性状.标准化主成分得分排序认为南昌种源具有较好的 N、P 吸收利用机制;南丹种源具有较好的种源特性,P 利用率较稳定.根据我国土壤有效 P 含量多样性的现状筛选出具有广适性特点的南昌种源和具有较好耐低 P 胁迫特性的南丹种源.     

小麦秸秆热解过程中碳和微量元素迁移转化规律

为研究小麦秸秆热解过程中碳元素和微量元素的迁移转化规律,依托连续式作物秸秆分段均匀炭化联产系统,基于热解炭化生产工艺,测算及分析碳元素在秸秆热解过程中的存在形式及迁移转化量,利用HSCChemistry软件模拟微量元素在秸秆热解炭化过程中的组分变化,分析了8种微量元素的迁移转化规律,为生物质热解机理的进一步研究提供支撑,为提高秸秆热解炭品质提供强有力保证。结果表明:经测试及测算得到的碳元素迁移足迹图符合碳元素质量守恒定律,碳元素迁移到热解炭中41.12%,以固定碳存在;22.83%迁移到焦油中,以大分子长链烃和环链烃存在;26.62%的碳元素以六碳内的短链烃存在于热解气;4.71%迁移到木醋液中为醛、酮、酸等。小麦秸秆中含量在100μg/L以上的8种高富集微量元素里,K、Na、Ca、Mg主要以硫酸盐、磷酸盐及氯化物形式存在于热解炭中,Al、Fe多以氧化物、硫化物以及硅、氧共融物形态被大量保留在热解炭中,而P、S元素在热解炭化过程中的析出主要是有机结合物的分解。     

Principal component analysis applied to nutrient balances in organic layers of beech and spruce forests

Yearly nutrient balances were established between August 1979 and October 1981 for the organic layers of beech and spruce forests. Principal component analysis has been applied to the monthly nutrient balances in order to understand the important differences which appear between both types of organic layers. Three main processes affect the redistribution of elements from the organic layers: exchange and solubilization, organic matter mineralization and nitrate immobilization and release. The relative importance of these three processes within the beech and the spruce layers is different. Moreover, it is shown that variations in the rainfall regime is an important factor which govern nitrogen redistribution and that rainfall acidity promotes phosphate leachings from the organic layers of both forests.     

Rare earth elements and other trace elements in wastewater treatment sludges

In order to evaluate the possibility of contamination of soil with trace elements by the application of sludges to soil, the contents of rare earth elements (REEs; La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) and other trace elements (Be, As, Ag, Cd, Sb, Cs, Bi, and U) in wastewater treatment sludges were determined. In sludges of night soil treatment plants (night soil sludges) and sludges of wastewater treatment plants in the food industry (food industry sludges), the distribution patterns of REEs normalized versus average REEs in the continental crust were almost flat. It was considered that the REE patterns of uncontaminated sludges reflected the pattern of the continental crust. The crust-normalized REE patterns of sludges of wastewater treatment plants in the chemical industry (chemical industry sludges) and municipal sewage sludges did not always show flat plots. The sludges that did not show a flat REE pattern were considered to be contaminated with some of the REEs.

The coefficient of variation of each element determined among the 10 samples of night soil sludges and the 14 samples of sewage sludges ranged from 34 to 77% and from 26 to 84%, respectively. Among the 10 samples of food industry sludges and the 10 samples of chemical industry sludges, the coefficient ranged from 60 to 143% and from 67 to 172%, respectively. The variations of the content of each element among the food industry sludges or the chemical industry sludges were larger than those among the night soil sludges or the sewage sludges.

The contents of Be, As, Cs, REEs, and U in all the sludges were lower than or the same as those in a field soil. Some of the food and chemical industry sludges contained larger amounts of Ag, Cd, and Sb than the soil. All the night soil sludges and sewage sludges contained much larger amounts of Ag and Bi than the soil.     

Crop contamination by selected trace elements

Goal and Background  The regulatory limit for the allowable concentration of heavy metals (HM) in agricultural soils should be based both on HM status and on soil parameters that influence HM mobility. In this paper, a soil categorization scheme is proposed which is based on the main factors that influence HM mobility in soils. The scheme also makes use of the existing regulatory limits for total concentrations of trace elements in Slovak soils but additionally takes into account the potential ability of the soils to mobilize trace elements. A map of the Slovak Republic showing the soil categorization using this scheme is presented. Methods  Besides total soil content of Cd, Pb, Cr, Hg, As, Cu, Zn, Ni, soil parameters with dominant influence on HM mobility are included in the scheme pH, organic matter content, quality of humus represented by spectral parameter Q⁴ ₆ and content of fraction f < 0.01 mm. Point rating approach was used for categorization. Database of localized soil data from 3556 locations was used for creation of map in GIS environment. Results  Based on the point scoring method described herein, soils are ranked from a (the least risk of crop contamination) to d (medium risk). Categories e and f are reserved for soils where the risk exceeds the allowable regulatory limits. For each of the six categories, the most suitable usage of agricultural land is recommended. The Slovak map presented shows that the main factor that affect the spatial distribution of each soil category is soil parent material which governs the existing total HM content and the predisposition for certain soil types to have high HM mobility. Agricultural usage of land in Slovakia is in most cases limited by exceedences of Cr and Ni, originating from widespread flysch rock parent material. Conclusions  Application to regional geochemical data shows that, for more than half of Slovak agricultural land, risk of crop contamination is low. For the rest of the area, planting should consider sensitivity of crops to HM uptake. Recommendation and Outlook  Evaluation of suitable agricultural usage based on HM contamination risk, should include not only the total HM content but also the potential for HM mobility, which can increase the risk of plant contamination. Where HM mobility data are not available, soil parameter data that influence HM mobility can be used to predict the potential HM soil contamination hazard.     

Source-receptor relationships for trace elements in Northern Europe

Measured air concentrations of several trace elements in southern Scandinavia have been related to long range transport and emissions of the same elements from sources in Europe using receptor modelling and statistical trajectory sector analysis. A good agreement, within a factor of 1.5 between estimates and measurements, has been obtained for Mn, Ni, Cu, and As. Significant differences were noted for V and Pb.     

Characterization of major and trace elements in sclerotium grains

Sclerotium grains in soil contain humus-metal complexes that are probably produced from fungal metabolites. The characterization of major elements in sclerotium grains collected from volcanic ash soils in Mt Myoko was examined by X-ray photoelectron spectroscopy, FT-IR spectrometry and CHN analysis, and the concentration of trace elements was determined by PIXE (particle induced X-ray emission spectrometer) analysis. The content of major elements, C, H, N, O and Al, was approximately 47.6, 3.32, 0.78, 30.2 and 1.4% by mass, respectively. Trace elements such as Ti, Cr, Mn, Cu, Zn, Br and Pb were detected in the grains at concentrations between 10 and 100 μg g⁻¹. Functional carbon groups for the whole grain were characterized by the dominance of O-alkyl C associated with aromatic C. The comparison between the surface and subsurface (matrix) of the grain showed that the concentrations of O, C and N were relatively greater on the surface of sclerotium grains than in the matrix. The proportion of carbon having C–O, C=O, and O–C=O bonds, O and N showed a tendency to decrease from the surface towards the matrix. The proportion of C assigned as C–C and/or C–H bonds had a tendency to increase towards the matrix associated with Al.     

Effects of trace elements on urease activity in soils

Disposal of sewage sludges and effluents on agricultural land is becoming a widespread practice. Most sludge samples disposed on soils contain large quantities of various trace elements. Studies of 20 trace elements commonly found in sludge samples showed that they inhibit the activity of urease in soils and that their order of effectiveness as inhibitors of urease depends on the soil. When the trace elements were compared by using 5 μmiol·g^?1 soil, however, some of them showed the same order of effectiveness as urease inhibitors in the six soils studied i.e., for the monovalent and divalent ions, Ag⁺ ≥ Hg²⁺ >Cu²⁺ >Cd²⁺ >Zn²⁺ >Sn²⁺ >Mn²⁺, and generally, Fe²⁺ >Fe²⁺andCu²⁺ >Cu⁺. Other trace element ions that inhibited urease were Ni²⁺, Co²⁺, Pb²⁺, Ba²⁺, As³⁺ B³⁺, Cr³⁺, Al³⁺. V⁴⁺ Se⁴⁺ and Mo⁶⁺. Of the trace element ions studied, only As⁵⁺ and W⁶⁺ did not inhibit urease activity in soils.Studies on the distribution of urease activity showed that it is concentrated in surface soils and decreases with depth. Urease activity was proportional to organic C distribution in each soil profile and was significantly correlated with organic C in the surface soils studied.     

Atmospheric deposition of trace elements in Norway: Temporal and spatial trends studied by moss analysis

The atmospheric deposition of sixteen trace elements, as inferred by their concentration in moss samples collected in 1985 from 500 sites in Norway, is compared with data from a similar survey in 1977. The deposition patterns of V, Zn, As, Se, Cd, Sb, and Pb are substantially influenced by long-range transport from other parts of Europe, but a general decline is evident from 1977 to 1985, most strongly for Pb. For Cr, Fe, Co, Ni, and Cu the deposition patterns are largely determined by contributions from point sources within Norway and on the Kola peninsula close to the Russian/ Norwegian border. The moss data for Br, I, and partly Se reflect airborne supply from the marine environment, whereas Al and Sc serve as indicators of contributions from soil dust. Contributions to the trace element concentrations in moss from sources other than atmospheric deposition are identified and discussed.     

主成分分析和长短时记忆神经网络预测水产养殖水体溶解氧

为了提高水产养殖溶解氧预测的精度,提出了基于主成分分析(principal component analysis,PCA)和长短时记忆神经网络(long short-term memory,LSTM)的水产养殖溶解氧预测模型。首先通过主成分分析提取水产养殖溶解氧的关键影响因子,消除了原始变量之间的相关性,降低了模型输入向量维度;然后,在Tensorflow深度学习框架的基础上建立LSTM神经网络的水产养殖溶解氧预测模型;最后,利用该模型对浙江省淡水水产养殖研究所综合实验基地某池塘溶解氧进行验证。试验结果表明:该模型与BP神经网络等其他浅层模型相比,模型评价指标平均绝对误差、均方根误差和平均绝对误差分别为0.274、0.089和0.147,均优于传统的预测方法;该模型具有良好的预测性能和泛化能力,能够满足水产养殖溶解氧精确预测的实际需要,可以为水产养殖水质精准调控提供参考。     

Field-based partition coefficients for trace elements in soil solutions

A total of 48 elements was detected in the soil solutions centrifuged from two acid sandy (humus-iron podzol) profiles from southern England. Concentrations ranged from mm for the major ions to mm for trace metals such as U and the rare earth elements. Field-based solid/solution partition coefficients, K_d, were determined by calculating the ratio of the amount of an element extracted by 0.43 m HNO₃ or a neutral salt (0.01 m CaCl₂ or 0.1 m Ba(NO₃)₂) to the concentration in the soil solution. These partition coefficients did not show the expected trend in selectivity. For example, Cd consistently had one of the highest K_d values, higher even than Cu. This was thought to be due in part to the nature of the K_d which reflects a balance between binding to the soil solids and to the dissolved organic carbon (DOC), which is present at relatively high concentrations (1–20 mm ) in the soil solutions. Because of the underlying functional similarity between metal binding by the solid and dissolved organic matter, the partition coefficient (and hence element mobility) will be relatively insensitive to changes in pH and metal-ion activity in the soil solution.     

土垫旱耕人为土中某些痕量元素的迁移富集特征及其成因

土壤中元素的分布特征反映了多个成土因素综合作用下土壤发生过程的结果。为探讨人为因素和自然成土因素在土垫旱耕人为土(塿土)形成过程中的影响,本研究在黄土高原区关中平原西部的渭河三级阶地上采集两个典型的土垫旱耕人为土剖面,以马兰黄土作为成土强度的参照样品,采用Zr作为稳定元素,研究痕量元素Cu、Zn、Pb、Rb、Sr的分布特征及其成因。结果表明,受介质的吸附、碳酸钙等易淋溶组分的淋溶淀积、作物吸收等因素影响,痕量元素Cu、Zn、Pb、Rb在剖面上总体呈中高型分布,即在干润淋溶土表层(2A层)和黏质化B层(2B t层)含量有所增加而表现为富集;而Sr则发生强烈迁移,在2A层、2B t层含量显著降低。在埋藏耕作层(Aupb层)、亚耕层(Aup2层)和现代耕作层(Aup1层),自下而上,Cu、Zn、Pb的含量呈缓慢增加趋势,但只有Zn的富集系数在YL01剖面0~15 cm内大于1.1,说明土壤发生过程是导致土垫旱耕人为土剖面中某些层次元素相对富集的主要原因,而人类活动对土垫旱耕人为土痕量元素的影响很弱,且主要在表层。