Salt-Water Dynamics in Soils: Ⅰ. Salt-Water Dynamics in Unsaturated Soils Under Stable Evaporation Condition

A long term simulation test on salt-water dynamics in unsaturated soils with different groundwater depths and soil texture profiles under stable evaporation condition was conducted.Salinity sensors and tensiometers were used to monitor salt and water variation in soils.The experiment revealed that in the process of fresh groundwater moving upwards by capillary rise in the column,the salts in subsoil were brought upwards and accumulated in the surface soil,and consequently the salinization of surface soil took place.The rate of salt accumulation is determined mainly by the volume of capillary water flow and the conditions of salts contained in the soil profile.Water flux in soils decreased obviously when groundwater depths fell below 1.5m.When there was an interbedded clay layer 30cm in thickness in the silty loam soil profile or a clay layer 100cm in thickness at the top layer,the water flux was 3-5 times less than in the soil profile of homogeneous silty loam soil.Therefore,the rate of salt accumulation was decreased and the effect of variation of groundwater depth on the water flux in soils was weakened comparatively.If there was precipitation or irrigation supplying water to the soil,the groundwater could rarely take a direct part in the process of salt accumulation in surface soil,especially,in soil profiles with an interbedded stratum or a clayey surface soil layer.     

Temperature variations in unfrozen soils with variable hydrothermal properties

A comprehensive understanding of the hydrothermal properties of soil is required to model heat distribution in unsaturated soils. In this study, we aim to model heat distribution throughout the profile of unfrozen soil while its thermal diffusivity varies with time and depth. The proposed model is based on the fundamental solution of the one‐dimensional transient heat conduction equation using the decomposition method. We calibrate our model using experimental data from soils of different textures in the literature. The new model can estimate soil thermal diffusivity at different depths and times and uses easily accessible characteristics such as the degree of saturation and the texture of the soil. In this study, the performance of the new model is compared to the performance of the simplified model in which constant thermal diffusivity is considered throughout the profile. Moreover, the model is validated by comparing it with in‐situ temperature measurements within depth of soil profiles with different textures. The results show a very good agreement between the predicted and the measured temperature throughout the soil profiles. Such a validation shows that with increasing degree of soil saturation, depletions in temperature for fine‐textured soils are more significant than those for coarse‐textured soils. Finally, the new model is applied to a double‐layer soil in the Alsace region to define temperature variation in the profile of soil with different characteristics in each layer. For a double‐layer profile, the continuity of the temperature as well as the heat flux is verified at the interface between the two layers.     

恒电荷土壤与可变电荷土壤K+的吸附特性

对我国 3种典型可变电荷土壤和 4种恒电荷土壤在不同 K 浓度和 p H下 K 的吸附特性进行了研究。结果表明 ,两类土壤 K 吸附量均随平衡 K 浓度增加而增加 ,在低浓度 (添加K 0 .1～ 1.0 mmol/ L )时两者符合线性 ,在高浓度 (添加 K 0 .5～ 5 .0 mmol/ L )下两者符合Langmuir方程。L angmuir方程的参数 K两类土壤间差异不大 ,但以可变电荷土壤 >恒电荷土壤 ,说明前类土壤 K吸附结合能较大 ,吸附 K 不易解吸 ,K 有效性较低。p H降低使土壤 K 吸附量减少 ,但恒电荷土壤与可变电荷土壤减少的机理不同 ,前者主要是由于 H 与 K 的竟争吸附 ,而后者主要是由于表面负电荷减少而引起的电性引力的改变。     

离子强度和pH对可变电荷土壤与铜离子相互作用的影响

研究了离子强度和pH对可变电荷土壤表面电荷与铜离子吸附的影响。作为对照 ,也研究了它们对恒电荷土壤黄棕壤的有关性质的影响。结果表明 ,随pH升高 ,土壤的表面负电荷增加 ,正电荷减少。对于可变电荷土壤 ,可出现电荷零点 (pH0 )。随pH升高 ,土壤对Cu2 的吸附量增大。随着离子强度增大 ,恒电荷土壤对Cu2 的吸附百分率明显降低 ,可变电荷土壤对Cu2 离子的吸附百分率也降低 ,但降低的幅度比恒电荷土壤者小得多。土壤中氧化铁的含量越高 ,降低的幅度越小。对于含 2 1 %左右游离氧化铁的铁质砖红壤 ,即使支持电解质NaNO3的浓度高达 1molL- 1,对Cu2 的吸附仍然几乎没有影响。从离子强度和pH与土壤表面电荷和铜离子吸附的关系 ,可以推测在土壤对铜离子的吸附中 ,既存在电性吸附 ,又存在专性吸附。在可变电荷土壤对铜离子的吸附中 ,专性吸附较为重要     

东北黑土有机碳的分布及其损失量研究

为了分析东北黑土土壤有机碳(SOC)的分布特征及其开垦以来黑土SOC的损失程度,我们于2004～2005年在黑龙江和吉林两省采集了32个自然黑土剖面样品,在每个自然黑土样品附近对应采集32个景观条件相似的耕作黑土样品。结果表明,自然黑土样品0～30cm土层SOC含量平均为32.20 g kg-1,最高可达63.46 g kg-1,黑龙江省自然黑土SOC含量(34.55 g kg-1)高于吉林省(23.80 g kg-1)。耕作土壤SOC平均含量为22.71 g kg-1,远低于自然土壤。受温度的影响,随着纬度的增加,自然黑土与耕作黑土SOC含量逐渐递增。由于土壤侵蚀以及耕垦和去除作物残留物等农业管理措施的综合作用,使得耕作黑土表层SOC含量小于自然黑土。与自然黑土相比,耕作黑土0～10cm土层SOC损失量在26.84%～46.57%之间,亚表层损失相对较少。黑土SOC含量下降也是土壤水土流失致使黑土层变薄的一个直接表现。耕作黑土表层流失厚度可以通过自然与耕作黑土剖面SOC含量的分异差值来估算。通过对土壤剖面上SOC的分布进行校正剔除土壤侵蚀的影响后得到的同等深度SOC含量的差值才可视为由耕作以及有机质输入量差异等因素造成的SOC损失量。未经校正而进行的自然黑土和耕作黑土同一深度SOC含量的比较可能过高估计了农业管理措施对土壤SOC损失量的影响。     

Direct determination of potassium-calcium activity ratio in soils with two ion-selective electrodes. II. Interactions of potassium and calcium ions with soils

The interactions of potassium and calcium ions with two variable charge soils and one constant charge soil were examined by measuring the pK-0.5pCa value with two ion-selective electrodes, together with measurements of single ion activities. The constant charge soil showed a much higher preference for calcium relative to potassium than the variable charge soils. The relative affinities of potassium, calcium, sodium and aluminum ions with exchange sites were not constant, but were a function of surface properties of the soil. pH affected the pK-0.5pCa value in both the variable charge soil and the constant charge soil. The strong competition of aluminum ions for exchange sites was the major cause of the higher preference of soils for calcium ions relative to potassium ions at low pH. The pK-0.5pCa value was always smaller in sulfate systems than in chloride systems, with the difference more distinct in variable charge soils. In addition to an initial fast reaction, some potassium ions were immobilized at later times, even for the highly weathered variable charge soil.     

土壤垂向分层和均匀处理下水分差异的数值探讨

在现有众多的陆面过程模型中,对土壤水分的定量描述一般是假设垂向分布均匀,取表层土壤质地来表示整个垂向土壤质地。垂向分层和均匀处理下的土壤水分是存在差异的,这种差异有多大目前少有研究。设置3组不同饱和导水率组合的层状土壤代表不同区域的非均匀土壤,取3组层状土壤的上层土壤代表整个均匀土壤,通过建立一维土壤水分运动模型分析这种差异,同时分析饱和导水率、饱和含水量、残余含水率、孔隙大小分布参数和形状参数对层状土壤和均匀土壤的渗透量和储水量差异的敏感性,探讨垂向层状和均匀处理下土壤水分运动的差异。研究结果表明:1)建立的一维土壤水分运动模型模拟的土壤水分剖面与Yeh解析解和室内五水转化试验的土壤水分剖面一致,表明模型无论是考虑还是不考虑根系吸水都具有可靠性。2)采用垂向均匀方式处理,上下层饱和导水率相差越大的层状土壤,各水文变量的差异越大。当层状土壤上下层饱和导水率相差1.5倍时,层状土壤和均匀土壤的水分分布差别小于0.05 cm~3×cm~(-3);而当层状土壤上下层饱和导水率相差达3.3倍时,层状土壤和均匀土壤的水分分布差别达0.15 cm~3×cm~(-3),渗漏量相差20 cm以上,储水量相差5 cm左右。3)相对于层状土壤下层,均匀土壤下层的持水能力更差,水流速度更快,导致下层水分分布减小,渗漏量增加,储水量减小。4)形状参数n对渗透量的敏感性最强,土壤孔隙大小分布参数对储水量的敏感性最强,形状参数n其次。在实际应用中,如果一个区域的土壤上下层饱和导水率相差较大,那么垂向均匀处理可能会导致很大的误差,和实际土壤的水分分布相差很大,这会严重影响土壤水分的准确估计,在实际处理中需要认真考虑。     

Messung und Simulation der anisothermen Feuchtebewegung in benetzungsgehemmten Mineralböden

Measurement and simulation of nonisothermal moisture movement in water-repellent mineral soils Water repellency often occurs in surface soil horizons, where the temperature may have a significant effect on water movement. Relatively few studies have been conducted to measure the effect of temperature gradients on hydraulic processes in water-repellent soils. The objective of this paper is to analyze the simultaneous impact of hydraulic and thermal gradients on water movement in unsaturated soils. Four sandy soils with organic matter contents between 1.0 and 2.4 percent were used in a laboratory column experiment. The soils had similar particle size distribution and contact angles between 25 and 111 degrees. The water repellency was measured with the “sessile drop method”. The experiments were conducted with open laboratory soil columns. A ceramic plate was placed at the upper end of the soil column to allow water movement from a reservoir, the lower end was closed. The matric potential of ?175 hPa at the upper part of the column was held constant. Simultaneously a constant temperature gradient of approximatly 1.1 °C/cm was applied during the nonisothermal runs. Hydraulic properties of the four soils were determined sequentially at different temperatures (5, 20 and 38°C). The time dependent volumetric water content, matric potential and temperature were measured at five positions in the column. It was found that after steady state was established the water content and matric potential profiles of the four soils differed considerably. A computer code based on the theory of Philip and De Vries (1957) was developed to simulate water and heat transport. For three soils with contact angles of 25–35, 93–108 and 109–111 degrees, respectively, the model performed well when the theoretically calculated thermal vapor difivisivity, D_TV, was multiplied by a factor between two and three. For the slightly water repellent soil with a contact angle between 45 and 83 degrees, however, this factor was about seven to eight. This factor could be the result of a combined impact of the moderate water repellency and the micromorphology of the humic substance.     

不同浓度铜离子土壤的吸附-解吸行为——兼论弱专性吸附态的存在

研究了三种可变电荷土壤和两种恒电荷土壤不同铜离子浓度条件下的吸附-解吸行为。结果表明,不同铜离子浓度下土壤的pH-Cu2+吸附率曲线均在低pH段出现会合,且随着铜离子浓度升高,pH-Cu2+吸附率曲线有向右偏移的趋势。证实了可变电荷土壤中吸附性铜离子可被去离子水解吸,并存在解吸峰现象。针对解吸前后吸附体系pH值的变化研究结果显示,吸附时体系pH低于5.0时,解吸后pH上升;而吸附体系pH高于5.0时,解吸后pH下降,表明pH5.0可能是土壤吸附铜离子机理发生变化的又一个转折点。本文还对专性吸附中弱吸附态的存在和形成原因进行了初步探讨。     

区域农田土壤质地剖面的随机模拟模型

冲积土壤剖面的质地层次分层是该类土壤的重要特性,对农田水分转化和溶质运移具有重要影响。本文论据已取得的研究结果,采用Ｍａｒｋｏｖ链理论提出了区域冲积土壤质地层次的随机模拟模型－ＭＣ模型和ＭＣ－ＬＮ模型,采用蒙特卡罗方法模拟了研究区的土壤质地剖面,并与实测结果进行了对比。     

可变电荷土壤中铜离子的解吸

研究了我国四种可变电荷土壤红壤、赤红壤、砖红壤和铁质砖红壤以及二种恒电荷土壤黄棕壤和黑土中吸附性铜离子的解吸特征。研究结果表明 ,可变电荷土壤吸附的一部分铜离子可以被去离子水解吸 ,而且在pH～解吸率曲线上在一定pH值时出现解吸率最大值。在最大值时不同土壤中铜离子解吸率的大小与土壤中氧化铁的含量有关。氧化铁的含量越高 ,在最大值时铜离子的解吸率越大。当用中性电解质解吸可变电荷土壤吸附的铜离子时 ,电解质的浓度越大 ,解吸率越低。与此相反 ,恒电荷土壤吸附的铜离子不能被去离子水解吸 ,只能被中性电解质解吸 ,且电解质的浓度越高 ,解吸率越大。这表明 ,可变电荷土壤中吸附性铜离子的解吸规律 ,完全不同于恒电荷土壤中者。本文初步讨论了其原因     

The possible effect of soluble silicon on the lepidocrocite content of gley soils from England and Bangladesh

Nine different gley profiles from England and Bangladesh were studied; out of these, four English soils contained variable amounts of lepidocrocite. The amounts of lepidocrocite present in various layers of these soils decreased with increasing concentrations of Si(OH)₄ in the soil solution. The amount of lepidocrocite formed was negatively correlated (r= -0.78) with the atomic ratios of Si/Fe in the citrate/dithionite extracts. Lepidocrocite was absent from the other five profiles, including three surface water gley soils from Bangladesh. These soils contained relatively large concentrations of Si(OH)₄ in soil solution, ranging between 0.7 mm and 1.0 mm. The atomic ratio of Si_d/Fe_d in the citrate/dithionite extracts was higher in these soils. Enborne soil contained maximum amount of citrate/dithionite extracted silicon (2.30 mg g^?1) with no X-ray crystalline iron oxides in the profile.     

荒漠-绿洲边缘区土壤水分时空动态研究

有梭梭群落和骆驼刺群落覆盖的沙地土壤剖面的含水量与裸沙地含水量显著不同,与前者相比,裸沙地土壤水分无明显的层次性变化,受降水及蒸发等因子影响明显。不同植物群落沙地土壤水分呈现明显的土壤水分积累期(4～5月、9月)、土壤水分消耗期(6～8月)和土壤水分稳定期(10月至次年3月)的季节性特点。不同坡位土壤水分基本呈现出从小到大的顺序是坡顶<中坡<丘间地。由于植被覆盖状况和土壤物理性质不同,土壤水分随坡度的变化幅度也有明显差异,与坡顶、中坡相比,丘间地土壤水分含量较高,最高达到14.60%。     

蔬菜地土壤磷饱和度及其对磷释放和水质的影响

为了解蔬菜地土壤磷素的积累对水环境的影响,我们在浙江省选择了33个代表性蔬菜地,采集和分析了土壤、地表水和地下水样的磷素状况,从土壤磷饱和度的角度,研究了浙江省主要蔬菜土壤磷积累状况及其对地表和地下水水质和土壤磷释放潜力的影响。结果表明,半透膜渗析法测得的磷释放量与土壤磷积累呈正相关,磷释放量随土壤磷饱和度的提高而增加。蔬菜地土壤磷饱和度的增加可显著提高地表水体和地下水中磷的浓度,当土壤磷饱和度小于25%左右时,水体中磷浓度随土壤磷饱和度增加较为缓慢;但当磷饱和度大于25%时,水体中磷浓度随土壤磷饱和度提高迅速上升。地表水中磷浓度主要与表层土壤磷饱和度有关;地下水中磷浓度主要受深层土壤磷饱和度的影响,与表层土壤磷饱和度的相关性较小。土壤磷饱和度可很好地表征土壤磷释放和对环境的潜在影响。     

大冶市农田土壤中镉的空间分布特征及污染评价

矿山开采和冶炼是造成土壤重金属Cd污染的主要原因,了解典型区域土壤中Cd的空间分布特征及其污染现状,可为区域土壤污染防治与安全利用提供重要信息。本研究针对湖北省大冶市所有农田采集92个表层土壤样品和3个土壤剖面,利用GIS方法对土壤重金属Cd空间分布特征及污染状况进行了研究。结果表明大冶市土壤中Cd的含量范围为0.6 ~ 4.6 mg/kg,平均值为1.41 mg/kg,Cd迁移深度可达 40 cm。区域内土壤Cd污染范围较广,空间变异较大,还地桥镇、罗桥街办、陈贵镇等地农田土壤Cd含量较高。地积累指数评价结果显示大冶市大部分农田土壤为轻度、中度污染程度,在合理调整种植结构等方式下仍可保障农田安全利用。     

Radioactive Contamination of Alluvial Soils in the Taiga Landscapes of Yakutia with <Superscript>137</Superscript>Cs, <Superscript>226</Superscript>Ra,and <Superscript>238</Superscript>U

The concentrations and distribution of ¹³⁷Cs in alluvial soils (Fluvisols) of the upper and middle reaches of the Markha River in the northwest of Yakutia and ²²⁶Ra and ²³⁸U in alluvial soils within the El’kon uranium ore deposit in the south of Yakutia have been studied. It is shown that the migration of radiocesium in the permafrost-affected soils of Yakutia owing to alluviation processes extends to more than 600 km from the source of the radioactive contamination. The migration of ¹³⁷Cs with water flows is accompanied by its deposition in the buried horizons of alluvial soils during extremely high floods caused by ice jams. In the technogenic landscapes of southern Yakutia, active water migration of ²³⁸U and ²²⁶Ra from radioactive dump rocks. The leaching of ²³⁸U with surface waters from the rocks is more intense than the leaching of ²²⁶Ra. The vertical distribution patterns of ²³⁸U and ²²⁶Ra in the profiles of alluvial soils are complex. Uranium tends to accumulate in the surface humus horizon and in the buried soil horizons, whereas radium does not display any definite regularities of its distribution in the soil profiles. At present, the migration of ²³⁸U and ²²⁶Ra with river water and their accumulation in the alluvial soils extend to about 30 km from the source.     

微咸水灌溉对斥水土壤水盐运移的影响

土壤斥水性影响着作物的产量,为了研究微咸水灌溉对斥水土壤水盐运移的影响,进行了室内土柱微咸水入渗试验。对比了不同矿化度和斥水程度对两种土质水盐运移的影响,探讨了微咸水入渗后土壤斥水性的变化特征。结果表明,不斥水土壤的入渗能力随矿化度的增加而增加。亲水和斥水土壤的入渗率均可采用Kostiakov公式简单模拟。斥水土壤入渗能力在矿化度为1?g/L时达到最大,超过1?g/L后则随矿化度的增大而减小。微咸水入渗的累积入渗量与湿润锋推进距离呈良好的线性关系,斥水性土壤中的相同剖面水盐的含量比不斥水的减小。微咸水入渗后土壤产生了一定的斥水性。该研究表明微咸水灌溉对盐渍化土壤的水盐分布和斥水性均有一定程度的影响。     

Soil selenium fractionation,depth profiles and time trends in a vegetated site at Kesterson Reservoir

Kesterson Reservoir, in the San Joaquin Valley of California, was used for disposal of saline, seleniferous agricultural drain waters during the years 1981 - 1986. The combined effects of infrequent drain water application, reduction and oxidation of Se, and evapotranspirative removal of soil water within the upper 1 m of the soil profiles appear to provide explanations for distribution patterns of Se in soils of upland sites. From 1987 to 1990, an approximate doubling in average soil solution Se concentrations was observed. It is shown that currently only relatively insignificant quantities of Se have been transported into the Pond 11 soils from the shallow water table. Sequential extraction of these upland soils indicated that substantial inventories of Se were associated with soluble, adsorbed, carbonate, and soil organic matter fractions, while Se retained within refractory inorganic fractions were minor. The mobilization of Se from these potentially labile pools may account for the observed increases in soil solution concentrations of Se following the draining of Kesterson Reservoir.     

Building upon the Conceptual Model for Soil Mercury Flux: Evidence of a Link Between Moisture Evaporation and Hg Evasion

Parameters known to influence mercury (Hg) release from soils include substrate and air Hg concentration, light, atmospheric oxidants, temperature, and soil moisture. However, for low Hg-containing soils, the influence of these parameters has been shown to vary across space and time. Here, we expand upon previous work by investigating whether soil–water evaporative loss, which integrates the influence of multiple parameters, could be applied for predicting Hg flux from soil with low Hg concentrations when bare and planted. To investigate our hypothesis, Hg flux was measured from three soil types (<100 ng Hg g^?1). When these soils were saturated, flux was suppressed. Soil moisture evaporative stage was used to partition the parameters most important for controlling Hg flux as the soils dried. Classification and regression tree (CART) analyses showed that soil moisture was the most important parameter predicting Hg flux. Results also showed an important predictor for Hg flux was whether actual evaporation (E _a) was equal to potential evaporation (E _p) or E _a < E _p. Depending on evaporative stage, the parameters with the next highest correlation to Hg flux were light, temperature, and soil moisture evaporation rate. The presence of vegetation also influenced flux with lower Hg flux when the plants were transpiring. Results indicate for those developing models that estimate Hg flux from low Hg-containing soils, soil moisture and evaporative stage are useful tools for predicting flux.