Cation exchange,hydrolysis and clay movement during the displacement of saline solutions from soils by water

Deterioration of soil physical conditions occurs when rain or irrigation water displaces soluble salts during reclamation and subsequent management of salinesodic soils. Damage, which depends primarily on the presence of exchangeable Na⁺, appears to be ameliorated during leaching by exchange of Ca²⁺ and Mg²⁺ for Na⁺ and loss of exchangeable Na⁺ by hydrolysis. The extent of these processes has been measured by leaching columns of repacked soil with water after preparation with Na⁺ and Ca²⁺ or Na⁺ and Mg²⁺ as the exchangeable cations and high or low (1 or 0.1 mol_cl^–1) initial salinities. Structural deterioration was monitored by changes in flow rate, and soil properties were measured both initially and after cutting the leached columns into layers. Preliminary studies established reliable methods for measuring exchangeable cations and cation exchange capacity in the saline soils. In a sandy loam (Na-Ca system), clay dispersion and movement occurred particularly in the upper layers as measured both by decreases in CEC and by the amount of clay in the leachate. Cation exchange and hydrolysis of exchangeable Na⁺ during leaching reduced the exchangeable Na⁺ percentage, although cation exchange was restricted to columns with high initial salinity. In a clay textured soil (Na-Ca system) there was negligible clay movement, and cation exchange and hydrolysis occurred in columns with both high and low initial salinities: cation exchange may have been encouraged by diffusion limited preferential release of Na⁺ from aggregates during by-pass flow. In the sandy loam (Na-Mg system) Mg²⁺ increased the preference of the soil for exchangeable Na⁺ compared to the Na-Ca system. There was no cation exchange even in columns with high initial salinity. The amounts of clay movement and hydrolysis were similar in the two systems. Conditions conductive to cation exchange are a high initial salinity, a Na-Ca rather than a Na-Mg system and, possibly, restricted release of the divalent cation from within soil aggregates. Attempts to model these changes are complicated by difficulties in predicting the effects of hydrolysis and by-pass flow.     

Trickle irrigation of cotton: Effect on soil chemical properties

The management of soil salinity and sodicity in the root zone (0–150 cm) of Panoche clay loam soil was studied during three consecutive growing seasons in a field experiment designed to determine the water requirement of Acala SJ-2 cotton (Gossypium hirsutum L.) under trickle irrigation in the western San Joaquin Valley of California. The trickle irrigation treatments (20, 40, 60, 80 and 100% of the previous day's pan evaporation, PE) were imposed on each of three preplant furrow irrigation depths of 0, 190 and 380 mm. The electrical conductivity, EC, of the irrigation water ranged from 0.4 to 0.5 dS m⁻¹ unless groundwater had to be mixed with the surface supply; this practice raised the EC to 0.6–0.9 dS m⁻¹ for short time periods. The unadjusted sodium adsorption ratio, SAR, of the irrigation water averaged < 4.Soil salinity, as measured by EC_e, was < 5 dS m⁻¹ and sodicity, as measured by SAR_e, was < 15 in the root zone. Changes in these soil chemical properties were more related to the amount of preplant irrigation at the lower (< 40% PE) trickle-irrigation levels than at the higher levels. Results suggest that soil salinity and sodicity can be maintained at acceptably low levels by appropriate preplant irrigation with consideration to amount of winter rainfall; even when during the season only sufficient trickle irrigation is given to meet crop water requirements without regards to leaching needs. The lint cotton yields over the 3-year period ranged from 357 to 1542 kg ha⁻¹; the corresponding applied water ranged from 175 to 744 mm.     

Effects of wastewater irrigation on soil sodicity and nutrient leaching in calcareous soils

Soil column studies were conducted with two soils to assess the effects of irrigation with wastewater on soil and groundwater quality. Upon the application of wastewater, exchange occurred between solution sodium (Na⁺) and exchangeable cations (Ca²⁺, Mg²⁺, K⁺), whereby these cations were released into solution. The average exchangeable sodium percentage (ESP) of the soils increased during leaching from 9 to 21 and 28.8 to 29.7 after applying 5.0 and 3.5 l (about 7 and 6 pore volumes) of wastewater to the soils columns, respectively. Adverse effect of high Na⁺ concentration in the wastewater on raising ESP was less pronounced in the soil having initial high ESP than in the soil with low initial ESP. Salinity of the soils was also increased with the application of wastewater and Mg²⁺ and K⁺ were leached from the soils. These losses would be more severe on soils having a low cation exchange capacity and if, uncorrected could lead eventually to their deficiencies for plant growth. When the soil columns were leached with distilled water the flow rate of one soil decreased to zero after 2.2 pore volume indicating damage to soil structure. Irrigation with wastewater, which is generally more sodic and saline than regional groundwater, increases the rate of soil sodification of shallow groundwater. A relatively simple chromatographic model was used to estimate final ESP profiles in the soils assuming the condition of local equilibrium. This approach had a limited success for one of the soil. Since the final leached concentrations are in good agreement with those of wastewater, we attribute these differences to non-uniform flow through the column. In terms of practical soil and water management, our study reveals that relatively simple means can be useful to predict the water quality in soils, their discharge to ground water, and the hazard of soil structure deterioration.     

Comparative effects of chemical amendments on salt and NA leaching

Summary Efficiency of sodic soil reclamation is thought to vary with types of chemicals used. This study examined the effects of five inorganic (H₂SO₄, CaCl₂ · 2H₂O, CaSO₄ · 2H₂O, FeSO₄, Al₂(SO₄)₃) and two organic compounds (polyacrylamide, and trihydroxy glutaric acid) on the rate and the extent of salt and Na leaching in moderately Na-affected saline soils: Saneli silty clay loam (Vertic Torrifluvents, ESP=17.5%) and Glendale silty clay (Typic Torrifluvents, ESP=13.5%). Air-dry soil samples (<2mm) were packed in columns, and chemicals, except H₂SO₄, were incorporated into the surface 5 cm of the soils, and in selected cases, to 30 cm. H₂SO₄ was surface-applied. Application rates of the inorganic chemicals were 3.57 and 10.7 mmol(+) kg^-1 (2.5 and 7.5 Mg ha^-1 in gypsum equivalent weight) in the silty clay loam, and 8 and 24 mmol(+) kg^-1 in the silty clay, and the organic compounds were applied at rates of less than 620 kg ha^-1. The soils were then leached with simulated Rio Grande water (EC = 1.1 dS m^-1, SAR = 3.5) under continuous ponding. The tested inorganic compounds removed approximately equivalent amounts of exchangeable Na after approximately 35 cm of water application. However, the rate of water percolation (consequently the rate of salt leaching) from CaCl₂ treated columns, became progressively slow after about 20 cm of water intake. The combined effect of rapid electrolyte leaching and insufficient replacement of Na in the surface layer seemed to be responsible for the flow reduction. Gypsum and H₂SO₄ treatments provided lower ratios of sodicity to salinity in percolating solutions and relatively uniform hydraulic gradients throughout the soil depth. Incorporation of chemicals to the surface 30 cm did not alter performance, except in CaCl₂ treatments where water intake rates became even slower. The tested organic amendments improved initial water infiltration, but neither increased subsequent percolation rates nor improved salt and Na leaching. The fastest reclamation may be attained when chemicals are chosen and applied to yield an electrolyte concentration that is high enough to overcome Na effects at any depth of soil profiles throughout the leaching period.Contribution from Texas Agr. Expt. Sta. Texas A & M University System. This project was supported in part by the Binational Agricultural Research and Development (BARD) Fund and the Expanded Research Area Fund of the Texas Agricultural Experiment Station.     

Long term responses of olive trees to salinity

Water demand for irrigation is increasing in olive orchards due to enhanced yields and profits. Because olive trees are considered moderately tolerant to salinity, irrigation water with salt concentrations that can be harmful for many of fruit tree crops is often used without considering the possible negative effects on olive tree growth and yield. We studied salt effects in mature olive trees in a long term field experiment (1998-2006). Eighteen-year-old olive trees (Olea europaea L.) cv. Picual were cultivated under drip irrigation with saline water composed of a mixture of NaCl and CaCl₂. Three irrigation regimes (i. no irrigation; ii. water application considering soil water reserves, short irrigation; iii. water application without considering soil water reserves and adding a 20% more as a leaching fraction, long irrigation) and three salt concentrations (0.5, 5 or 10 dS m⁻¹) were applied. Treatments were the result of the combination of three salt concentrations with two irrigation regimes, plus the non-irrigated treatment. Growth parameters, leaf and fruit nutrition, yield, oil content and fruit characteristics were annually studied. Annual leaf nutrient analyses indicate that all nutrients were within the adequate levels. After 8 years of treatment, salinity did not affect any growth measurement and leaf Na⁺ and Cl⁻ concentration were always below the toxicity threshold of 0.2 and 0.5%, respectively. Annual and accumulated yield, fruit size and pulp:stone ratio were also not affected by salts. However, oil content increased linearly with salinity, in most of the years studied. Soil salinity measurements showed that there was no accumulation of salts in the upper 30 cm of the soil (where most of the roots are present) because of leaching by rainfall at the end of the irrigation period. Results suggest that a proper management of saline water, supplying Ca²⁺ to the irrigation water, using drip irrigation until winter rest and seasonal rainfall typical of the Mediterranean climate leach the salts from the first 0-60 cm depth, and growing a tolerant cultivar, can allow using high saline irrigation water (up to 10 dS m⁻¹) for a long time without affecting growth and yield in olive trees.     

Twenty years of research on reclamation of salt-affected soils in Romanian rice fields

The physiological particularities of rice enable this plant to obtain its necessary oxygen for the roots through stems. This characteristic permits the use of rice during the reclamation of salt-affected soils with ponded flooding. This paper presents some results of twenty years of research in Romania, on the reclamation of saline and sodic soils under rice, including requirements for soil drainage, soil amendments, and salt leaching, at different stages of the reclamation period.Specific data are provided on the tolerance of rice to salinity, crop rotation in rice fields, fertilization, and irrigation practices.     

Optimizing the rate and timing of phosphogypsum application to magnesium-affected soils for crop yield and water productivity enhancement

The levels of magnesium (Mg²⁺) in irrigation waters and soils are increasing in several irrigation schemes worldwide. Excess levels of Mg²⁺ in irrigation waters and/or in soils negatively affect soil physical properties (infiltration rate and hydraulic conductivity) and ultimately crop growth and yield. Although few studies have been undertaken on productivity enhancement of magnesium-affected soils by adding a source of calcium (Ca²⁺) to mitigate the effects of excess Mg²⁺, there is no information available on optimizing the rate and time of the Ca²⁺-amendments. A 2-year field study was undertaken in southern Kazakhstan by applying phosphogypsum (PG), a source of Ca²⁺ and a byproduct of the phosphorous fertilizer industry, to a magnesium-affected soil. There were five treatments with four replications: (1) control (without PG application); (2) PG application in January (before snowfall) equivalent to PG requirement for 0.3 m soil depth (3.3 t ha⁻¹); (3) PG application in January equivalent to PG requirement for 0.6 m soil depth (8.0 t ha⁻¹); (4) PG application in April (after snowmelt) at 3.3 t ha⁻¹; and (5) PG application in April (after snowmelt) at 8.0 t ha⁻¹. All treatment plots were grown with cotton (Gossypium hirsutum L.), which is the most important summer crop in the region. The PG treatments performed significantly better than the control in terms of (1) improved soil quality with a reduction in exchangeable magnesium percentage (EMP) levels; (2) enhanced water movement into and through the soil vis-à-vis increased moisture storage in the root zone for use by the plant roots; (3) increased irrigation efficiency; (4) increased cotton yield and water productivity; and (5) greater financial benefits. In terms of the best rate and time of application, PG applied before the snowfall improved the soil properties to a greater extent than its application in spring after snowmelt. The economic benefits from the amendment application at 3.3 t ha⁻¹ were double those from the treatments where it was applied at 8.0 t ha⁻¹, suggesting that the lower rate was economically optimal. In addition to improving crop productivity, the study demonstrated the beneficial use of an industrial waste material in agriculture.     

The effect of organic manuring and water quality on water transmission parameters and sodication of a sandy loam soil

Water transmission characteristics under saturated and unsaturated conditions were studied in a sandy loam soil with (F₁) and without (F₀) long-term farmyard manure (FYM) treatments, in relation to sodium adsorption ratios (SAR) and electrolyte concentrations of water. The effect of FYM and ratios of Ca²⁺ : Mg²⁺ in water at a given SAR on sodication of the soil was also studied.Saturated hydraulic conductivity (k) and weighted mean diffusivity ($\text{D}\text{?}$) were slightly higher for F₁ than for F₀, whereas sodication indices like Gapon constant (K_G), Krishnamoorthy-Davis-Overstreet constant (K_KDO) and Vanselow constant (K_V) were slightly smaller. The k and $\text{D}\text{?}$ decreased with an increase of SAR and decrease of electrolyte concentration, the effect of SAR being more pronounced. There was proportionately a sharper decrease in the k and $\text{D}\text{?}$ values at SAR 10 with total electrolyte concentrations of 10–40 meq 1^?1. However, with a total electrolyte concentration of 80 meq 1^?1, there was a smaller drop at SAR 10.A small difference in the build-up of exchangeable sodium percentage (ESP) in F₁ and F₀ treatments at a given SAR suggests that, apart from slightly improving water transmission parameters, the use of FYM also reduces the sodication hazard in a soil irrigated with sodic waters. An increase in the Ca²⁺ : Mg²⁺ ratio from 25:75 to 75:25 slightly decreased the values of K_G, K_KDO and K_V, thus indicating somewhat more preference for Ca²⁺ to Mg²⁺ at a given SAR, which was more so in F₁ soil. This fact could also be expressed in terms of a slight shift of thermodynamic exchange constant (K) and standard free energy change of the exchange reaction (ΔG⁰_r). The presence of some unidentified Na⁺ releasing minerals in the soils studied was observed and correction for exchangeable Na⁺ determination applied.     

Soil solution and exchange complex response to repeated wetting–drying with modestly saline–sodic water

Coal bed natural gas (CBNG) extraction in the Powder River (PR) Basin of Wyoming and Montana produces modestly saline-sodic wastewater, which may have electrical conductivity (EC) and sodium adsorption ratios (SAR) exceeding accepted thresholds for irrigation (EC = 3 dS m⁻¹, SAR = 12 (mmol_c l⁻¹)^1/2. As an approach to managing large volumes of CBNG-produced water, treatment processes have been developed to adjust produced water salinity and sodicity to published irrigation guidelines and legislated in-stream standards. The objective of this laboratory study was to assess acute and chronic soil solution EC and SAR responses to various wetting regimes simulating repeated flood irrigation with treated CBNG product water, followed by single rainfall events. Fifty-four soil samples from irrigated fields in southeast Montana were subjected to simulated PR water or CBNG water treated to EC and SAR values accepted as thresholds for designation of saline × sodic water, in a single wetting event, five wetting–drying events, or five wetting–drying events, followed by leaching with distilled water. Resultant saturated paste extract EC (ECe) and SAR of soils having <33% clay did not differ from one another, but resulting ECe and SAR were all less than those for soil having >33% clay. Repeated wetting with PR water having EC of 1.56 dS m⁻¹ and SAR of 4.54 led to SAR <12, but brought ECe near 3 dS m⁻¹. Repeated wetting with water having salinity = 3.12 dS m⁻¹ and SAR = 13.09 led to ECe >3 dS m⁻¹ and SAR near 12. Subsequent inundation and drainage with distilled water, simulating rainfall-quality leaching, reduced ECe and SAR more often in coarse-textured, high salt content soils than in finer-textured, lower salt content soils. Decreases in ECe upon leaching with distilled water were of greater magnitude than corresponding decreases in SAR, reinforcing supposition of sodium-induced dispersion of fine-textured soils as a consequence of rainfall following irrigation with water having salinity and sodicity levels equal to previously published thresholds.     

Soil sodicity as a result of periodical drought

Soil sodicity development is a process that depends nonlinearly on both salt concentration and composition of soil water. In particular in hot climates, soil water composition is subject to temporal variation due to dry–wet cycles. To investigate the effect of such cycles on soil salinity and sodicity, a simple root zone model is developed that accounts for annual salt accumulation and leaching periods. Cation exchange is simplified to considering only Ca/Na exchange, using the Gapon exchange equation. The resulting salt and Ca/Na-balances are solved for a series of dry/wet cycles with a standard numerical approach. Due to the nonlinearities in the Gapon equation, the fluctuations of soil salinity that may be induced, e.g. by fluctuating soil water content, affect sodicity development. Even for the case that salinity is in a periodic steady state, where salt concentrations do not increase on the long term, sodicity may still grow as a function of time from year to year. For the longer term, sodicity, as quantified by Exchangeable Sodium Percentage (ESP), approaches a maximum value that depends on drought and inflowing water quality, but not on soil cation exchange capacity. Analytical approaches for the salinity and sodicity developing under such fluctuating regimes appear to be in good agreement with numerical approximations and are very useful for checking numerical results and anticipating changes in practical situations.     

Effects of fixed partial root-zone drying irrigation and soil texture on water and solute dynamics in calcareous soils and corn yield

Water dynamics and salt distribution in the soil were studied under Fixed Partial Root zone Drying irrigation (FPRD) conditions in corn fields in Northern Greece. FPRD irrigation technique was applied without deficit treatment in two calcareous soils, a sandy clay loam and a sandy loam. Soil water content was recorded in the vertical profile of 0.6 m with the use of capacitance sensors in the row and interrow positions of plants. Salt built-up was monitored to the depth of the root zone, bi-weekly, by measuring electrical conductivity (EC_e) and the concentrations of soluble cations Ca²⁺, Mg²⁺, Na⁺ and K⁺ of the saturation extract on irrigated and non irrigated interrow positions. Soil moisture distribution and salt built-up in soil were used to evaluate the potentials and constraints of FPRD efficiency to sustain plant growth and crop production as a low cost drip irrigation technique. The results indicated that FPRD application on both soils was capable of supplying sufficient amounts of water on plant row. Soil analyses showed that salts accumulated to high levels in the soil surface and decreased in depth at the non irrigated interrow positions. Spatial and temporal variability of salt movement and distribution in the soil profile of 0.6 m were ascribed to soil textural differences. The development and yield of corn plants for both soils reached the usual standards for the area with a minor decrease in the sandy loam soil.     

Drip irrigation water and salt flow model for table grapes in Coachella Valley,California

Unlike annual crops where reclamation leaching of salts can be readily conducted between cropping, leaching of salts in permanent crops that are drip irrigated pose challenges. A need exists to formulate and test a management-type of salinity model for drip irrigation of table grapes. The model reported herein predicts the distribution of salts along the vine row and between the rows during the growing season, as affected by reactivity of salts of the applied irrigation water as well as rate and duration of drip application. The calibrated model reproduced the initial field salinity profiles after repeated irrigation cycles by adjusting only the routing factor α which is the ratio of horizontal to vertical water flow. After eight cycles the profiles stabilized and the calibrated horizontal to vertical flow routing ratio was 0.6. There is remarkable agreement between measured and simulated salinity. Corresponding soil moisture profiles show the expected high water content with depth at the emitter, the decrease in surface water content with radial distance and the increase with depth, at the distal end of the wedge. Although the model is location specific it can be applied knowing soil, initial and boundary conditions, as well as irrigation application quantity and quality and as such can be applied location by location in order to assess flow and quality of deep percolation recharging the groundwater system. With this capacity the model can predict soil water quantity and quality outcomes for possible land and water management scenarios.     

Soil salinity in Aceh after the December 2004 Indian Ocean tsunami

The 2004 Indian Ocean tsunami inundated about 37,500 ha of coastal farmland in Aceh, and crops planted after the tsunami were severely affected by soil salinity. This paper describes the changes of soil salinity over time on tsunami affected farms and the implications for resuming crop production after natural disasters.Soil salinity and salt leaching processes were assessed across the tsunami affected region by measuring soil apparent electrical conductivity (ECa) using an electromagnetic induction soil conductivity instrument (EM38) combined with limited soil analysis. The ECa was measured 5 times between August 2005 and December 2007 in both the vertical (EMv) and horizontal (EMh) dipole orientations at 23 sites across Aceh. The level of salinity and direction of salt movement were assessed by comparing changes in mean profile ECa and relative changes in EMv and EMh.Eight months after the tsunami the average soil salinity in the 0-1.2 m soil depth varied from ECe 22.6 to 1.6 dS m⁻¹ across sites in the affected region and three years after the tsunami it varied from 13.0 to 1.4 dS m⁻¹. Soil salinity tended to be higher in rice paddy areas that trapped saline tsunami sediments and held seawater for longer periods. Leaching of salts occurred slowly by both vertical displacement and horizontal movement in surface waters. Hence, soil salinity persisted at a level which could reduce crop production for several years after the 2004 tsunami. High soil salinity persisted three years after the tsunami even though there had been more than 3000-7000 mm of accumulated rainfall to leach salts. The slow leaching is likely to have been due to the loss of functional drainage systems and general low relief of the affected areas.Monitoring of soil salinity with EM38 assisted local agricultural extension agencies to identify sites that were too saline for crops and determine when they were suitable for cropping again. The methodology used in this study could be used after similar disasters where coastal agriculture areas become inundated by seawater from storm surges or future tsunamis.     

Drainage and desalinization of heavy clay soil in Portugal

The Leziria Grande area consists mainly of poorly drained, saline clay soils of marine origin. Three experimental fields were laid out to find whether subsurface drainage can be effective in lowering the groundwater table and improving desalinization.Subsurface drainage results in a lower groundwater table than does surface drainage. With increasing spacing, the groundwater remains at a higher level for longer periods, which is expressed here by the sum of exceedances of the groundwater table above 30 cm during winter.Soil salinity, expressed as EC_1:2, and sodicity, expressed as E.S.P., decreased during the first 3 years, in which precipitation varied between 600 and 750 mm and the average drain outflow was about 250 mm. The leaching efficiency decreased with time, indicating that the removal of salt is a slow process in fine-textured soil.Application of gypsum lowered the E.S.P. The infiltration rate and the drain outflow increased. Although the total amount of salts in the drainwater was 40% higher than for the untreated plots, no lower EC_1:2 values were found. This is ascribed to spatial variability in soil salinity.     

Ameliorative effects of inoculation with the plant growth-promoting rhizobacterium Pseudomonas sp. DW1 on growth of eggplant (Solanum melongena L.) seedlings under salt stress

The objective of this work was to evaluate the effect of inoculation with the plant growth-promoting rhizobacterium Pseudomonas sp. DW1 on eggplant (Solanum melongena L.) growth, mineral uptake and activities of the antioxidant enzymes including superoxide dismutase (SOD), peroxidase (POD) and catalase (CAT) of plant leaves under salinity stress. The study was conducted in pot experiments using eggplant (S. melongena L., cv. Yinjia) and a coastal soil. The NaCl concentration of the coastal soil was 0.57 g (kg soil)⁻¹. Four NaCl levels were tested: 0.57, 1.0, 2.0, and 3.0 g NaCl (kg soil)⁻¹, by adding NaCl to soil, respectively. Pseudomonas-inoculated seeds had an increase in the germination percentage over its non-inoculated seeds under salinity. Salinity negatively affected growth of eggplant; however, plants inoculated with Pseudomonas sp. DW1 grew to a significantly greater extent than plants that were not treated with this bacterium. Salinity significantly decreased K⁺ concentration, increased Na⁺ concentration, and did not significantly decrease Ca²⁺ content in shoots of eggplants. Inoculating with Pseudomonas sp. DW1 increased shoot Ca²⁺ of eggplant compared to the non-inoculating eggplant plants under salinity. Inoculating treatments with Pseudomonas sp. DW1 had no effect on shoot Na⁺ concentration in 0.57 and 1 g (kg soil)⁻¹ NaCl, but there were significant decreases in inoculated treatments than in non-inoculated ones at 2 and 3 g (kg soil)⁻¹ NaCl. Salinity decreased SOD activities and increased POD activities, and inoculated Pseudomonas sp. DW1 had an increase effect on SOD activity in the leaves of eggplants. Alteration of mineral uptake and increase in the antioxidant enzyme activities may be two mechanisms for the alleviation of salt stress. Based on the results of the experiment reported herein, the use of the plant growth-promoting rhizobacterium treatment may provide a means of facilitating plant growth under salt stress.     

Net changes of main ions in the soil profile of irrigated field plots in central Spain

Implementation of improved irrigation schedules in some semiarid zones improve water efficiency and can be recommended where occasional periods of heavy rainfall may remove some of the accumulated salts. We hypothesized, however, that the leaching pattern of the main ions may differ regarding their potential contribution to the total salt discharge. The experiment was conducted near Madrid in Spain on a typical Xerofluvent soil with sandy-loam texture in the first 0.5 m. For 4 years, a traditional crop rotation of corn–wheat–corn–oat (Zea mays L.–Triticum aestivum L.–Zea mays L.–Avena sativa L.) was planted and two irrigation treatments (traditional and improved) were applied only to the corn. In an experimental set-up of 24 plots, samples of the soil solutions were extracted 61 times during the experiment at soil depths of 0.4, 0.9 and 1.4 m. During the experiment, drainage volume was estimated in plots under the two irrigation schedules. Main ions in the soil solution were SO₄²⁻, Cl⁻, Ca²⁺, Na⁺ and HCO₃⁻. These solutes accounted for 88% of total salt discharge under the two irrigation treatments. Two main patterns of salt leaching were observed. For most main ions, except HCO₃⁻, the input to discharge ratio was lower than one. Also for HCO₃⁻ , the irrigation treatment did not affect the leaching pattern (higher input than discharge under the two irrigation treatments). Improved irrigation schedules can be implemented without increasing the total salt load, but attention should be paid to specific leaching patterns of individual ions.     

Sodicity and salinity in a Brazilian Oxisol cultivated with sugarcane irrigated with wastewater

Changes in soil sodicity-salinity parameters are one of the most characteristic alterations after treated sewage effluent (TSE) irrigation in agro-systems. Considering the importance of these parameters for agricultural management, as well as the economical value of sugarcane for Brazil, the present study aimed at evaluating effects on soil sodicity and salinity under tropical conditions over 16 months of TSE irrigation in a sugarcane plantation at Lins, São Paulo State, Brazil. Soil samplings were carried out in February 2005 (before planting), December 2005 (after 8 months of TSE irrigation) and September 2006 (after 16 months of TSE irrigation) following a complete block design with four treatments and four replicates. Treatments consisted of: (i) control, without TSE irrigation; (ii) T100, T150 and T200, with TSE irrigation supplying 100% (0% surplus, total of 2524 mm), 150% (50% surplus, total of 3832 mm) and 200% (100% surplus, total of 5092 mm) of crop water demand, respectively. Compared to initial soil conditions, at the end of the experiment increases of exchangeable sodium (from 2.4 to 5.9 mmol_c kg⁻¹), exchangeable sodium percentage (ESP) (from 8 to 18%), soluble Na (from 1.4 to 4.7 mmol L⁻¹) and sodium adsorption ratio (SAR) of soil solution (from 3.6 to 12.6 (mmol L⁻¹)^0.5) were found in the soil profile (0-100 cm) as an average for the irrigated plots due to high SAR of TSE. Associated with the increments were mostly significant increases in clay dispersion rates at depths 0-10, 10-20 and 20-40 cm. Electrical conductivity (EC) of soil solution increased during the TSE irrigation period whereas at the end of the experiment, after short term discontinuation of irrigation and harvest, EC in the topsoil (0-10 and 10-20 cm) decreased compared to the previous samplings. Moreover, despite increasing sodicity over time mainly insignificant differences within the different irrigated treatments were found in December 2005 and September 2006. This suggests that independent of varying irrigation amounts the increasing soil sodicity over time were rather caused by the continuous use of TSE than by its quantity applied. Moreover, also plant productivity showed no significant differences within the TSE irrigated plots. The study indicates that monitoring as well as remediation of soil after TSE irrigation is required for a sustainable TSE use in order to maintain agricultural quality parameters.     

Salinity and sodicity influences on infiltration during surge flow irrigation

The interactive influences of water quality and surge-flow irrigation (intermittent application of water) on infiltration into a bare loam soil, packed into a long metal flume, were measured with a laboratory recirculating infiltrometer devised for the experiments. Cumulative infiltration and final infiltration rates were measured over three irrigation episodes using synthetic waters of different qualities. Four water-quality combinations of low and high salinity levels (i.e., electrical conductivity, EC=1.5 and 7.5 dS/m) and low and high degree of sodicity [i.e., sodium adsorption ratio in the range of 5-10 and 25-35 mmol^1/2 l^-1/2] were tested. Results showed that surge-flow cumulative infiltration of low saline waters - especially during the first irrigation episode - was lower than the corresponding continuous-flow cumulative infiltration. Conversely, it was higher for high saline and high saline-sodic waters. Effects of the water-quality treatments on final infiltration rate were similar to and in agreement with the effects on cumulative infiltration. However, the range of the final infiltration rates among surge-flow treatments was larger than with the continuous-flow treatments. Overall, infiltration was higher with surge-flow application of high saline and high saline-sodic waters than with the continuous-flow treatment. The observed contrasting results for the surge effect with the low saline, high saline, and high saline-sodic water-quality treatments were attributed to soil consolidation, formation of a depositional seal layer, and the different levels of irrigation water salinity and sodicity. It was concluded that the "surge effect" phenomena (reduction in soil infiltration caused by surge flow) under brackish (saline, sodic, and saline-sodic) water application was not pronounced and had adverse effects, in comparison to the low saline-sodic water application. Consequently, from theory, practical application of surge-flow irrigation under these circumstances, from viewpoints of infiltration reduction and irrigation efficiency improvements, is questionable.     

Modelling soil water and salt dynamics under pulsed and continuous surface drip irrigation of almond and implications of system design

The HYDRUS-2D model was experimentally verified for water and salinity distribution during the profile establishment stage (33?days) of almond under pulsed and continuous drip irrigation. The model simulated values of water content obtained at different lateral distances (0, 20, 40, 60, 100?cm) from a dripper at 10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 120, 140 and 160?cm soil depths at different times (5, 12, 19, 26 and 33?days of profile establishment) were compared with neutron probe measured values under both irrigation scenarios. The model closely predicted water content distribution at all distances, times and soil depths as RMSE values ranged between 0.017 and 0.049. The measured mean soil water salinity (ECsw) at 25?cm from the dripper at 30, 60, 90 and 150?cm soil depth also matched well with the predicted values. A correlation of 0.97 in pulsed and 0.98 in continuous drip systems with measured values indicated the model closely predicted total salts in the root zone. Thus, HYDRUS-2D successfully simulated the change in soil water content and soil water salinity in both the wetting pattern and in the flow domain. The initial mean ECsw below the dripper in pulsed (5.25?dSm^?1) and continuous (6.07?dSm^?1) irrigations decreased to 1.31 and 1.36?dSm^?1, respectively, showing a respective 75.1 and 77.6% decrease in the initial salinity. The power function [y?=?ax ^?b ] best described the mathematical relationship between salt removal from the soil profile as a function of irrigation time under both irrigation scenarios. Contrary to other studies, higher leaching fraction (6.4–43.1%) was recorded in pulsed than continuous (1.1–35.1%) irrigation with the same amount of applied water which was brought about by the variation in initial soil water content and time of irrigation application. It was pertinent to note that a small (0.012) increase in mean antecedent water content (θ _i ) brought about 8.25–9.06% increase in the leaching fraction during the profile establishment irrespective of the emitter geometry, discharge rate, and irrigation scenario. Under similar θ _i , water applied at a higher discharge rate (3.876?Lh^?1) has resulted in slightly higher leaching fraction than at a low discharge rate (1.91?Lh^?1) under pulsing only owing to the variation in time of irrigation application. The influence of pulsing on soil water content, salinity distribution, and drainage flux vanished completely when irrigation was applied daily on the basis of crop evapotranspiration (ETc) with a suitable leaching fraction. Therefore, antecedent soil water content and scheduling or duration of water application play a significant role in the design of drip irrigation systems for light textured soils. These factors are the major driving force to move water and solutes within the soil profile and may influence the off-site impacts such as drainage flux and pollution of the groundwater.     

Leaching irrigated saline sandy to sandy loam apedal soils with water of a constant salinity

With the optimization of irrigation, more salts accumulate in the root zone of soils, due to less over-irrigation. On-farm irrigation management requires a certain amount of leaching to ensure sustainability. The objective is to quantify the pore volume of water required to efficiently leach excess salts from two saline soils, widely irrigated in central South Africa. A total of 30 lysimeters, 15 per soil type arranged in two parallel rows under a moveable rain shelter, were used. Five different salinity profiles per soil type, replicated three times, were leached using irrigation water with a 75 mS m⁻¹ electrical conductivity. During irrigation the residual more saline pore water was displaced from the top downward through the root zone. The mean salinity of the soil profiles approached an equilibrium concentration equal to that of the irrigation water after 0.9 pore volume of soil was displaced by drainage water. For the sandy soil 0.2 and for the sandy loam soil 0.3 pore volumes were required to efficiently remove 70% of the excess salts. The remainder of the water was needed to leach the remaining 20% of the excess salts. This, however, was not efficient in terms of the amount of water required.