Real-time observation of molecular motion on a surface

The laser-induced movement of CO molecules over a platinum surface was followed in real time by means of ultrafast vibrational spectroscopy. Because the CO molecules bound on different surface sites exhibit different C-O stretch vibrational frequencies, the site-to-site hopping, triggered by excitation with a laser pulse, can be determined from subpicosecond changes in the vibrational spectra. The unexpectedly fast motion--characterized by a 500-femtosecond time constant--reveals that a rotational motion of the CO molecules, rather than pure translation, is required for this diffusion process. This conclusion is corroborated by density functional theory calculations.     

Real-time observation of adsorbate atom motion above a metal surface

The dynamics of cesium atom motion above the copper(111) surface following electronic excitation with light was studied with femtosecond (10(-15) seconds) time resolution. Unusual changes in the surface electronic structure within 160 femtoseconds after excitation, observed by time-resolved two-photon photoemission spectroscopy, are attributed to atomic motion in a copper-cesium bond-breaking process. Describing the change in energy of the cesium antibonding state with a simple classical model provides information on the mechanical forces acting on cesium atoms that are "turned on" by photoexcitation. Within 160 femtoseconds, the copper-cesium bond extends by 0.35 angstrom from its equilibrium value.     

Molecular layering of fluorinated ionic liquids at a charged sapphire (0001) surface

Room-temperature ionic liquids (RTILs) are promising candidates for a broad range of "green" applications, for which their interaction with solid surfaces plays a crucial role. In this high-energy x-ray reflectivity study, the temperature-dependent structures of three ionic liquids with the tris(pentafluoroethyl)trifluorophosphate anion in contact with a charged sapphire substrate were investigated with submolecular resolution. All three RTILs show strong interfacial layering, starting with a cation layer at the substrate and decaying exponentially into the bulk liquid. The observed decay length and layering period point to an interfacial ordering mechanism, akin to the charge inversion effect, which is suggested to originate from strong correlations between the unscreened ions. The observed layering is expected to be a generic feature of RTILs at charged interfaces.     

Splashing of drops on shallow liquids

The events that follow the splashing of a drop on a liquid depend on the depth of the liquid. When the depth is less than about 5 millimeters the crown that is ejected is more unstable than that from a splash on a deep liquid. As the depth is decreased from 25 to 7 millimeters, there is an increase in the maximum height to which the Rayleigh jet rises, and in the number of drops that break away from the jet. With depths less than 7 millimeters these two quantities fall off sharply, and no jet drops are produced for depths less than about 3 millimeters.     

微波光波组合无溶剂法促进光敏性偶氮人工受体的合成

由醇、酚或胺与中间体芳酰氯经微波光波组合干法合成了一系列新型光敏性偶氮类分子钳,其结构经1H NMR,IR,MS确证.考察了栽体、辐射时间、微波功率、催化剂对受体合成的影响.     

Spreading of liquids on highly curved surfaces

Because of surface tension, liquid films coating fibers or the insides of capillary tubes are usually unstable and break up into a periodic array of droplets. However, if these films are very thin (of thickness in the range of tens of angstroms), they can be stabilized by long-range van der Waals forces. A simple method for making such wetting films consists of slowly drawing the fiber out of a bath of liquid; the thickness of the film is then measured using a method based on gas chromatography. If these liquid films are thick, and are forced to flow, they may then not break up: the instability becomes "saturated."     

六种离子液体的合成研究

离子液体被认为是环境友好的“绿色”反应溶剂,引起了研究者将离子液体应用于食品工业和农业等领域的浓厚兴趣.根据离子液体种类不同,建立不同的合成方法,合成一系列离子液体,用核磁共振氢谱表征,并对合成方法进行研究,以满足离子液体大规模生产和应用的需要.     

Structure of a Langmuir film on a liquid metal surface

The structure of organic monolayers on liquid surfaces depends sensitively on the details of the molecular interactions. The structure of a stearic acid film on a mercury surface was measured as a function of coverage with angstrom resolution. Unlike monolayers on water, the molecules were found here to undergo a transition from surface-parallel to surface-normal orientation with increasing coverage. At high coverage, two condensed hexatic phases of standing-up molecules were found. At low coverage, a two-dimensional (2D) gas phase and condensed single- and double-layered phases of flat-lying molecular dimers were revealed, exhibiting a 1D longitudinal positional order. This system should provide a broader tunability range for nanostructure construction than solid-supported self-assembled monolayers.     

Ionization of liquids by radiation: measurement by a clearing field

A method has been developed for determining the yield of free ions formed by irradiation of a liquid with high-energy x-rays. Contrary to expectation, branched-chain paraffins produce many more free ions than straight-chain paraffins do, and the ether 1,4-dioxane produced only a third as many free ions as its hydrocarbon analog, cyclohexane.     

Linear alkane polymerization on a gold surface

In contrast to the many methods of selectively coupling olefins, few protocols catenate saturated hydrocarbons in a predictable manner. We report here the highly selective carbon-hydrogen (C-H) activation and subsequent dehydrogenative C-C coupling reaction of long-chain (>C(20)) linear alkanes on an anisotropic gold(110) surface, which undergoes an appropriate reconstruction by adsorption of the molecules and subsequent mild annealing, resulting in nanometer-sized channels (1.22 nanometers in width). Owing to the orientational constraint of the reactant molecules in these one-dimensional channels, the reaction takes place exclusively at specific sites (terminal CH(3) or penultimate CH(2) groups) in the chains at intermediate temperatures (420 to 470 kelvin) and selects for aliphatic over aromatic C-H activation.     

Electrochemical principles for active control of liquids on submillimeter scales

Electrochemical methods were combined with redox-active surfactants to actively control the motions and positions of aqueous and organic liquids on millimeter and smaller scales. Surfactant species generated at one electrode and consumed at another were used to manipulate the magnitude and direction of spatial gradients in surface tension and guide droplets of organic liquids through simple fluidic networks. Solid microparticles could be transported across unconfined surfaces. Electrochemical control of the position of surface-active species within aqueous films of liquid supported on homogeneous surfaces was used to direct these films into periodic arrays of droplets with deterministic shapes and sizes.     

Subsurface phenomena and the splashing of drops on shallow liquids

High-speed movies have been taken of the formation of the sub-surface cavity and of the Rayleigh jet formed during the splash of a drop on a shallow liquid. They show that the initial increase and subsequent decrease in the rate of rise of the jet and the maximum jet height with decreasing depth of liquid are the result of the interaction of the subsurface cavity with the solid boundary beneath the liquid. This interaction modifies considerably the pressure gradients in the liquid during the formation and collapse of the cavity.     

芳香族化合物在杯芳烃固定液上的保留机理研究

分离测得了不同结构芳香族化合物在杯芳冠醚聚硅氧烷（M－C[4]4C－5PSO）和杯芳烃四苄基醚聚硅氧烷（C[4]TBE-PSO）固定液上的热力学参数－溶解焓△H、溶解熵△S和自由能△G；研究探讨了杯芳烃上不同取代基的固定液结构对芳香族位置异构体保留行为的影响。     

Modeling the motion of particles of a pile on a screen under the action of conveyor slats

The effect of physical and mechanical properties of grain material and technological operating conditions of a slat conveyor for cleaning and fractionating grain material on its design parameters is determined.     

Motions and relaxations of confined liquids

When a liquid is confined in a narrow gap (as near a cell membrane, in a lubricated contact between solids, or in a porous medium), new dynamic behavior emerges. The effective shear viscosity is enhanced compared to the bulk, relaxation times are prolonged, and nonlinear responses set in at lower shear rates. These effects are more prominent, the thinner the liquid film. They appear to be the manifestation of collective motions. The flow of liquids under extreme confinement cannot be understood simply by intuitive extrapolation of bulk properties. Practical consequences are possible in areas from tribology and materials processing to membrane physics.     

Aftereffect of seen motion with a stabilized retinal image

Prolonged inspection of uniformly moving contours affects differentially the luminance threshold for the detection of test contours as a function of the direction of motion of the test contours. This finding supports a new explanation of the well-known aftereffect.