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不同处理竹材的表面性能分析
引用本文:于文吉,余养伦,江泽慧. 不同处理竹材的表面性能分析[J]. 北京林业大学学报, 2007, 29(1): 136-140
作者姓名:于文吉  余养伦  江泽慧
作者单位:中国林业科学研究院木材工业研究所;中国林业科学研究院木材工业研究所;中国林业科学研究院木材工业研究所
基金项目:国家高技术研究发展计划(863计划)
摘    要:为了揭示不同处理方法对竹材表面性能的影响规律,该文以毛竹为研究对象,采用ESCA和FTIR分析技术,对不同部位和不同处理条件竹材表面的碳氧比和C1s4种结合形式的分布情况,以及红外光谱的谱峰位置和相对吸收强度进行了分析.结果表明:不同部位和不同处理条件下竹材表面的碳氧比有很大差异;竹材表面主要以木素和各种抽提物为主;高温干燥导致竹材表面易挥发的抽提物分解,使部分纤维素和半纤维素的结构特征得以显露,而硼酸处理效果不明显;高温处理和硼酸处理后竹材表面的自由羟基减少,活性降低;竹黄表面的活性自由羟基的数量高于竹青表面. 

关 键 词:竹材  表面性能  ESCA分析  FFIR分析
文章编号:1000-1522(2007)01-0136-05
收稿时间:1900-01-01
修稿时间:2006-01-14

Surface chemical performance of bamboo wood treated by different methods
YU Wen-ji,YU Yang-lun,JIANG Ze-hui. Surface chemical performance of bamboo wood treated by different methods[J]. Journal of Beijing Forestry University, 2007, 29(1): 136-140
Authors:YU Wen-ji  YU Yang-lun  JIANG Ze-hui
Affiliation:Research Institute of Wood Industry , Chinese Academy of Forestry, Beijing, 100091, P. R. China
Abstract:To explore the effects of different treatments on the surface chemical performance,components of Phgllochys heterocyclavar.pubscensewere studied in this paper.The carbon to oxygen ratio(C/Oratio),distribution of C1sinfour combiningforms,andthe positionandrelative absorbingintensityof peaks of Fourier TransformationInfrared Spectroscopy(FTIR)were analyzed by Electron Spectroscopy for Chemical Analysis(ESCA)and FTIRunder various positions and processing conditions of the bamboo surface.Results showedthat:there were significant differences in the carbon to oxygen ratio(C/Oratio)among various positions and processingconditions;lignin and abstracts mainly made up the surface of bamboo;high temperature drying resulted in the decomposition of volatile abstracts in the surface,whichindicated some structure of cellulose and hemicellulose,while the effects of processing with boracic acid were not apparent;the bamboo processed in hightemperature and with boracic acid showed decreasedfree hydroxide and activity at the same time;theamount of active free hydroxide of inner layer was higher thanthat of the outer.
Keywords:bamboo wood  surface performance  ESCA analysis   FTIR analysis
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