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农药残留检测方法中关于基质效应补偿的相关阀题探讨
引用本文:黄宝勇,肖志勇,陈丹,颜小宁,赵玉乐,孙江.农药残留检测方法中关于基质效应补偿的相关阀题探讨[J].农药科学与管理,2010,31(3):39-43.
作者姓名:黄宝勇  肖志勇  陈丹  颜小宁  赵玉乐  孙江
作者单位:北京市农业环境监测站、农业部农业环境质检中心(北京),北京,100029
摘    要:农药残留检测过程中基质效应现象是影响定量准确度的关键因素之一,会对某些待测物的准确定量与定性造成影响,建立分析方法之前,必须要对待测物进行基质效应的评估。对农药残留分析中基质效应的涵义、表征、影响因素及补偿措施进行了总结,重点对基质匹配标准校正和分析物保护剂的应用等补偿与校正措施进行了阐述。

关 键 词:农药残留  基质效应  补偿  基质匹配校正  分析保护剂

Discussion on Compensation of Matrix Effects in Pesticide Residue analysis
Huang Baoyong,Xiao Zhiyong,Chen Dan,Yan Xiaoning,Zhao Yule,Sun Jiang.Discussion on Compensation of Matrix Effects in Pesticide Residue analysis[J].Pesticide Science and Administration,2010,31(3):39-43.
Authors:Huang Baoyong  Xiao Zhiyong  Chen Dan  Yan Xiaoning  Zhao Yule  Sun Jiang
Institution:Beijing Municipal Station of Agro-Environment Monitoring/a>;Center of Supervision and Test of Agro- Environmental quality/a>;MOA/a>;Beijing 100029/a>;China
Abstract:Matrix-induced-effect is one of main sources of uncertainty in multiresidue analytical methods,and would have some impact on quantification and identification of certain susceptive analytes.The influence of co-extractives from some used matrices to the analyte responses must be evaluated prior to development and validation of analytical method.Based on previous re- search,the progress of matrix -effect were summed up,including the meaning,expression,influence factors and compensation,with emphasis on the st...
Keywords:pesticide  residues  matrix effect  compensation  matrix-matched calibration  analyte protectants  
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