| 咪鲜胺·抑霉唑混配制剂的反相离子对液相色谱分析 |
| |
| 引用本文： | 姜军侠,雷琪,刘伟,宋喜峰,刘琪.咪鲜胺·抑霉唑混配制剂的反相离子对液相色谱分析[J].农药科学与管理,2005,26(2):8-11. |
| |
| 作者姓名： | 姜军侠 雷琪 刘伟 宋喜峰 刘琪 |
| |
| 作者单位： | 1. 陕西省农药管理检定所,陕西,西安,710003
2. 西北大学化学系,陕西,西安,710003 |
| |
| 摘 要： | 本文采用反相离子对色谱梯度洗脱外标法对咪鲜胺．抑霉唑乳油的2种有效成分进行一次性定量检测，采用C18色谱柱，以0．012mol／L庚烷磺酸钠(pH=2．5) 甲醇=30 70；20 80为流动相，流速1．5mL／min，二极管阵列检测器，检测波长：220nm。该方法中咪鲜胺和抑霉唑的标准偏差分别为0．065和0．024，变异系数分别为0．53％和1．13％．线性相关系数分别为0．9994和0．9995，平均回收率分别为99．4％、100．1％。
|
| 关 键 词： | 咪鲜胺 抑霉唑 反相离子对液相色谱 |
| 文章编号： | 1002-5480(2005)02-0008-04 |
| 修稿时间： | 2004年11月8日 |
Quantitative Analysis of Mixture of Prochloraz and Imazalil by Reversed Phase Ion Pair High Performance Liquid Chromatography |
| |
| Jiang Junxia,Lei Qi,Liu Wei,Song Xifeng.Quantitative Analysis of Mixture of Prochloraz and Imazalil by Reversed Phase Ion Pair High Performance Liquid Chromatography[J].Pesticide Science and Administration,2005,26(2):8-11. |
| |
| Authors: | Jiang Junxia Lei Qi Liu Wei Song Xifeng |
| |
| Abstract: | A reversed phase ion pair high performance liquid chromatography(RP-HPLC)methed with gradient elution and external standard was proposed for the simultaneous determination of prochloraz and imazalil in the mixture.A C18 column and a binary mobile phase of methanol and heptane sulfonic acid sodium were used with flow rate of 1.5mL/min.A photo diode array detector was used with 220nm.The results showed that the standard deviations were 0.024 and 0.065;the coefficient of variation were 1.13% and 0.53%;the linear correlations were 0.999 4 and 0.999 5;the average recoveries were 99.4% and 100.1% repectively. |
| |
| Keywords: | prochloraz imazalil RP-HPLC |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
