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Comparison of the volatile profiles of the crumb of gluten-free breads by DHE-GC/MS
Institution:1. I.U.Cinquima, Analytical Chemistry Department, University of Valladolid, Paseo Belén Street 5, E-47011, Valladolid, Spain;2. Department of Food Science, University of Copenhagen, Rolighedsvej 26, DK-1958FC, Copenhagen, Denmark;1. Dipartimento di Agraria, University of Naples Federico II, Via Università, 100, 80055 Portici, Naples, Italy;2. Istituto di Scienze dell''Alimentazione, ISA-CNR, Via Roma, 64, 83100 Avellino, Italy;3. Centre for Food Innovation and Development in the Food Industry, University of Naples Federico II, Via Università, 100, 80055 Portici, Naples, Italy;1. State Key Laboratory of Food Science and Technology, School of Food Science and Technology, National Engineering Research Center for Functional Food, Jiangnan University, 1800 Lihu Avenue, Wuxi, 214122, China;2. College of Food and Pharmaceutical Science, Ningbo University, Ningbo, 315832, China
Abstract:The aroma of gluten-free bread has been considered of lower quality than that of the common wheat bread. With the aim of improving the aroma of gluten-free bread, the volatile profiles of the crumb of gluten-free breads made from rice, teff, buckwheat, amaranth and quinoa flours as well as corn starch, respectively, were evaluated. Wheat bread was used as a reference and dynamic headspace extraction together with GC/MS was employed. It was found that the whole grain breads, made with teff, quinoa and amaranth flours, presented a stronger aroma with higher number of important aroma contributors. Rice bread was characterised by the highest levels in nonanal and 2,4-decadienal and corn starch bread by 2,3-pentanedione and 2-furaldehyde. Teff presented the highest abundance of ethyl hexanoate and ethyl nonanoate, but also of alcohols and aldehydes from lipid oxidation. Quinoa and amaranth were classified by the highest content in Strecker and Ehrlich aldehydes as well as 1-propanol, 2-methyl-1-propanol, 3-methyl-1-butanol or 3-hydroxy-2-butanone from fermentation. Corn starch bread was the closest to wheat bread in the PCA due to the highest content mainly in 2,3-butanedione and furfural as well as the lowest contents in 1-propanol, 1-hexanol and pentanal.
Keywords:Gluten-free bread crumb  Volatile compounds  Dynamic headspace extraction  Gas chromatography/mass spectrometry  DHE"}  {"#name":"keyword"  "$":{"id":"kwrd0035"}  "$$":[{"#name":"text"  "_":"(dynamic headspace)  (GC/MS)"}  {"#name":"keyword"  "$":{"id":"kwrd0045"}  "$$":[{"#name":"text"  "_":"gas chromatography-mass spectrometry  HPMC"}  {"#name":"keyword"  "$":{"id":"kwrd0055"}  "$$":[{"#name":"text"  "_":"(hydroxyl propyl methyl cellulose)  MSD"}  {"#name":"keyword"  "$":{"id":"kwrd0065"}  "$$":[{"#name":"text"  "_":"(mass spectrometric detector)  PCA"}  {"#name":"keyword"  "$":{"id":"kwrd0075"}  "$$":[{"#name":"text"  "_":"(principal component analysis)  OT"}  {"#name":"keyword"  "$":{"id":"kwrd0085"}  "$$":[{"#name":"text"  "_":"(odour thresholds)  PC1"}  {"#name":"keyword"  "$":{"id":"kwrd0095"}  "$$":[{"#name":"text"  "_":"(first principal component)  PC2"}  {"#name":"keyword"  "$":{"id":"kwrd0105"}  "$$":[{"#name":"text"  "_":"(second principal component)
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