Application of the amount of oxygen consumption to the investigation of the oxidation mechanism of lignin during oxygen-alkali treatment |
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Authors: | Aiko Imai Iori Tomoda Tomoya Yokoyama Yuji Matsumoto Gyosuke Meshitsuka Guolin Tong |
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Institution: | (1) Laboratory of Wood Chemistry, Department of Biomaterial Sciences, Graduate School of Agricultural and Life Sciences, the University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo 113-8657, Japan;(2) Department of Pulp and Paper Science, College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China |
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Abstract: | The dioxygen consumption by kraft lignin and several lignin model compounds during oxygen-alkali treatments were directly
analyzed using a dioxygen fl owmeter. The average dioxygen consumption by 200 g of kraft lignin was about 3 moles. Because
this value was as much as those obtained for monomeric phenolic lignin model compounds, guaiacol and vanillyl alcohol, it
was postulated that not only phenolic but also nonphenolic moieties in kraft lignin are extensively oxidized. The dioxygen
consumption by 0.5 moles (one equivalent of aromatic units) of a dimeric lignin model compound, guaiacylglycerol-β-guaiacyl
ether (GG), was also similar to that for 1 mole of guaiacol and vanillyl alcohol, regardless of the type of the aromatic moiety,
which supports the above postulation. The most plausible mechanism for the oxidation of nonphenolic moieties is the oxidation
of side chains of residual β-O-4 substructures by active oxygen species. By this mechanism, nonphenolic moieties in kraft lignin and GG are converted into
corresponding phenolic moieties, and the oxidation by dioxygen progresses.
Part of this article was presented at the 13th International Symposium on Wood, Fiber, and Pulping Chemistry (13th ISWFPC),
Auckland, New Zealand, May 2005 |
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Keywords: | Delignification Lignin Oxidation Oxygen bleaching Phenolic |
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