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茶油皂脚脂肪酸甲酯制备的水溶性改性胺固化物性能研究
引用本文:李梅,夏建陵,黄坤,连建伟.茶油皂脚脂肪酸甲酯制备的水溶性改性胺固化物性能研究[J].林产化学与工业,2011,31(4):53-57.
作者姓名:李梅  夏建陵  黄坤  连建伟
作者单位:1. 中国林业科学研究院林产化学工业研究所,生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室,江苏南京210042
2. 中国林业科学研究院林产化学工业研究所,生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室,江苏南京210042;中国林业科学研究院林业新技术研究所,北京100091
基金项目:“十一五”国家科技支撑计划资助(2009BADB1B10)
摘    要:以茶油皂脚脂肪酸甲酯制备的水溶性改性胺(CA-921)与水性环氧树脂固化,通过热重分析、差示扫描量热法(DSC)、机械性能测试及扫描电镜分析,研究了环氧树脂分散相粒子的粒径和黏度、环氧基与胺氢物质的量之比及固化温度对固化物性能的影响.研究结果表明,黏度及粒径均较小的水性环氧乳液AB-EP-20与固化剂CA-921复配所...

关 键 词:茶油皂脚脂肪酸甲酯  改性胺  水性固化剂  性能

Properties of the Cured Water-soluble Modified Amine from Fatty Acid Methyl Esters of Tea Oil Soapstock
LI Mei,XIA Jian-ling,HUANG Kun,LIAN Jian-wei.Properties of the Cured Water-soluble Modified Amine from Fatty Acid Methyl Esters of Tea Oil Soapstock[J].Chemistry & Industry of Forest Products,2011,31(4):53-57.
Authors:LI Mei  XIA Jian-ling  HUANG Kun  LIAN Jian-wei
Institution:LI Mei1,XIA Jian-ling1,2,HUANG Kun1,LIAN Jian-wei1 (1.Institute of Chemical Industry of Forestry Products,CAF,National Engineering Lab.for Biomass Chemical Utilization,Key and Open Lab.on Forest Chemical Engineering,SFA,Key Lab.of Biomass Energy and Material,Jiangsu Province,Nanjing 210042,China,2.Institute of New Technology of Forestry,Beijing 100091,China)
Abstract:The effects of the diameter and viscosity of epoxy resin dispersion,the molar ratio of epoxy group to amino hydrogen and the curing temperature on the properties of the cured water soluble modified amine from fatty acid methyl esters of tea oil soapstock were investigated by thermal gravimetric analysis(TGA),differential scanning calorimetry(DSC),mechanical pro-perty test and scanning electron microscopy(SEM).It was shown from the results that the thermal stability of the cured film from the water-soluble m...
Keywords:fatty acid methyl ester of tea oil soapstock  modified amine  water-soluble curing agent  property  
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