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草炭溶解态有机物质与Cu~(2+)、Cd~(2+)、Pb~(2+)、Zn~(2+)络合物的红外光谱
引用本文:蒋疆,王果,林志亮,陈晓婷.草炭溶解态有机物质与Cu~(2+)、Cd~(2+)、Pb~(2+)、Zn~(2+)络合物的红外光谱[J].福建农林大学学报(自然科学版),2002,31(2):266-269.
作者姓名:蒋疆  王果  林志亮  陈晓婷
作者单位:1. 福建农林大学生命科学学院
2. 福建农林大学资源与环境学院,福建,福州,350002
基金项目:国家自然科学基金,49671048,
摘    要:草炭有机质提取物胡敏酸、富里酸、水溶解态有机质的红外光谱研究显示 ,三者的含氧官能团组成相似 ,但基团含量差异较大 .胡敏酸、富里酸、水溶解态有机质与金属离子 (Cu2 +、Cd2 +、Pb2 +、Zn2 + )络合物的红外光谱表明 ,除 -COOH外 ,-OH、C=O、-NH2 等官能团也参与了对金属离子的络合 ,但不能很好地揭示哪种金属离子具有形成络合物的最大倾向

关 键 词:溶解态有机质  金属离子  络合物  红外光谱
文章编号:1006-7817(2002)02-0266-04
修稿时间:2001年8月1日

Infrared spectra of Cu2+, Cd2+, Pb2+ and Zn2+ complexes of dissolved-organic-matter of peat
JIANG Jiang ,WANG Guo ,LIN Zhi liang ,CHEN Xiao ting.Infrared spectra of Cu2+, Cd2+, Pb2+ and Zn2+ complexes of dissolved-organic-matter of peat[J].Journal of Fujian Agricultural and Forestry University,2002,31(2):266-269.
Authors:JIANG Jiang  WANG Guo  LIN Zhi liang  CHEN Xiao ting
Institution:JIANG Jiang 1,WANG Guo 2,LIN Zhi liang 2,CHEN Xiao ting 1
Abstract:The infrared spectra of humic acid (HA), fulvic acid(FA) and water soluble organic matter (WSOM) extracted from peat indicated that their oxygen containing functional groups were similar. But the contents of functional groups were obviously different. An infrared spectroscopic investigation of the complexes of four metal ions with HA, FA, WSOM demonstrated the participation of -OH, C=O and -NH 2 groups in addition to -COOH in binding of heavy metal cations. But which metal ion had the biggest complexing tendency with HA, FA or WSOM could not be clearly revealed by the IR method.
Keywords:dissolved  organic  matter  metal  ion  complex  infrared spectrum
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