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1-(1H-1,2,4-三唑基)-1-环(氧)烷基-取代苯甲醇的合成
引用本文:张耀谋,陈君,徐汉虹,金桂玉.1-(1H-1,2,4-三唑基)-1-环(氧)烷基-取代苯甲醇的合成[J].华南农业大学学报,2005,26(1):67-69.
作者姓名:张耀谋  陈君  徐汉虹  金桂玉
作者单位:1. 农药与化学生物学教育部重点实验室,华南农业大学,昆虫毒理研究室,广东,广州,510642
2. 南开大学,元素有机化学研究所,元素有机化学国家重点实验室,天津,300071
摘    要:用α-(1H-1,2,4-三唑-1-基)取代苯乙酮与二卤化物进行取代关环反应,合成了8个新型三唑类化合物,其化学结构经IR、^1H NMR、MS和元素分析确证,讨论了化合物的反应性质及波谱性质,化合物的生测数据表明,化合物对小麦锈病有良好抑制作用。

关 键 词:取代苯  1,2,4-三唑  烷基  苯乙酮  波谱性质  三唑类化合物  元素分析  苯甲醇  合成  小麦锈病
文章编号:1001-411X(2005)01-0067-03

Synthesis of 1- ( 1 H- 1,2,4-triazolyl) - 1- cycloalkyl- (sub) phenylmethanol
ZHANG Yao-mou,CHEN Jun,XU Han-hong,JIN Gui-yu Insect Toxicology,South China Agric. Univ.,Guangzhou,China.Synthesis of 1- ( 1 H- 1,2,4-triazolyl) - 1- cycloalkyl- (sub) phenylmethanol[J].Journal of South China Agricultural University,2005,26(1):67-69.
Authors:ZHANG Yao-mou  CHEN Jun  XU Han-hong  JIN Gui-yu Insect Toxicology  South China Agric Univ  Guangzhou  China
Institution:ZHANG Yao-mou~1,CHEN Jun~1,XU Han-hong~1,JIN Gui-yu~2 Insect Toxicology,South China Agric. Univ.,Guangzhou 510642,China, 2 Institute of Elemento-Organic Chemistry,China)
Abstract:Eight new 1-(1H-1,2,4-triazolyl)-1-Cycloalkyl-(Sub)phenylmathanol compounds were synthesized through the reaction of 1-(1H-1,2,4-triazolyl)-1-(sub)benzoyl-cycloalkane with KBH_4, which were identified by IR, ?~1?H NMR, MS and elemental analysis. The reactive properties and spectrum data were also discussed. Biological activity data indicated that some of the above compounds had good inhibitory action on Puccinia recondite in wheat.
Keywords:1  2  4-triazole  reduction  spectrum properties  fungicide
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