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2,5-二苯乙炔基噻吩的微胶囊化及其性能
引用本文:杨静美,王正辉,徐汉虹,王海清.2,5-二苯乙炔基噻吩的微胶囊化及其性能[J].华中农业大学学报,2010,29(1):41-44.
作者姓名:杨静美  王正辉  徐汉虹  王海清
作者单位:1. 华南农业大学天然农药与化学生物学教育部重点实验室,广州,510642
2. 华南农业大学理学院,广州,510642
基金项目:广东省重大科技成果转化项目(cgzhzd0712);;农药与化学生物学教育部重点实验室开放基金资助
摘    要:以异佛尔酮二异氰酸酯三聚体和二乙烯三胺为原料,通过界面聚合法,制备包含光活化化合物2,5-二苯乙炔基噻吩的聚脲微胶囊悬浮剂。用扫描电镜(SEM)和荧光显微镜(FOM)研究了微胶囊的表面形态和粒径大小,同时对微胶囊的初期包封率、释放特性、热失重行为、生物活性进行了研究。结果表明:微胶囊的表面形态近似球形,初期包封率均高于90%;与原药相比,微胶囊化后的2,5-二苯乙炔基噻吩对菜粉蝶幼虫仍有较好的活性,且持效期延长。

关 键 词:2  5-二苯乙炔基噻吩  微胶囊  界面聚合法  异佛尔酮二异氰酸酯三聚体  
收稿时间:3/3/2009 12:00:00 AM
修稿时间:2009/7/21 0:00:00

The Preparation and Properties of Microcapsule Containing 2,5-Diphenylethynylthiophene
YANG Jing-mei,WANG Zheng-hui,XU Han-hong and WANG Hai-qing.The Preparation and Properties of Microcapsule Containing 2,5-Diphenylethynylthiophene[J].Journal of Huazhong Agricultural University,2010,29(1):41-44.
Authors:YANG Jing-mei  WANG Zheng-hui  XU Han-hong and WANG Hai-qing
Institution:YANG Jing-mei1 WANG Zheng-hui2 XU Han-hong 1 WANG Hai-qing21.Key Laboratory of Pesticide , Chemical Biology of Ministry of Education,Guangzhou 510642,China,2.College of Science,South China Agricultural University
Abstract:Microcapsule suspensions containing photoactivatable compound 2,5-diphenylethynylthiophene were prepared by interfacial polymerization with trimer of isophorone diisocyanate and diethylenetriamine.The surface morphology and diameter of microcapsules were studied by scanning electron microscopy and fluorescence optical microscopy.The release characterization,preliminary microencapsulated efficiency,thermal stability and bioactivity of the microcapsules were investigated.The results showed that microcapsules ...
Keywords:2  5-diphenylethynylthiophene  microcapsule  interfacial polymerization  trimer of isophorone diisocyanate  
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