| Gouy法测定〔Cu（NH_3）_4〕SO_4和〔Co（NH_3）_6〕Cl_3的磁化率与配合物结构研究 |
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| 引用本文： | 谷名学,雷皇书,朱伟,叶云凯.Gouy法测定〔Cu（NH_3）_4〕SO_4和〔Co（NH_3）_6〕Cl_3的磁化率与配合物结构研究[J].西南农业大学学报,1995(4). |
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| 作者姓名： | 谷名学 雷皇书 朱伟 叶云凯 |
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| 作者单位： | 西南师范大学化学系，西南农业大学基科院 |
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| 摘 要： | 用古埃（Ｇｏｕｙ）磁天平法测定（Ｃｕ（ＮＨ_３）_４）ＳＯ_４和（Ｃｏ（ＮＨ_３）_６）Ｃｌ_３的磁化率。根据测定得的摩尔磁化率Ｘ_Ｍ，求出该配合物分子的磁矩Ｕ_ｍ和未成对电子数，并推断（Ｃｕ（ＮＨ_３）_４）ＳＯ_４和（Ｃｏ（ＮＨ_３）_６）Ｃｌ_３的共价结构。
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| 关 键 词： | 磁导率 ／电子结构 Gouy法 Cu（Ⅱ）、Co（Ⅲ）配合物 |
DETERMINATION OF SUSCEPTIBILITU AND COMPLEX STRUCTURE OF[Cu(NH_(34)]SO_4 AND(Co(NH_3))6]Cl_3 BY GOUY METHOD |
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| Gu Mingxue,Lei Huangsbu.DETERMINATION OF SUSCEPTIBILITU AND COMPLEX STRUCTURE OF[Cu(NH_(34)]SO_4 AND(Co(NH_3))6]Cl_3 BY GOUY METHOD[J].Journal of Southwest Agricultural University,1995(4). |
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| Authors: | Gu Mingxue Lei Huangsbu |
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| Abstract: | The paper reportedthe determination of the molecular susceptibility ofCu(NH_3))SO_4 and(Co(NH_3)_6)Cl_3 by Gouy magnetic-balance method.According to the measuredX_m,the magnetic moment(U_m ) and unpaired electron number have been calculated,andthen the covalent structure of(Cu(NH_3)_6)Cl_3 is deduced.The paper also pointed out that ithas the advantage of simple equipment,trusty data and good repeatability to use Gouy method for the study of magnetic susceptibility. |
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