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交联羧甲基魔芋葡甘聚糖吸附Cu~(2+)的机理
引用本文:王金玲,沈敏,瞿阳,薛爱芳,陈浩.交联羧甲基魔芋葡甘聚糖吸附Cu~(2+)的机理[J].湖北农业科学,2009,48(1).
作者姓名:王金玲  沈敏  瞿阳  薛爱芳  陈浩
作者单位:1. 华中农业大学,理学院,武汉430070
2. 华中农业大学,理学院,武汉430070;华中农业大学,食品科技学院,武汉430070
摘    要:研究了CCMKGM对Cu2+的吸附热力学行为,用FTIR和RAMAN对吸附产物进行了结构表征,同时考察了不同解吸剂对吸附于CCMKGM上Cu2+解吸效果的影响.结果表明,CCMKGM主要以配位的形式吸附Cu2+:CCMKGM对Cu2+的吸附行为同时符合Langmuir和Freundlich等温方程;吸附为自发的、吸热的熵增加过程.

关 键 词:交联羧甲基魔芋葡甘聚糖(CCMKGM)  吸附机理

Mechanism on Adsorption Cu~(2+) by Crosslinked Carboxymethyl Konjac Glucomannan
WANG Jin-ling,SHEN Min,QU Yang,XIE Ai-fang,CHEN Hao.Mechanism on Adsorption Cu~(2+) by Crosslinked Carboxymethyl Konjac Glucomannan[J].Hubei Agricultural Sciences,2009,48(1).
Authors:WANG Jin-ling  SHEN Min  QU Yang  XIE Ai-fang  CHEN Hao
Institution:a.Science College;b.Food Science and Technology College;Huazhong Agricultural University;Wuhan 430070;China
Abstract:In this paper the adsorption thermodynamics properties of CCMKGM with Cu2+ were investigated.The structure of adsorption products were characterized by the FTIR and RAMAN.The influence of different elution on desorption was stud-ied.The results showed that CCMKGM adsorbed Cu2+ mainly by complication,the experimental date fit well into the Lang-muir and Freundlich adsorption isotherm.The adsorption was a spontaneous endothermic process of increased entropy.
Keywords:Cu2
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